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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Geochemistry and origin of gold mineralization in the Kolar Schist Belt

Geological, mineralogical, mineral-textural and geochemical data of the sulfide lodes in the belt indicate that the gold mineralization could be related to low temperature, low Eh and high pH rock-dominated geothermal systems set up in the submarine volcanic pile prior to amphibolite metamorphism. A relatively long-lived geothermal system produced an economic deposit, whereas short-lived ones, because of rapid burial by younger basalts throttled the geothermal system and diffused the discharge yielding low grade ore bodies. The source for gold and iron could be iron enriched tholeiites derived from source regions enriched in komatiitic melt components and komatiitic rocks derived by very low extents of melting of metasomatised mantle sources. On the other hand, the geographical restriction of the quartz-calcite lodes, their mineralogical and geochemical data and their estimated temperature of formation all seem to suggest that a major part of the hydrothermal fluids, and a significant portion of gold could have been derived from mantle derived intrusive, sanukitoid type magma sources, similar to the Champion Gneiss occurring on the eastern part of the belt. However, the possibility of some input by remobilization of a premetamorphic sulfide protore to quartz lodes cannot be ruled out completely.

Siddaiah, N. Siva↗
NASA NTRS1989

Lithologic mapping of mafic intrusions in East Greenland using Landsat Thematic Mapper data

The East Greenland Tertiary Igneous Province contains a variety of intrusive and extrusive rock types. The Skaergaard complex is the most well known of the intrusive centers. Landsat thematic mapping (TM) was used in conjunction with field spectrometer data to map these mafic intrusions. These intrusions are of interest as possible precious metal ore deposits. They are spectrally distinct from the surrounding Precambrian gneisses. However, subpixel contamination by snow, oxide surface coatings, lichen cover and severe topography limit the discrimination of lithologic units within the gabbro. Imagery of the Skaergaard and surrounding vicinity, and image processing and enhancement techniques are presented. Student theses and other publications resulting from this work are also listed.

Naslund, H. Richard↗
NASA NTRS1988

The electrochemical generation of useful chemical species from lunar materials

A high temperature electrolytic cell which simultaneously generates oxygen at the anode and liquid alkali metals at the cathode is electrochemically characterized. The electrolytic technology being investigated utilizes the oxygen vacancy conducting solid electrolyte, yttria stabilized zirconia, which effectively separates the oxygen evolving (at La0.89Sr0.10MnO3) and alkali metal (Li, Na) reducing (from a molten salt at either Pt or FeSi2) half cell reactions. In the finally engineered cell liquid alkali metal would be continuously removed from the cathode compartment and used as an effective reductant for the direct thermochemical refining of lunar ores to their metallic state with simultaneous oxidation of the alkali metal to its oxide. The alkali metal oxide would then be reintroduced into the electrolytic cell to complete the overall system cycle.

Sammells, Anthony F.↗
NASA NTRS1990

Initial results of positron ionization mass spectrometry

The use of monoenergetic positrons for the ionization of organic molecules in the gas phase is described. The ionic products are analyzed with a time-of-flight mass spectrometer and detected to produce a mass spectrum. The ionization mechanisms which can be studied in this way include positron impact at energies above the ionization limit of the target molecules, positronium formation in the Ore gap energy range, and positron attachment at energies less than 1eV. The technique of positron ionization mass spectrometry (PIMS) may have analytical utility in that chemical selectivity is observed for one or more of these processes.

Donohue, D. L.↗
NASA NTRS1989

The electrochemical generation of useful chemical species from lunar materials

Electrochemical cells have been fabricated for the simultaneous generation of oxygen and lithium from a Li2O containing molten salt (Li2O-LiCl-LiF). The cell utilizes an oxygen vacancy conducting solid electrolyte, yttria-stabilized zirconia (YSZ), to effect separation between oxygen evolving and lithium reduction half-cell reactions. The cell, which operates at 700 to 850 C, possesses rapid electrode kinetics at the lithium-alloy electrode with exchange current density (i sub o) values being greater than 60mA sq cm. When used in the electrolytic mode, lithium produced at the negative electrode would be continuously removed from the cell for later use (under lunar conditions) as an easily storable reducing agent (compared to H2) for the chemical refining of lunar ores. Because of the high reversibility of this electrochemical system, it has also formed tha basis for the lithium oxygen secondary battery system which possesses the highest theoretical energy density yet investigated.

Tsai, Kan J.↗
NASA NTRS1989

Applications of Landsat Thematic Mapper and ground-based spectrometer data to a study of the Skaergaard and other mafic intrusions of East Greenland

Landsat TM data have been used in conjunction with field spectrometer data to map the lithologic units associated with a series of gabbroic intrusions in the East Greenland Tertiary Igneous Province. The general lack of vegetation combined with the difficulty of access to these intrusions make them ideal candidates for lithologic mapping using remote sensing techniques. In addition, these bodies are of interest as possible precious metal ore deposits. The intrusions are spectrally distinct from the surrounding Precambrian gneisses; however, subpixel contamination by snow, oxide surface coatings, and lichen cover and severe topography limit the discrimination of lithologic units within the gabbro. The spectral nature of the surface contaminants was evaluated with a Barringer Hand Held Ratioing Radiometer (HHRR). These HHRR data indicate that bare rock exposures have distinct TM signatures for each lithologic unit but that even small amounts of subpixel contamination are enough to mask these differences because of the large differences between the TM signatures of the rocks and the contaminants.

Birnie, Richard W.↗
NASA NTRS1989

Lead isotopes in trade wind aerosols at Barbados - The influence of European emissions over the North Atlantic

Previous studies have shown that Pb can be used as a transient tracer in the atmosphere and the ocean because of strong time-variability of industrial inputs and because Pb isotopic composition can be used to identify contributions from different sources. Pb isotopic measurements on aerosols collected from the North Atlantic Ocean in the trade wind belt are presented. Aerosols sampled at Barbados during the 1969-1985 period have a Pb isotopic composition different from that observed by previous investigators in Bermuda corals and Sargasso Sea waters. Barbados aerosols appear to contain significant amounts of relatively unradiogenic industrial and automotive Pb that is derived from Europe and carried to Barbados by the trade winds. In contrast, Bermuda corals and Sargasso sea waters are influenced mainly by U.S.-derived emissions, which contain more radiogenic Pb originating from Missouri-type ores. This difference generates a strong latitudinal Europe-U.S.A. isotopic gradient, thus allowing study of trans-Atlantic atmospheric transport and ocean mixing processes.

Hamelin, B.↗
NASA NTRS1989

Fractals in geology and geophysics

The definition of a fractal distribution is that the number of objects N with a characteristic size greater than r scales with the relation N of about r exp -D. The frequency-size distributions for islands, earthquakes, fragments, ore deposits, and oil fields often satisfy this relation. This application illustrates a fundamental aspect of fractal distributions, scale invariance. The requirement of an object to define a scale in photograhs of many geological features is one indication of the wide applicability of scale invariance to geological problems; scale invariance can lead to fractal clustering. Geophysical spectra can also be related to fractals; these are self-affine fractals rather than self-similar fractals. Examples include the earth's topography and geoid.

Turcotte, Donald L.↗
NASA NTRS1989

Re-Os, Rb-Sr, and O isotopic systematics of the Archean Kolar schist belt, Karnataka, India

The Re-Os, Rb-Sr, and O isotopic compositions of mafic and ultramafic amphibolites, gold ores, and granitic gneisses of the circa 2700 Ma Kolar schist belt are reported which reveal at least two episodes of postmagmatic alteration that affected these systems. The Re-Os isotopic systematics of many of the belt rocks indicate that Os was introduced to the area via fluids that carried very radiogenic Os, probably from ancient crust. The Rb-Sr systematics of most of these rocks indicate that the alteration event probably occurred no later than the early Proterozoic. Samples of several komatiitic amphibolites have very Os-187-depleted compositions, indicating that open-system behavior also occurred at a much later time than the late Archean or early Proterozoic. The results suggest that the Re-Os system may have only limited utility for geochronologic applications in regions for which postcrystallization noble metal mineralization is evident.

Walker, Richard J.↗
NASA NTRS1989

Products from lunar anorthite

Lunar anorthositic soil can be processed to produce oxygen, silicon, aluminum, and calcium. A process scheme starting with the beneficiation of the ore by magnetic separation and yielding the pure products is being developed. Simplifications in the process are possible if requirements regarding product purity and separation may be relaxed.

Anthony, Donald L.↗
NASA NTRS1990

The electrochemical generation of useful chemical species from lunar materials

Electrochemical cells have been fabricated for the simultaneous generation of oxygen and lithium from a Li2O-containing molten salt (Li2O-LiCl-LiF). The cell utilizes an oxygen vacancy conducting solid electrolyte, yttria-stabilized zirconia (YSZ), to effect separation between oxygen evolving and lithium reduction half-cell reactions. The cell, which operates at 700-850 C, possesses rapid electrode kinetics at the lithium-alloy electrode with exchange current density values being greater than 60 mA/sq cm. When used in the electrolytic mode, lithium produced at the negative electrode would be continuously removed from the cell for later use (under lunar conditions) as an easily storable reducing agent for the chemical refining of lunar ores. Because of the high reversibility of this electrochemical system, it has also formed the basis for the lithium-oxygen secondary battery system which possesses the highest theoretical energy density yet investigated.

Tsai, Kan J.↗
NASA NTRS1990

Kinetics of hydrogen release from lunar soil

With increasing interest in a lunar base, there is a need for extensive examination of possible lunar resources. Hydrogen will be needed on a lunar base for many activities including providing fuel, making water, and serving as a reducing agent in the extraction of oxygen from its ores. Previous studies have shown the solar wind has implanted hydrogen in the lunar regolith and that hydrogen is present not only in the outer layer of soil but to considerable depths, depending on the sampling site. If this hydrogen is to be mined and used on the lunar surface, a number of questions need to be answered. How much energy must be expended in order to release the hydrogen from the soil. What temperatures must be attained, and how long must the soil be heated. This study was undertaken to provide answers to practical questions such as these. Hydrogen was determined using a Pyrolysis/GC technique in which hydrogen was released by heating the soil sample contained in a quartz tube in a resistance wire furnace, followed by separation and quantitative determination using a gas chromatograph with a helium ionization detector. Heating times and temperatures were varied, and particle separates were studied in addition to bulk soils. The typical sample size was 10 mg of lunar soil. All of the soils used were mature soils with similar hydrogen abundances. Pre-treatments with air and steam were used in an effort to find a more efficient way of releasing hydrogen.

Bustin, Roberta↗
NASA NTRS1991

Experimental study of the electrolysis of silicate melts

To produce oxygen from lunar resources, it may be feasible to melt and electrolyze local silicate ores. This possibility was explored experimentally with synthesized melts of appropriate compositions. Platinum electrodes were employed at a melt temperature of 1425 C. When silicon components of the melt were reduced, the platinum cathode degraded rapidly, which prompted the substitution of a graphite cathode substrate. Discrete particles containing iron or titanium were found in the solidified electrolyte after three hours of electrolysis. Electrolyte conductivities did not decrease substantially, but the escape of gas bubbles, in some cases, appeared to be hindered by high viscosity of the melt.

Keller, R.↗
NASA NTRS1989

NASA Space Engineering Research Center for Utilization of Local Planetary Resources

Progress toward the goal of exploiting extraterrestrial resources for space missions is documented. Some areas of research included are as follows: Propellant and propulsion optimization; Automation of propellant processing with quantitative simulation; Ore reduction through chlorination and free radical production; Characterization of lunar ilmenite and its simulants; Carbothermal reduction of ilmenite with special reference to microgravity chemical reactor design; Gaseous carbonyl extraction and purification of ferrous metals; Overall energy management; and Information management for space processing.

Ramohalli, Kumar↗
NASA NTRS1990

Ilmenite beneficiation and high-precision analyses of extraterrestrial material

During the past year, work on characterizing lunar material that has the potential of becoming ilmenite lunar ore was performed. The important aspects of any such material are that it has abundant ilmenite and that the ilmenite be easily separated. The final result sought is a pure (greater than 99 percent ilmenite) concentrate that will be used as feed for the ilmenite reduction process. There are two types of starting material available on the moon. Solid rock (basalt or anorthosite) and regolith. Extensive literature reviews of ilmenite separation experiments were performed, and simulants (meteorites) were separated. It was concluded that, because of the large amounts of agglomerates, regolith may not be the best starting material for ilmenite beneficiation and that either basalts or anorthosites may be better. This is because no matter how finely the regolith is ground, it would not be possible to efficiently separate all the ilmenite. This hypotheses, however, needs to be tested with lunar material.

Ruiz, J.↗
NASA NTRS1990

Engineering, construction, and operations in space

The century-old Mond process for carbonyl extraction of metals from ore shows great promise as an efficient low energy scheme for producing high-purity Fe, Ni, Cr, Mn, and Co from lunar or asteroidal feedstocks. Scenarios for winning oxygen from the lunar regolith can be enhanced by carbonyl processing of the metallic alloy by-products of such operations. The native metal content of asteroidal regoliths is even more suitable to carbonyl processing. High-purity, corrosion resistant Fe and Ni can be extracted from asteroidial feedstocks along with a Co-rich residue containing 0.5 percent platinum-group metals. The resulting gaseous metal carbonyl can produce a variety of end products using efficient vapor forming techniques.

Johnson, Stewart W.↗
NASA NTRS1991

Mechanisms of ilmenite reduction and their impact on the design of effective reactor systems

One of the first activities at a lunar base could be oxygen recovery from ilmenite (FeTiO3). Oxygen produced from lunar soils could be used to fuel transportation vehicles operating in near-earth space. The first step in developing a suitable reactor system for lunar operation is to determine the mechanisms and rates of oxygen removal from ilmenite. In-situ gravimetric measurements and microscopic examinations were used to determine the hydrogen reduction mechanisms of synthetic ilmenite discs between 823 to 1353 K. A shrinking core reaction model, modified to account for the growth of an iron film on the surface of discs, was capable of predicting experimentally observed conversion-time relationships. The observed reduction mechanism, kinetic rates, and associated activation energy established a base line from which comparisons could be made to improve oxygen yield and removal rates. One proposed technique to improve the rate and extent of oxygen removal was to preoxidize ilmenite. Preoxidation is commonly used during the reduction of ilmenite ores in the iron industry and has been employed for many years to lower operating temperatures and increase reduction rates. This technology could prove beneficial for oxygen production facilities on the Moon as less massive reactor vessels and/or less energy could be associated with a process including preoxidation. X ray diffraction and energy dispersive spectroscopy were utilized to follow the progression of ilmenite oxidation at 1123 and 1140 K and the reduction of pseudobrookite (Fe2TiO5) at 873 and 973 K. Structures formed during the progress of oxidation were related to the system's phase diagrams. Results indicated that after initially producing ilmenite-hematite solutions and rutile (TiO2), pseudobrookite was the end product of oxidation at all temperatures examined (1049 to 1273 K). Initial results from the reduction of pseudobrookite indicate a series of phases are produced including ferropseudobrookite (FeTi2O5), ulvospinel (Fe2TiO4), and ilmenite. Rates of pseudobrookite reduction were typically 50 to 200 times that of ilmenite.

Briggs, R. A.↗
NASA NTRS1991

Mining and beneficiation: A review of possible lunar applications

Successful exploration of Mars and outer space may require base stations strategically located on the Moon. Such bases must develop a certain self-sufficiency, particularly in the critical life support materials, fuel components, and construction materials. Technology is reviewed for the first steps in lunar resource recovery-mining and beneficiation. The topic is covered in three main categories: site selection; mining; and beneficiation. It will also include (in less detail) in-situ processes. The text described mining technology ranging from simple diggings and hauling vehicles (the strawman) to more specialized technology including underground excavation methods. The section of beneficiation emphasizes dry separation techniques and methods of sorting the ore by particle size. In-situ processes, chemical and thermal, are identified to stimulate further thinking by future researchers.

Chamberlain, Peter G.↗