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At least 163 records · Page 9

The abundances of elements and isotopes in the solar wind

Solar wind abundances have now been measured for eleven elements and the isotopes of the noble gases. Aside from solar wind protons and alpha particles, which have been studied extensively since the 1960's, information for heavier elements is limited. Nevertheless, two effects stand out. First is the enrichment of abundances of elements with low first ionization potential (FIP), most likely the combined result of an atom-ion separation process in the upper chromosphere, and a marginal coupling of low-charge-state heavy ions to protons and alphas during the acceleration of the solar wind. Second, there is variability in the solar wind composition over a whole range of time scales. Recent measurements carried out in the earth's magnetosheath during times that included high-speed coronal-hole-associated flows indicate a significantly lower overabundance of low FIP elements. Given the fact that the He/H ratio is remarkably constant in the coronal hole solar wind, this result suggests that both enrichment and variability are reduced in such flows.

Gloeckler, George↗

Solar abundances as derived from solar energetic particles

Recent studies have shown that there are well defined average abundances of heavy (Z above 2) solar energetic particles (SEPs), with variations in the acceleration and propagation producing a systematic flare-to-flare fractionation that depends on the charge per unit mass of the ion. Correcting the average SEP abundances for this fractionation yields SEP-derived coronal abundances for 20 elements. High-resolution SEP studies have also provided isotopic abundances for five elements. SEP-derived abundances indicate that elements with high first ionization potentials (greater than 10 eV) are depleted in the corona relative to the photosphere and provide new information on the solar abundance of C and Ne-22.

Stone, E. C.↗

Observations of molecular and atomic gas in photodissociation regions

Dense gas at the ionized/neutral boundaries of molecular clouds illuminated by far-UV photons plays an important role in the appearance of the neutral interstellar medium. It also is a laboratory for the study of UV-photochemistry and of a number of heating and cooling phenomena not seen elsewhere. Fine structure lines of neutral and low ionization potential species dominate the cooling in the outer part of the photodissociation regions. Observations of these lines show that the regions are dense and highly clumped. Observations of H2 and CO show that heating by UV photons plays a significant role in the excitation of molecular lines near the H II/neutral boundary. Warm CO is more abundant in these regions than predicted by the standard theoretical models. Optical reflection nebulas provide an ideal laboratory for the study of photodissocciation region phenomena.

Jaffe, D. T.↗

A SIMS study of lunar 'komatiitic glasses' - Trace element characteristics and possible origin

In Apollo 16 regolith breccias, Wentworth and McKay (1988) identified a suite of minute (less than 120 microns) 'komatiitic glass beads'. The wide major element compositional range, and ultra-Mg-prime character of the glasses suggest a variety of possible origins from complex impact processes to complex volcanic processes involving rather unusual and primitive magmatism. The extent of trace element depletion or enrichment in these glasses appears to be correlated to the siderophile character of the element (ionization potential or experimentally determined silicate melt/Fe metal partition coefficients. The ultra-Mg-prime glasses are depleted in Co relative to a bulk Moon Mg/Co exhibited by many lunar samples (volcanic glasses, basalts, regolith breccia, estimated upper mantle). The low Co and high incompatible element concentrations diminish the possibility that these glasses are a product of lunar komatiitic volcanism or impact, excavation, and melting of a very high Mg-prime plutonic unit.

Shearer, C. K.↗

Theoretical studies of the first- and second-row transition-metal mono- and dicarbonyl positive ions

Ab initio calculations have been carried out on the first- and second-row transition-metal mono- and dicarbonyl positive ions. The bonding in these systems is discussed in detail. Trends in the series of mono- and dicarbonyl ions and between the first- and second-row transition metals are explained in terms of a dominantly electrostatic bonding interaction and differences in metal ion state separations, ionization potentials, and s and d orbital sizes. Dissociation energies are presented and a detailed comparison is made with experimental data. Where reliable experimental data exists, agreement with the theoretical results is generally good.

Barnes, Leslie A.↗

Solar coronal Ar/Fe and Ne/Mg abundance ratios derived from ultraviolet forbidden line spectra

An Ar/Fe abundance ratio of 0.031 + or - 35 percent and an upper limit of 0.4 to the Ne/Mg abundance ratio are determined for solar coronal active regions using solar spectra. Forbidden lines occur at 1324.45 A for Mg V, 1349.38 A for Fe XII, 1375.98 A for Ca XV, and 1392.12 A for Ar XI. The unobserved Ne V line is predicted to fall at 1574.68 A. These abundance ratios are consistent with lower abundances of Ne and Ar in the corona relative to low first ionization potential elements.

Doschek, G. A.↗

The Joint NASA/Goddard-University of Maryland Research Program in Charged Particle and High Energy Photon Detector Technology

The Univ. of Maryland portion investigated the following areas. The Space Physics Group performed studies of data from the AMPTE/CCE spacecraft CHEM experiment and found that the ratio of solar wind to photospheric abundances decreased rather smoothly with the first ionization potential (FIP) of the ion with the low FIP ion being about a factor of two overabundant. Carbon and hydrogen fit this trend particularly well. Several occurrences were analyzed of field aligned beams observed when CCE was upstream of the Earth's bow shock. Also using CHEM data, ring current intensity and composition changes during the main and recovery phases of the great geomagnetic storm that occurred in February 1986 was examined in detail. Still using CHEM data, ring current characteristics were examined in a survey of 20 magnetic storms ranging in size from -50 nT to -312 nT. A study was done of energetic ion anisotropy characteristics in the Earth's magnetosheath region using data from the UMD/MPE experiment on ISEE-1. The properties were analyzed of approx. 30 to 130 keV/e protons and alpha particles upstream of six quasi-parallel interplanetary shocks that passed by the ISEE-3 spacecraft during 1978 to 1979. Work from NASA-Goddard include studies from the High Energy Cosmic Ray Group, Low Energy Cosmic Ray Group, Low Energy Gamma Ray Group, High Energy Astrophysics Theory Group, and the X ray Astronomy Group.

Ipavich, F. M.↗

Studies of the chemistry of the nightside ionosphere of Venus

A combination of numerical modeling and analysis of the Pioneer Venus UADS data base is studied, specifically data from the orbiter ion mass spectrometer (OIMS), orbiter neutral mass spectrometer (ONMS), and orbiter electron temperature probe (OETP). A one dimensional model of the Venus nightside ionosphere was set up in which downward fluxes of atomic ions are introduced at the upper boundary to simulate transport of ions from the dayside. The model shows that the densities of mass-28 ions, CO(+) + N(2+), resulting from an influx of atomic ions from the dayside are quite small, due to the high ionization potentials of CO and N2 that make chemical production difficult. A look at the data reveals that the actual densities of mass-28 ions are quite variable, from values near 10 to more than 10(exp 4) cm(exp -3). The excess mass-28 ions are assumed to be produced by electron precipitation and that the presence of high densities of mass-28 ions is a signature of auroral precipitation. A discussion of the atomic oxygen green line in the nightglow of Venus, which is produced mainly by dissociative recombination of O(2+), is presented. Original calculations of production rates of excited states for models based on Pioneer Venus data are also presented.

Fox, J. L.↗

Theoretical study of the homonuclear tetramers and pentamers of the group IB metals (Cu, Ag, and Au)

The optimal structures of the homonuclear tetramers and pentamers of Cu, Ag, and Au are found to be planar trapezoidal. However, on the basis of spin densities deduced from electron spin resonance experiments, it has been suggested that these pentamers have distorted trigonal bipyramidal structures. This apparent discrepancy is reconciled by the fact that Mulliken populational analyses indicate that the open-shell spin density distribution on the planar structures are also consistent with experiment. Since the vertical electron attachment energies for both the tetramers and pentamers are in good agreement with experiment, the negative ions probably also have planar trapezoidal structures. The trends in ionization potentials, atomization energies, and electron affinities with cluster size are discussed.

Bauschlicher, Charles W., Jr.↗

NO(gamma) emission by energy transfer from NO(+) (a) to NO

Ultraviolet emission produced by photoexcitation of NO at 50-80 nm is observed using synchrotron radiation as a light source. The emission increases at an excitation wavelength corresponding to the ionization potential of the NO(+) (a) state. The emission spectra at several excitation wavelengths are dispersed and identified to be mainly the NO(gamma) band. The dependence of emission intensity on gas pressure and delay time indicates that the emission is produced by a secondary reaction, which is attributed to the energy transfer from NO(+) (a) to NO.

Ma, Guang↗

Observation of fullerenes (C60-C70) associated with LDEF crater number 31

The presence of fullerenes in and around the LDEF crater number 31 is reported. This crater has a high C level associated with it, and is interpreted as having been produced by the impact of a C-rich micrometeoroid. Fullerenes are large 3-D C structures, among which the species C sub 60 (MW 720) and C sub 70 (MW 840) are preeminent. Fullerenes have several UV absorption bands, hence fullerenes should be detectable using UV laser ionization time-of-flight mass spectrometry. We use a LIMA-2A instrument with pulsed UV laser (266 nm) to search for high mass C species associated with LDEF crater number 31. The mass range was 0 to 1200 amu. Low ablating laser power levels were used (less than or = 5 x 10 exp 7 W/sq. cm); 200 mass spectra were acquired and summed. We observed high mass signals near m/z 720, exhibiting 24 amu separation, which is characteristic of fullerenes. Alkali ion signals were also observed. Little or no C clusters of intermediate mass were observed. We interpret the signals around m/z 720 as fullerenes, mainly C sub 60+ with lower levels of C sub 70+. We propose that the mechanism that produces these signals is resonant multiphoton ionization (REMPI). This selective mechanism explains why low mass C cluster ions are not observed along with the fullerenes, since they have much higher ionization potentials. This finding is unexpected, since up to now the search for fullerenes in extraterrestrial materials has not been successful. We conclude that the fullerenes became associated with crater number 31 in space. Two alternative (and exciting) scenarios are being considered at this time: either the fullerenes were carried by the C-rich projectile that formed crater number 31, or the fullerenes formed upon impact with the LDEF. We show the results of experiments at the ARC Vertical Gun Facility, which may establish some constraints on the origin of the fullerenes.

Radicatidibrozolo, Filippo↗

Investigation of nonlinear E.M. phenomena in the tethered magnetospheric cloud

Nonlinear effects of parametric and of heating type, produced in a plasma under the action of an electric field E(sub 0)(e exp i(omega)t), are considered in this work in connection with the Tethered Magnetospheric Cloud (TMC) accompanying the Tether Satellite System (TSS). The theoretical results show that these phenomena should appear in the ionosphere at high altitudes Z greater than or = (150-200) km, particularly, at Z approximately = 300 km of the TSS system orbit. Therefore, it is of a special interest to search these phenomena by such a unique experiment as the forthcoming first TSS-I and by the future, perhaps modified TSS missions. Because of the parametric decay instability, new branches of wave may be excited both around the electron and ion Lengmuir frequencies Omega (sub 0) = 2(pi)f(sub 0) and Omega (sub 0) = 2(pi)f(sub 0) under the influence of high frequency (HF), (f less than or = 10(exp 6) to few 10(exp 6) Hz), strong electric waves. The heating of all the kinds of particles is growing up very quickly in the ionosphere with altitude in the extra low and very low frequency ranges, F approximately = (1 to 10(exp 4) Hz, discussed below. The temperatures (energies), for example, of the electrons accelerated by the electric field become larger than the ionization potential in this frequency range already at altitudes Z greater than or = (150 - 200) km when the amplitude of the electric field is the absolute value of E(sub 0) approximately = (1-2) mV/m. The sources of these electric fields may be in the TSS-I mission, that so called Phantom Loop (PL) - the Tethered Electrodynamic Tail (TET), and the different kind of electromagnetic oscillations produced by different kinds of instabilities in the TMC plasma. The growth rates of these instabilities will become very high in the TSS surrounding magnetoplasma. However, in the future TSS missions, special artificial sources (generators) of electric fields should be used for these investigations.

Alpert, Yakov L.↗

On the differences in element abundances of energetic ions from corotating events and from large solar events

The abundances of energetic ions accelerated from high-speed solar wind streams by shock waves formed at corotating interaction regions (CIRs) where high-speed streams overtake the lower-speed solar wind are examined. The observed element abundances appear to represent those of the high-speed solar wind, unmodified by the shock acceleration. These abundances, relative to those in the solar photosphere, are organized by the first ionization potential (FIP) of the ions in a way that is different from the FIP effect commonly used to describe differences between abundances in the solar photosphere and those in the solar corona, solar energetic particles (SEPs), and the low-speed solar wind. In contrast, the FIP effect of the ion abundances in the CIR events is characterized by a smaller amplitude of the differences between high-FIP and low-FIP ions and by elevated abundances of He, C, and S.

Reames, D. V.↗

A comparison of solar wind and estimated solar system xenon abundances - A test for solid/gas fractionation in the solar nebula

The solar Xe elemental abundance is determined here using solar wind measurements from lunar ilmenites which are normalized to Si by spacecraft data. The results are compared with estimated abundances assuming no fractionation. When corrected for solar wind/photospheric fractionation, the Xe-130 abundance given by surface layer oxidation of ilmenite from solid 71501 exposed within the last 200 m.y. is 0.24 +/- 0.09 normalized to Si = 10 exp 6. This is indistinguishable from estimates made assuming no solid/gas fractionation. Results from breccia 79035 ilmenite exposed at least 1 Gyr ago indicate that the solar wind Xe flux may have been significantly higher relative to other noble gases, perhaps due to more efficient Xe ionization. If this is true, fluxes of C and S, which have first ionization potentials similar to Xe, should also be higher in the ancient solar wind from the same time period.

Wiens, Roger C.↗

Energetic particle observations and the abundances of elements in the solar corona

During the last few years it has become clear that energetic particles in the largest solar events, where abundances are commonly measured, are not accelerated in flares. Rather they are accelerated from the ambient plasma above active regions by shock waves driven by coronal mass ejections. The lowest energy particles from these events have abundances that almost directly reflect those of the source plasma. Residual effects of acceleration, that depend smoothly on the ion's corona Q/A, vanish when abundances are averaged over many events, yielding the characteristic dependence of the average coronal abundances of the First Ionization Potential (FIP) of the elements from H through Fe. In contrast, energetic ions accelerated out of the high speed solar wind from large coronal holes show a reduced FIP effect with a different pattern.

Reames, Donald V.↗

Radiation exposure and dose estimates for a nuclear-powered manned Mars sprint mission

A conceptual manned mission to Mars is analyzed in order to estimate potential ionizing radiation doses that may be incurred by crew members during the course of the mission. The scenario is set for a journey during the solar active period and includes a brief stay on the Martian surface. Propulsion is assumed to be provided by nuclear thermal rocket power, and estimates of the dose contributions from the reactors are included. However, due to effective shielding of the reactors by large propellant tanks, it is found that the incurred doses are principally due to the charged particle natural environment. Recent data (August-December 1989) for large solar proton events are used to simulate the flame environment, while standard models are used for the trapped particle and galactic cosmic ray contributions. Shield effectiveness for several candidate materials are investigated.

Nealy, John E.↗

Ions with low charges in the solar wind as measured by SWICS on board Ulysses

We present new data on rare ions in the solar wind. Using the Ulysses-SWICS instrument with its very low background we have searched for low-charge ions during a 6-d period of low-speed solar wind and established sensitive upper limits for many species. In the solar wind, we found He(1+)/He(2+) of less than 5 x 10 exp -4. This result and the charge state distributions of heavier elements indicate that all components of the investigated ion population went through a regular coronal expansion and experienced the typical electron temperatures of 1 to 2 million Kelvin. We argue that the virtual absence of low-charge ions demonstrates a very low level of nonsolar contamination in the source region of the solar wind sample we studied. Since this sample showed the FlP effect typical for low-speed solar wind, i.e., an enhancement in the abundances of elements with low first ionization potential, we conclude that this enhancement was caused by an ion-atom separation mechanism operating near the solar surface and not by foreign material in the corona.

Geiss, J.↗

Elemental abundances of flaring solar plasma - Enhanced neon and sulfur

Elemental abundances of two flares observed with the SMM Flat Crystal Spectrometer are compared and contrasted. The first had a gradual rise and a slow decay, while the second was much more impulsive. Simultaneous spectra of seven bright soft X-ray resonance lines provide information over a broad temperature range and are available throughout both flares, making these events unique in the SMM data base. For the first flare, the plasma seemed to be characterized by coronal abundances but, for the second, the plasma composition could not be coronal, photospheric, or a linear combination of both. A good differential emission measure fit required enhanced neon such that Ne/O = 0.32 +/- 0.02, a value which is inconsistent with the current models of coronal abundances based on the elemental first-ionization potential. Similar values of enhanced neon are found for flaring plasma observed by the SMM gamma-ray spectrometer, in (He-3)-rich solar energetic particle events, and in the decay phase of several long duration soft X-ray events. Sulfur is also enhanced in the impulsive flare, but not as dramatically as neon. These events are compared with two models which attempt to explain the enhanced values of neon and sulfur.

Schmelz, J. T.↗