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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Clear evidence for the presence of O VI absorption in QSO metal systems

We have detected O VI 1031.93 A, 1037.62 A doublet absorption in a composite QSO spectrum formed from a large number of intervening C IV absorption systems. The detections constitute the first firm evidence for the presence of O VI in intervening QSO metal absorption systems. The equivalent width of the detected O VI absorption implies an O VI column density N(O VI) not less than 2.8 x 10 exp 14/sq cm. This value, together with the nondetection of the N V 1238.82 A, 1242.80 A doublet absorption, suggests that N(O VI)/N(N V) not less than 4.4. For collisionally ionized gas with a solar O to N abundance ratio in thermal equilibrium the above ratio requires a temperature T not less than 2.5 x 10 exp 5 K. It is found that C IV systems which show low-ionization species and those which do not both have associated O VI absorption, suggesting that O VI is probably present in all C IV systems. We also find that C IV systems which show low-ionization species on average have stronger high-ionization absorption lines than those which do not. A simple interpretation was given to explain this trend.

Lu, Limin↗
NASA NTRS1994

The effect of wave-particle interactions on the polar winds O(+)

The escape of the polar wind plasma is an important element in the ionosphere-magnetosphere coupling. Both theory and observations indicate that the wave-particle interactions (WPI) play a significant role in the dynamics of ion outflow along open geomagnetic field lines. A Monte Carlo simulation was developed in order to include the effect of the WPI in addition to the factors that are traditionally included in the 'classical' polar wind (i.e. gravity, electrostatic field, and divergence of geomagnetic field lines). The ion distribution function (f(sub j)), as well as the profiles of its moments (density, drift velocity, temperature, etc.) were found for different levels of WPI, that is, for different values of the normalized diffusion rate in the velocity space (D(tilde) (sub j perpendicular). Although the model included O(=), H(+) and eletrons, we presented only the results related to the O(+) ion. We found that (1) both the density and drift velocity of O(+) increased with the WPI strength, and consequently, the O(+) escape flux was enhanced by a factor of up to 10(exp 5), (2) The O(+) ions could be energized up to a few electron volts; (3) for moderate and high levels of WPI D(tilde) (sub perpendicular) (O(+) greater than (tilde) 1, the distribution function f(O(+)) displayed very pronounced conic features at altitudes around 3 R(sub e). Finally, the interplay between the downward body force, the upward mirror force, and the perpendicular heating resulted in the formation of the 'pressure cooker' effect. This phenomena explained some interesting features of our solution, such as, the peak in the O(=) temperature, and the formation of 'ears' and conics for f(O(+)) around 2.5 R(sub e).

Barakat, A. R.↗
NASA NTRS2006

Evidence in CO3.0 Chondrules for a drift in the O Isotopic Composition of the Solar Nebula

Several recent studies have shown that materials such as magnetite that formed in asteroids tend to have higher Delta O-17 (=delta O-17 -0.52 delta O-18) values than those recorded in unaltered chondrules. Other recent studies have shown that, in sets of chondrules from carbonaceous chondrites, Delta O-17 tends to increase as the FeO contents of the silicates increase. We report a comparison of the O isotopic composition of olivine phenocrysts in low-FeO ( Fal5) type II porphyritic chondrules in the highly primitive C03.0 chondrite Yamato-81020. In agreement with a similar study of chondrules in C03.0 ALH A77307 by Jones et al., Delta O-17 tends to increase with increasing FeO. We find that Delta O-17 values are resolved (but only marginally) between the two sets of olivine phenocrysts. In two of the high-FeO chondrules, the difference between Delta O-17 of the late-formed, high-FeO phenocryst olivine and those in the low-FeO cores of relict grains is well-resolved (although one of the relicts is interpreted to be a partly melted amoeboid olivine inclusion by Yurimoto and Wasson). It appears that, during much of the chondrule-forming period, there was a small upward drift in the Delta O-17 of nebular solids and that relict cores preserve the record of a different (and earlier) nebular environment.

Wasson, John T.↗
NASA NTRS2011

A Contemporary Analysis of the O'Neill-Glaser Model for Space-Based Solar Power and Habitat Construction

In 1975 Gerard O Neill published in the journal Science a model for the construction of solar power satellites. He found that the solar power satellites suggested by Peter Glaser would be too massive to launch economically from Earth, but could be financially viable if the workforce was permanently located in free space habitats and if lunar and asteroid materials were used for construction. All new worldwide electrical generating capacity could be then achieved by solar power satellites. The project would financially break even in about 20 years after which it would generate substantial income selling power below fossil fuel prices. Two NASA / Stanford University led studies at Ames Research center during the summers of 1974 and 1976 found the concept technically sound and developed a detailed financial parametric model. Although the project was not undertaken when suggested in the 1970s, several contemporary issues make pursuing the O Neill -- Glaser concept more compelling today. First, our analysis suggests that if in the first ten years of construction that small habitats (compared to the large vista habitats envisioned by O Neill) supporting approximately 300 people were utilized, development costs of the program and the time for financial break even could be substantially improved. Second, the contemporary consensus is developing that carbon free energy is required to mitigate global climate change. It is estimated that 300 GW of new carbon free energy would be necessary per year to stabilize global atmospheric carbon. This is about 4 times greater energy demand than was considered by the O Neill Glaser model. Our analysis suggests that after the initial investments in lunar mining and space manufacturing and transportation, that the profit margin for producing space solar power is very high (even when selling power below fossil fuel prices). We have investigated the financial scaling of ground launched versus space derived space solar power satellites. We find that for the carbon mitigation case even modernized ground launched space solar power satellites are not financially viable. For space derived solar power satellites, however, the increased demand makes them break even substantially sooner and yield much higher profit. Third, current awareness is increasing about the dangers of humanity remaining a single planet species. Our technological power has been increasing relative to the size of the planet Earth. Since the middle of the 20th century our technological power has grown large relative to our planet's size. This presents a very real potential for human self-extinction. We argue that the potential for human self-extinction is increasing with time in proportion to the exponential growth of our technological power making self-extinction likely within this century if humanity remains a single planet species. The O Neill model of multiple independent free space habitats, it is argued, can protect humanity from extinction in the same way that portfolio diversification protects ones assets from total loss. We show that about 1 million people for the electricity only case, and about 1 billion people for the carbon mitigation case, can be provided with permanent space habitats and transportation from Earth in 30 years and can be funded by the space derived solar power satellite program. 1.2 Scope of this Chapter The goal of this chapter is to illustrate the power and importance of the O'Neill-Glaser concept in the context of human survival and maintaining a healthy planet Earth. We argue that at this point in human history our technological power is too dangerous to our selves and our home planet for us not to expand into space. We show by the models presented in the chapter that the imminent dangers of global warming and human self-extinction mandate that humanity move aggressively into the solar system in this generation. We show that the production of solar power satellites using space resources and with a work foe living in space provides a viable financial model to mitigate CO2 preventing the worst global warming scenarios, and safeguards humanity against self-extinction by providing hundreds of habitats and a billion people living in space within about 35 years. To accomplish this goal we need only consider the classic O'Neill-Glaser model which was parameterized for 1970's technological projections. Only habitat size optimization for the first ten years of production is added. This is a conservative approach since the innovations of the last 30 years will make the financial projections more favorable. However, the classic O'Neill-Glaser model represented a broad technological consensus. The model is well documented in the references and our calculations can be easily reproduced In this chapter the economics of the O Neill - Glaser model is compared with models that rely exclusively on Earth launched materials. Although many studies of Earth launched Solar Power Satellites have been made, we found that the NASA "Fresh Look Study" was the most comprehensive and well documented. It also provided one of the most optimistic Earth launch financial projections. We thus chose it for comparison purposes.

Curreri, Peter A.↗
NASA NTRS2011

Energetic O+ and H+ Ions in the Plasma Sheet: Implications for the Transport of Ionospheric Ions

The present study statistically examines the characteristics of energetic ions in the plasma sheet using the Geotail/Energetic Particle and Ion Composition data. An emphasis is placed on the O+ ions, and the characteristics of the H+ ions are used as references. The following is a summary of the results. (1) The average O+ energy is lower during solar maximum and higher during solar minimum. A similar tendency is also found for the average H+ energy, but only for geomagnetically active times; (2) The O+ -to -H+ ratios of number and energy densities are several times higher during solar maximum than during solar minimum; (3) The average H+ and O+ energies and the O+ -to -H+ ratios of number and energy densities all increase with geomagnetic activity. The differences among different solar phases not only persist but also increase with increasing geomagnetic activity; (4) Whereas the average H+ energy increases toward Earth, the average O+ energy decreases toward Earth. The average energy increases toward dusk for both the H+ and O+ ions; (5) The O+ -to -H+ ratios of number and energy densities increase toward Earth during all solar phases, but most clearly during solar maximum. These results suggest that the solar illumination enhances the ionospheric outflow more effectively with increasing geomagnetic activity and that a significant portion of the O+ ions is transported directly from the ionosphere to the near ]Earth region rather than through the distant tail.

Ohtani, S.↗
NASA NTRS2015

Late-Glacial to Late-holocene Shifts in Global Precipitation Delta(sup 18)O

Reconstructions of Quaternary climate are often based on the isotopic content of paleo-precipitation preserved in proxy records. While many paleo-precipitation isotope records are available, few studies have synthesized these dispersed records to explore spatial patterns of late-glacial precipitation delta(sup 18)O. Here we present a synthesis of 86 globally distributed groundwater (n 59), cave calcite (n 15) and ice core (n 12) isotope records spanning the late-glacial (defined as 50,000 to 20,000 years ago) to the late-Holocene (within the past 5000 years). We show that precipitation delta(sup 18)O changes from the late-glacial to the late-Holocene range from -7.1% (delta(sup 18)O(late-Holocene) > delta(sup 18)O(late-glacial) to +1.7% (delta(sup 18)O(late-glacial) > delta(sup 18)O(late-Holocene), with the majority (77) of records having lower late-glacial delta(sup 18)O than late-Holocene delta(sup 18)O values. High-magnitude, negative precipitation delta(sup 18)O shifts are common at high latitudes, high altitudes and continental interiors.

isotopes↗
NASA NTRS2019

Seasonal, Solar Zenith Angle, and Solar Flux Variations of O+ in the Topside Ionosphere of Mars

Using observations from Mars Atmosphere and Volatile EvolutioN's Neutral Gas and Ion Mass Spectrometer, we characterize the seasonal, solar zenith angle (SZA), and solar flux dependent variations of the O+ peak and the O+/O+2 ratio in the topside ionosphere of Mars.We find that the O+ peak is between 220 and 300 km and forms at a roughly constant neutral atmospheric pressure level of 10(−8.7±0.4) Pa. The O+ peak altitude also decreases with increasing SZA near the terminator and varies sinusoidally with an amplitude of 26 km over a period of one Mars year in response to the changing solar insolation. The O+ peak altitude reaches a maximum near Northern Winter solstice and Mars perihelion. The O+ peak density on the dayside has an average value of (1.1 ± 0.5) × 103 cm−3, has no dependence on SZA for SZAs up to ∼90◦, and is mainly controlled by the thermospheric O/CO2 ratio as predicted by photochemical theory. Above the O+ peak, the O+/O+2 ratio in the dayside ionosphere approaches a constant value of 1.1 ± 0.6, decreases with increasing SZA, and is highly variable on timescales of days or less.We discuss why the O+ peak is different than the main (M2) peak at Mars and why it is similar to the F2 peak at Earth.

Girazian, Z.↗
NASA NTRS2024

EMIC Wave Energy Dissipation as a Source of O + Conics and Warm Plasma Cloak in the Earth's Inner Magnetosphere

This study focuses on a specific source of the O + conics and warm plasma cloak in the Earth's inner magnetosphere due to electromagnetic ion cyclotron (EMIC) wave energy dissipation. We analyze the EMIC wave event observed by Van Allen Probe-A in the early afternoon off equatorial magnetosphere on 18 November 2015, where the two dominant EMIC wave bands, He + -band and H + -band, were observed for ∼4 min. All the wave and plasma parameters, the DC magnetic field, and ion distributions needed for our analysis are taken from the Van Allen Probe-A observations during the event. The major results of our analysis are as follows. (a) The H + and He + heating by EMIC waves is negligible. (b) A strong heating of O + by the wave energy dissipation around the third, fifth, and sixth harmonics of the O + gyrofrequency is revealed, where the majority of energy dissipated goes into heating of O + with the energies ≲100 eV and pitch angles ∼20°–90°. The estimated energy deposition rate is ∼0.1–3.4 eV/s per O + , totaling to the deposition of ∼20–800 eV per O + during the event. (c) EMIC waves substantially contribute to the formation of O + conics and warm plasma cloak by heating the upgoing low-energy ionospheric O + because waves heat ions with the energies and pitch angles that are characteristic of conics and warm plasma cloak, and the energy deposition per O + is comparable to those characteristic energies.

Konstantin V. Gamayunov↗
NASA NTRS1986

Distributions of (C-13)O emission in the disks of late-type spiral galaxies

In studies of molecular clouds in external galaxies, the distribution of (C-12)O emissivity as a function of radius in a galaxy has been employed to infer the surface density of molecular hydrogen with galactocentric radius. In principle, observations of more optically thin molecular species, such as (C-13)O, can be used as an alternative tracer of the mass of molecular hydrogen in a galaxy. Since the (C-13)O lines have a much lower opacity than the saturated, nearly thermalized (C-12)O lines, their intensity variations as a function of galactocentric radius are more readily interpreted in terms of gas density variations. The first strip maps of the (C-13)O distributions in six spiral galaxies are presented, and the (C-13)O and (C-12)O radial distributions are compared. Attention is given to the reliability of H2 masses and H2 distributions derived from (C-12)O data.

Young, J. S.↗
NASA NTRS1993

Parallel O(log n) algorithms for open- and closed-chain rigid multibody systems based on a new mass matrix factorization technique

In this paper, parallel O(log n) algorithms for computation of rigid multibody dynamics are developed. These parallel algorithms are derived by parallelization of new O(n) algorithms for the problem. The underlying feature of these O(n) algorithms is a drastically different strategy for decomposition of interbody force which leads to a new factorization of the mass matrix (M). Specifically, it is shown that a factorization of the inverse of the mass matrix in the form of the Schur Complement is derived as M(exp -1) = C - B(exp *)A(exp -1)B, wherein matrices C, A, and B are block tridiagonal matrices. The new O(n) algorithm is then derived as a recursive implementation of this factorization of M(exp -1). For the closed-chain systems, similar factorizations and O(n) algorithms for computation of Operational Space Mass Matrix lambda and its inverse lambda(exp -1) are also derived. It is shown that these O(n) algorithms are strictly parallel, that is, they are less efficient than other algorithms for serial computation of the problem. But, to our knowledge, they are the only known algorithms that can be parallelized and that lead to both time- and processor-optimal parallel algorithms for the problem, i.e., parallel O(log n) algorithms with O(n) processors. The developed parallel algorithms, in addition to their theoretical significance, are also practical from an implementation point of view due to their simple architectural requirements.

Fijany, Amir↗
NASA NTRS1993

Variability of (O I) 6300-A emission near Io

Observations of (O I) 6300-A emission near Io have been obtained in 1990, 1991, and 1992 by the National Solar Observatory staff using the solar-stellar spectrography on the McMath-Pierce telescope at Kitt Peak. High-resolution spectra with a resolving power of about 1.2 x 10(exp 5) were obtained with an integration time of 10-15 min each. The viewing aperture for the observations was 5.2 arc sec x 5.2 arc sec centered on Io, with spatial resolution limited within this area by seeing conditions. Observations thus far have been reduced to obtain average brightness values over the aperture which range from approximately 200 to 1000 R for a number of different Io phase angles and Io system III longitudes. The (O I) 6300-A emission brightness exhibits an east-west asymmetry, where the average intensity for Io phase angles in the west (receding ansa) is 1.5 times brighter than in the east (approaching ansa). Similar east-west intensity ratios have also been observed for neutrals near Io and ions in the plasma torus for a number of other optical and ultraviolet emission lines which are excited by electron impact. In addition to the east-west asymmetry, the (O I) 6300-A emission brightness exhibits a strong dependence on the Io system III longitude angle, with a maximum value occurring in the range 200 deg +/- 50 deg. Earlier IUE observations of ultraviolet emission lines of O and S near Io obtained over a number of years have measured the east-west asymmetry, but the long IUE integration times of approximately 7-14 hours masked any detection of system III variability. For the (O I) 6300-A emission, the O(1D) state may be excited by electron impact of atomic oxygen and by electron impact dissociation of SO. The molecule SO may be present at the exobase or may be produced above the exobase as the dominant product of SO2 dissociation by electron impact. Preliminary assessment indicates that production of O(1D) by molecular dissociation may be more important. The (O I) 6300-A emission may therefore provide a remote signature for monitoring (1) the upward transport rates of molecular species in Io's atmosphere, (2) the relative abundance and time-variable dissociation of SO2 and/or SO at the exobase and in the corona of Io, and (3) the spatial distribution of these escaping molecular and atomic species and their ion production rates in the planetary magnetosphere.

Scherb, F.↗
NASA NTRS2001

Sunlit Io Atmospheric [O I] 6300 A and the Plasma Torus

A large database of sunlit Io [O I] 6300A emission, acquired over the period 1990-1999, with extensive coverage of Io orbital phase angle phi and System III longitude lambda(sub III), exhibits significant long-term and short-term variations in [O I] 6300A emission intensities. The long-term average intensity shows a clear dependence on lambda(sub III), which establishes conclusively that the emission is produced by the interaction between Io's atmosphere and the plasma torus. Two prominent average intensity maxima, 70 deg to 90 deg wide, are centered at lambda(sub III) about 130deg. and about 295 deg. A comparison of data from October 1998 with a three-dimensional plasma torus model, based upon electron impact excitation of atomic oxygen, suggests a basis for study of the torus interaction with Io's atmosphere. The observed short-term, erratic [O I] 6300A intensity variations fluctuate approximately 20% to 50% on time scale of tens of minutes with less frequent fluctuations of a factor of about 2. The most likely candidate to produce these fluctuations is a time-variable energy flux of field-aligned nonthermal electrons identified recently in Galileo PLS data. If true, the short-term [O I] intensity fluctuations may be related to variable field-aligned currents driven by inward and outward torus plasma transport and/or transient high-latitude, field-aligned potential drops. A correlation between the intensity and emission line width indicates molecular dissociation may contribute significantly to the [O I] 6300A emission. The nonthermal electron energy flux may produce O(1-D) by electron impact dissociation of SO2 and SO, with the excess energy going into excitation of O and its kinetic energy. The [O I] 6300A emission database establishes Io as a valuable probe of the torus, responding to local conditions at Io's position.

Oliversen, Ronald J.↗
NASA NTRS2007

Conceptual Design of the TPF-O SC Bus

One option under current study for the Terrestrial Planet Finder-Occulter (TPF-O) observatory shares some key features of the Hubble Space Telescope (HST). Both are space telescopes with a primary mirror aperture of around 2.4 meters and designed to observe in the visible to near infrared range of wavelengths, with the major difference in science capability being that TPF-O has an areal FOV on the order of 100 times larger than that of HST. This larger FOV, whose science camera is also expected to provide fine guidance, and other mission differences, mean that most TPF-O SC bus subsystems will have very different requirements than those of HST. Unlike HST in LEO, TPF-O is designed to operate in an orbit around the Sun-Earth lagrange 2 (SEL2) point. The longer communications range to SEL2 and the large FOV require much higher performance data processing and communications than HST. Maintaining a SEL2 orbit requires TPF-O, unlike HST, to have a propulsion system. TPF-O will have a specialized tracking system that allows the formation flying occulter to maintain its required position. However, despite these additional features, the velocity required for reaching SEL2 and the limited capabilities of affordable launch vehicles require TPF-O to have a compact and low-mass design relative to HST. Finally, TPF-O may utilize a modular design to reduce development cost and, if it required, allow servicing using approaches different from those of HST.

Purves, Lloyd R.↗
NASA NTRS2007

Conceptual Design of the TPF-O SC Buses

The Terrestrial Planet Finder - Occulter (TPF-O) mission has two Spacecraft (SC) buses, one for a space telescope and the other for a formation-flying occulter. SC buses typically supply the utilities (support structures, propulsion, attitude control, power, communications, etc) required by the payloads. Unique requirements for the occulter SC bus are to provide the large delta V required for the slewing maneuvers of the occulter, and comunications for formation flying. The TPF-O telescope SC bus shares some key features of the one for the Hubble Space Telescope (HST): both support space telescopes designed to observe in the visible to near infrared range of wavelengths with comparable primary mirror apertures (2.4 m for HST, 2.4 - 4.0 m for TPF-O). However, TPF-O is expected to have a Wide Field Camera (WFC) with a Field of View (FOV) much larger than that of HST. Ths WFC is also expected to provide fine guidance. TPF-O is designed to operate in an orbit around the Sun-Earth Lagrange 2 (SEL2) point. The longer communications range to SEL2 and the large science FOV require higher performance communications than HST. Maintaining a SEL2 orbit requires TPF-O, unlike HST, to have a propulsion system. The velocity required for reachng SEL2 and the limited capabilities of affordable launch vehicles require both TPF-O elements to have compact, low-mass designs. Finally, it is possible that TPF-O may utilize a modular design derived fiom that of HST to allow servicing in the SEL2 orbit.

Purves, Lloyd R.↗
NASA NTRS2013

Herschel - PACS Survey Of Protoplanetary Disks In Taurus - Auriga Observations Of [O I] And [C Ii], And Far-Infrared Continuum

The Herschel Space Observatory was used to observe approx. 120 pre-main-sequence stars in Taurus as part of the GASPS Open Time Key project. Photodetector Array Camera and Spectrometer was used to measure the continuum as well as several gas tracers such as [O I] 63 micron, [O I] 145 micron, [C II] 158, micron OH, H2O, and CO. The strongest line seen is [O I] at 63 micron. We find a clear correlation between the strength of the [O I] 63 micron line and the 63 micron continuum for disk sources. In outflow sources, the line emission can be up to 20 times stronger than in disk sources, suggesting that the line emission is dominated by the outflow. The tight correlation seen for disk sources suggests that the emission arises from the inner disk (<50 AU) and lower surface layers of the disk where the gas and dust are coupled. The [O I] 63 micron is fainter in transitional stars than in normal Class II disks. Simple spectral energy distribution models indicate that the dust responsible for the continuum emission is colder in these disks, leading to weaker line emission. [C II] 158 micron emission is only detected in strong outflow sources. The observed line ratios of [O I] 63 micron to [O I] 145 micron are in the regime where we are insensitive to the gas-to-dust ratio, neither can we discriminate between shock or photodissociation region emission. We detect no Class III object in [O I] 63 micron and only three in continuum, at least one of which is a candidate debris disk.

GASPS Open Time Key project↗
NASA NTRS2015

Fe and O EELS Studies of Ion Irradiated Murchison CM2 Carbonaceous Chondrite Matrix

Introduction: The physical and chemical response of hydrated carbonaceous chondrite materials to space weathering processes is poorly understood. Improving this understanding is a key part of establishing how regoliths on primitive carbonaceous asteroids respond to space weathering processes, knowledge that supports future sample return missions (Hayabusa 2 and OSIRISREx) that are targeting objects of this type. We previously reported on He+ irradiation of Murchison matrix and showed that the irradiation resulted in amorphization of the matrix phyllosilicates, loss of OH, and surface vesiculation. Here, we report electron energy-loss spectroscopy (EELS) measurements of the irradiated material with emphasis on the Fe and O speciation. Sample and Methods: A polished thin section of the Murchison CM2 carbonaceous chondrite was irradiated with 4 kilovolts He(+) (normal incidence) to a total dose of 1 x 10(exp 18) He(+) per square centimeter. We extracted thin sections from both irradiated and unirradiated regions in matrix using focused ion beam (FIB) techniques with electron beam deposition for the protective carbon strap to minimize surface damage artifacts from the FIB milling. The FIB sections were analyzed using a JEOL 2500SE scanning and transmission electron microscope (STEM) equipped with a Gatan Tridiem imaging filter. EELS spectra were collected from 50 nanometer diameter regions with an energy resolution of 0.7 electronvolts FWHM at the zero loss. EELS spectra were collected at low electron doses to minimize possible artifacts from electron-beam irradiation damage. Results and Discussion: Fe L (sub 2,3) EELS spectra from matrix phyllosilicates in CM chondrites show mixed Fe(2+)/Fe(3+) oxidation states with Fe(3+)/Sigma Fe approximately 0.5. Fe L(sub 2,3) spectra from the irradiated/ amorphized matrix phyllosilicates show higher Fe(2+)/Fe(3+) ratios compared to spectra obtained from pristine material at depths beyond the implantation/amorphization layer. We also obtained O Ka spectra from phyllosilicates in both regions of the sample. The O Ka spectra show a pre-edge feature at approximately 530.5 electronvolts that is related to O 2p states hybridized with Fe 3d states. The intensity ratio of the O Ka pre-edge peak relative to the main part of the O Ka edge (that results from transitions of O 1s to 2p states) is lower in the irradiated layer compared to the pristine material and may reflect the loss of O (as OH) as was observed by IR spectroscopy. Conclusions: In addition to amorphization and OH loss, EELS spectra of He(+) irradiated matrix phyllosilicates in Murchison show that some of the Fe(3+) is reduced to Fe(2+). Spectral deconvolution is underway to extract quantitative ratios from the EELS spectra.

Keller, L. P.↗
NASA NTRS2024

Reliable and Efficient Electrochemical Recovery of O 2 from Metabolic CO 2 at the International Space Station (ISS)

Maximum O 2 recovery from metabolic carbon dioxide (CO 2 ) is desired for future long-duration missions beyond Low Earth Orbit (LEO). The O 2 recovery for the Environmental Control and Life Support System (ECLSS) at the International Space Station (ISS), presently limited to 50% (Sabatier), must be highly reliable and efficient and recover a minimum of 75% oxygen (O 2 ) from metabolic CO 2 . An alternative technology development effort currently underway at NASA Marshall Space Flight Center (MSFC) via a Microfluidic Electrochemical Reactor (MFECR) approach has the potential to increase O 2 recovery significantly and reduce the complexity of the ECLSS O 2 recovery at the ISS as it would replace three pieces, the CO 2 Reduction Assembly (CRA) (Sabatier reactor), the Oxygen Generation Assembly (OGA), and the Plasma Pyrolysis Assembly (PPA). The MFECR's electrochemical process generates ethylene (C 2 H 4 ) and carbon moxide (CO) instead of methane (CH 4 ) (Sabatier) as a byproduct, eliminating the need for further dehydrogenation through the PPA. As in the OGA, the MFECR's electrochemical process generates O 2 and hydrogen (H 2 ) from the water electrolysis process. MSFC and the University of Texas in Arlington (UTA) have jointly designed and fabricated an MFECR's single cell that operates at ambient conditions and utilizes a proprietary catalysis highly selective on reducing CO 2 to C 2 H 4 and CO at the cathode. This MFECR's single cell consists of gas diffusion layers at the cathode and anode for respective intake of CO 2 and output of O 2 from the catalytic layer. This approach is expected to substantially improve the ISS ECLSS sustainability and reduce power and weight requirements as the MFECR would replace three units currently installed in the ISS. In this paper, the authors discuss the outcome of preliminary tests, the current development, and the evaluation efforts on different alternatives for the cathode and the anode configurations, the setup of the MFECR at an engineering development unit (EDU) scale, and the O 2 recovery performance, and evaluation efforts on different alternatives on not only the configuration and setup of the MFECR at an Engineering Design Unit (EDU) scale but also the selection of component materials.

Jesus A Dominguez↗
NASA NTRS1998

Expression of extracellular calcium (Ca2+o)-sensing receptor in human peripheral blood monocytes

The calcium-sensing receptor (CaR) is a G protein-coupled receptor playing key roles in extracellular calcium ion (Ca2+o) homeostasis in parathyroid gland and kidney. Macrophage-like mononuclear cells appear at sites of osteoclastic bone resorption during bone turnover and may play a role in the "reversal" phase of skeletal remodeling that follows osteoclastic resorption and precedes osteoblastic bone formation. Bone resorption produces substantial local increases in Ca2+o that could provide a signal for such mononuclear cells present locally within the bone marrow microenvironment. Indeed, previous studies by other investigators have shown that raising Ca2+o either in vivo or in vitro stimulated the release of interleukin-6 (IL-6) from human peripheral blood monocytes, suggesting that these cells express a Ca2+o-sensing mechanism. In these earlier studies, however, the use of reverse transcription-polymerase chain reaction (RT-PCR) failed to detect transcripts for the CaR previously cloned from parathyroid and kidney in peripheral blood monocytes. Since we recently found that non-specific esterase-positive, putative monocytes isolated from murine bone marrow express the CaR, we reevaluated the expression of this receptor in human peripheral blood monocytes. Immunocytochemistry, flow cytometry, and Western blot analysis, performed using a polyclonal antiserum specific for the CaR, detected CaR protein in human monocytes. In addition, the use of RT-PCR with CaR-specific primers, followed by nucleotide sequencing of the amplified products, identified CaR transcripts in the cells. Therefore, taken together, our data show that human peripheral blood monocytes possess both CaR protein and mRNA very similar if not identical to those expressed in parathyroid and kidney that could mediate the previously described, direct effects of Ca2+o on these cells. Furthermore, since mononuclear cells isolated from bone marrow also express the CaR, the latter might play some role in the "reversal" phase of bone remodeling, sensing local changes in Ca2+o resulting from osteoclastic bone resorption and secreting osteotropic cytokines or performing other Ca2+o-regulated functions that contribute to the control of bone turnover.

NASA Discipline Musculoskeletal↗