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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Phonon excitations in Eu 2 Ir 2 O 7 probed by inelastic x-ray scattering

The study of phonon dynamics and its interplay with magnetic ordering is crucial for understanding the unique quantum phases in the pyrochlore iridates. Here, through inelastic x-ray scattering on a single crystal sample of the pyrochlore iridate Eu 2 Ir 2 O 7 , we map out the phonon excitation spectra in Eu 2 Ir 2 O 7 and compare them with the theoretical phonon spectra calculated using the density functional theory. Further, possible phonon renormalization across the magnetic long-range order transition is observed in our experiments, which is consistent with the results of the previous Raman scattering experiments.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Persistent short-range spin fluctuation in rare-earth substituted square lattice Sr 2 ⁢Ir 0.89 ⁢Tb 0.11⁢ O 4

Sr 2 ⁢IrO 4 , a prototypical 𝐽 eff = 1/2 square lattice system, is widely studied for novel physics. While transition metal substitution effects are well explored, rare-earth doping at the Ir 4+ site is less explored. Here we present a detailed magnetization and neutron diffraction study on Sr 2 ⁢Ir 1−𝑥 ⁢Tb 𝑥 ⁢O 4 (𝑥 = 0.11). The system tends to adopt an in-plane antiferromagnetic configuration with a “++++” stacking sequence. Strong spin fluctuations persist down to the lowest measured temperature, consistent with the concave shape order parameter. A pronounced magnetic diffuse scattering rod develops along the 𝐿 direction at low temperature, indicating the formation of short-range magnetic correlations with a characteristic length of ∼ 24⁢(2) ⁢Å. In conclusion, this work provides a new pathway to exotic quantum phases in the strongly spin-orbit-coupled iridates.

Iridates↗
DOE OSTI2025

Understanding the optoelectronic properties of doped 2D organic-inorganic halide perovskite quantum wells: towards efficient quantum well IR photodetectors

Metal halide perovskite (MHP) multiple quantum wells which consist of multilayers of alternate organic and inorganic layers exhibit large exciton binding energies due to the dielectric confinement between the inorganic and organic layers. These naturally formed multiple quantum wells have strong spin-orbit coupling (SOC) due to the presence of heavy elements in their crystal structures. Although the fundamental properties of 2D MHPs are far from being entirely understood, it is widely accepted that their band edge absorption coefficient results from strong exciton interactions. However, studies demonstrating how different exciton interactions and doping effects influence electronic traps and disorder on the band edge absorption coefficient of 2D MHPs have not been demonstrated. Understanding these interactions in MHPs will allow us to access low energy optical transitions for the fabrication of solution processable short-to-mid-wavelength IR photodetectors (1 – 8 μm). Moreover, upon doping, it is possible to move the Fermi energy into the conduction band (CB) to favorably promote the transport of charges in a working device. Herein, we study the development of 2D MHPs having strong SOC, high carrier mobility, and tunable quantum well structures. Our studies shed light on the design and modulation of fundamental physical phenomena by carefully elucidating the role of dopants (n-type and p-type), exciton heterogeneity, orientation, structure, and bias stress effects on the performance of MHPs as potential IR photodetectors.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Understanding the optoelectronic properties of doped 2D organic-inorganic halide perovskite quantum wells: towards efficient ultrafast quantum well IR photodetectors

This project, titled “Understanding the optoelectronic properties of doped 2D organic-inorganic halide perovskite quantum wells: towards efficient quantum well IR photodetectors”, was funded by the U.S. Department of Energy to explore a new class of materials that could make future light-sensing technologies, such as infrared (IR) cameras and detectors more efficient, affordable, and widely available. The research focused on special layered materials called 2D halide perovskites, which are made up of alternating organic and inorganic layers only a few atoms thick. These materials can be tuned at the atomic level to absorb and emit light in precise ways, making them very attractive for use in optoelectronic devices. The main goal of the project was to understand how these perovskite materials absorb light and move electrical charges at very small scales. However, this is not an easy task. These materials often contain a mixture of different structures in the same film, and traditional tools like regular absorption or photoluminescence spectroscopy are not good at telling those structures apart. To solve this, the research team, led by Professor Luisa Whittaker-Brooks at the University of Utah developed a powerful method called electroabsorption spectroscopy. This technique uses electric fields to highlight the unique “fingerprints” of different excitons, which are tiny packets of energy formed when light hits the material. By using this method, the team could separate overlapping signals and learn exactly how the materials respond to light under different conditions, including changes in temperature, thickness, and chemical makeup.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Autonomous Infrared and Small (Wide) Angle X-Ray Scattering (IR-S(W)AXS) Capability

Thin water films are 2-D, nanoconfined layers that form on solid surfaces exposed to humid atmospheres—environments ubiquitous across catalysis, corrosion science, soil science, and subsurface geochemistry. At relative humidity (RH) values below saturation, these films are Å–nm thick and exhibit properties that differ sharply from bulk water, including disrupted H-bonding and impeded mass transport. Owing to their high surface-to-volume ratio, dissolution of the solid can rapidly drive strong supersaturation with respect to secondary phases. Reactivity in thin water films is highly sensitive to film thickness, and critically, thickness evolves during reaction because the hygroscopicity of the interfacial system changes as ions accumulate or diminish in the film and as reaction products transform. To accurately probe and control these dynamics, a capability is needed that can measure and automatically maintain a constant water-film thickness while simultaneously monitoring solid dissolution, nucleation, and growth. This project developed an autonomous Infrared/Small Angle X-ray Scattering-Wide Angle X-ray Scattering (IR/(W)SAXS) for investigating reactivity in thin water films on solid surfaces exposed to humidified gases. The capability consists of an IR spectrometer, a (W)SAXS instrument, and a mass flow controller system for generating variably humidified gas flows to a custom reaction cell. Progress on each of the major components of the capability are detailed below.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

SABRE Ir-IMes Catalysis for the Masses

The Signal Amplification By Reversible Exchange (SABRE) technique provides enhancement of Nuclear Magnetic Resonance (NMR) signals up to several orders of magnitude using chemical exchange of a substrate and parahydrogen on an iridium complex. Therefore, the availability of such a catalytic complex to a broader community is an absolutely vital step for dissemination of the groundbreaking SABRE methodology. The most common SABRE catalyst, which is activated in situ, is based on Ir-IMes system (IMes = 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene). Earlier approaches for the synthesis of this catalyst often relied on specialized equipment and were limited to a comparatively small scale. This, in turn, increased the barrier of entry for new scientists to the area of SABRE hyperpolarization. Here, we present a robust, inexpensive, and easy to reproduce synthetic procedure for the preparation of this SABRE catalyst, which does not require specialized inert atmosphere equipment like a glove box or Schlenk line. The synthesis was validated on the scale of several grams vs. tens of milligrams scale in the reported approaches. The resulting SABRE catalyst, [Ir(IMes)(COD)Cl], was activated in situ and further evaluated in hyperpolarization experiments resulting in signal enhancements comparable to (or higher than) those for the catalyst prepared using Schlenk line equipment.

Biochemistry & Molecular Biology↗
NASA NTRS1967

IR vidicon scanner monitors many test points

Infrared /IR/ scanners are used in test systems that involve many signal paths from transducers to a central evaluation point. The scanner, an IR-sensitive vidicon, looks at the indicator panels of each subsystem of the equipment being tested and picks up the level of radiation from each IR source mounted thereon.

Fortier, R. J.↗
NASA NTRS1972

Evidence for association between Ir and Al in L chondrites.

The nature of the Al-Ir association was investigated by plotting the whole chondrite abundance of Ir as determined by Mueller et al. (1971), and the Al abundance for the same chondrites. Ten of the 11 L chondrites plotted show a definite positive trend. The results are most consistent with the condensation mechanism of Larimer (1967) and the prediction of Larimer and Anders (1970).

Osborn, T. W.↗
NASA NTRS1972

Flight test evaluation and analysis of an optical IR PWI system

The flight test results of the optical infrared (IR) Pilot Warning Instrument (PWI) system are presented. The test program is described and the flight test data presented. The data is analyzed and used to calibrate a model that is developed to characterize the system performance. The cumulative probability of detection versus range from a given system threshold is calculated and compared with the PWI performance specification. The comparison indicates that the Optical IR PWI system tested met the specifications for a detection likelihood of 95 percent for a 1 nmi range for an appreciable fraction of the testing time.

Phillips, C. O.↗
NASA NTRS1976

Noise analysis of spaceborne IR spatial interferometer

Analysis is performed to determine the relationship between the signal-to-noise ratio and the integration time for a spaceborne IR heterodyne spatial interferometer. The analysis includes consideration of the transformation of the interferogram to obtain the angular intensity distribution. The results presented show that for an IR source such as IRC + 10216, an integration time of 50 seconds per interferogram point will yield a signal-to-noise ratio greater than 10 dB in the angular intensity profile obtained from a 30-point transformation.

Wolfe, R. H., Jr.↗
NASA NTRS1977

The application of IR- and MSS-data in the Ruhr District, Germany

The methods used by Ruhr Planning Authority to interpret IR pictures are described along with production of maps indicating the thermal distribution in the conurbation. Topics studied with the IR data include thermal loading of the Rhine and climatology of the urban and surrounding country areas.

Stock, P.↗
NASA NTRS1978

Remote sensing of the ozone profile in the lower stratosphere using UV and IR measurements from Nimbus-4

A method of combining the information from the infrared interferometer spectrometer (IRIS) and the backscatter ultraviolet spectrometer (BUV) on board the Nimbus-4 satellite to derive the ozone profile from 10 mb to surface is described. The radiance in the IRIS 9-micron band can be related to the ozone profile by the radiative transfer equation. The IR intensity due to ozone is dependent on the pressure broadening of spectral lines, and an estimate of a weighted mean pressure of the ozone layer can be obtained from total ozone supplied by BUV long wave intensity measurements. With the aid of the Chapman function, a model of the ozone concentration profile described by three parameters is obtained. Given the ozone concentration at 10 mb one calculates several possible combinations of the three parameters that can produce the required total ozone, and the final choice of parameter is determined from IR measurements. An ozone profile calculated in this way reproduces well the gross features of balloon ozone sounding results. Meridional cross sections of ozone concentration have also been derived which are in reasonably good agreement with balloon-derived cross-section for the northern latitudes and tropics.

Prabhakara, C.↗
NASA NTRS1979

Exposure time for space-borne IR spatial interferometer

A mathematical analysis is performed to determine the relationship between the signal-to-noise ratio and the exposure time for an orbiting IR heterodyne spatial interferometer. The analysis includes consideration of the transformation of the interferogram to obtain the source angular intensity distribution so that the signal-to-noise ratio pertains to the angular distribution rather than to the interferogram. The analysis is applied to a number of known IR sources. The results presented show that an interferometer with a 30-m baseline using half-meter telescopes should be able to image a source such as IRC + 30219 with a signal-to-noise ratio of 10 in a total exposure time of less than an hour.

Wolfe, R. H., Jr.↗
NASA NTRS1980

Modeling of growth, evaporation and sedimentation effects on transmission of visible and IR laser beams in artificial fogs

The dense polydisperse aerosol particles in a quiet chamber may spontaneously go through different microphysical processes including gravitational sedimentation, thermal coagulation, and growth or evaporation. In an earlier paper, we presented the results of a parametric study of the combined and separate effects of thermal coagulation and sedimentation on the time dependence of extinction of four visible and IR laser beams traversing an aerosol medium. As a continuation of this series of studies, the separate and combined effects of growth or evaporation and gravitational sedimentation on the time dependence of extinction of the same four visible and IR laser beams traversing in artificial fogs will be reported in this paper. The method of numerically modeling the change of water droplet size distribution with time due to growth/evaporation and the cutoff of larger aerosols due to gravitational sedimentation is described in detail. Factors governing the relative importance of these two processes are discussed. Results of this study show that the relative humidity or ambient temperature is a crucial parameter in determining the optical depth of the water droplet and aerosol media undergoing microphysical processes.

Yue, G. K.↗
NASA NTRS1981

Design and preliminary tests of an IR-airborne LLWS remote sensing system

Recent history underscores the need for in-cockpit alerts of LLWS for takeoffs and landings. The 13-15 micron portion of the CO2 molecular spectrum can be used to remote sense LLWS in and around thunderstorms. A radiometer with a designed look-distance of about 10 km remote senses an average air temperature along a forward, horizontal path. Wind shear alerts are based on the difference between this forward air temperature and the air temperature near the aircraft. Although spectral ranging, a major design improvement of an IR LLWS alert system, is not at present feasible with noncooled detectors, it is an important technique to keep in mind, given the rapid advance in IR technology.

Caracena, F.↗
NASA NTRS1981

Thermal IR exitance model of a plant canopy

A thermal IR exitance model of a plant canopy based on a mathematical abstraction of three horizontal layers of vegetation was developed. Canopy geometry within each layer is quantitatively described by the foliage and branch orientation distributions and number density. Given this geometric information for each layer and the driving meteorological variables, a system of energy budget equations was determined and solved for average layer temperatures. These estimated layer temperatures, together with the angular distributions of radiating elements, were used to calculate the emitted thermal IR radiation as a function of view angle above the canopy. The model was applied to a lodgepole pine (Pinus contorta) canopy over a diurnal cycle. Simulated vs measured radiometric average temperatures of the midcanopy layer corresponded with 2 C. Simulation results suggested that canopy geometry can significantly influence the effective radiant temperature recorded at varying sensor view angles.

Kimes, D. S.↗
NASA NTRS1981

Quasi-simultaneous observations of BL Lac object Mrk 501 in X-ray, UV, visible, IR, and radio frequencies

Observations in the X-ray, UV, visible, IR and radio regions of the BL Lac object Mrk 501 made over the course of two months are reported. The measurements were made with the A2 experiment on HEAO 1 (X-ray), the SWP and LWR cameras on IUE (UV), the 5-m Hale telescope (visible), the 2.5-m telescope at Mount Wilson (IR), the NRAO 92-m radio telescope at Green Bank (4750 MHz) and the 46-m radio telescope at the Algonquin Observatory (10275 and 10650 MHz). The quasi-simultaneously observed spectral slope is found to be positive and continuous from the X-ray to the UV, but to gradually flatten and possibly turn down from the mid-UV to the visible; the optical-radio emission cannot be accounted for by a single power law. The total spectrum is shown to be compatible with a synchrotron self-Compton emission mechanism, while the spectrum from the visible to the X-ray is consistent with synchrotron radiation or inverse-Compton scattering by a hot thermal electron cloud. The continuity of the spectrum from the UV to the X-ray is noted to imply a total luminosity greater than previous estimates by a factor of 3-4.

Kondo, Y.↗
NASA NTRS1980

Thermal IR imaging system using a self-scanned HgCdTe/CCD detector array

It is likely that future high resolution earth observation imaging systems will utilize self-scanned IR detectors. In an initial step toward this goal, an IR imaging system operating in the 10 to 12 micron spectral region has been developed. This system uses a 9-element HgCdTe/CCD linear array operating in the photoconductive mode, nine pre-amplifiers and a silicon CCD multiplexer integrated into a focal plane assembly. Opto-mechanical techniques are used to scan the scene and images are produced in real time. The imaging performance of this system is described and measurements of noise, responsivity, specific detectivity, and detector sensitivity profiles are presented. The requirements for more advanced detector arrays for use in future NASA remote sensing missions are also discussed.

Husain-Abidi, A. S.↗