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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

On the evolution of Lyman alpha clouds based upon the Minihalo model

Intergalactic clouds confined by the gravity of cold dark matter (CDM), the so called mini-halo, is considered. Assuming a simplified evolution law of UV flux and mass function of gas clouds, number density evolution and H1 column density distribution can be reproduced by mini-halo model. Considering interaction between supersonic flow and a mini-halo, spatial correlation and the proximity effect of Ly-alpha forest can be investigated.

Murakami, Izumi↗
NASA NTRS1994

Gravitational collapse of small-scale structure as the origin of the Lyman-alpha forest

If gravitational clustering is a hierarchical process, the present large-scale structure of the galaxy distribution implies that structures on smaller scales must have formed at high redshift. We simulate the formation of small-scale structure (average cell mass: (delta) bar m(sub b) = 10(sup 4.2) solar mass) and the evolution of photoionized gas, in the specific case of the CDM + Lambda model. The photoionized gas has a natural minimal scale of collapse, the Jeans scale (m(sub b,J) is approximately equal to 10(exp 9) solar mass). We find that low column density (N(sub HI) is less than or equal to 10(exp 14)/sq cm) lines originate in regions resembling Zel'dovich pancakes, where gas with overdensities in the range 3-30 is enclosed by two shocks but is typically reexpanding at approximately the Hubble velocity. However, higher column density lines stem from more overdense regions where the shocked gas is cooling. We show that this model can probably account for the observed number of lines, their distribution in column density and b-parameters, as well as the cloud physical sizes as observed in gravitationally lensed quasars. We find a redshift evolution that is too steep; however, this may be due to insufficient dynamical range in the simulation or because the specific model is incorrect. The model predicts that high signal-to-noise observations should find systematic deviations from Voigt profiles, mainly in the form of broad wings in the line profiles, and that a fluctuating Gunn-Peterson effect will be detected, which can be modeled as a superposition of weak lines with a wide range of b-parameters.

Cen, Renyue↗
NASA NTRS1995

High rotational CO lines in post-AGB stars and PNe

A significant fraction of a star's initial mass is lost while it is on the Asymptotic Giant Branch (AGB). Mass loss rates range from 10(exp -7) solar mass/yr for early AGB stars to a few 10(exp -4) solar mass/yr for stars at the tip of the AGB. Dust grains condense from the outflow as the gas expands and form a dust shell around the central star. A superwind (approximately 10(exp -4) to 10(exp -3) solar mass/yr) is thought to terminate the AGB phase. In the post-AGB phase, the star evolves to a higher effective temperature, the mass loss decreases (approximately 10(exp -8) solar mass/yr), but the wind velocity increases (approximately 1000 km/s). During this evolution, dust and gas are exposed to an increasingly harsher radiation field and when T(sub eff) reaches about 30,000 K, the nebula is ionized and becomes a planetary nebula (PN). Photons from the central star can create a photodissociation region (PDR) in the expanding superwind. Gas can be heated through the photoelectric effect working on small grains and polycyclic aromatic hydrocarbons (PAH's). This gas can cool via the atomic fine structure lines of O I (63 microns and 145 microns) and C II (158 microns), as well as the rotational lines of CO. In the post-AGB phase, the fast wind from the central star will interact with the material ejected during the AGB phase. The shock caused by this interaction will dissociate and heat the gas. This warm gas will cool through atomic fine structure lines of O I and the rotational lines of (newly formed) CO.

Justtanont, K.↗
DOE OSTI2024

Modeling Approach for the Aluminum-clad Dry Storage Pilot using HFIR Fuel

To confirm that the dry storage of aluminum-clad research reactor spent nuclear fuel (ASNF) will remain within the safety envelope after applied drying schemes and that the resulting evolution of the gas space composition, temperature, and pressure conditions are understood, a dry storage pilot project is being established. The pilot will incorporate an instrumented lid for discrete interval or for on-demand gas composition and temperature monitoring of two DOE Standard Canisters (DSCs) loaded with three High Flux Isotope Reactor (HFIR) inner cores per DSC. Each DSC would be subjected to a separate alternative candidate drying scheme. Canisters will undergo 1 to 5 years of monitoring, including internal temperature and gas sampling to track pressure and composition changes. This report outlines the approach for modeling the ASNF-in-canister behavior in terms of evolving gas space conditions for the ASNF dry storage pilot using HFIR fuel. The ASNF has an adherent surface oxyhydroxide layer comprised of boehmite/bayerite that generates hydrogen when subjected to irradiation. Three-dimensional multi-physics computational fluid dynamics simulations will be executed to compute the thermal field within the DSC and provide inputs to a chemical model employed to compute pressure buildup as hydrogen is generated in the system. Implemented in Cantera, the chemical model solves gas phase and aluminum oxyhydroxide surface-mediated radiolysis reactions. Gas phase reactions are sourced from Wittman and Hanson (2015), whereas surface-mediated reactions are incorporated by fitting experimental data using an optimization algorithm (Abboud, 2023). Water radiolysis reactions from Wren and Ball (2001) are adopted with modifications as described in Abboud (2023c). Understanding the effect of the hydrogen buildup over time is important for long-term storage safety considerations. Modeling results will include the canister pressure, temperature, and composition evolution from the initial helium backfill with the addition of radiolytically-evolved chemical species (e.g., hydrogen and oxygen). The specific HFIR cores for the pilot program have not yet been selected, and the overall design is still in development. The CFD-chemical model used for this work will be based on prior models with necessary updates to allow for improved accuracy and efficiency. The experimental data obtained from the HFIR demonstration will be used to improve and validate the computational models to predict the ASNF-in-canister behavior.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Comparative post-irradiation examination of high burnup U-19Pu-10Zr: Assessing steady-state irradiation behavior against historical and modeled fuel performance

Here, the development of next-generation sodium-cooled fast reactors necessitates comprehensive research on metallic fuels to maximize economic performance while ensuring safe operation. In this study, we investigated the steady-state irradiation behavior of two high burnup U-19Pu-10Zr fuel pins, DP-36 and DP-40, in preparation for planned safety testing. Post-irradiation examination (PIE) was performed to quantify fuel column elongation, regions of low-density at the top of the fuel column, pin deformation, fission product distribution, fractional fission gas release, microstructural evolution, and fuel constituent redistribution. Benchmarking against existing PIE data from U-19Pu-10Zr fuel pins irradiated in EBR-II revealed consistent patterns in fuel column elongation and cladding diametral strain. However, both pins exhibited longer low-density structures, and destructive examination of DP-36 revealed more complex constituent redistribution patterns compared to previously reported data for ternary fuel pins. The steady-state irradiation of both pins was also modeled using BISON. Comparisons of PIE results with modeled predictions showed overall agreement in fractional fission gas release but consistent overestimation of axial and radial swelling due to gaseous and solid swelling models. These findings underscore the critical importance of pre-test characterization on test and sibling pins to accurately capture steady-state fuel behavior ahead of transient testing, thus establishing a baseline for post-test comparison. Additionally, these analyses identified key data gaps that warrant further investigation to improve the understanding and prediction of fuel swelling, thereby enhancing the synergy between modeling and experimental efforts in supporting accident testing.

BISON↗
NASA NTRS1984

The structure of clusters of galaxies observed with Einstein

Imaging observations from the Einstein Observatory are used to determine properties of galactic clusters and the intracluster gas. The hydrostatic-isothermal gas model is applied to obtain the cluster core radius, the limiting slope of the X-ray surface brightness distribution, and the presence and magnitude of a central luminosity excess above that predicted from the model when fit to the outer regions of the cluster. It is concluded that clusters can be divided into two basic families, one with small core radii and X-ray emission centered on a central dominant galaxy, and one with larger core radii and generally no central, stationary bright galaxy. The former type probably begins to form in the early stages of a cluster's dynamical evolution. The intracluster gas has a larger scale height than that of the galaxies based on the fit of the hydrostatic-isothermal model to the X-ray surface brightness profiles.

Jones, C.↗
NASA NTRS1987

Liner cooling research at NASA Lewis Research Center

Described are recently completed and current advanced liner research applicable to advanced small gas turbine engines. Research relating to the evolution of fuel efficient small gas turbine engines capable of meeting future commercial and military aviation needs is currently under way at NASA Lewis Research Center. As part of this research, a reverse-flow combustor geometry was maintained while different advanced liner wall cooling techniques were investigated and compared to a baseline combustor. The performance of the combustors featuring counterflow film-cooled (CFFC) panels, transpiration cooled liner walls (TRANS), and compliant metal/ceramic (CMC) walls was obtained over a range of simulated flight conditions of a 16:1 pressure ratio gas turbine engine and fuel/air ratios up to 0.034. All the combustors featured an identical fuel injection system, identical geometric configuration outline, and similar designed internal aerothermodynamics.

Acosta, Waldo A.↗
NASA NTRS1987

Liner cooling research at NASA Lewis Research Center

Described are recently completed and current advanced liner research applicable to advanced small gas turbine engines. Research relating to the evolution of fuel efficient small gas turbine engines capable of meeting future commercial and military aviation needs is currently under way at NASA Lewis Research Center. As part of this research, a reverse-flow combustor geometry was maintained while different advanced liner wall cooling techniques were investigated and compared to a baseline combustor. The performance of the combustors featuring counterflow film-cooled (CFFC) panels, transpiration cooled liner walls (TRANS), and compliant metal/ceramic (CMC) walls was obtained over a range of simulated flight conditions of a 16:1 pressure ratio gas turbine engine and fuel/air ratios up to 0.034. All the combustors featured an identical fuel injection system, identical geometric configuration outline, and similar designed internal aerothermodynamics.

Acosta, Waldo A.↗
NASA NTRS2010

Multi-Model Assessment of the Factors Driving the Ozone Evolution Over the 21st Century

The evolution of ozone from 1960 to 2100 is examined in simulations from fourteen chemistry-climate models. There is general agreement among the models at the broadest levels, with all showing column ozone decreasing at all latitudes from 1960 to around 2000, then increasing at all latitudes over the first half of the 21 st century (21 C), and latitudinal variations in the rate of increase and date of return to historical values. In the second half of the century, ozone is projected to carry on increasing, level off or even decrease depending on the latitude, resulting in variable dates of return to historical values at latitudes where column ozone has declined below those levels. Separation into partial column above and below 20 hPa reveals that these latitudinal differences are almost completely due to differences in the lower stratosphere. At all latitudes, upper stratospheric ozone increases throughout the 21 C and returns to 1960 levels before the end of the century, although there is a spread among the models in dates that ozone returns to historical values. Using multiple linear regression the upper stratospheric ozone increase comes from almost equal contributions due to decrease in halogens and cooling from increased greenhouse gas concentrations. The evolution of lower stratospheric ozone differs with latitude. In the tropical lower stratosphere an increase in tropical upwelling causes a steady decrease in ozone through the 21C, and total column ozone does not return to 1960 levels in all models. In contrast, lower stratospheric and total column ozone in middle and high latitudes increases during the 21 C and returns to 1960 levels. For all models there is an earlier return for ozone to historical levels in the northern hemisphere. This is thought to be due to interhemispheric differences in transport.

Oman, L.↗
DOE OSTI2025

Understanding the Cathode Electrochemistry of Humidified Solid‐State Lithium‐Oxygen Batteries

Lithium-oxygen batteries (LOBs) possess a high theoretical energy density, making them potential candidates for next-generation energy storage. However, challenges such as reactive oxygen species-induced component degradation hinder their practical use. Inorganic solid-state electrolytes offer an alternative to degradation-prone aprotic electrolytes, while also protecting lithium anodes from potential atmospheric reactants. Here, this study explores the cathode electrochemistry of solid-state LOBs using humidified oxygen, which forms an aqueous catholyte during initial cycling, thereby improving cathode-electrolyte contact. To quantitatively analyze the cathode electrochemistry, a ‘Humidity-Incorporated’ Differential Electrochemical Gas Monitoring System (HiDEMS) is developed to control humidity and monitor gas consumption and evolution in real time. When studying a Li-O 2 cell that employs a NASICON-type Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) solid electrolyte and a porous carbon cathode, a shift in discharge products from Li 2 O 2 to LiOH is observed over repeated cycles. While Li 2 O 2 evolves O 2 during charging, LiOH oxidation leads to minimal O 2 release and increased CO 2 production, originating from oxidation of carbon electrodes. Further, dissolution of Al and P from LATP is observed, likely driven by the formation of the alkaline catholyte. The findings highlight the need for carbon-free cathode materials and more stable solid-state conductors to minimize side reactions and improve rechargeability in humidified solid-state Li-O 2 batteries.

LATP degradation↗
DOE OSTI2025

Role of Mg:Al ratio and Pt promotion on mitigating the deactivation of Ni-based methane steam reforming catalysts

Ni-based catalysts for CH 4 steam reforming require fine-tuning to withstand deactivation under dynamic operation conditions relevant to emerging H 2 -driven technologies. This study investigates the impact of the Mg:Al ratio and Pt presence in catalyst composition on the activity and stability of industrially relevant Ni-based mono- and bimetallic catalysts during simulated daily start-up and shut-down cycles in various gas atmospheres. The evolution of the catalyst structure during extensive testing procedures was investigated in detail by complementary electron microscopy, in situ/operando XAS and XRD. The results obtained revealed that catalyst deactivation is promoted at high Mg:Al ratios and especially affects the monometallic catalysts. By converting CH 4 at lower temperatures, Pt regulates the extent of Ni oxidation and its incorporation into MgO lattice. Further prevention of catalyst deactivation was achieved by optimizing the reactor shut-down procedure to minimize the simultaneous exposure to high temperatures and H 2 O vapors. By flushing the reactor with N 2 only around the reaction extinction temperature, a fraction of Ni species is maintained in metallic state, which is beneficial for the long-term activity and reaction operation economy.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Viking labeled release biology experiment - Interim results

All results of the labeled-release life-detection experiment conducted on Mars prior to conjunction are summarized. Tests at both landing sites provide remarkably similar evolution of radioactive gas upon addition of a radioactive nutrient to the Mars sample. The 'active' agent in the sample is stable to 18 C, but is substantially inactivated by heat treatment for 3 hours at 50 C and completely inactivated at 160 C, as would be anticipated if the active response were caused by microorganisms. Results from test and heat-sterilized control samples are compared with those obtained from terrestrial soils and a lunar sample. Possible nonbiological explanations of the Mars data are reviewed. Although such explanations of the labeled-release data depend on UV irradiation, the labeled-release response does not appear to depend on recent direct UV activation of surface material. Available facts do not yet permit a conclusion regarding the existence of life on Mars.

Levin, G. V.↗
NASA NTRS1976

Labeled Release - An experiment in radiorespirometry

The Labeled Release extraterrestrial life detection experiment onboard the Viking spacecraft is described as it will be implemented on the surface of Mars in 1976. This experiment is designed to detect heterotrophic life by supplying a dilute solution of radioactive organic substrates to a sample of Martian soil and monitoring for evolution of radioactive gas. A significantly attenuated response by a heat-sterilized control sample of the same soil would confirm a positive metabolic response. Experimental assumptions as well as criteria for the selection of organic substrates are presented. The Labeled Release nutrient has been widely tested, is versatile in eliciting terrestrial metabolic responses, and is stable to heat sterilization and to the long-term storage required before its use on Mars. A testing program has been conducted with flight-like instruments to acquire science data relevant to the interpretation of the Mars experiment. Factors involved in the delineation of a positive result are presented and the significance of the possible results discussed.

Levin, G. V.↗
NASA NTRS1981

Numerical simulation of the magnetospheric gate model for X-ray bursters

A Lagrangian, fully implicit, one dimensional hydrodynamic computer code was used to investigate the evolution of a gas cloud impacting the surface of a 20 km, 1 Msub solar neutron star. This gas is initially at rest with respect to the surface of the neutron star, extends to 185 km above the surface, and is optically thick. The infall results in a burst which lasts about 0.1 seconds and reached a peak luminosity and effective temperature of 240,000 Lsub solar and 9 million; respectively. The burst was followed by a phase of oscillations with a period 0.2 seconds.

Starrfield, S. G.↗