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155 records · Page 9

Toxic Hazards Research Unit

The activities of the Toxic Hazards Research Unit (THRU) for the period of June 1970 through May 1971 reviewed. Modification of the animal exposure facilities primarily for improved human safety but also for experimental integrity and continuity are discussed. Acute toxicity experiments were conducted on hydrogen fluoride (HF), hydrogen chloride (HCl), nitrogen dioxide (NO2), and hydrogen cyanide (HCN) both singly and in combination with carbon dioxide (CO). Additional acute toxicity experiments were conducted on oxygen difluoride (OF2) and chlorine pentafluoride (ClF5). Subacute toxicity studies were conducted on methylisobutylketone and dichloromethane (methylene dichloride). The interim results of further chronic toxicity experiments on monomethylhydrazine (MMH) are also described.

Macewen, J. D.↗

Regeneratively cooled rocket engine for space storable propellants

Analysis, design, fabrication, and test efforts were performed for the existing OF2/B2H6 regeneratively cooled lK (4448 N) thrust chamber to illustrate simultaneous B2H6 fuel and OF2 oxidizer cooling and to provide results for a gaseous propellant condition injected into the combustion chamber. Data derived from performance, thermal and flow measurements confirmed predictions derived from previous test work and from concurrent analytical study. Development data derived from the experimental study were indicated to be sufficient to develop a preflight thrust chamber demonstrator prototype for future space mission objectives.

Wagner, W. R.↗

Pilot Plant Makes Oxygen Difluoride

Pilot plant makes oxygen difluoride highly-energetic, space-storable oxidizer not made commercially. Designed to handle reactants, product, and byproduct, most of which highly reactive, corrosive, and toxic. Oxygen difluoride evolves continuously from reactor containing potassium hydroxide in water at 10 degree C. Collection tanks alternated; one filled while other drained to storage cylinder. Excess OF2 and F2 dissipated in combustion of charcoal in burn barrel. Toxic byproduct, potassium fluoride, reacted with calcium hydroxide to form nontoxic calcium fluoride and to regenerate potassium hydroxide. Equipment processes toxic, difficult-to-make substance efficiently and safely.

Humphrey, Marshall F.↗

Theoretical performance of JP-4 fuel with a 70-30 mixture of fluorine and oxygen as a rocket propellant : equilibrium composition

Data were calculated for equivalence ratios of 1 to 4, chamber pressures of 300 and 600 pounds per square inch absolute, and pressure ratios of 1 to 1500. Parameters included are specific impulse, combustion and exit temperatures, molecular weight, characteristic velocity, coefficient of thrust, ratio of nozzle-exit area to throat area, specific heat at constant pressure, isentropic exponent, viscosity, and thermal conductivity. A correlation is given which permits determination of performance for a wide range of chamber pressures. A method for obtaining specific impulse of JP-4 fuel with OF2 and O3-F2 mixtures is given.

Gordon, Sanford↗

Polar Northern Hemisphere Middle Atmospheric Influence due to Energetic Particle Precipitation in January 2005

Solar eruptions and geomagnetic activity led to energetic particle precipitation in early 2005, primarily during the January 16-21 period. Production of OH and destruction of ozone have been documented due to the enhanced energetic solar proton flux in January 2005 [e.g., Verronen et al., Geophys. Res. Lett.,33,L24811,doi:10.1029/2006GL028115, 2006; Seppala et al., Geophys. Res. Lett.,33,L07804, doi:10.1029/2005GL025571,2006]. These solar protons as well as precipitating electrons also led to the production of NO(x) (NO, NO2). Our simulations with the Whole Atmosphere Community Climate Model (WACCM) show that NO(x) is enhanced by 20-50 ppbv in the polar Northern Hemisphere middle mesosphere (approx.60-70 km) by January 18. Both the SCISAT-1 Atmospheric Chemistry Experiment (ACE) NO(x) measurements and Envisat Michelson Interferometer for Passive Atmospheric Sounding (MIP AS) nighttime NO2 observations show large increases during this period, in reasonable agreement with WACCM predictions. Such enhancements are considerable for the mesosphere and led to simulated increases in polar Northern Hemisphere upper stratospheric odd nitrogen (NO(y)) of2-5 ppbv into February 2005. The largest ground level enhancement (GLE) of solar cycle 23 occurred on January 20, 2005 with a neutron monitor increase of about 270 percent [Gopalswamy et al., 29th International Cosmic Ray Conference, Pune,00,101-104,2005]. We found that protons of energies 300 to 20,000 MeV, not normally included in our computations, led to enhanced stratospheric NO(y) of less than 1 percent as a result of this GLE. The atmospheric impact of precipitating middle energy electrons (30-2,500 keV) during the January 16-21, 2005 period is also of interest, and an effort is ongoing to include these in WACCM computations. This presentation will show both short- and longer-term changes due to the January 2005 energetic particle precipitation.

Jackman, Charles H.↗

Cloud Condensation in Titan's Lower Stratosphere

A 1-D condensation model is developed for the purpose of reproducing ice clouds in Titan's lower stratosphere observed by the Composite Infrared Spectrometer (CIRS) onboard Cassini. Hydrogen cyanide (HCN), cyanoacetylene (HC3N), and ethane (C2H6) vapors are treated as chemically inert gas species that flow from an upper boundary at 500 km to a condensation sink near Titan's tropopause (-45 km). Gas vertical profiles are determined from eddy mixing and a downward flux at the upper boundary. The condensation sink is based upon diffusive growth of the cloud particles and is proportional to the degree of supersaturation in the cloud formation regIOn. Observations of the vapor phase abundances above the condensation levels and the locations and properties of the ice clouds provide constraints on the free parameters in the model. Vapor phase abundances are determined from CIRS mid-IR observations, whereas cloud particle sizes, altitudes, and latitudinal distributions are derived from analyses of CIRS far-IR observations of Titan. Specific cloud constraints include: I) mean particle radii of2-3 J.lm inferred from the V6 506 cm- band of HC3N, 2) latitudinal abundance distributions of condensed nitriles, inferred from a composite emission feature that peaks at 160/cm , and 3) a possible hydrocarbon cloud layer at high latitudes, located near an altitude of 60 km, which peaks between 60 and 80 cm l . Nitrile abundances appear to diminish substantially at high northern latitudes over the time period 2005 to 2010 (northern mid winter to early spring). Use of multiple gas species provides a consistency check on the eddy mixing coefficient profile. The flux at the upper boundary is the net column chemical production from the upper atmosphere and provides a constraint on chemical pathways leading to the production of these compounds. Comparison of the differing lifetimes, vapor phase transport, vapor phase loss rate, and particle sedimentation, sheds light on temporal stability of the clouds.

Romani, Paul N.↗

Observations of the Lunar Impact Plume from the LCROSS Event

We observed emission from sodium (Na) ejected from the Lunar Crater Observing and Sensing Satellite (LCROSS) impact into Cabeus Crater on October 9, 2009, using the McMath-Pierce telescope. In our 88 sq km field of view, we saw on the order of2 g of Na in the first 9 minutes after the LCROSS impact. A comparison of our observed Na above the limb with simulations that assume a gas temperature of 1000 K indicates that 0.5-2.6 (1.5 +/- 1) kg of Na were released during the LCROSS impact. Lower temperatures would result in a lower total sodium release. The model of an isotropic expanding cloud best reproduces the observations.

Killen, R. M.↗

Lightning NOx Production and Its Consequences for Tropospheric Chemistry

Cloud-resolving case-study simulations of convective transport and lightning NO production have yielded results which are directly applicable to the design of lightning parameterizations for global chemical transport models. In this work we have used cloud-resolving models (the Goddard Cumulus Ensemble Model (GCE) and MMS) to drive an off-line cloud-scale chemical transport model (CSCTM). The CSCTM, in conjunction with aircraft measurements of NO x in thunderstorms and ground-l;>ased lightning observations, has been used to constrain the amount of NO produced per flash. Cloud and chemistry simulations for several case studies of storms in different environments will be presented. Observed lightning flash rates have been incorporated into the CSCTM, and several scenarios of NO production per intracloud (IC) and per cloud-to-ground (CG) flash have been tested for each storm. The resulting NOx mixing ratios are compared with aircraft measurements taken within the storm (typically the anvil region) to determine the most likely NO production scenario. The range of values of NO production per flash (or per meter of lightning channel length) that have been deduced from the model will be shown and compared with values of production in the literature that have been deduced from observed NO spikes and from anvil flux calculations. Results show that on a per flash basis, IC flashes are nearly as productive of NO as CG flashes. This result simplifies the lightning parameterization for global models (ie., an algorithm for estimating the IC/CG ratio is not necessary). Vertical profiles of lightning NOx mass at the end of the 3-D storm simulations have been summarized to yield suggested profiles for use in global models. Estimates of mean NO production per flash vary by a factor of three from one simulated storm to another. When combined with the global flash rate of 44 flashes per second from NASA's Optical Transient Detector (OTD) measurements, these estimates and the results from other techniques yield global NO production rates of2-9 TgN/year. Simulations of the photochemistry over the 24 hours following a storm has been performed to determine the additional ozone production which can be attributed to lightning NO. Convective transport of HOx precursors leads to the generation of a HOx plume which substantially aids the downstream ozone production.

Pickering, Kenneth E.↗

Using a Cold Radiometer to Measure Heat Loads and Survey Heat Leaks

We have developed an inexpensive cold radiometer for use in thermal/vacuum chambers to measure heat loads, characterize emissivity and specularity of surfaces and to survey areas to evaluate stray heat loads. We report here the results of two such tests for the James Webb Space Telescope to measure heat loads and effective emissivities of2 major pieces of optical ground support equipment that will be used in upcoming thermal vacuum testing of the Telescope.

DiPirro, M.↗

A Black Hole X-ray Binary at ~100 Hz: Multiwavelength Timing of MAXI J1820+070 with HiPERCAM and NICER

We report on simultaneous sub-second optical and X-ray timing observations of the low-mass X-ray binary black hole candidate MAXI J1820+070. The bright 2018 outburst rise allowed simultaneous photometry in five optical bands (ugrizs) with HiPERCAM/GTC (Optical) atf rame rates over 100 Hz, together with NICER/ISS observations (X-rays). Intense (factor of2) red flaring activity in the optical is seen over a broad range of time-scales down to∼10 ms. Cross-correlating the bands reveals a prominent anticorrelation on time-scales of ∼seconds, and a narrow sub-second correlation at a lag of≈+165 ms (optical lagging X-rays). This lag increases with optical wavelength, and is approximately constant over Fourier frequencies of∼0.3–10 Hz. These features are consistent with an origin in the inner accretion flow and jet base within∼5000 Gravitational radii. An additional∼+5 s lag feature may be ascribable to disc reprocessing. MAXI J1820+070 is the third black hole transient to display a clear∼0.1 s optical lag, which may be common feature in such objects. The sub-second lag variation with wavelength is novel, and may allow constraints on internal shock jet stratification models.

J A Paice↗