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At least 163 records · Page 9

DAWN Mission Bus and Waveguide Venting Analysis Review

A concern was raised regarding the time after launch when the DAWN Mission Communications Subsystem, which contains a 100 Watt X-Band Traveling Wave Tube Amplifier (TWTA) with a high voltage ((approximately 7 Kilo Volt (KV)) Electronic Power Converter (EPC), will be powered on for the first post-launch downlink. This activation is planned to be approximately one hour after launch. Orbital Sciences (the DAWN Mission spacecraft contractor) typically requires a 24-hour wait period prior to high voltage initiation for Earth-orbiting Science and GEO spacecraft. The concern relates to the issue of corona and/or radio frequency (RF) breakdown of the TWTA ((high voltage direct current (DC) and RF)), and of the microwave components (high voltage RF) in the presence of partial atmospheric pressures or outgassing constituents. In particular, generally the diplexer and circulator are susceptible to RF breakdown in the corona region due to the presence of small physical gaps ((~ 2.5 millimeter (mm)) between conductors that carry an RF voltage. The NESC concurred the DAWN Mission communication system is safe for activation.

Cragg, Clinton H.↗

VLF-emissions from ring current electrons. An interpretation of the band of missing emissions

VLF-emissions associated with the enhancement of ring current electrons during magnetic storms and substorms which were detected by the equatorially orbiting S-A satellite (Explorer 45) are described. The emissions observed near the geomagnetic equator consist of essentially two frequency regimes, i.e., one above the electron gyrofrequency, f sub H at the equator and the other below f sub H. This is indicated as a part of the wide-band data obtained during the main phase of the December 17, 1971 magnetic storm. The upper figure is the ac-magnetic field data measured by the search-coil magnetometer with the upper cutoff of 3kHz and the lower figure is the ac-electric field data obtained by the electric field sensor with the upper cutoff of 10kHz. These figures show the time sequence of the observed emissions along the inbound orbit (No. 101) of the satellite as f sub H changes approximately from 3 kHz at 20 UT to 6 kHz at 21 UT. The emissions above f sub H are electrostatic mode, which peak near the frequencies of (n + 1/2) f sub H where n is positive integer, and sometimes emissions up to n = 10 are observed. The emissions below f sub H are whistler mode, which have a conspicuous gap along exactly half electron gyrofrequency, f sub H/2.

Maeda, K.↗

Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Hydrocarbon Cations: The Polyacenes Anthracene, Tetracence, and Pentacene - 3

Gaseous, ionized polycyclic aromatic hydrocarbons (PAHS) are thought to be responsible for a very common family of interstellar infrared emission bands. Unfortunately, very little infrared spectroscopic data are available on ionized PAHS. Here we present the near- and mid-infrared spectra of the polyacene cations anthracene, tetracene, and pentacene. We also report the vibrational frequencies and relative intensities of the pentacene anion. The cation bands corresponding to the CC modes are typically about 10-20 times more intense than those of the CH out-of-plane bending vibrations. For the cations the CC stretching and CH in-plane bending modes give rise to bands which are an order of magnitude stronger than for the neutral species, and the CH out-of-plane bends produce bands which are 3-20 times weaker than in the neutral species. This behavior is similar to that found for most other PAH cations. The most intense PAH cation bands fall within the envelopes of the most intense interstellar features. The strongest absorptions in the polyacenes anthracene, tetracene, and pentacene tend to group around 1400/cm (between about 1340 and 1500/cm) and near 1180/cm, regions of only moderate interstellar emission. These very strong polyacene bands tend to fall in gaps in the spectra of the other PAH cations studied to date suggesting that while PAHs with polyacene structures may contribute to specific regions of the interstellar emission spectra, they are not dominant members of the interstellar PAH family.

Hudgins, D. M.↗

Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Hydrocarbon Cations. 3. The Polyacenes Anthracene, Tetracene, and Pentacene

Gaseous, ionized Polycyclic Aromatic Hydrocarbons (PAH's) are thought to be responsible for a very common family of interstellar infrared emission bands. Unfortunately, very little infrared spectroscopic data are available on ionized PAH's. Here we present the near- and mid-infrared spectra of the polyacene cations anthracene, tetracene, and pentacene. We also report the vibrational frequencies and relative intensities of the pentacene anion. The cation bands corresponding to the CC modes are typically about 10-20 times more intense than those of the CH out-of-plane bending vibrations. For the cations the CC stretching and CH in-plane bending modes give rise to bands which are an order of magnitude stronger than for the neutral species, and the CH out-of-plane bends produce bands which are 3-20 times weaker than in the neutral species. This behavior is similar to that found for most other PAH cations. The most intense PAH cation bands fall within the envelopes of the most intense interstellar features. The strongest absorptions in the polyacenes anthracene, tetracene, and pentacene tend to group around 1400 / cm (between about 1340 and 1500 / cm) and near 1180 /cm, regions of only moderate interstellar emission. These very strong polyacene bands tend to fall in gaps in the spectra of the other PAH cations studied to date suggesting that while PAHs with polyacene structures may contribute to specific regions of the interstellar emission spectra, they are not dominant members of the interstellar PAH family.

Hudgins, D. M.↗

An algorithm for extraction of periodic signals from sparse, irregularly sampled data

Temporal gaps in discrete sampling sequences produce spurious Fourier components at the intermodulation frequencies of an oscillatory signal and the temporal gaps, thus significantly complicating spectral analysis of such sparsely sampled data. A new fast Fourier transform (FFT)-based algorithm has been developed, suitable for spectral analysis of sparsely sampled data with a relatively small number of oscillatory components buried in background noise. The algorithm's principal idea has its origin in the so-called 'clean' algorithm used to sharpen images of scenes corrupted by atmospheric and sensor aperture effects. It identifies as the signal's 'true' frequency that oscillatory component which, when passed through the same sampling sequence as the original data, produces a Fourier image that is the best match to the original Fourier space. The algorithm has generally met with succession trials with simulated data with a low signal-to-noise ratio, including those of a type similar to hourly residuals for Earth orientation parameters extracted from VLBI data. For eight oscillatory components in the diurnal and semidiurnal bands, all components with an amplitude-noise ratio greater than 0.2 were successfully extracted for all sequences and duty cycles (greater than 0.1) tested; the amplitude-noise ratios of the extracted signals were as low as 0.05 for high duty cycles and long sampling sequences. When, in addition to these high frequencies, strong low-frequency components are present in the data, the low-frequency components are generally eliminated first, by employing a version of the algorithm that searches for non-integer multiples of the discrete FET minimum frequency.

Wilcox, J. Z.↗

Global tropospheric and total ozone monitoring with a Double-Etalon Fabry-Perot interferometer

Knowledge of the global scale distribution of atmospheric ozone and its temporal variability can be achieved using a satellite-based nadir-viewing device making high spectral resolution measurements with high signal-to-noise ratios. This would enable observation in the pressure-broadened wings of strong O3 lines while minimizing the impact of undesirable signal contributions associated with, for example, the terrestrial surface and interfering species. The Fabry-Perot interferometer (FPI) provides high spectral resolution and high throughput capabilities that are essential for this measurement task. The periodic nature of the Fabry-Perot instrument function can be advantageous when observation of periodic spectra is desired. However, for most applications, additional optical elements are necessary to reduce the effect of unwanted passbands. This is frequently accomplished using additional Fabry-Perot etalons in a series configuration in conjunction with a bandpass filter. This paper discusses a Fabry-Perot interferometer conceptual instrument design to achieve tropospheric and total ozone monitoring capability from a satellite-based nadir-viewing geometry. The design involves a double-etalon fixed-gap series configuration FPI along with an ultra-narrow bandpass filter to achieve single-order operation with an overall spectral resolution of approximately .068 cm(exp -1). The impact of inter-etalon reflections has been reduced to acceptable levels by placement of a slightly attenuating medium in between the etalons. A passive device is selected for low power consumption, and continuous day/night coverage, independent of solar zenith angle, is enabled by observing within the strong 9.6 micron ozone infrared band. The IR-FPI detection will be performed through implementation of the new Circle to Line Interferometer Optical (CLIO) system, developed by researchers at the Space Physics Research Laboratory (SPRL) of the University of Michigan, to accomplish focal plane fringe detection; the CLIO system converts the circular interferometric fringes into a linear pattern which then can be detected by conventional linear array detectors. A multiplex signal advantage is achievable as all necessary frequencies can be measured simultaneously using a multichannel configuration. Through proper selection of channel spectral regions, the FPI optimized for tropospheric O3 measurements can simultaneously observe a stratospheric component and thus the total O3 column abundance.

Larar, Allen M.↗

Impact of a midband gravitational wave experiment on detectability of cosmological stochastic gravitational wave backgrounds

In this report we make forecasts for the impact a future “midband” space-based gravitational wave experiment, most sensitive to 10 -2 - 10Hz,could have on potential detections of cosmological stochastic gravitational wave backgrounds (SGWBs). Specific proposed midband experiments considered are TianGo, B-DECIGO, and AEDGE. We propose a combined power-law integrated sensitivity (CPLS) curve combining GW experiments over different frequency bands, which shows the midband improves sensitivity to SGWBs by up to two orders of magnitude at 10 -2 - 10 Hz . We consider GW emission from cosmic strings and phase transitions as benchmark examples of cosmological SGWBs. We explicitly model various astrophysical SGWB sources, most importantly from unresolved black hole mergers. Using Markov Chain Monte Carlo, we demonstrated that midband experiments can, when combined with LIGO A+ and LISA, significantly improve sensitivities to cosmological SGWBs and better separate them from astrophysical SGWBs. In particular, we forecast that a midband experiment improves sensitivity to cosmic string tension G μ by up to a factor of 10, driven by improved component separation from astrophysical sources. For phase transitions, a midband experiment can detect signals peaking at 0.1–1 Hz, which for our fiducial model corresponds to early Universe temperatures of T * ~10 4 – 10 6 GeV , generally beyond the reach of LIGO and LISA. The midband closes an energy gap and better captures characteristic spectral shape information. It thus substantially improves measurement of the properties of phase transitions at lower energies of T * ~ O(10 3 ) GeV , potentially relevant to new physics at the electroweak scale, whereas in this energy range LISA alone will detect an excess but not effectively measure the phase transition parameters. Our modeling code and chains are publicly available.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Assessing Spectrum Compatibility for Beyond-Line-of-Sight UAS Control and Non-Payload Communications

In order to provide for the safe integration of unmanned aircraft systems (UAS) into the National Airspace System (NAS), the control and non-payload communications (CNPC) link must be highly reliable. A specific requirement is that it must operate using aviation safety radiofrequency spectrum. Two types of links are required - line-of-sight (LOS) using terrestrial-based communications and beyond-line-of-sight (BLOS) using satellite communications. The 2012 World Radiocommunication Conference (WRC-12) provided a suitable allocation for LOS CNPC spectrum in the 5030 to 5091 MHz band which, when combined with a previously existing allocation fulfills the LOS spectrum requirement. The 5030 to 5091 MHz band is also allocated for BLOS CNPC, but since a significant portion of that band is required for LOS CNPC, additional BLOS spectrum is required. More critically, there are no satellites in operation or in development to provide such services in that band. Hence BLOS CNPC cannot be provided in protected aviation spectrum under current conditions. To fill this gap and enable integration of UAS into the NAS, it has been proposed to allow CNPC to operate over certain Fixed Satellite Service (FSS) bands in which many satellites currently provide commercial services. To enable this, changes in international regulation must be enacted. Agenda Item 1.5 of the 2015 WRC examines the possible regulatory changes needed. As part of the examination process, sharing between potential UAS using satellite communications for BLOS CNPC and other services allocated to the FSS bands being considered must be studied. This paper reviews the technical requirements and approach being undertaken for these sharing studies, with emphasis on study of interference from UAS into digital repeater links operating under the Fixed Service allocation. These studies are being conducted by NASA Glenn Research Center.

superhigh frequencies↗

Novel Micro Strip-to-Waveguide Feed Employing a Double-Y Junction

Previous micro strip -to -waveguide transitions either required a hermetically sealed waveguide configuration, or a balun that needed to be tuned according to the frequency band of interest. In this design, the balun is realized using a double -Y junction to transition from microstrip to coplanar strip feeding a quasi-Yagi dipole array (see figure). The length of the feed (Lf) extending into the waveguide is 15.54 mm. The length of the ground plane below the ULTRALAM substrate is 7.75 mm. The lengths L1 , L2, and L3 are 8.50 mm, 4.38 mm, and 2.14 mm, respectively. These lengths were computed via a preliminary optimization aimed at improving the return loss at the band edges. The waveguide feed was designed to excite the TE10 mode in a WR-90 waveguide, and to operate over the recommended frequencies of 8.2 to 12.4 GHz. The feed employs a Rogers 6010 substrate (dielectric constant Er approx. equals 10.2) bonded with a Rogers ULTRALAM substrate (Er approx. equals 2.5). The ULTRALAM substrate serves to provide mechanical strength for 6010 substrate, and to mitigate loses due to parasitic modes (the ground plane is etched on the bottom of this layer due to the topology of the double -Y balun). The double-Y balun transitioning from an unbalanced microstrip line to a balanced coplanar strip (CPS) line does not provide inherent impedance transformation; hence, Klopfenstein impedance tapers were synthesized to transition from 50 to 77 Ohms in the microstrip section and from 77 to 110 Ohms in the CPS section. At the balun junction, the CPS stub lengths were chosen such that the X/ 8 resonance is pushed outside the bandwidth of operation. Also, the smallest allowable conductor width and gap spacing were chosen to meet acceptable manufacturing tolerances.

Venkatesan, Jaikrishina↗

Assessing Spectrum Compatibility for Beyond-Line-of-Sight UAS Control and Non-Payload Communications

In order to provide for the safe integration of unmanned aircraft systems (UAS) into the National Airspace System (NAS), the control and non-payload communications (CNPC) link must be highly reliable. A specific requirement is that it must operate using aviation safety radiofrequency spectrum. Two types of links are required - line-of-sight (LOS) using terrestrial-based communications and beyond-line- of-sight (BLOS) using satellite communications. The 2012 World Radiocommunication Conference (WRC-12) provided a suitable allocation for LOS CNPC spectrum in the 5030-5091 MHz band which, when combined with a previously existing allocation fulfills the LOS spectrum requirement. The 5030- 5091 MHz band is also allocated for BLOS CNPC, but since a significant portion of that band is required for LOS CNPC, additional BLOS spectrum is required. More critically, there are no satellites in operation or in development to provide such services in that band. Hence BLOS CNPC cannot be provided in protected aviation spectrum under current conditions. To fill this gap and enable integration of UAS into the NAS, it has been proposed to allow CNPC to operate over certain Fixed Satellite Service (FSS) bands in which many satellites currently provide commercial services. To enable this, changes in international regulation must be enacted. Agenda Item 1.5 of the 2015 WRC examines the possible regulatory changes needed. As part of the examination process, sharing between potential UAS using satellite communications for BLOS CNPC and other services allocated to the FSS bands being considered must be studied. This paper reviews the technical requirements and approach being undertaken for these sharing studies, with emphasis on study of interference from UAS into digital repeater links operating under the Fixed Service allocation. These studies are being conducted by NASA Glenn Research Center.

compatibility↗

An Efficient, Highly Flexible Multi-Channel Digital Downconverter Architecture

In this innovation, a digital downconverter has been created that produces a large (16 or greater) number of output channels of smaller bandwidths. Additionally, this design has the flexibility to tune each channel independently to anywhere in the input bandwidth to cover a wide range of output bandwidths (from 32 MHz down to 1 kHz). Both the flexibility in channel frequency selection and the more than four orders of magnitude range in output bandwidths (decimation rates from 32 to 640,000) presented significant challenges to be solved. The solution involved breaking the digital downconversion process into a two-stage process. The first stage is a 2 oversampled filter bank that divides the whole input bandwidth as a real input signal into seven overlapping, contiguous channels represented with complex samples. Using the symmetry of the sine and cosine functions in a similar way to that of an FFT (fast Fourier transform), this downconversion is very efficient and gives seven channels fixed in frequency. An arbitrary number of smaller bandwidth channels can be formed from second-stage downconverters placed after the first stage of downconversion. Because of the overlapping of the first stage, there is no gap in coverage of the entire input bandwidth. The input to any of the second-stage downconverting channels has a multiplexer that chooses one of the seven wideband channels from the first stage. These second-stage downconverters take up fewer resources because they operate at lower bandwidths than doing the entire downconversion process from the input bandwidth for each independent channel. These second-stage downconverters are each independent with fine frequency control tuning, providing extreme flexibility in positioning the center frequency of a downconverted channel. Finally, these second-stage downconverters have flexible decimation factors over four orders of magnitude The algorithm was developed to run in an FPGA (field programmable gate array) at input data sampling rates of up to 1,280 MHz. The current implementation takes a 1,280-MHz real input, and first breaks it up into seven 160-MHz complex channels, each spaced 80 MHz apart. The eighth channel at baseband was not required for this implementation, and led to more optimization. Afterwards, 16 second stage narrow band channels with independently tunable center frequencies and bandwidth settings are implemented A future implementation in a larger Xilinx FPGA will hold up to 32 independent second-stage channels.

Goodhart, Charles E.↗

Preliminary SnowSAR Results from SnowEx 2017

SnowEx 2017 was the first in a multi-year series of airborne remote sensing campaigns, designed to address gaps in snow retrieval techniques in preparation for a future snow satellite mission. A variety of sensor types were flown to collect multi-sensor airborne data. In combination with detailed ground truth, this multi-sensor dataset enables critical trade studies to determine optimum sensor-plus-model combinations for different snow conditions and confounding factors. Up to half of terrestrial snow-covered areas are forested, and forests are a major confounding factor for global snow retrievals. Therefore, the main focus of SnowEx 2017 was evaluating the performance of the various sensing techniques to retrieve snow water equivalent (SWE) under steadily increasing amounts of forest cover. The primary site of Grand Mesa, Colorado, USA was selected for its natural gradients of forest density and SWE with a minimum of other factors. Radar retrievals of SWE relying on volume scattering have been studied for three decades, using a variety of frequencies, with varying degrees of success. The most recent volume scattering algorithms have focused on using 2 to 3 frequencies and both co- and cross-polarizations in the 9—18 GHz range (X through Ku bands). As such, one of the primary SnowEx 2017 airborne sensors was a dual-band (X & Ku) radar, the SnowSAR. Earlier versions of SnowSAR were used in 2011 and 2012 campaigns in Finland as well as a 2013 campaign in Canada. For SnowEx 2017, SnowSAR was installed on a P-3 aircraft from the US Naval Research Laboratory. Challenges associated with the aircraft, the installation, schedule, and flying weather all contrived to limit the amount of data collected. However, months of painstaking processing has yielded data that should be of value to the original objectives of SnowEx 2017. This paper will describe in detail the SnowSAR data that were collected, and provide quality assessments of the backscatter coefficient in terms of date, time, location, frequency, polarization, snow conditions, overlap with ground truth sites, forest density, etc. The challenges as well as potential remedies/caveats will be described in order to help guide users and maximize exploitation of this valuable data.

airborne sensors↗

Spectroscopic study of the coupling effect between the two gaps of magnesium diboride on its RF properties

This program studied the two-gap nature of magnesium diboride and its possible effects on the superconducting rf properties of this material. Magnesium diboride (MgB 2 ) is a BCS superconductor with a superconducting critical temperature of 39 K, high critical current density and no weak link behavior across the grain boundary. These properties make this material ideal for both power applications and electronic devices. In particular, the high superconducting critical temperature and high thermodynamic field suggests that MgB 2 could be an ideal material also for superconducting radio frequency (SRF) cavities operating at a much higher temperature than Nb cavities and, therefore, reducing noticeably the cryogenics costs. However, MgB 2 is a two gap superconductor and it has been suggested that the RF properties are dominated by the smaller gap, which would make this material not competitive with Nb and especially Nb 3 Sn. The main problem does not seem to be the double-gap nature of this material but rather the weak-coupling of the two gaps that in the presence of an RF field suppresses superconductivity all together at fields much lower than the thermodynamic field. The main goal of this proposal is to address the fundamental question of the coupling between the two gaps in MgB 2 and understand if it is possible to control it and ultimately improve the RF performance of MgB 2 . The project studied these questions by measuring the density of states in the presence of an in-plane current and focused on the effect of controlled disorder. Disorder, indeed, provides an important knob to tune the properties of MgB2 and provides the possibility of changing the coupling between the two bands, making this material a competitive material for SRF applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Aperture-Coupled Thin-Membrane L-Band Antenna

The upper part of the figure depicts an aperture-coupled L-band antenna comprising patterned metal conductor films supported on two thin polyimide membranes separated by an air gap. In this antenna, power is coupled from a microstrip line on the lower surface of the lower membrane, through a slot in a metal ground plane on the upper surface of the lower membrane, to a radiating metal patch on the upper surface of the upper membrane. The two-membrane configuration of this antenna stands in contrast to a three-membrane configuration heretofore considered as the basis for developing arrays of dual-polarization, wideband microwave antennas that could be thin and could be, variously, incorporated into, or supported on, thin structures, including inflatable structures. By reducing the number of membranes from three to two, the present design simplifies the problems of designing and fabricating such antennas or arrays of such antennas, including the problems of integrating such antennas or arrays with thin-membrane-mounted transmit/ receive modules. In addition, the use of aperture (slot) coupling eliminates the need for rigid coaxial feed pins and associated solder connections on thin membranes, making this antenna more mechanically reliable, relative to antennas that include coaxial feed pins. This antenna is designed for a nominal frequency of 1.26 GHz. The polyimide membranes are 0.05 mm thick and have a relative permittivity of 3.4. The radiating patch is square, 8.89 cm on each side. This radiating patch lies 1.27 cm above the ground plane. The feeding microstrip line is 0.12 mm wide and has a characteristic impedance of 50 . The aperture-coupling slot, etched in the ground plane, is 0.48 mm wide and 79.5 mm long. In order to maximize coupling, the microstrip line is extended beyond the middle of the slot by a length of 36 mm, which corresponds to a transmission- line electrical length of about a quarter wavelength. The other end of the microstrip line is transformed to a 50-Ohm coplanar waveguide line, which is used for connection to a transmit/receive module. Some plated-through vias are added to the outer conductors of the coplanar waveguide to suppress parallel-plate modes. The measured and calculated 10-dB-return-loss bandwidth of the antenna is 100 MHz. By eliminating the radiating patch and the upper membrane that supports it, and performing two other simple modifications, one can convert the two-membrane antenna described above to a paper-thin single-membrane antenna, shown in the lower part of the figure. One modification is to increase the slot length to 104.95 mm; the other is to extend the microstrip to 36.68 mm past the middle of the slot. With these modifications, the slot now becomes a half-wavelength radiator with a nearly omnidirectional radiation pattern. In one potential use, such a paper-thin antenna could be pasted on an automobile window to enable omnidirectional communication.

Huang, John↗

Robust Optimization Design Algorithm for High-Frequency TWTs

Traveling-wave tubes (TWTs), such as the Ka-band (26-GHz) model recently developed for the Lunar Reconnaissance Orbiter, are essential as communication amplifiers in spacecraft for virtually all near- and deep-space missions. This innovation is a computational design algorithm that, for the first time, optimizes the efficiency and output power of a TWT while taking into account the effects of dimensional tolerance variations. Because they are primary power consumers and power generation is very expensive in space, much effort has been exerted over the last 30 years to increase the power efficiency of TWTs. However, at frequencies higher than about 60 GHz, efficiencies of TWTs are still quite low. A major reason is that at higher frequencies, dimensional tolerance variations from conventional micromachining techniques become relatively large with respect to the circuit dimensions. When this is the case, conventional design- optimization procedures, which ignore dimensional variations, provide inaccurate designs for which the actual amplifier performance substantially under-performs that of the design. Thus, this new, robust TWT optimization design algorithm was created to take account of and ameliorate the deleterious effects of dimensional variations and to increase efficiency, power, and yield of high-frequency TWTs. This design algorithm can help extend the use of TWTs into the terahertz frequency regime of 300-3000 GHz. Currently, these frequencies are under-utilized because of the lack of efficient amplifiers, thus this regime is known as the "terahertz gap." The development of an efficient terahertz TWT amplifier could enable breakthrough applications in space science molecular spectroscopy, remote sensing, nondestructive testing, high-resolution "through-the-wall" imaging, biomedical imaging, and detection of explosives and toxic biochemical agents.

Wilson, Jeffrey D.↗

Uncovering extreme nonlinear dynamics in solids through time-domain field analysis

Time-domain analysis of harmonic fields with sub-cycle resolution is now experimentally viable due to the emergence of sensitive, on-chip techniques for petahertz-scale optical-field sampling. We demonstrate how such a time-domain, field-resolved analysis uncovers the extreme nonlinear electron dynamics responsible for high-harmonic generation within solids. Time-dependent density functional theory was used to simulate harmonic generation from a solid-state band-gap system driven by near- to mid-infrared waveforms. Particular attention was paid to regimes where both intraband and interband emission mechanisms play a critical role in shaping the nonlinear response. We show that a time-domain analysis of the harmonic radiation fields identifies the interplay between intra- and interband dynamical processes underlying the nonlinear light generation. With further analysis, we show that changes to the dominant emission regime can occur after only slight changes to the peak driving intensity and central driving wavelength. Furthermore, time-domain analysis of harmonic fields also reveals, for the first time, the possibility of rapid changes in the dominant emission mechanism within the temporal window of the driving pulse envelope. Finally, we examine the experimental viability of performing time-domain analysis of harmonic fields with sub-cycle resolution using realistic parameters.

74 ATOMIC AND MOLECULAR PHYSICS↗

Metastable piezoelectric group-IV monochalcogenide monolayers with a buckled honeycomb structure

Multiple two-dimensional materials are being naïvely termed stable on the grounds of displaying phonon dispersions with no negative frequencies and of not collapsing on molecular dynamics calculations at fixed volume. But, if these phases do not possess the smallest possible structural energy, how does one understand and establish their actual meta stability? To answer this question, twelve two-dimensional group-IV monochalcogenide monolayers (SiS, SiSe, SiTe, GeS, GeSe, GeTe, SnS, SnSe, SnTe, PbS, PbSe, and PbTe) with a buckled honeycomb atomistic structure—belonging to symmetry group P3m1—displaying an out-of-plane intrinsic electric polarization are shown to be metastable by three independent methods. First, we uncover a coordination-preserving structural transformation from the low-buckled honeycomb structure onto the lower-energy Pnm2 1 (or Pmmn for PbS, PbSe, and PbTe) phase to estimate energy barriers E B that must be overcome during such structural transformation. Using the curvature of the local minima and E B as inputs to Kramers escape formula, large escape times are found, implying the structural metastability of the buckled honeycomb phase (with the exception of PbS and PbSe, these phases display escape times ranging from 700 years to multiple times the age of the universe and can be considered “stable” for practical purposes in that relative sense). The second demonstration is provided by phonon dispersion relations that include the effect of long-range Coulomb forces and display no negative vibrational modes. The third and final demonstration of structural metastability is furnished by room-temperature ab initio molecular dynamics for selected compounds. Here, the magnitude of the electronic band gap evolves with chemical composition. Different from other binary two-dimensional compounds such as transition metal dichalcogenide monolayers and hexagonal boron nitride monolayers which only develop an in-plane piezoelectric response, the twelve group-IV monochalcogenide monolayers with a buckled honeycomb structure also display out-of-plane piezoelectric properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Assessing Flooding Vulnerability to Assist High Water Intervention and Urban Planning Programs in the Charles River Watershed with NASA DEVELOP

The Charles River watershed intersects 35 municipalities within the Boston Metropolitan Area and has a total population of 1.2 million, making it one of the most densely populated watersheds in New England. In recent years, the watershed has observed higher rates of flood inundation, mainly due to increased development, extreme precipitation events, and increased surface runoff. As the frequency of flooding events increases and a changing climate poses an ongoing threat to local communities, governments and organizations in Massachusetts are in need of accurate flood risk assessments. NASA DEVELOP partnered with the Charles River Watershed Association, the Town of Natick’s Office of Sustainability, and the Massachusetts Audubon Society to assess flood vulnerability and susceptibility in the watershed. The team used Landsat 5 Thematic Mapper, Landsat 8 Operational Land Imager, Sentinel-1 C-Band Synthetic Aperture Radar, and Sentinel-2 MultiSpectral Instrument to assess the feasibility of identifying the extent of past flood events using remote sensing. After identifying images that overlapped with reported flood events, the team concluded that it was not feasible to use Earth observation data to detect localized flooding in the time available for this study. Instead, the Federal Emergency Management Agency (FEMA) 100-year floodplain was used as a proxy for areas where flooding may occur. The team used statistical regression analysis and validation and supervised classification to develop a flood susceptibility map, incorporating several flood conditioning factors. The susceptibility maps were calibrated to various thresholds, including two that highlight hypothetical flooding under more liberal and more conservative planning scenarios. These were overlaid with demographic and socioeconomic data to create flood vulnerability maps. The team’s flood susceptibility maps showed an improvement in capturing known flood events over the FEMA 100-year and 500-year floodplain maps. These results will be improved with the addition of stormwater drainage mapping and precipitation data. Results can be used to fill in the gaps to help the stakeholders understand their communities’ vulnerability and susceptibility to flooding and improve their preparedness plans.

Trista Brophy↗