Geochemistry of precambrian diabase dikes from Wyoming
Major and trace element concentration in contact zones of Precambrian diabase dikes from Wyoming ranges, showing dikes as continental tholeiites
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Major and trace element concentration in contact zones of Precambrian diabase dikes from Wyoming ranges, showing dikes as continental tholeiites
Radioactive age determination and isotopic composition analyses on rocks, meteorites, and lunar samples
Analyzing glaciers, hot springs, and volcanic ash from erupting volcanoes in Iceland for hydrocarbon content as test for life detection techniques
Soil and ground rock amino acids preparation and analysis by desalting method
Spectral reflectance curves for red spruce and balsam fir in the 350- to 1100-nanometer region showed differences between specimens growing over and away from a concealed copper deposit at Catheart Mountain, Maine. A sample group of 15 anomalous spruce, 9 background spruce, 10 anomalous fir, and 10 background fir was studied. Measurements of copper and molybdenum contents in the supporting soil were used to categorize the trees as anomalous or background. Analyses using parametric and nonparametric statistical tests were performed to establish whether significant differences existed between the anomalous and background groups. At the 95% confidence level, significant differences were found to exist for both species, generally in the chlorophyll band centered at about 550 nanometers and in the region from 700 to 900 nanometers.
A new indirect approach to crustal analysis of a specific sector of the Ethiopian plateaus and rift is discussed. It is suggested that progressive changes in basalt chemistry across this area are related to crustal thinning and shallowing of the zone of melting under the Afar rift.
Data are presented on major and trace element concentrations determined by atomic absorption spectrophotometry, colorimetry, and isotope dilution in Apollo 15 mare basalt 15555 from the Hadley Rille area, as well as on trace element concentrations determined in plagioclase and pyroxene separates from basalt 15555 and in soil 15531 from the same area. Most of the chemical differences between basalt 15555 and soil 15531 could be accounted for if the soil were a mixture of 88% basalt, 6% KREEP (a component, identified in other Apollo soils, rich in potassium, rare-earth elements, and phosphorus), and 6% plagioclase.
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Aluminum/silicon and magnesium/silicon concentration measurements along Apollo-15 and -16 lunar groundtracks by X-rays show that the highlands are very rich in aluminum, and that mare basalts cover large areas.
Lunar gamma ray spectra obtained during Apollo-15 and -16 flights show a natural radioactivity due to potassium, thorium, and uranium as well as a cosmic ray induced activity in the lunar surface due to high neutron interactions produced by (p,n) reaction in the lunar surface. The radioactivity is at a low in the highlands on the backside of the moon; most of the radioactivity is confined to the Oceanus Procellarum/Mare Imbrium region and to the Van de Graff area on the lunar backside.
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Study of C-13 nuclear magnetic resonance (NMR) spectra of polycyclic fused systems. The fingerprint qualities of the natural abundance in C-13 NMR spectra permitting unequivocal identification of these compounds is discussed. The principle of structural additivity of C-13 NMR information is exemplified on alpha and beta androstanes, alpha and beta cholestanes, ergostanes, sitostanes, and isodecanes.
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The lunar samples from the Apollo 16 and 17 flights which were analyzed include soil, igneous rock, anorthositic gabbro, orange soil, subfloor basalt, and norite breccia. Up to 57 elements including majors, minors, rare earths and other trace elements were determined in the lunar samples. The analytical techniques used were spark source mass spectrometry and neutron activation analysis. The latter was done either instrumentally or with group radiochemical separations. The differences in abundances of the elements in lunar soils at the various sites are discussed. With regard to the major elements only Si is about the same at all the sites. A detailed analysis which was performed on a sample of the Allende meteorite is summarized.
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Soil samples 74220 ('orange soil'), 74241 and 75081 were sized, and the compositions of the opaque and silicate phases were determined. The ilmenites, particularly in 74241, contain up to 7.8 wt % MgO and display higher bireflectance than low-Mg ilmenites. They commonly contain exsolution-like chromite and rutile and occasionally are in association with native Fe in an assemblage probably resulting from reduction. The chromian ulvospinels are similar to Apollo 11 spinels in that they contain near-equal amounts of chromite and ulvospinel molecules. No primary chromites were observed. Most native Fe has No and Co contents of less than 1 wt %; some in 74220 contained 5-6% Ni and less than 1% Co in association with schreibersite.
Primordial Pb as Pb-204 is present in Apollo 15 samples in concentrations ranging from less than 0.2 ppb in basalts to 6 ppb in soils. An acid soluble, pH-5-6, readily volatile component of this Pb is present, possibly as PbBr2; the remainder is correlated with the metal content of the sample. Leachable Bi and Pb-204 are correlated; residual Bi is probably present in a phosphate, possibly apatite. Zn is also highly leachable; residual Zn and Pb-204 are correlated.
The K, Rb, Sr, Ba and rare-earth-element contents of some Archean volcanic rocks from the Vermilion greenstone belt, northeast Minnesota, were determined by the isotopic dilution method. The characteristics of trace element abundances, supported by the field occurrences and major element chemistry, suggest that these volcanic rocks were formed in an ancient island arc system.