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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

In situ electrosynthesis of anthraquinone electrolytes in aqueous flow batteries

In this work, we demonstrate the electrochemical oxidation of an anthracene derivative to a redox-active anthraquinone at room temperature in a flow cell without the use of hazardous oxidants or noble metal catalysts. The anthraquinone, generated in situ, was used as the active species in a flow battery electrolyte without further modification or purification. This potentially scalable, safe, green, and economical electrosynthetic method is also applied to another anthracene-based derivative and may be extended to other redox-active aromatics.

25 ENERGY STORAGE↗
DOE OSTI2026

CO2 Handling & Electrolyzer Efficiency Scaling Evaluator

CHEESE is an interactive dashboard tool for estimating the performance and material requirements of carbon dioxide electrolysis systems. It helps users evaluate how electrode area, current density, product selectivity, gas flow, cell voltage, and the number of cells in a stack affect system operation. The dashboard provides simple and advanced modes so it can be used for both quick estimates and more detailed engineering analysis. Users can estimate product output, carbon dioxide use, electrical power, electrode area, gas and liquid flow rates, energy efficiency, material cost per test, and the effect of scaling from a single cell to a multi cell stack. It also includes tools for examining carbon balance, equipment durability, component replacement, and changes in performance over time. This is intended to help both academia and industry researchers who are either getting into CO2 electrolysis on lab-scale or are trying to establish a larger footprint. CHEESE presents results through tables, charts, and simplified cell and stack diagrams. It is intended to support research planning, experimental design, comparison of operating conditions, and early stage scale up studies.

Prajapati, Aditya [Lawrence Livermore National Lab↗
DOE OSTI2024

Oxadiazole derivatives as stable anolytes for >3 V non-aqueous redox flow battery

Effective utilization of energy from renewable sources such as wind and solar requires the development of long duration energy storage (LDES) systems that can accommodate intermittent energy accrual. One option under investigation is the use of a redox flow battery (RFB). A significant amount of work has explored aqueous RFB systems with a variety of inorganic and organic carriers. However, moving to a nonaqueous solvent such as acetonitrile (MeCN) for RFB provides a much larger electrochemical window, which could lead to increased energy density if properly utilized. Here, in this work, we investigate a series of 2,5-diphenyl-1,3,4-oxadiazole (DiPhenOx) derivatives as anolytes for a redox flow battery. DiPhenOx has a low voltage redox event that, while reversible by cyclic voltammetry, was determined to be irreversible during bulk electrolysis. To improve cycling performance, we introduced various ester and cyano groups to the phenyl rings of DiPhenOx using molecular engineering. We characterized these derivatives spectroscopically and electrochemically to assess their feasibility for flow battery applications. The ester derivatives with the best cycling performance were tested in a flow cell vs. ferrocene, 2,5-di-tert-butyl-1,4-bis(2-methoxyethoxy)benzene (DBBB) and thianthrene, which resulted in ~2 V, ~3 V and ~3 V redox flow batteries, respectively.

25 ENERGY STORAGE↗
NASA NTRS2021

Design and Development of Nano-electro Fuel Batteries and Rim-driven Motors for Electrified Aircraft Applications

The National Aeronautics and Space Administration Convergent Aeronautics Solutions project seeks to determine feasibility of emerging technologies in aeronautics. The Aqueous, QUick-Charging Battery Integration For Electric flight Research study pursued the feasibility of nano-electro fuel and rim-driven motor technologies integrated together for aircraft implementation. Development of the NEF technology was in partnership with Influit Energy, LLC (Chicago, Illinois). A rim-driven motor, designed by the project team, sized to represent one of 24 motors in the propulsion system of the tandem electric super-short takeoff and landing aircraft is discussed. The development of this electric super-short takeoff and landing concept was in partnership with The Boeing Company (Chicago, Illinois). The integrated system design of the nano-electro fuel and rim-driven motor technologies within the wing section was in partnership with Empirical Systems Aerospace, Inc. (ESAero) (San Luis Obispo, California). The feasibility benchmark for the nano-electro fuel battery was to attain 100 mA/sq. cm within two years, a 50-fold increase over the demonstrated cell performance before the Convergent Aeronautics Solutions Aqueous, QUick-Charging Battery Integration For Electric flight Research activity. The team achieved 85 mA/sq. cm in the nano-electro fuel flow cell at the end of the two years. The Aqueous, QUick-Charging Battery Integration For Electric flight Research project team determined the technology to be both inflammable and nonexplosive (unless multiple, simultaneous system failures occur) which would provide a safer alternative to conventional lithium-ion based battery systems.

Kurt V. Papathakis↗
NASA NTRS1989

Laboratory and theoretical studies of baroclinic processes

An understanding is being developed for processes which may be important in the atmosphere, and the definition and analysis of baroclinic experiments utilizing the geophysical fluid flow cells (GFFC) apparatus in microgravity space flights. Included are studies using numerical codes, theoretical models, and terrestrial laboratory experiments. The numerical modeling is performed in three stages: calculation of steady axisymmetric flow, calculation of fastest-growing linear eigenmodes, and nonlinear effects (first, wave-mean flow interactions, then wave-wave interactions). The code can accommodate cylindrical, spherical, or channel geometry. It uses finite differences in the vertical and meridional directions, and is spectral in the azimuthal. The theoretical work was mostly in the area of effects of topography upon the baroclinic instability problem. The laboratory experiments are performed in a cylindrical annulus which has a temperture gradient imposed upon the lower surface and an approximately isothermal outer wall, with the upper and inner surfaces being nominally thermally insulating.

Miller, Timothy↗
DOE OSTI2025

Ultrathin liquid sheets: water gets in shape for VUV absorption

We present absorption spectra of thin, free-flowing liquid sheets in the vacuum ultraviolet energy range using a gas-squeezed liquid jet. Compared to liquid flow cells, operation without transmission windows eliminates restrictions on the energy range. The temperature of the water sheet is estimated at 0 ± 3 °C, at the verge of the supercooled regime. By adjusting flow conditions in situ, we recorded absorption spectra at water sheet thicknesses ranging from 20 to 50 nm. We show that the absorption spectra of thin jets contain significant contributions from interference effects that need to be deconvoluted from spectral contributions due to the electronic structure. We employ a Fresnel propagation model to model the spectral changes and understand the impact of thickness variations and thin film interference. This opens the door for the investigation of solvation, interface, and similar effects by recording valence band spectra.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Basic studies of baroclinic flows

A fully nonlinear 3-dimensional numerical model (GEOSIM), previously developed and validated for several cases of geophysical fluid flow, has been used to investigate the dynamical behavior of laboratory experiments of fluid flows similar to those of the Earth's atmosphere. The phenomena investigated are amplitude vacillation, and the response of the fluid system to uneven heating and cooling. The previous year's work included hysteresis in the transition between axisymmetric and wave flow. Investigation is also continuing of the flows in the Geophysical Fluid Flow Cell (GFFC), a low-gravity Spacelab experiment. Much of the effort in the past year has been spent in validation of the model under a wide range of external parameters including nonlinear flow regimes. With the implementation of a 3-dimensional upwind differencing scheme, higher spectral resolution, and a shorter time step, the model has been found capable of predicting the majority of flow regimes observed in one complete series of baroclinic annulus experiments of Pfeffer and co-workers. Detailed analysis of amplitude vacillation has revealed that the phase splitting described in the laboratory experiments occurs in some but not all cases. Through the use of animation of the models output, a vivid 3-dimensional view of the phase splitting was shown to the audience of the Southeastern Geophysical Fluid Dynamics Conference in March of this year. A study on interannual variability was made using GEOSIM with periodic variations in the thermal forcing. Thus far, the model has not predicted a chaotic behavior as observed in the experiments, although there is a sensitivity in the wavenumber selection to the initial conditions. Work on this subject, and on annulus experiments with non-axisymmetric thermal heating, will continue. The comparison of GEOSIM's predictions will result from the Spacelab 3 GFFC experiments continued over the past year, on a 'back-burner' basis. At this point, the study (in the form of a draft of a journal article) is nearly completed. The results from GEOSIM compared very well with the experiments, and the use of the model allows the demonstration of flow mechanics that were not possible with the experimental data. For example, animation of the model output shows that the forking of the spiral bands is a transient phenomenon, due to the differential east-west propagation of convection bands from different latitudes.

Miller, Timothy L.↗
NASA NTRS1977

Gels as battery separators for soluble electrode cells

Gels are formed from silica powders and hydrochloric acid. The gels are then impregnated into a polymeric foam and the resultant sheet material is then used in applications where the transport of chloride ions is desired. Specifically disclosed is the utilization of the sheet in electrically rechargeable redox flow cells which find application in bulk power storage systems.

Sheibley, D. W.↗
DOE OSTI2025

A polysulfide/ferricyanide redox flow battery with extended cycling

The inexpensive sulfur raw material is promising to enable cost-effective redox flow batteries for long duration energy storage. But the catastrophic through-membrane crossover of polysulfides remains a severe challenge resulting in irreversible performance degradation and short cycle life. In this work, we demonstrate that use of a permselective cation exchange membrane yields a two orders of magnitude enhancement in polysulfide retention compared to the benchmark Nafion membrane. Combined physico-chemical, spectroscopic, and microscopic analyses suggest more disordered sidechain structures, which lead to the more hydrophobic nature and smaller hydrophilic domains in the membrane. The microstructural features contribute to the effective mitigation of polysulfide crossover. As a result, the cycle life of polysulfide/ferricyanide flow cells is boosted over a substantially extended test time. This finding sheds light on the fundamental membrane factors that cause polysulfide permeation and can provide feasible directions in the development of permselective membranes for polysulfide flow batteries.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Along the Channel Gradients Impact on the Spatioactivity of Gas Diffusion Electrodes at High Conversions during CO 2 Electroreduction

Results of a 2-D transport model for a gas diffusion electrode performing CO 2 reduction to CO with a flowing catholyte are presented, including the concentration gradients along the flow cell, spatial distribution of the current density and local pH in the catalyst layer. The model predicts that both the concentration of CO 2 and the buffer electrolyte gradually diminish along the channels for a parallel flow of gas and electrolyte as a result of electrochemical conversion and nonelectrochemical consumption. At high single-pass conversions, significant concentration gradients exist along the flow channels leading to large local variations in the current density (>150 mA/cm 2 ), which becomes prominent when compared to ohmic losses. In addition, concentration overpotentials change dramatically with CO 2 flow rate, which results in significant differences in outlet concentrations at high conversions. The outlet concentration of CO attains a maximum of 80% along with 5% CO 2 and 15% H 2 , although the maximum single-pass conversion is limited to below 60% due to homogeneous consumption by the electrolyte. Fundamental and practical implications of our findings on electrochemical CO 2 reduction are discussed with a focus on the trade-off between high current density operation and high single-pass conversion efficiency.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2008

Modifications and Modelling of the Fission Surface Power Primary Test Circuit (FSP-PTC)

An actively pumped alkali metal flow circuit, designed and fabricated at the NASA Marshall Space Flight Center, underwent a range of tests at MSFC in early 2007. During this period, system transient responses and the performance of the liquid metal pump were evaluated. In May of 2007, the circuit was drained and cleaned to prepare for multiple modifications: the addition of larger upper and lower reservoirs, the installation of an annular linear induction pump (ALIP), and the inclusion of the Single Flow Cell Test Apparatus (SFCTA) in the test section. Performance of the ALIP, provided by Idaho National Laboratory (INL), will be evaluated when testing resumes. The SFCTA, which will be tested simultaneously, will provide data on alkali metal flow behavior through the simulated core channels and assist in the development of a second generation thermal simulator. Additionally, data from the first round of testing has been used to refine the working system model, developed using the Generalized Fluid System Simulation Program (GFSSP). This paper covers the modifications of the FSP-PTC and the updated GFSSP system model.

Garber, Ann E.↗
DOE OSTI2022

Soluble and stable symmetric tetrazines as anolytes in redox flow batteries

We report nonaqueous redox flow batteries are a promising technology for grid-scale energy storage, however, their commercial success relies on identifying redox-active materials that exhibit extreme potentials, high solubilities in all states of charge, and long cycling stabilities. Meeting these requirements has been particularly challenging for molecules capable of storing negative charge. Within this context, tetrazines remain unexplored despite their unique structural properties that enable them to meet some of these challenges. Herein, we prepared symmetric s-tetrazines substituted with methyl, methoxy, and thiomethyl substituents and evaluated their electrochemical properties, solubility, and cycling stability. These studies revealed that highly soluble 3,6-dimethoxy-s-tetrazine undergoes a reversible one-electron reduction to generate a stable (t 1/2 > 1240 h) radical anion. When implemented in a lab-scale symmetric flow cell (0.125 M), it exhibited a relatively slow capacity fade of 8% over 50 cycles (17 h). Given their high solubility and cycling stability, we believe that s-tetrazine derivatives should be further explored for nonaqueous redox flow batteries.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Basic studies of baroclinic flows

Computations were completed of transition curves in the conventional annulus, including hysteresis effect. The model GEOSIM was used to compute the transition between axisymmetric flow and baroclinic wave flow in the conventional annulus experiments. Thorough testing and documentation of the GEOSIM code were also completed. The Spacelab 3 results from the Geophysical Fluid Flow Cell (GFFC) were reviewed and numerical modeling was performed of many of the cases with horizontal temperature gradients as well as heating from below, with different rates of rotation. A numerical study of the lower transition to axisymmetric flow in the baroclinic annulus was performed using GEOSIM.

Miller, Tim L.↗
DOE OSTI2024

Screening aqueous organic redox couples for spontaneous hydrogen generation on catalysts

Two low-cost redox couples with near neutral or alkaline pH - 7,8-dihydroxyphenazine-2-sulfonic acid (DHPS) and chrome chelated ethylenediaminetetraacetic acid (Cr-EDTA) with ammonia – are identified to generate hydrogen evolution spontaneously on Pt/C catalysts. Cr-EDTA redox couple has two times higher hydrogen evolution rate than that of DHPS, and the charged Cr-EDTA molecules are fully utilized to generate hydrogen gas, while ~ 50% of DHPS molecules are utilized to produce hydrogen spontaneously on Pt/C catalysts. The Cr-EDTA electrolyte enables cost reduction by allowing cheap raw material of Cr and corrosion resistant alloy instead of costly superalloy for catalytic reactor systems. Furthermore, the Cr-EDTA with ammonia as a negolyte for flow batteries was validated to suppress hydrogen evolution side reaction, reach 99% of coulombic efficiency in flow cell operation paired with Fe(CN)6 redox couple near neutral pH.

08 HYDROGEN↗
DOE OSTI2021

Development of High Energy Density Diaminocyclopropenium-Phenothiazine Hybrid Catholytes for Non-Aqueous Redox Flow Batteries

Our work describes the design of diaminocyclopropenium-phenothiazine hybrid catholytes for non-aqueous redox flow batteries. The molecules are synthesized in a rapid and modular fashion by appending a diaminocyclopropenium (DAC) substituent to the nitrogen of the phenothiazine. Combining a versatile C-N coupling protocol (which provides access to diverse derivatives) with computation and structure-property analysis enabled the identification of a catholyte that displays stable two-electron cycling at potentials of 0.64 and 1.00 V vs. Fc/Fc + as well as high solubility in all oxidation states (≥0.45 M in TBAPF 6 /MeCN). This catholyte was deployed in a high energy density two-electron RFB, exhibiting >90 % capacity retention over 266 hours of flow cell cycling at >0.5 M electron concentration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

On the magnetoaerothermal instability

A fundamental instability in MHD channel flow, hitherto unknown or unappreciated, is described. Lorentz force-driven secondary flow cells preferentially couple core temperature gradient modes into the near fields of the anode wall leading to a locally growing Lorentz force which eventually separates the anode boundary layer. The instability is described with both heuristic order-of-magnitude analyses and detailed three-dimensional, turbulent, MHD flow computations. This magnetoaerothermal instability will be manifested in commercial scale MHD generators of moderate MHD interaction parameter. Methods of control and prevention of the magnetoaerothermal instability exist.

Demetriades, S. T.↗
NASA NTRS1990

Theoretical and experimental studies of baroclinic processes

The geophysical fluid flow simulation code, GEOSIM, is being used to study the phenomenon of vacillation in the baroclinic annulus. Having verified that the code predicts vacillation for the same points as the experiments, the work is aiming toward explaining the mechanics of vacillation and pointing out some of the sensitivities of the results to the numerical method. Researchers are finding that there is a structural change associated with amplitude vacillation, where the structural changes are in the vertical. The results disagree with the premise of Lindzen et al, that the vacillation is due to constructive and destructive interference of neutral modes with different phase speeds. The researchers are continuing to study the Spacelab 3 Geophysical Fluid Flow Cell (GFFC) results with horizontal temperature gradients and heating from below. GEOSIM has been used to compute a wide range of cases, and these are being compared with the observations. The computations and observations compare well, and the model is being used to extend the results beyond cases studied in the experiments and to study the mechanics and predictability of the flows. The study of fully nonlinear baroclinic instability using the GFFC apparatus is proceeding with the numerical code. While the first instability that occurs is of planetary scale, secondary instabilities consisting of small-scale, penetrative convection occurs where cold fluid flows over a warm surface. The simultaneous modeling of the planetary scale and the convective scale is possible because of the nonhydrostatic formulation of the model. Some of these results have been animated on the Stardent computer, which shows the explosive nature of the small-scale convection.

Miller, Tim↗
NASA NTRS1975

Cost and size estimates for an electrochemical bulk energy storage concept

Preliminary capital cost and size estimates were made for a titanium trichloride, titanium tetrachloride, ferric chloride, ferrous chloride redox-flow-cell electric power system. On the basis of these preliminary estimates plus other important considerations, this electrochemical system emerged as having great promise as a bulk energy storage system for power load leveling. The size of this system is less than two per cent of that of a comparable pumped hydroelectric plant. The estimated capital cost of a 10 MW, 60- and 85-MWh redox-flow system compared well with that of competing systems.

Warshay, M.↗