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At least 163 records · Page 9

Life Cycle Assessment and Cost Analysis of a Process-Based Sorbent-Based Direct Air Capture with Temperature-Vacuum Swing Adsorption Model

This presentation discusses different aspects of LCA and TEA of sorbent-based case study updates and methodologies utilized for carbon dioxide removal technologies. The combined TEA and LCA approach adopted herein provides insight into trade-offs between environmental performance and cost efficiency under various energy supply scenarios.

carbon dioxide removal↗

2016 U.S. Petroleum Fuels Life Cycle Baseline

The National Energy Technology Laboratory (NETL) has performed a well-to-wheels life cycle assessment (LCA) of petroleum production and refining for the United States (US), both from international and domestic oil sources. This analysis largely follows the same methods and framework established by Cooney et al., which performed a greenhouse gas (GHG) LCA of crude products for the 2014 data year (Cooney et al., 2017). Results are presented for six major petroleum products (gasoline, diesel, jet fuel, fuel oil, coke, bunker/residual fuel oil) across each of the five Petroleum Administration for Defense Districts (PADDs) and at the national US level. However, there are at least seven other refinery outputs (liquified petroleum gas, refinery fuel gas, hydrogen, petrochemical feedstocks, asphalt, sulfur) that are modeled but not shown in this report for brevity. Petroleum product amounts are compared against those reported by US Energy Information Administration (EIA) for each region.

02 PETROLEUM↗

Life Cycle Assessment of Recycling High-Density Polyethylene Plastic Waste

Increasing production and use of various novel plastics products, a low recycling rate, and lack of effective recycling/disposal methods have resulted in an exponential growth in plastic waste accumulation in landfills and in the environment. To better understand the effects of plastic waste, Life Cycle Analysis (LCA) was done to compare the effects of various production and disposal methods. LCA shows the specific effects of the cradle-to-grave or cradle-to-cradle scenarios for landfill, incineration, and mechanical recycling. The analysis clearly indicates that increasing recycling of plastics can significantly save energy and eliminate harmful emissions of various carcinogens and GHGs into the environment. As recycling increases, the need for virgin-plastic production can be greatly reduced. Furthermore, the results of this study may help improve current mechanical recycling processes as well as potential future recycling methods, such as chemical recycling. Concerns about the current recycling/disposal methods for plastics have brought increasing attention to the waste accumulation problem. However, with the current COVID-19 pandemic, plastic accumulation is expected to increase significantly in the near future. A better understanding of the quantitative effects of the various disposal methods can help guide policies and future research toward effective solutions of the plastic waste problem.

36 MATERIALS SCIENCE↗

WBS 1.2.3.405 - Life Cycle Assessment of Storage Technologies

Recent commitments by the Biden administration have established targets to achieve a net-zero energy system by 2050. Meeting these targets will spur a rapid transition to clean energy technologies and a commensurate need to develop and deploy energy storage technologies at scale. Pumped Storage Hydro (PSH) is expected to be part of this solution because its ability to provide grid flexibility and stability and enable the dispatching of disparate variable renewable energy technologies. Despite PSH being a mature technology with a history of deployment dating back several decades, there is very little information on the greenhouse gas (GHG) implications of PSH as compared to other storage technologies. The objective of this project is to perform a full lifecycle assessment (LCA) of new PSH projects in the U.S. This LCA includes all project phases (resource extraction, construction, operation, maintenance, end-of-life). The functional unit for this study is 1 kWh electricity delivered by system to grid substation connection point and the estimated lifetime for our base case is 80 years. Data used in this study are based on over 30 potential PSH projects that are in preliminary planning phases and are represent a wide range of potential closed-loop PSH systems in terms of location, technology, and capacity. The project approach, data sources, and modeling assumptions have been informed by a technical review committee of stakeholders that include experts from academia, national and international government, industry, and utilities. The GHGs and energy return on investment (EROI) from PSH will be compared to other storage technologies (e.g., stationary battery storage). Results from this project will improve the PSH community's understanding of the environmental impacts and sustainability of new PSH projects and how PSH compares to other storage technologies. The approach used in this project relies on open-source programming. The analysis framework (source code and data) and will be made publicly available at the end of the project. In addition to reporting results for the base case, we will perform rigorous sensitivity analysis to identify the major drivers, understand impacts of different configurations, and future energy markets. Results from this project will be published in a suitable journal.

ENERGY PLANNING, POLICY, AND ECONOMY,HYDRO ENERGY↗

Analysis and Design for Sustainable Circularity of Barrier Films Used in Sheet Molding Composites Production

Sheet molding composites (SMC) are thermoset based molding compounds with a global market size of USD 2.1 billion in 2020. SMC is usually processed with multilayer barrier/carrier films to prevent emissions from volatile organic compounds (VOC). The plastic barriers are separated from SMC after the curing process and discarded. To illustrate the high consumption volume of SMC barrier/carrier films, Kohler Co., a company which uses SMC in their bath and showering product lines, alone generates over 1M lb/year of SMC barrier/carrier film waste. Therefore, high amount of SMC barrier/carrier film plastic waste creates a great opportunity for reusing, recycling, or valorization at its end of life. This can be achieved through transition from a linear to a circular supply chain design. However, this transition will not be feasible without overcoming the technical and economic barriers. This project aims to tackle this by making the film circular. Different end of life alternatives will be evaluated experimentally. The reusability of the film will be studied through applying different mechanical and solvent cleaning techniques. The operability concerns regarding the utilization of the cleaned film for long run operations will be addressed by thermally stitching the film. Pelletizing of the cleaned film will also be investigated as a viable technique for recycling or downcycling of the film as molded products. In addition to technical barriers, designing a sustainable circular supply chain for SMC carrier film products requires uncovering the collaboration opportunities between suppliers and users at different stages of the value chain to expand its use to other products. These opportunities will be investigated by finding companies willing to buy or treat the plastic film waste. Finally, the economic viability and environmental impacts of these circular design alternatives will be evaluated through techno-economic assessment (TEA) and life cycle analysis (LCA). Techno-economic and life cycle inventory data for various pathways will also be made available as one of the main outcomes of this project. Preliminary LCA results indicate that the current SMC film supply chain (base case) emits 5.81 tonne CO2 eq. and consumes 104 GJ energy per tonne of SMC film. It is estimated that alternative circular pathways result in 14-20% less CO2 emissions and 34-44% reduction in embodied energy. This project will develop a tool to analyze the circularity and sustainability of hundreds of combinations of alternatives in different life cycle stages. Users of this tool will be able to choose the best combination among these alternatives with respect to the selected economic, environmental and circularity objectives.

circular economy↗

Impact of landscape design on the greenhouse gas emissions of shrub willow bioenergy buffers in a US Midwest corn-production landscape

Previous studies have evaluated the economics and ecosystem services of perennial bioenergy crops when replacing grain crops on marginal (environmentally critical and/or underproductive) lands. This study used life-cycle analysis (LCA) to investigate the greenhouse gas (GHG) emissions of perennial crops when grown in targeted landscape positions and their impact in reducing nitrogen leaching. Specifically, LCA was performed to evaluate the GHG emissions of growing shrub willow on marginal lands in the Indian Creek watershed in Illinois to assess the sustainability of strategically planted willow buffer strips. Willow was grown as a short-rotation woody crop with a 21-year rotation under three scenarios including a business-as-usual (BAU) field-scale production with nitrogen fertilizer application and two unfertilized subfield buffer scenarios – landscape single subfield (LSSF) or landscape multiple subfields (LMSF) – grown alongside cornfields to reduce nitrate leaching. Each scenario also considers three field sizes, 2.0, 10.1, and 40.5 ha. The average annual GHG emissions from willow production and depot transportation were 0.32–0.77 Mg-CO 2 e ha-1 with the lowest emissions for the LSSF scenario and highest for the BAU. The GHG emissions for the LSSF and BAU scenarios are independent of field size, whereas LMSF emissions increase with increasing field size, 0.41 Mg-CO 2 e ha-1 at 2.0 ha and 0.76 Mg-CO 2 e ha-1 at 40.5 ha. Emission results were most sensitive to the willow yield, followed by fertilizer application rate (BAU only), harvest fuel consumption, and transportation distance.

09 BIOMASS FUELS↗

Uncertainty in inventories for life cycle assessment: State‐of‐the‐art, challenges, and new technologies

Uncertainty is a critical factor that can hinder the quality and potential applications of life cycle assessment (LCA) results. A prominent source of uncertainty stems from the life cycle inventory (LCI) data. Various methodologies exist to estimate the uncertainty associated with LCI data, primarily based on the widely used structured pedigree matrix approach or the computationally intensive Monte Carlo simulation. This perspective review explores how new technologies (e.g., computational algorithms and data collection methods) from data science and related fields can contribute to identifying, quantifying, and reducing uncertainty in LCI modeling. A brief overview of the sources of uncertainty in LCI modeling and how they are addressed in current LCA practice is provided. Additionally, several new technologies are identified, and the potential benefits of their implementation in reducing uncertainties in LCI modeling are discussed. This perspective review concludes by identifying potential areas that require further development for these technologies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Life cycle energy demand and carbon emissions of scalable single-junction and tandem perovskite PV

Perovskite photovoltaics reached record efficiencies in the laboratory and, if sustainably commercialized, they would accelerate a green energy transition. Here, this article presents the development of life-cycle inventory material and energy databases of most promising four single-junction and three tandem scalable perovskite systems with assumptions regarding scalable production validated by industry experts. We conducted comprehensive “ex ante” Life Cycle Analysis (LCA) and Net Energy Analysis, analyzing their cumulative energy demand, global warming potential profiles, energy payback times and energy return on investment (EROI). LCA contribution analysis elucidates the most impactful material and process choices. It shows that solution-based perovskite manufacturing would have lower environmental impact than vapor-based methods, and that roll-to-roll (RtR) printing offers the lowest impact. Among material choices, MoOx/Al has lower impact than Ag, and fluorine-tin-oxide lower than indium-tin-oxide. Furthermore, we compare perovskites with commercial crystalline-silicon and thin-film PV, accounting for the most recent developments in crystalline-Si wafer production and differences in life expectancies and efficiencies. It is shown that perovskite systems produced with RtR manufacturing could reach in only 12 years of life the same EROI as that of single-crystalline-Si PV lasting 30-years. This work lays a foundation for sustainability investigations of perovskite large-scale deployment.

14 SOLAR ENERGY↗

Derivation and assessment of regional electricity generation emission factors in the USA

Electricity production is one of the largest sources of environmental emissions - especially greenhouse gases (GHGs) - in the USA. Emission factors (EFs) vary from region to region, which requires the use of spatially relevant EF data for electricity production while performing life cycle assessments (LCAs). Uncertainty information, which is sought by LCA practitioners, is rarely supplied with available life cycle inventories (LCIs). To address these challenges, we present a method for collecting data from different sources for electricity generation and environmental emissions; discuss the challenges involved in agglomerating such data; provide relevant suggestions and solutions to merge the information; and calculate EFs for electricity generation processes from various fuel sources for different spatial regions and spatial resolutions. The EFs from the US 2016 Electricity Life Cycle Inventory (eLCI) are analyzed and explored in this study. We also explore the method of uncertainty information derivation for the EFs. We explore the EFs from different technologies across Emissions & Generation Resource Integrated Database (eGRID) regions in the USA. We find that for certain eGRID regions, the same electricity production technology may have worse emissions. This may be a result of the age of the plants in the region, the quality of fuel used, or other underlying factors. Region-wise life cycle impact assessment (LCIA) ISO 14040 impacts for total generation mix activities provide an overview of the total sustainability profile of electricity production in a particular region, rather than only global warming potential (GWP). We also find that, for different LCIA impacts, several eGRID regions are consistently worse than the US average LCIA impact for every unit of electricity generated. Here this work describes the development of an electricity production LCI at different spatial resolutions by combining and harmonizing information from several databases. The inventory consists of emissions, fuel inputs, and electricity and steam outputs from different electricity production technologies located across various regions of the USA. This LCI for electricity production in the USA will prove to be an enormous resource for all LCA researchers - considering the detailed sources of the information and the breadth of emissions covered by it.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The effect of functional unit and co-product handling methods on life cycle assessment of an algal biorefinery

Microalgae are a promising feedstock for sustainable fuel and nutritional products. To be economically viable, algal biorefineries will need to produce multiple products, such as nutraceuticals and animal feed, in addition to fuel. Life cycle assessment (LCA) has been applied widely to algal biorefineries, but results vary across studies. Here we address two methodological challenges that can lead to variability in LCAs of multi-product algal biorefineries: the choice of functional unit and the method used to handle co-products. LCA was conducted for an algal biorefinery that produces two representative products—fuel and animal feed—using three functional units: (1) 1 MJ fuel, (2) 1 kg animal feed, and (3) 1 ha of production area, coupled with the system expansion method. For the fuel-based functional unit, the system expansion method was compared to impact allocation based on mass, energy, and market value of the biorefinery products. The choice of functional unit affects the results for several environmental indicators. For ecosystem quality, the choice of functional unit can change the overall balance of environmental impacts from harmful to beneficial. The effect of functional unit on climate change depends on the boundary considered in the model—i.e., “well to gate” or “well to wheels”. When a fuel-based functional unit is used, the choice of co-product handling method (i.e., allocation versus the system expansion method) affects environmental impacts, such as ecosystem quality and climate change, differently. For LCAs that use a fuel-based functional unit to compare algal biofuel to other fuels, multiple co-product handling methods should be analyzed and presented to stakeholders. A land based functional unit coupled with the system expansion method can be used to improve LCAs that compare among multi-product algal biorefineries.

09 BIOMASS FUELS↗

Life cycle analysis of dedicated energy crops for fuel production in the United States

Dedicated energy crops are promising feedstocks to make biofuels including jet fuels. This study applies life cycle analysis (LCA) to estimate direct well-to-wake (WTW) greenhouse gas (GHG) emissions (g CO 2 e/MJ) for jet fuel derived from five energy crops-biomass sorghum, miscanthus, switchgrass, poplar, and willow-via Fischer-Tropsch-to-Jet (FTJ) and Ethanol-to-Jet (ETJ) pathways. The WTW boundary includes direct emissions from biomass production, fuel production, and fuel combustion. The R&D GREET model is expanded to conduct the LCA, using national average biomass yields and farming inputs from the 2023 Billion-Ton Study. In addition, this study estimates emissions from market-mediated effects, including induced land-use change, induced other crop (non-feedstock) production changes, and induced livestock production changes using global economic and emissions factor models. On a per-dry U.S. ton basis, cultivation and harvest emissions are lowest for willow (51,565 g CO 2 e) and highest for biomass sorghum (104,488 g CO 2 e). Per-acre results show similarly high emissions for sorghum and lowest values for poplar and willow. Direct WTW emissions are substantially lower for FTJ (biomass sorghum: 5.5; miscanthus: 10.3; switchgrass: 11.7; poplar: 11.9; and willow: 8.7 g CO 2 e/MJ) than ETJ (33.2; 33.8; 34.8; 36.2; and 31.7 g CO 2 e/MJ, respectively). When market-mediated emissions are included, miscanthus exhibits the lowest total emissions across energy crop pathways. Although results are sensitive to modeling assumptions, they indicate that high-yielding perennial and woody crops, particularly when planted on marginal land, could significantly reduce WTW emissions for bio-jet fuels by combining low direct emissions with soil carbon gains and favorable market-mediated effects.

Billion-Ton Study↗

Advancing technologies for lignin-based jet fuel production in aqueous phase

Integrating lignin into a cellulosic ethanol plant for the co-production of lignin-based jet fuel (LJF) in aqueous phase offers a significant opportunity to boost operational efficiency, economic viability, carbon conversion, and the overall sustainability of biofuel and chemical production. LJF is lignin-structure-based jet fuel blendstocks primarily composed of alkyl-substituted mono-, bi-, and tri-cyclohexanes. It exhibits high energy density, potential for low emissions, and favourable blend characteristics that comply with drop-in specifications. An overview of lignin feedstock, catalytic processes, LJF chemical compositions, fuel properties tests, and techno-economic analysis (TEA) and life cycle assessment (LCA) indicate that (1) the reactivity of lignin plays a crucial role in its structure transformation to LJF molecules; (2) catalytic processing of lignin to LJF can occur through a simultaneous depolymerization and hydrodeoxygenation process, bypassing the intermediate step of producing and upgrading lignin-derived oil; (3) LJF's uniqueness molecules making it more promising for high energy content and low emission jet fuel properties for next generation sustainable aviation fuel (SAF); and (4) TEA and LCA demonstrate that LJF is not only potentially cost-effective but also offers favourable carbon footprint compared to other SAFs. In conclusion, this review highlights the most recent advancements in LJF technology, along with the challenges and opportunities that lie ahead in fulfilling its potential.

09 BIOMASS FUELS↗

Screening green solvents for multilayer plastic film recycling processes

Multilayer (ML) plastic films are essential packaging materials that help protect products from diverse external factors; however, only 5% of all ML films are recycled in the United States. Solvent-based technologies are a promising alternative for recycling ML films because they enable recovery of constituent polymer resins. For example, the Solvent Targeted Recovery and Precipitation (STRAPTM) process sequentially dissolves and separates polymer components using a series of targeted solvent washes. A crucial design aspect of this process is the impact of selected solvents on human health and on the environment. Here, this work introduces a computational framework that integrates molecular modeling, process modeling, techno-economic analysis (TEA), and life-cycle analysis (LCA) to quickly screen green solvents for solvent-based ML recycling processes. Initial screening for solvents based on selectivity is performed by estimating temperature-dependent solubilities using molecular-scale models. Subsequent screening uses basic estimates of energy use and octanol-water partition coefficients (logP) as key measures of health, safety, and environmental hazards. Detailed process modeling, TEA, and LCA are used on a reduced set of promising solvents identified in early screening steps to more accurately determine how solvent selection and associated operating conditions impact overall economics and environmental impacts. The framework is used for the identification of green solvents (from a database of 1,000 solvents) that separate an industrial ML film composed of polyethylene (PE), ethylene vinyl alcohol (EVOH), and polyethylene terephthalate (PET). Our analysis shows the effectiveness of the framework and reveals fundamental trade-offs between solvent greenness, solubility, and economics. Our work emphasizes the importance of taking a holistic systems view during solvent design and aims to inform the development of new processes for ML film recycling and the identification of new ML films that are easier to recycle.

economics↗

Democratizing life cycle assessment by developing a streamlined model of greenhouse gas emissions from US natural gas supply chains

Natural gas (NG) supply chains contribute substantially to the global energy supply and anthropogenic methane emissions, making them frequent subjects of life cycle assessments (LCAs). To better characterize central tendencies and variability, we systematically reviewed and harmonized published estimates of life cycle greenhouse gas (GHG) emissions from United States NG supply chains. Results informed a streamlined LCA model (SLiNG-GHG: streamlined LCAs of NG-GHGs) that quantifies carbon dioxide and methane from three gates: transmission, distribution, and shipping. Median estimates employing harmonized emission inputs, are 10, 11, and 21 g CO2e/MJ gas (100-year global warming potentials [GWPs]), and 20, 22, and 33 g CO2e/MJ gas (20-year GWPs), delivered to each gate, respectively. Alternatively, inputting available, independent methane measurements, SLiNG-GHG estimates varied from -23% to +316% relative to baseline. Bottom-up inventories used in LCAs tend to underestimate methane compared with measurements. Results underscore the need for open-source, streamlined LCA models that can easily incorporate rapidly evolving measurements for non-experts like investors and regulators.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A multi-product landscape life-cycle assessment approach for evaluating local climate mitigation potential

Increasing demand for land-based climate mitigation requires more efficient management of agricultural landscapes for competing objectives. Here we develop methods for assessing trade-offs and synergies between intensification and carbon-sequestering conservation measures in annual crop production landscapes using the DayCent ecosystem model and the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (GREET) life-cycle assessment (LCA) model. We compiled county-scaled crop yields, fertilizer application rates, and tillage intensity for a corn–soybean farming case study landscape in the US state of Iowa. Using DayCent, we estimated a baseline soil organic carbon (SOC) accrual rate of 0.29 Mg C ha -1 y -1 driven by historical increases in crop productivity and reductions in tillage intensity. We then simulated the effects of management interventions targeted toward intensification (stover removal) and SOC sequestration (tillage intensity reduction and winter cover crop addition) individually and in combination. We propose a new multi-product landscape–LCA approach that analyzes marginal changes in corn grain, corn stover, and soybean production from the landscape in terms of their value for biofuel production (corn ethanol, soy biodiesel, and cellulosic ethanol from stover) and associated net displacement of conventional fossil-derived fuel use. This enables us to evaluate both intensification and sequestration effects in common CO 2 -equivalent mitigation units. We also used DayCent-simulated yields under the different land management scenarios to estimate farm-level costs and revenues. Our results show that intensification via collecting 30% of corn stover for biofuel production would increase the total greenhouse gas (GHG) mitigation potential of this landscape by 0.93 Mg CO 2 e ha -1 y -1 and provide $49 ha -1 y -1 of additional net revenue from biomass sales, but would reduce the baseline SOC accumulation rate by approximately 40%. In contrast, integrated approaches that include co-adoption of winter cover cropping and/or tillage intensity reduction would result in increased rates of SOC accumulation above the baseline, achieving simultaneous improvements in both farm profits and the overall GHG mitigation potential of the landscape.

54 ENVIRONMENTAL SCIENCES↗

Evaluating CO 2 mitigation strategies in SAF biorefineries: Techno-economic and life cycle analysis

The aviation sector requires scalable decarbonization strategies, and lignocellulosic sustainable aviation fuel (SAF) represents a promising pathway. This study comparatively evaluates the techno-economic analysis and life cycle assessment (LCA) of three CO 2 management strategies integrated within a U.S.-based gasification–Fischer–Tropsch SAF biorefinery: (i) catalytic hydrogenation of captured CO 2 to methanol, (ii) geological CO 2 sequestration, and (iii) mineralization to sodium bicarbonate (NaHCO 3 ). Techno-economic analysis indicates that methanol synthesis requires approximately 26% higher capital investment and 33% higher operating costs than mineralization. Although methanol co-production generates the highest gross revenue, NaHCO 3 production reduces the SAF minimum selling price by approximately 38% relative to both methanol synthesis and geological sequestration pathways, reflecting a more balanced cost allocation through mineral co-product valorization. Geological sequestration lowers operating costs by nearly 50% compared with methanol synthesis but remains highly dependent on carbon credit mechanisms. LCA reveals substantial divergence in climate performance. Relative to methanol synthesis, sequestration improves net greenhouse gas performance by approximately 163%, transitioning the system from net-positive to net-negative emissions. Mineralization further enhances carbon mitigation, achieving roughly 85% greater carbon reduction than sequestration and over sixfold improvement relative to methanol synthesis within the defined system boundary. Sensitivity analysis identified hydrogen price, co-product market value, and process emissions as dominant drivers. Under baseline assumptions, CO 2 mineralization is found to offer the most balanced pathway.

Carbon capture and storage↗

Cradle-to-gate life cycle assessment of advanced composite panels incorporating CO 2 -derived multi-walled carbon nanotubes and hemp fiber for sustainable building applications

Advanced composite panels represent a promising pathway to reducing carbon emissions in the construction industry, yet comprehensive environmental impact assessments remain limited. Here, in this study, we conduct a life cycle assessment (LCA) to evaluate the environmental impacts of innovative composite panels produced from multi-walled carbon nanotubes (MWCNTs), hemp fiber (HF), recycled carbon fiber (rCF), and recycled polypropylene (PP), exploring their potential as baseline structural equivalents to conventional gypsum board. MWCNTs and HF play a critical role in sequestering carbon during raw material production, while the recycling processes for CF and PP generally require less energy compared to virgin material production. The LCA evaluates environmental performance using the TRACI 2.1 method, covering global warming potential (GWP), ozone depletion, smog formation, acidification, eutrophication, carcinogenic and non-carcinogenic effects, respiratory impacts, ecotoxicity, and fossil fuel depletion. Compositional variations—resin type (virgin vs. recycled), rCF content (9–29 wt%), and HF content (10–30 wt%)—are introduced for sensitivity and hotspot analyses. Results demonstrate that, when compared on the basis of preliminary structural equivalence, increasing recycled PP, rCF, and HF content can significantly reduce global warming potential compared to gypsum board. Beyond carbon reduction, the composite panels show trade-offs across other environmental categories. With the growing demand for composite materials in interior panels, ceiling systems, and exterior claddings, these findings highlight the environmental benefits and potential trade-offs of the proposed composites, establishing a foundational framework to support their continued development toward full building-system integration.

Advanced composite manufacturing↗

Energy, greenhouse gas, and water life cycle analysis of lithium carbonate and lithium hydroxide monohydrate from brine and ore resources and their use in lithium ion battery cathodes and lithium ion batteries

Life cycle analyses (LCAs) were conducted for battery-grade lithium carbonate (Li 2 CO 3 ) and lithium hydroxide monohydrate (LiOH·H 2 O) produced from Chilean brines (Salar de Atacama) and Australian spodumene ores. The LCA was also extended beyond the production of Li 2 CO 3 and LiOH·H 2 O to include battery cathode materials as well as full automotive traction batteries to observe the effect that the lithium production pathways had on these end products. The LCA here covers material, water, and energy flows associated with lithium acquisition; lithium concentration; production of lithium chemicals, battery cathode powders, and batteries; and associated transportation activities along the supply chain. Based on battery cathode material, the difference in lithium source represents a difference of up to 20% for NMC811 cathode greenhouse gases (GHGs) and up to 45% for NMC622 cathode GHGs. For full batteries, this represents a difference of up to 9% for NMC811 batteries and 20% for NMC622 batteries. Production of Li 2 CO 3 from brine-based resources had less life cycle GHG emissions and freshwater consumption per tonne of Li 2 CO 3 than Li 2 CO 3 from ore-based resources. And LiOH·H 2 O produced from brine-based lithium also had less life cycle GHG emissions and freshwater consumption per tonne of LiOH·H 2 O than LiOH·H 2 O from ore-based resources.

25 ENERGY STORAGE↗