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NASA NTRS2003

Laboratory Studies of Heterogeneous Chemical Processes of Atmospheric Importance

The objective of this study is to conduct measurements of chemical kinetics parameters for heterogeneous reactions of importance in the stratosphere and the troposphere. It involves the elucidation of the mechanism of the interaction of HC1 vapor with ice surfaces, which is the first step in the heterogeneous chlorine activation processes, as well as the investigation of the atmospheric oxidation mechanism of soot particles emitted by biomass and fossil fuels. The techniques being employed include turbulent flow- chemical ionization mass spectrometry and optical ellipsometry, among others. The next section summarizes our research activities during the first year of the project, and the section that follows consists of the statement of work for the second year.

Molina, Mario J.↗

NASA NTRS1989

Solar activity influence on cosmic ray penetration in the middle atmosphere

A new improved model for cosmic rays-middle atmosphere interaction is developed. The ionization q(h)-profile dependence on penetrating high energy particles composition (protons, alpha-particles and heavier nuclei) and energy spectra (solar activity modulation included) are investigated. A computer program, realizing the Gaussian algorithm for solving of multidimensional integrals is created. The corresponding electron density profiles N(h) at solar minimum and maximum are obtained.

Vellinov, P. I.↗

NASA NTRS1973

Rates and mechanisms of the atomic oxygen reaction with nickel at elevated temperatures

The oxidation of nickel by atomic oxygen at pressure from 1 to 45 N/sq m between 1050 and 1250 K was investigated. In these ranges, the oxidation was found to follow the parobolic rate law, viz., K sub p = 0.0000114 exp(-13410/T) g squared/cm4/sec for films of greater than 1 micron thickness and was pressure independent. The activation enthalpy for the oxidation reaction was 112 + or - 11 kj/mole (27 + or - 3 kcal/mole). Of a number of possible mechanisms and defect structures considered, it was shown that the most likely was a saturated surface defect model for atomic oxidation, based on reaction activation enthalpies, impurity effects, pressure independence, and magnitudes of rates. A model judged somewhat less likely was one having doubly ionized cationic defects rate controlling in both atomic and molecular oxygen. From comparisons of the appropriate processes, the following enthalpy values were derived: enthalpy of activation (Ni diffusion in Ni0) = 110 + or - 30 kj/mole and standard enthalpy change for reaction formation (doubly ionized cation vacancies in Ni0 from atomic oxygen)= -9 + or - 25 kj/mole.

Christian, J. D.↗

NASA NTRS1972

Experimental active and passive dosimetry systems for the NASA Skylab program

Active and passive dosimetry instrumentation to measure absorbed dose, charged particle spectra, and linear energy transfer spectra inside the command module and orbital workshop on the Skylab program were developed and tested. The active dosimetry system consists of one integral unit employing both a tissue equivalent ionization chamber and silicon solid state detectors. The instrument measures dose rates from 0.2 millirad/hour to 25 rads/hour, linear energy transfer spectra from 2.8 to 42.4 Kev/micron, and the proton and alpha particle energy spectra from 0.5 to 75 Mev. The active dosimeter is equipped with a portable radiation sensor for use in astronaut on-body and spacecraft shielding surveys during passage of the Skylab through significant space radiations. Data are transmitted in real time or are recorded by onboard spacecraft tape recorder for rapid evaluation of the radiation levels. The passive dosimetry systems consist of twelve (12) hard-mounted assemblies, each containing a variety of passive radiation sensors which are recoverable at the end of the mission for analysis.

Schneider, M. F.↗

NASA NTRS1993

Lightning-induced effects on VLF/LF radio propagation

In recent years, at least two different ways in which energy from lightning discharges couples into the lower ionosphere and the radiation belts have come to the fore. In this paper, we briefly review these recent results especially from the point of view of their effects on VLF/LF radio propagation in the earth-ionosphere wave guide. We separately discuss two different mechanisms of coupling, namely lightning-induced electron precipitation, and lightning-induced heating and ionization of the lower ionosphere. We also discuss a planned active VLF wave-injection experiment designed to investigate ionospheric heating by VLF waves under controlled conditions and to generate ELF waves by modulated VLF heating.

Inan, U. S.↗

NASA NTRS1999

DK UMa: A Star on the Ascent

DK UMa (= 24 UMa = HD 82210) is a G4 IV-III star. According to its M(sub v) and B - V color, it is located at the base of the red giant branch, having recently exited from the Hertzsprung Gap. Now poised to start its first ascent along the giant branch, DK UMa is at a significant juncture in its post-main-sequence evolution, offering an important evolutionary comparison for magnetic activity with stars like 31 Comae, which is just entering the Hertzsprung Gap, and older stars like the Hyades giants or P Ceti, which have passed the tip of the giant branch and lie in the so-called 'clump'. As part of a major survey of the ultraviolet and X ray properties of a well-defined sample of evolved giant stars, DK UMa was observed with the Extreme Ultraviolet Explorer (EUVE) spacecraft in March 1997, for a total exposure time of 230 kiloseconds. A plot of the extracted short-wavelength (SW) spectrum of this star is shown, where it is compared with similar EUVE exposures for other yellow and red giant stars in the activity survey. In terms of the spectral lines of different ionization stages present in these spectra, the transition region and coronal temperature of DK UMa appears to be intermediate between those of 31 Com and P Ceti. Combining the relative strengths of the EUVE lines with Hubble Space Telescope (HST) data at near UV wavelengths and with ROSAT X-ray fluxes, the differential emission measure (DEM) distributions of these stars form a sequence in coronal temperature, which peaks at 10(exp 7.2) K for 31 Com, at 10(exp 6.8) K for B Ceti, and at intermediate temperatures for DK UMa - consistent with the evolutionary stages represented by the three stars. The integrated fluxes of the strongest emission lines found in the EUVE spectrum of DK UMa are listed, again compared with similar measurements for other giant stars that were observed in the course of other EUVE Guest Observer programs.

Simon, Theodore↗

NASA NTRS2002

MALDI TOF MS: An Exobiology Surface-Science Approach for Europa

If Europa is to be of primary exobiological interest, namely as a habitat for extant life, it is obvious that: (i) a hydrosphere must prevail beneath the cryosphere for a long time, (ii) internal energy sources must be present in a sufficient state of activity, and (iii) a reasonable technical means must be available for assessing if indeed life does exist in the hypothesized hydrosphere. This discussion focuses on technological issues, because the compounding evidence about Europa indicates that the first two are highly likely to be true. We present a consideration of time-of-flight mass spectroscopy (TOF MS) conducted in-situ on the cryosphere surface of Europa during a landed robotic mission. We assert that this is a reasonable technical means not only for exploring the composition of the cryosphere itself, but also for locating any biomolecular indicators of extant life brought to the surface through cryosphere activity. We also describe a MALDI (MAtrix Laser Desorption and Ionization) TOF MS system that we are constructing as a proof-of-concept prototype for conducting TOF MS measurements on Europa.

Gerakines, Perry A.↗

NASA NTRS2007

Effect of Thermospheric Neutral Density upon Inner Trapped-belt Proton Flux

We wish to point out that a secular change in the Earth's atmospheric neutral density alters charged-particle lifetime in the inner trapped radiation belts, in addition to the changes recently reported as produced by greenhouse gases. Heretofore, changes in neutral density have been of interest primarily because of their effect on the orbital drag of satellites. We extend this to include the orbital lifetime of charged particles in the lower radiation belts. It is known that the charged-belt population is coupled to the neutral density of the atmosphere through changes induced by solar activity, an effect produced by multiple scattering off neutral and ionized atoms along with ionization loss in the thermosphere where charged and neutral populations interact. It will be shown here that trapped-belt flux J is bivariant in energy E and thermospheric neutral density , as J(E,rho). One can conclude that proton lifetimes in these belts are also directly affected by secular changes in the neutral species populating the Earth s thermosphere. This result is a consequence of an intrinsic property of charged-particle flux, that flux is not merely a function of E but is dependent upon density rho when a background of neutrals is present.

Wilson, Thomas L.↗

NASA NTRS2011

Ionization Processes in the Atmosphere of Titan (Research Note). III. Ionization by High-Z Nuclei Cosmic Rays

Context. The Cassini-Huygens mission has revealed the importance of particle precipitation in the atmosphere of Titan thanks to in-situ measurements. These ionizing particles (electrons, protons, and cosmic rays) have a strong impact on the chemistry, hence must be modeled. Aims. We revisit our computation of ionization in the atmosphere of Titan by cosmic rays. The high-energy high-mass ions are taken into account to improve the precision of the calculation of the ion production profile. Methods. The Badhwahr and O Neill model for cosmic ray spectrum was adapted for the Titan model. We used the TransTitan model coupled with the Planetocosmics model to compute the ion production by cosmic rays. We compared the results with the NAIRAS/HZETRN ionization model used for the first time for a body that differs from the Earth. Results. The cosmic ray ionization is computed for five groups of cosmic rays, depending on their charge and mass: protons, alpha, Z = 8 (oxygen), Z = 14 (silicon), and Z = 26 (iron) nucleus. Protons and alpha particles ionize mainly at 65 km altitude, while the higher mass nucleons ionize at higher altitudes. Nevertheless, the ionization at higher altitude is insufficient to obscure the impact of Saturn s magnetosphere protons at a 500 km altitude. The ionization rate at the peak (altitude: 65 km, for all the different conditions) lies between 30 and 40/cu cm/s. Conclusions. These new computations show for the first time the importance of high Z cosmic rays on the ionization of the Titan atmosphere. The updated full ionization profile shape does not differ significantly from that found in our previous calculations (Paper I: Gronoff et al. 2009, 506, 955) but undergoes a strong increase in intensity below an altitude of 400 km, especially between 200 and 400 km altitude where alpha and heavier particles (in the cosmic ray spectrum) are responsible for 40% of the ionization. The comparison of several models of ionization and cosmic ray spectra (in intensity and composition) reassures us about the stability of the altitude of the ionization peak (65 km altitude) with respect to the solar activity.

Gronoff, G.↗

NASA NTRS2018

Effect of Additives: Gamma-Ray Sensors Based on Ionizing Organic Nanocomposites

We have developed ionizing organic-based composites which have demonstrated great promise for radiation sensing. Nickel oxide has been proven as an active material for detecting high energy radiation. The oxidation state of unusual oxides such as nickel oxide in nanocomposites of ionizing organics changes much faster than thin film or bulk, and hence increases the sensitivity for radiation sensing. The resistivity of the oxide composite increases following sequential irradiation processes because of the decrease in holes' concentration. In this paper, we will present the effect of additional oxidizing agent on the morphology, processing and sensing of gamma-rays by oxides - urea based nanocomposites. It was observed that addition of MnO2 decreases the sensitivity. However, it recovers to original properties after irradiation much faster than undoped composites.

Vishall Dayal↗

NASA NTRS2011

Improvements to the Ionizing Radiation Risk Assessment Program for NASA Astronauts

To perform dosimetry and risk assessment, NASA collects astronaut ionizing radiation exposure data from space flight, medical imaging and therapy, aviation training activities and prior occupational exposure histories. Career risk of exposure induced death (REID) from radiation is limited to 3 percent at a 95 percent confidence level. The Radiation Health Office at Johnson Space Center (JSC) is implementing a program to integrate the gathering, storage, analysis and reporting of astronaut ionizing radiation dose and risk data and records. This work has several motivations, including more efficient analyses and greater flexibility in testing and adopting new methods for evaluating risks. The foundation for these improvements is a set of software tools called the Astronaut Radiation Exposure Analysis System (AREAS). AREAS is a series of MATLAB(Registered TradeMark)-based dose and risk analysis modules that interface with an enterprise level SQL Server database by means of a secure web service. It communicates with other JSC medical and space weather databases to maintain data integrity and consistency across systems. AREAS is part of a larger NASA Space Medicine effort, the Mission Medical Integration Strategy, with the goal of collecting accurate, high-quality and detailed astronaut health data, and then securely, timely and reliably presenting it to medical support personnel. The modular approach to the AREAS design accommodates past, current, and future sources of data from active and passive detectors, space radiation transport algorithms, computational phantoms and cancer risk models. Revisions of the cancer risk model, new radiation detection equipment and improved anthropomorphic computational phantoms can be incorporated. Notable hardware updates include the Radiation Environment Monitor (which uses Medipix technology to report real-time, on-board dosimetry measurements), an updated Tissue-Equivalent Proportional Counter, and the Southwest Research Institute Radiation Assessment Detector. Also, the University of Florida hybrid phantoms, which are flexible in morphometry and positioning, are being explored as alternatives to the current NASA computational phantoms.

Semones, E. J.↗

NASA NTRS2013

Variability of a Stellar Corona on a Time Scale of Days: Evidence for Abundance Fractionation in an Emerging Coronal Active Region

Elemental abundance effects in active coronae have eluded our understanding for almost three decades, since the discovery of the first ionization potential (FIP) effect on the sun. The goal of this paper is to monitor the same coronal structures over a time interval of six days and resolve active regions on a stellar corona through rotational modulation. We report on four iso-phase X-ray spectroscopic observations of the RS CVn binary EI Eri with XMM-Newton, carried out approximately every two days, to match the rotation period of EI Eri. We present an analysis of the thermal and chemical structure of the EI Eri corona as it evolves over the six days. Although the corona is rather steady in its temperature distribution, the emission measure and FIP bias both vary and seem to be correlated. An active region, predating the beginning of the campaign, repeatedly enters into our view at the same phase as it rotates from beyond the stellar limb. As a result, the abundances tend slightly, but consistently, to increase for high FIP elements (an inverse FIP effect) with phase. We estimate the abundance increase of high FIP elements in the active region to be of about 75% over the coronal mean. This observed fractionation of elements in an active region on time scales of days provides circumstantial clues regarding the element enrichment mechanism of non-flaring stellar coronae.

Nordon, R.↗

NASA NTRS2004

Ionization Cross Sections and Dissociation Channels of DNA Bases by Electron Collisions

Free secondary electrons are the most abundant secondary species in ionizing radiation. Their role in DNA damage, both direct and indirect, is an active area of research. While indirect damage by free radicals, particularly by the hydroxyl radical generated by electron collision with water. is relatively well studied, damage by direct electron collision with DNA is less well understood. Only recently Boudaiffa et al. demonstrated that electrons at energies well below ionization thresholds can induce substantial yields of single- and double-strand breaks in DNA by a resonant, dissociative attachment process. This study attracted renewed interest in electron collisions with DNA, especially in the low energy region. At higher energies ionization becomes important. While Monte Carlo track simulations of radiation damage always include ionization, the probability of dissociative ionization, i.e., simultaneous ionization and dissociation, is ignored. Just like dissociative attachment, dissociative ionization may be an important contributor to double-strand breaks since the radicals and ions produced by dissociative ionization, located in the vicinity of the DNA coil, can readily interact with other parts of the DNA. Using the improved binary-encounter dipole (iBED) formulation, we calculated the ionization cross sections of the four DNA bases, adenine, cytosine, guanine, and thymine, by electrons at energies from threshold to 1 KeV. The present calculation gives cross sections approximately 20% lower than the results by Bemhardt and Paretzke using the Deutsch-Mark and Binary-Encounter-Bethe (BEB) formalisms. The difference is most likely due to the lack of a shielding term in the dipole potential used in the Deutsch-Mark and BEB formalisms. The dissociation channels of ionization for the bases are currently being studied.

Huo, Winifred M.↗

NASA NTRSDate not supplied

Stellar Energetic Particle-driven Production of Biologically Relevant Molecules in Atmospheres of Young Earth-like Exoplanets Around Active G-K Stars

The chemistry of N2, CO2, CH4-rich atmospheres of terrestrial-type exoplanets around active G-K stars is a complex problem: the star's ionizing radiation in the form of X-ray and Extreme UV radiation and the precipitating energetic particles accelerated in coronal mass ejection driven shocks can drive complex chemistry in the exoplanetary atmosphere, and ignite the production of complex molecules (Airapetian et al., 2016). We developed a set of atmospheric models to simulate the formation of organic molecules that can be considered as atmospheric pre-biosignatures from exoplanets around active stars. The model has recently been extended to account for the production of ions, their role in the enhanced chemistry in the lower atmosphere, as well as the interaction of these ions with the aerosols. We applied the photochemical-collisional model to simulate the chemistry of a young terrestrial-type exoplanets resembling the Hadean Earth to highlight the creation of atmospheric pre-biosignatures, relevant greenhouse gases, and the presence of aerosols driven by stellar activity sources. We also discuss the impact of that modified atmospheric chemistry on the exoplanetary climate.

Guillaume Philippe Gronoff↗

NASA NTRS2011

First Detections of the [N II] 122 micron Line at High Redshift: Demonstrating the Utility of the Line for Studying Galaxies in the Early Universe

We report the first detections of the [N II] 122 micron line from a high-redshift galaxy. The line was strongly (>6(sigma)) detected from SMMJ02399-0136, and H1413 + 117 (the Cloverleaf QSO) using the Redshift (zeta) and Early Universe Spectrometer on the Caltech Submillimeter Observatory. The lines from both sources are quite bright with line to far-infrared (FIR) continuum luminosity ratios that are approx.7.0 x 10(exp -4) (Cloverleaf) and 2.1 x 10(exo -3) (SMMJ02399). With ratios 2-10 times larger than the average value for nearby galaxies, neither source exhibits the line to continuum deficits seen in nearby sources. The line strengths also indicate large ionized gas fractions, approx.8%-17% of the molecUlar gas mass. The [O III]/[N II] line ratio is very sensitive to the effective temperature of ionizing stars and the ionization parameter for emission arising in the narrow-line region (NLR) of an active galactic nucleus (AGN). Using Our previous detection of the [O III] 88 micron line, the [O III]/[N II]line ratio for SMMJ02399-0136 indicates that the dominant source of the line emission is either stellar H II regions ionized by O9.5 stars, or the NLR of the AGN with ionization parameter log(U) = -3.3 to -4.0. A composite system, where 30%-50% of the FIR lines arise in the NLR also matches the data. The Cloverleaf is best modeled by a superposition of approx.200 M82-like starbursts accounting for all of the FIR emission and 43% of the [N II]line. The remainder may come from the NLR. This war!< demonstrates the utility of the [N II] and [O III] lines in constraining properties of the ionized medium.

Ferkinhoff, Carl↗

NASA NTRS1996

Wind Variability of B Supergiants: The Two-component Stellar Wind of gamma Arae - No. 2

The stellar wind of the rapidly rotating early-B supergiant, gamma Ara, is studied using time series, high-resolution IUE spectroscopy secured over approx. 6 days in 1993 March. Results are presented based on an analysis of several line species, including N(N), C(IV), Si(IV), Si(III), C(II), and Al(III). The wind of this star is grossly structured, with evidence for latitude-dependent mass loss which reflects the role of rapid rotation. Independent, co-existing time variable features are identified at low-velocity (redward of approx. -750 km/s) and at higher-speeds extending to approx. -1500 km/s. The interface between these structures is 'defined' by the appearance of a discrete absorption component which is extremely sharp (in velocity space). The central velocity of this 'Super DAC' changes only gradually, over several days, between approx. -400 and -750 km/s in most of the ions. However, its location is shifted redward by almost 400 km/s in Al(III) and C(II), indicating that the physical structure giving rise to this feature has a substantial velocity and ionization jump. Constraints on the relative ionization properties of the wind structures are discussed, together with results based on SEI line-profile-fitting methods. The overall wind activity in gamma Ara exhibits a clear ion dependence, such that low-speed features are promoted in low-ionization species, including Al(III), C(II), and Si(III). We also highlight that - in contrast to most OB stars - there are substantial differences in the epoch-to-epoch time-averaged wind profiles of gamma Ara. We interpret the results in terms of a two-component wind model for gamma Ara, with an equatorially compressed low ionization region, and a high speed, higher-ionization polar outflow. This picture is discussed in the context of the predicted bi-stability mechanism for line-driven winds in rapidly rotating early-B type stars, and the formation of compressed wind regions in rapidly rotating hot stars. The apparent absence of a substantial shift in the wind ionization mixture of gamma Ara, and the normal nature of its photospheric spectrum, suggests wind-compression as the likely dominant cause for the observed equatorial density enhancements.

Prinja, R. K.↗

NASA NTRS2000

Natural Hazards of the Space Environment

Spacecraft in Low Earth Orbit (LEO) are subject to numerous environmental hazards. Here I'll briefly discuss three environment factors that pose acute threats to the survival of spacecraft systems and crew: atmospheric drag, impacts by meteoroids and orbital debris, and ionizing radiation. Atmospheric drag continuously opposes the orbital motion of a satellite, causing the orbit to decay. This decay will lead to reentry if not countered by reboost maneuvers. Orbital debris is a by-product of man's activities in space, and consists of objects ranging in size from miniscule paint chips to spent rocket stages and dead satellites. Ionizing radiation experienced in LEO has several components: geomagnetically trapped protons and electrons (Van Allen belts); energetic solar particles; galactic cosmic rays; and albedo neutrons. These particles can have several types of prompt harmful effects on equipment and crew, from single-event upsets, latchup, and burnout of electronics, to lethal doses to crew.All three types of prompt threat show some dependence on the solar activity cycle. Atmospheric drag mitigation and large debris avoidance require propulsive maneuvers. M/OD and ionizing radiation require some form of shielding for crew and sensitive equipment. Limiting exposure time is a mitigation technique for ionizing radiation and meteor streams.

Evans, Steven W.↗

NASA NTRS1981

A survey of X-ray line emission from the supernova remnant Puppis A

Initial results from the first high-resolution study of the X-ray spectrum of a supernova remnant are reported. The spectrum of Puppis A between 500 and 1100 eV has been surveyed with the Focal Plane Crystal Spectrometer on the Einstein Observatory and the flux in eight lines and three line blends from various transitions of highly ionized nitrogen, oxygen, neon, and iron has been measured. The spectrum resembles that of active regions in the solar corona, but the neon lines seem enhanced relative to the oxygen lines, and both are enhanced relative to iron. The observed line strengths serve as diagnostics of the physical conditions in the emitting material. Without a priori assumptions, the ionization temperatures of O (2.2 million K) and Ne (4 million K) and the dominant ionization stage of Fe (Fe XVII) are deduced. Isothermal equilibrium plasmas or homogeneous nonequilibrium plasmas as descriptions of the source are ruled out. It is concluded that Puppis A must contain plasma over a temperature range 2-million to 5-million K with an intervening absorption column of 4 x 10 to the 21st/sq cm.

Winkler, P. F.↗