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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Theoretical Study of the First Transition Row Oxides and Sulfides

The first transition row oxides and sulfides are studied using several different levels of theory. The calculations show the bonding mechanism in the sulfides and oxides to be very similar. For the oxides, accurate experimental data allow the theoretical methods to be calibrated. The same level of theory is used to study the sulfides where there is far less experimental information. For ScO through MnO and CuO the coupled cluster singles and doubles technique including a perturbational estimate of the unliked triple excitations [CCSD(T)] yields spectroscopic constants ((tau)e, (omega)e, and D0) in good agreement with experiment. The triple excitations are found to be very important in achieving this accuracy. For FeO to NiO, the single determinant self-consistent-field (SCF) approach yields pi orbitals that are localized on the metal or oxygen. This appears to cause problems for the single reference techniques; this is discussed in detail for NiO. The complete-active-space SCF/internally contracted averaged coupled pair functional approach (CASSCF/ICACPF) works well for FeO to NiO. The calculation of accurate dipole moments is found to be very difficult.

Bauschlicher, Charles W., Jt.↗
NASA NTRS1993

Higher-Order Ionospheric Effects on the GPS Observables and Means of Modeling Them

Based on realistic modeling of the electron density of the ionosphere and using a dipole moment approximation for the earth magnetic field, we are able to estimate the effect of the ionosphere on the GPS signal for a ground user. Our study implies reduction of the second-order ionospheric error to less than 2 mm on the average and, therefore, potential improvement of orbit determination and baseline solutions.

ionosphere↗
NASA NTRS1998

Galileo Direction Finding of Jovian Radio Emissions

The Galileo spacecraft, in orbit about Jupiter, has observed distinct spin modulation of plasma wave emissions near the Ganymede (G1 and G2) encounters in the frequency range from about 100 kHz to approximately 6 MHz. Assuming circularly polarized, transverse electromagnetic radiation, we have used the spin modulation of the sweep-frequency receivers of the electric dipole antenna over many spins to estimate the source location in the spin plane of the spacecraft. Hectometric (HOM) and decametric (DAM) emission is observed by Galileo as a general and continuous background with frequent bursts that last tens of minutes and can be separated by minutes or hours. We have analyzed HOM and DAM emissions observed near Jupiter just after the GI and G2 encounters, including two HOM/DAM "arc" signatures observed after the G2 encounter. These latter appear to be low-frequency extensions of DAM arcs, with source regions along either the Io or the Ganymede flux tube. While the uncertainties associated with the data analysis do not allow a precise source location, the HOM/DAM emission observed near the G1 and G2 encounters is consistent with a gyroresonant source region, but it is necessary to require refraction due to the Io torus to understand the results. To explain emission from apparent source regions above a gyroresonant source region, wave refraction from asymmetries in the Io plasma torus that extend along magnetic field lines is postulated. Alternatively, if such torus density asymmetries do not exist, emission with sources above a gyroresonant source region would require another free-energy source such as energetic plasma beams in the presence of density gradients or temperature anisotropies.

Menietti, J. D.↗
NASA NTRS2001

The System and Implementation Aspects of the Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS)

MARSIS is a radar sounder operating in the HF frequency range to sound the surface of Mars, which will operate from the ESA Mars Express spacecraft. It is scheduled for launch from Baikonour, Russia in June 2003 and arrives in orbit around Mars in early 2004 for a two-year mission. This system is the result of an international collaboration between NASA, the Italian Space Agency (ASI), and European Space Agency (ESA). The MARSIS instrument is a 17 Kilogram total mass sounder consisting of a 40 meter tip-to-tip dipole antenna, a 7 meter long monopole antenna and the electronics module. This design of MARSIS is a tradeoff between the expected penetration into the Martian subsurface that is proportional to the wavelength of the system and the desire to operate at a short wavelength in order to minimize the effects of the ionosphere. Additional information is contained in the original extended abstract.

Jordan, R.↗
NASA NTRS1989

A priori predictions of the rotational constants for HC13N, HC15N, C5O

Ab initio molecular orbital theory is used to estimate the rotational constant for several carbon-chain molecules that are candidates for discovery in interstellar space. These estimated rotational constants can be used in laboratory or astronomical searches for the molecules. The rotational constant for HC13N is estimated to be 0.1073 +/- 0.0002 GHz and its dipole moment 5.4 D. The rotational constant for HC15N is estimated to be 0.0724 GHz, with a somewhat larger uncertainty. The rotational constant of C5O is estimated to be 1.360 +/- 2% GHz and its dipole moment 4.4. D.

NASA Discipline Exobiology↗
NASA NTRS1991

Early results from the Cosmic Background Explorer (COBE)

Data obtained with the FIR Absolute Spectrophotometer, Differential Microwave Radiometers, and Diffuse IR Background Experiment (DIRBE) on the COBE satellite since its launch in November 1989 are briefly characterized. The COBE spacecraft and its 900-km 99-deg orbit are described; the scientific goals and capabilities of the instruments are reviewed; and sample DIRBE data are presented in a map and graph. Upper limits on the Comptonization parameter (y less than 0.001) and the chemical potential (mu less than 0.01 at the 3sigma level) are determined, and the spectrum of the dipole anisotropy is shown to be that of a Doppler-shifted blackbody. The DIRBE 100-micron sky brightness values at the ecliptic poles are found to be significantly lower than those measured by IRAS.

Mather, J. C.↗
NASA NTRS1972

The light-ion trough, the main trough, and the plasmapause.

Although the plasmapause has been detected as a global phenomenon by both VLF and ion composition measurements, the electron and ion density troughs have been identified primarily as nightside features. This problem, as well as the difficulty in explaining various inconsistencies in relating the position of the plasmapause and the ionization trough, is explained by a close examination of the ion composition, generally unavailable in previous trough studies. In particular, ion composition results from the polar-orbiting Ogo satellites identify the persistence of a pronounced light-ion trough (LIT) in H(+) and He(+), often identified by order-of-magnitude decreases in the light-ion concentrations, that occurs within a few degrees of latitude and reaches residual concentration levels of 100 to 1000 ions/cu cm near 60 deg dipole latitude. The LIT, observed both within the thermosphere and at high latitudes in the magnetosphere, has been correlated directly with the VLF whistler identification of the plasmapause.

Taylor, H. A., Jr.↗
NASA NTRS2011

A Laboratory and Theoretical Study of Silicon Hydroxide SiOH

The rotational spectrum of the triatomic free radical SiOH in its X 2A' ground electronic state has been observed in a supersonic molecular beam by Fourier transform microwave spectroscopy. The fundamental (10,1 yields 00,0) transition has been detected for normal SiOH and for three rare isotopic species: (30)SiOH, Si(18)OH, and SiOD. The same transition has also been observed in two of three excited vibrational states, v2 and v3, for the most abundant species. Precise spectroscopic constants, including those that describe the effective spin doubling and hydrogen hyperfine structure, have been derived for each isotopic species or vibrational state. To complement the laboratory work, theoretical calculations of the structure, dipole moment, and energies of the X 2A' and low-lying 1 2A'' states have also been undertaken at the coupled cluster level of theory. In agreement with theoretical predictions, we conclude from the hyperfine constants that SiOH is a best described as a pi-type radical, with the unpaired electron localized on a p orbital on the silicon atom. Assuming a bond angle of 118.5 deg, the Si-O bond length is 1.647(2) Angstroms and the O-H bond length is 0.969(4) Angstrom.

McCarthy, M. C.↗
NASA NTRS1983

The Geopotential Research Mission - Mapping the near earth gravity and magnetic fields

The Geopotential Research Mission (GRM), NASA's low-level satellite system designed to measure the gravity and magnetic fields of the earth, and its objectives are described. The GRM will consist of two, Shuttle launched, satellite systems (300 km apart) that will operate simultaneously at a 160 km circular-polar orbit for six months. Current mission goals include mapping the global geoid to 10 cm, measuring gravity-field anomalies to 2 mgal with a spatial resolution of 100 km, detecting crustal magnetic anomalies of 100 km wavelength with 1 nT accuracy, measuring the vectors components to + or - 5 arc sec and 5 nT, and computing the main dipole or core field to 5 nT with a 2 nT/year secular variation detection. Resource analysis and exploration geology are additional applications considered.

Taylor, P. T.↗
NASA NTRS1989

VLF space transmitter

A practical operational system for communicating with submarines located at high latitudes, particularly those under the ice cap, is described. A 10-20-km dipole is deployed which utilized tether technology and which operated at 1-3 kHz. A pair of hollow-cathode-based plasma sources, establishing contact between the ends of the tether system and the ambient plasma, allows utilization of the natural dynamo effect of the tether. It is suggested that a 12-satellite constellation in quasi-polar orbit at 500-1000 km altitude could provide coverage for a 4 million sq km area at 75 percent duty cycle.

Olsen, R. C.↗
NASA NTRS1974

The motion of a proton in the equatorial magnetosphere

A proton of low energy moving in the equatorial plane of the earth will experience drift motions due to both the magnetic field (magnetic gradient drift only, if the field is assumed to be that of a dipole) and the electric field. The electric drift again separates into two parts - the drift due to the main electric field (or convection electric field) existing in the frame of the earth, and that due to the earth's rotation. One result indicated by this work is that at distances of 4 - 6 earth radii, a transition from trapped proton orbits to open trajectories leading to the tail occurs at about 10 kev, the precise value depending upon local time. Such a transition also seems to be indicated by particle observations using Explorer 45. The energy spectrum (at magnetically quiet times) of equatorial protons above this energy can be explained by charge exchange but increased flux observed below it seems to be related to the influx of particles on open orbits from the tail.

Stern, D. P.↗
NASA NTRS2012

Broadband Spectroscopy Using Two Suzaku Observations of the HMXB GX 301-2

We present the analysis of two Suzaku observations of GX 301-2 at two orbital phases after the periastron passage. Variations in the column density of the line-of-sight absorber are observed, consistent with accretion from a clumpy wind. In addition to a CRSF, multiple fluorescence emission lines were detected in both observations. The variations in the pulse profiles and the CRSF throughout the pulse phase have a signature of a magnetic dipole field. Using a simple dipole model we calculated the expected magnetic field values for different pulse phases and were able to extract a set of geometrical angles, loosely constraining the dipole geometry in the neutron star. From the variation of the CRSF width and energy, we found a geometrical solution for the dipole, making the inclination consistent with previously published values.

Suchy, Slawomir↗
NASA NTRS2000

Chandra X-Ray Observatory's Radiation Environment and the AP-8/AE-8 Model

The Chandra X-ray Observatory (CXO) was launched on July 23, 1999 and reached its final orbit on August 7, 1999. The CXO is in a highly elliptical orbit, approximately 140,000 km x 10,000 km, and has a period of roughly 63.5 hours (approx. 2.6 days). It transits the Earth's Van Allen belts once per orbit during which no science observations can be performed due to the high radiation environment. The Chandra X-ray Observatory Center (CXC) currently uses the National Space Science Data Center's "near Earth" AP-8/AE-8 radiation belt model to predict the start and end times of passage through the radiation belts. However, our scheduling software only uses a simple dipole model of the Earth's magnetic field. The resulting B, L magnet coordinates, do not always give sufficiently accurate predictions of the start and end times of transit of the Van Allen belts. We show this by comparing to the data from Chandra's on-board radiation monitor, the EPHIN (Electron, Proton, Helium Instrument particle detector) instrument. We present evidence that demonstrates this mis- of the radiation belts as well as data that also demonstrate the significant variability of one radiation belt transit to the next as experienced by the CXO. We present an explanation for why the dipole implementation of the AP-8/AE-8 gives inaccurate results. We are also investigating use of the Magnetospheric Specification and Forecast Model (MSM) - a model that also accounts for radiation belt variability and geometry.

Virani, S. N.↗
NASA NTRS1987

Technology for satellite power conversion

Components were examined that will be needed for high frequency rectenna devices. The majority of the effort was spent on measuring the directivity and efficiency of the half-wave dipole antenna. It is felt that the antenna and diode should be roughly optimized before they are combined into a rectenna structure. An integrated low pass filter had to be added to the antenna structure in order to facilitate the field pattern measurements. A calculation was also made of the power density of the Earth's radiant energy as seen by satellites in Earth orbit. Finally, the feasibility of using a Metal-Oxide-Metal (MOM) diode for rectification of the received power was assessed.

Gouker, M. A.↗
NASA NTRS1980

Limits on the possible intrinsic magnetic field of Venus

Magnetic field measurements obtained by the Pioneer Venus orbiter at low altitudes in the solar wind wake region are examined for possible surface-correlated features and any possible intrinsic magnetic moment. The field variations observed in the wake do not resemble those expected for a solar wind interaction with even a weak intrinsic magnetic field. Little orbit-to-orbit persistence of features is found in the magnetic records. The magnetic field measurements in the wake are averaged in 10 deg x 10 deg bins to minimize the effects of external field sources. In these 37 bins, the average fields appear to be randomly oriented and consistent with zero mean in the region mapped. Using these 37 averaged vector fields, a maximum intrinsic magnetic dipole moment is obtained of 4.3 + or - 2.0 x 10 to the 21st G cu cm, approximately an order of magnitude less than previous estimates. It is noted that a more conservative estimate of the probable error of the mean is 5.5 x 10 to the 21st G cu cm. The Pioneer Venus measurements are thus consistent with zero planetary moment. The present measurements are found to be far below estimates made on the basis of angular momentum, the so-called magnetic Bode's law, and far below the dynamo scaling law of Busse.

Russell, C. T.↗
NASA NTRS1989

The permanent electric dipole moment of chromium monoxide

The permanent electric dipole moments for the X 5Pi and B 5pi states of gas-phase CrO have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 + or - 0.13 and 4.1 + or - 1.8 D for the X and B states, respectively. The theoretical values determined for the X state using multireference CI iterative-natural-orbital and finite-field calculations are in excellent agreement with the experimental value.

Steimle, Timothy C.↗
NASA NTRS1972

Equatorial electron energy and number densities in the Jovian magnetosphere

A synchrotron model with a Maxwellian energy distribution of the form e to the (-E/E sub 0) power is used in a comparison with spatially resolved radio interferometric measurements of the Jovian emission. The observations of the decimeter radiation as a function of equatorial distance at 10.4 and 21 cm wavelength were reduced to source emission/cc of source electrons in each of 16 concentric rings. The peak energies for isotropically distributed electrons exceeded the maximum energy for flat orbiting electrons, and the peaks were generally located from 2.25 to 3 Jupiter radii. Beyond 3 radii, the order of magnitude on number density became a sensitive function of pitch angle distribution. The total equatorial intensities at 75 cm wavelength were computed for (E sub 0)(r) and n(r) at different values of B sub 0. The radiative half life for electrons of initial energy E sub 0 in a dipole field was calculated and found to be nearly constant at one year or less for altitudes at and below the position in peak energy.

Luthey, J. L.↗
NASA NTRS1976

Injection boundary dynamics during a geomagnetic storm

A series of proton and electron injections were observed by Explorer 45 associated with several substorms during the main phase of the Feb. 24, 1972 geomagnetic storm. The 1- to 290-keV protons and 1- to 560-keV electrons were observed in the evening quadrant up to L of about 5.2. A model distorted dipole magnetic field and McIlwain's E3 convection electric field were used to backtrack the energy-dispersed electron and proton fluxes to their source at the time of injection. The source turns out to be a region extending over several earth radii outside an injection boundary. In the night magnetosphere, the inferred injection boundary is displaced inward with each successive substorm. The energy dispersion plot of the particles injected during orbit 314 indicates that as the energy of the observed particles decreases there is a smooth transition to the position of the plasmapause. This suggests that for that substorm the injection boundary and the plasmapause were one and the same. The proton 'noses' reported by Smith and Hoffman (1974) are discussed.

Konradi, A.↗