Magnetic core/shell-type composites composed of coarse FePt particles coated with finely powdered iron nitride
Highlights: • Magnetic core/shell-type composites were prepared on α″-Fe{sub 16}N{sub 2}-like compound with FePt core. • α″-Fe{sub 16}N{sub 2}-like compound grew epitaxially on the FePt core. • Magnetic coupling increased the magnetic coercivity of α″-Fe{sub 16}N{sub 2}-like compound. - Abstract: Although α″-Fe{sub 16}N{sub 2}-like compounds exhibit enhanced magnetization compared to α-Fe, it is important to increase their magnetic coercivity to obtain new hard magnetic materials for electric vehicle application. In the present work, coarse FePt particles were coated with finely powdered Fe{sub 3}O{sub 4} produced by the hydrolysis of Fe(acac){sub 3} in benzyl alcohol. This Fe{sub 3}O{sub 4} coating layer was subsequently reduced under hydrogen and then nitrided by ammonolysis at 150 °C to obtain a dual-phase mixture of an α″-Fe{sub 16}N{sub 2}-like compound (referred to herein as “α″-Fe{sub 16}N{sub 2}”) and residual α-Fe. The (“α″-Fe{sub 16}N{sub 2}” + α-Fe){sub 1-x}/(FePt){sub x} composite particles for which x = 0.2, 0.4 or 0.6 generated smooth magnetization hysteresis curves, and the magnetic coercivity of these materials increased with increases in the proportion of FePt. Magnetic coupling was clearly evident between the core and shell regions in the composite powder for which x = 0.6, as demonstrated by a plot of the Wohlfarth interaction against the magnetic field. Transmission electron microscopy images confirmed magnetic coupling between the coarse FePt particles (several hundred nm in diameter) and the coating of fine mixed particles (several tens of nm in diameter) of “α″-Fe{sub 16}N{sub 2}” and α-Fe. The “α″-Fe{sub 16}N{sub 2}” crystals forming the particle shell were found to grow epitaxially, aligning their c-axes parallel to that of the tetragonal FePt.