Fuel cells incorporating ion exchange membranes - current state of development.
Ion exchange single and double membrane fuel cell performance limits including product water removal and power density considerations
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Ion exchange single and double membrane fuel cell performance limits including product water removal and power density considerations
The electron-ion recombination coefficients for H3(+) and H5(+) ions were determined by means of a microwave afterglow/mass spectrometer apparatus. Measurements of electron density decays in helium-hydrogen mixtures are correlated with the decay of mass-identified ion currents to the wall of the microwave cavity. At low partial pressures of hydrogen in the mixture, the ion H3(+) dominates the ion composition and the ion wall current tracks the electron density decay curves. From recombination controlled electron density decay curves, the values alpha (H3(+)) = (2.9 + or - 0.3), (2.3 + or - 0.3), and (2.0 + or - 0.2) x 0.0000001 cu cm per sec, are obtained at 205, 300 and 450 K, respectively. At higher partial pressures of hydrogen and low temperatures, where (H5(+)) is the dominant ion, the value alpha (H5(+)) = (3.6 + or - 1.0) x 0.0000001 cu cm per sec is obtained at 205 K. The implications of these results concerning ionization levels in the atmospheres of the outer planets and in the interstellar medium are discussed.
Flow equation for representing ion beam current density profile from bombardment ion thrusters
Heating of heavy ions has been observed in the equatorial magnetosphere in GEOS 1 and 2 and ATS 6 data due to ion cyclotron waves generated by anisotropic hot ring current ions. A one-dimensional hybrid-Darwin code has been developed to study ion heating in the ring current. Here, a strong instability and heating of thermal ions is investigated in a plasma with a los cone distribution of hot ions. The linear growth rate calculation and particle simulations are conducted for cases with different loss cones and relative ion densities. The linear instability of the waves, the quasi-linear heating of cold ions and dependence on the thermal H(+)/He(+) density ratio are analyzed, as well as nonlinear parallel heating of thermal ions. Effects of thermal oxygen and hot oxygen are also studied.
Data obtained by Bennett radio-frequency ion mass spectrometers indicate that the ionosphere envelope, dominated above 200 km by O(+), responds dramatically to variations in the solar wind pressure. The pressure compresses the thermal ion distributions from heights as great as 1800 km inward to 280 km. At the thermal ion boundary, or ionopause, the ambient ions are swept away by the solar wind, while at higher altitudes energetic ion currents are detected. Within the ionosphere, ion convection stimulated by the solar wind interaction causes pass-to-pass differences in the ion scale heights.
An analysis is conducted for the Atmosphere Explorer C observations of O(++) in the daytime thermosphere which supercedes that of Breig et al (1977) and restricts attention to five orbits of data from the high-grain mode of the magnetic ion-mass spectrometer. The present investigation adopts a model for O(++) ionospheric chemistry which has been revised in light of recent laboratory measurements of a fast loss rate for O(++) through reaction with N2. An improved procedure is also introduced which analyzes the basic ion currents recorded by the magnetic ion-mass spectrometer and has special application for the very low concentrations near and below 200 km. It is found that large scale features in the low altitude data are best represented with an additive term which is proportional to the N2 or O2 density, with the preferred interpretation as a contaminant signal induced by neutral particles impinging on instrument or spacecraft surfaces.
The sensitivity of xenon ionization rates to collision cross-sections is studied within the framework of a hybrid-PIC model of a Hall thruster discharge. A revised curve fit based on the Drawin form is proposed and is shown to better reproduce the measured crosssections at high electron energies, with differences in the integrated rate coefficients being on the order of 10% for electron temperatures between 20 eV and 30 eV. The revised fit is implemented into HPHall and the updated model is used to simulate NASA's HiVHAc EDU2 Hall thruster at discharge voltages of 300, 400, and 500 V. For all three operating points, the revised cross-sections result in an increase in the predicted thrust and anode efficiency, reducing the error relative to experimental performance measurements. Electron temperature and ionization reaction rates are shown to follow the trends expected based on the integrated rate coefficients. The effects of triply-charged xenon are also assessed. The predicted thruster performance is found to have little or no dependence on the presence of triply-charged ions. The fraction of ion current carried by triply-charged ions is found to be on the order of 1% and increases slightly with increasing discharge voltage. The reaction rates for the 0→III, I→III, and II→III ionization reactions are found to be of similar order of magnitude and are about one order of magnitude smaller than the rate of 0→II ionization in the discharge channel.
Complete description of a self-consistent model for magnetospheric ring current interacting with electromagnetic ion cyclotron waves is presented. The model is based on the system of two kinetic equations; one equation describes the ring current ion dynamics, and another equation describes the wave evolution. The effects on ring current ions interacting with electromagnetic ion cyclotron waves, and back on waves, are considered self-consistently by solving both equations on a global magnetospheric scale under non steady-state conditions. In the paper by Khazanov et al. [2002] this self-consistent model has only been shortly outlined, and discussions of many the model related details have been omitted. For example, in present study for the first time a new algorithm for numerical finding of the resonant numbers for quasilinear wave-particle interaction is described, or it is demonstrated that in order to describe quasilinear interaction in a multi-ion thermal plasma correctly, both e and He(+) modes of electromagnetic ion cyclotron waves should be employed. The developed model is used to simulate the entire May 2-7, 1998 storm period. Trapped number fluxes of the ring current protons are calculated and presented along with their comparison with the data measured by the 3D hot plasma instrument Polar/HYDRA. Examining of the wave (MLT, L shell) distributions produced during the storm progress reveals an essential intensification of the wave emissions in about two days after main phase of storm. This result is well consistent with the earlier ground-based observations. Also the theoretical shapes and the occurrence rates for power spectral densities of electromagnetic ion cyclotron waves are studied. It is found that in about 2 days after the storm main phase on May 4, mainly non Gaussian shapes of power spectral densities are produced.
Anomaly in ion current response of cylindrical Langmuir probe carried aboard Explorer XVII SATELLITE
A complete description of a self-consistent model of magnetospheric ring current interacting with electromagnetic ion cyclotron waves is presented. The model is based on the system of two kinetic equations; one equation describes the ring current ion dynamics, and another equation describes the wave evolution. The effects on ring current ions interacting with electromagnetic ion cyclotron waves and back on waves are considered self-consistently by solving both equations on a global magnetospheric scale under nonsteady state conditions. The developed model is employed to simulate the entire 2-7 May 1998 storm period. First, the trapped number fluxes of the ring current protons are calculated and presented along with comparison with the data measured by the three- dimensional hot plasma instrument Polar/HYDRA. Incorporating in the model the wave-particle interaction leads to much better agreement between the experimental data and the model results. Second, examining of the wave (MLT, L shell) distributions produced by the model during the storm progress reveals an essential intensification of the wave emission about 2 days after the main phase of the storm. This result is well consistent with the earlier ground-based observations. Finally, the theoretical shapes and the occurrence rates of the wave power spectral densities are studied. It is found that about 2 days after the storm s main phase on 4 May, mainly non-Gaussian shapes of power spectral densities are produced.
Tangential drag measurements at electrodes of arc in plasma accelerator, ion current partitioning at cathode and electrode damage
Two-dimensional (three velocity) electrostatic particle simulations are used to investigate the particle heating and acceleration associated with the impulsive phase of a solar flare. A crossfield current in the high corona (which is presumably driven by reconnection processes) is used to initiate the flare. Due to the differential motion of the electrons and ions, currents, and associated quasi-static electric fields are generated with the primary current and balancing return current being on adjacent field lines. These currents extend from the corona down into the chromosphere. Electrons can be accelerated to energies exceeding 100 keV on short time scales via the quasi-static fields and wave-particle interactions. The spectra of these electrons has a broken power-law distribution which hardens in time. The spatially separate primary and return currents are closed by the cross-field acceleration of the ambient ions into the primary current regions. These ions are then accelerated upwards into the corona by the same quasi-static electric field accelerating the electrons downwards. This acceleration can account for the broadened stationary and weak blue shifted component seen in soft x ray line emissions and enhancements in heavy ion abundances seen in the solar wind in associations with solar flares.
Ion current produced by illuminating materials with focused output of pulsed ruby laser
The statistical occurrence of spacecraft charging at near-geosynchronous orbit in daylight is studied with reference to results of an experiment conducted on the SCATHA satellite. In particular, it is found that: (1) the external current that creates high negative satellite frame potentials is the high-energy electron current from the electron population with energies greater than about 30 keV; (2) the electron current to the satellite from particles with energies less than about 30 keV neither drives the frame potential nor provides the current to balance the high-energy populations; and (3) the ion current provided from the entire range of measured ions is also not the primary source of the balancing current.
Magnetic field variations and positive ion current inside earth magnetosphere - Elektron II SATELLITE
He ion identification problems in topside ionosphere, suggesting confirmation by N ion current modulation curves and rocket measurements of ion scale heights
Solar flare observations are consistent with the phenomenological description that a loop of magnetic flux is convected to the surface of the star and twisted. The resulting inductive current parallel to the field is dissipated at an enhanced rate throughout the field volume by current limiting instabilities. The steady state balance between joule heating and thermal conduction along the field lines of force to the denser, cooler surface establishes a temperature distribution. The expansion of heated and ionized surface layers leads to a pressure balance and hence predictable density and X-ray emission measure. The current limitation instabilities result observationally in the parallel current being transferred to run-away ions that reach a kinetic energy of some finite fraction of the inductive potential drop. The nuclear excitation gamma rays produced by such a run-away ion current are calculated for a white dwarf flare.
Nitrogen plasma instabilities have been identified through fluctuations in the ion current density and substrate floating potential. The plasma characteristics for both nitrogen and silane-nitrogen plasmas are consistent with a transition from an underdense to overdense plasma at 0.9 and 1.0 mTorr respectively.