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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Iodine Capture Studies of Copper- and Bismuth-Based Sorbents

The release of radioiodine, one of several radionuclides of concern when recycling used nuclear fuel (UNF), is an important consideration in the fuel cycle. In this study, two sorbent materials, Cu 0 -polyacrylonitrile (PAN) and Bi 0 -PAN, were tested as solid sorbent candidates for iodine capture. Experiments using a thin bed of sorbent material were exposed to vaporized iodine for over 300 hours (~2 weeks) under varied conditions in a dynamic flow environment. The overall performance was monitored in real-time using thermogravimetric analysis, and the materials were subsequently characterized for surface and bulk analysis using scanning electron microscopy – energy-dispersive spectroscopy (SEM-EDS) and powder x-ray diffraction (pXRD), respectively. Iodine (in the form of I 2 ) is expected to be released primarily in the dissolver off-gas (DOG) stream; therefore, this study demonstrates the effects of elemental iodine (I 2 ), water vapor (H 2 O), and nitrogen dioxide (NO 2 ). When exposed to ‘ideal’ conditions (in which I 2 is carried by dry air), Cu 0 -PAN and Bi 0 -PAN behave differently, with TGA analysis indicating that Cu 0 sorption performance is higher than that of Bi 0 , as evidenced by a larger mass change. Under ‘harsh’ conditions—such as a gaseous feed containing I 2 , H 2 O, and NO 2 vapors carried by air,—iodine capture performance for both Cu 0 - and Bi 0 -PAN are affected. SEM-EDS and pXRD analysis of these materials is discussed herein.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Probing the Critical Element Chemistry of Coal-Combustion Fly Ash: Examination of Zircon and Associated Minerals from a Beneficiated Kentucky Fly Ash

Along with the principal rare earth (REE) minerals such as monazite, xenotime, and bastnasite, Y-and REE-bearing zircon and associated minerals survive the combustion process and are found in coal-combustion fly ash. Beneficiated fly ash from a power plant burning an eastern-Kentucky-sourced coal blend was found to have zircon (ZrSiO4), baddeleyite (ZrO2), fergusonite (YNbO4), yttriaite (Y2O3), and xenotime (YPO4). Previous studies of the same fly had also identified monazite with a broad REE suite. Scanning electron microscopy–electron dispersive spectroscopy (EDS) and transmission electron microscopy (TEM)–EDS as well as other TEM-based techniques revealed a variety of zircon associations, including heavy-REE suites with Y, Nb, and Hf. Hafnium is a common accessory element in zircons and the Y and Nb may be present as fergusonite (YNbO4) intermixed with zircon.

Berti, Debora (ORCID:0000000311237794)↗
DOE OSTI2024

Focused Ion Beam Tomography of Alloy 617 Corroded in Molten Chloride Salt

Materials qualification of reactor structural materials is a critical step in rapid implementation of advanced nuclear reactor technologies, particularly to assess the corrosion performance in these designs. Accelerated qualification of reactor structural materials requires incorporating powerful computational toolsets, such as phase field modelling in the Multiphysics Object-Oriented Simulation Environment (MOOSE) framework, to predict the evolution of structural materials due to corrosion. Accordingly, computational toolsets will require experimental data generated at appropriate length scales to validate accuracy. Focused ion beam (FIB) provides a high degree of control over manipulation of materials for analytical purposes, including capturing data on the evolution in the microstructure and elemental composition of materials at the mesoscale, an appropriate length scale for phase field modelling of intergranular diffusion phenomena using the MOOSE framework. For instance, the FEI Helios G4 UX dual beam plasma FIB microscope at the Irradiated Materials Characterization Laboratory (IMCL) is capable of backscatter diffraction (EBSD) and energy-dispersive x-ray spectroscopy (EDS) documenting the evolution in the microstructure and elemental composition, respectively. The Helios can perform EDS and EBSD three-dimensionally (3D) using tomography, which is then combined using different software packages to visualize 3D volumes correlating elemental composition to microstructural data. The purpose of this investigation was to develop a streamlined characterization and data processing workflow for 3D tomography studies on the FEI Helios G4 plasma FIB. The investigation is segmented into three parts: 1) Optimizing the data collection workflow, 2) identifying appropriate data processing and visualization software (i.e. DREAM.3D, MIPAR, and VGStudioMax), and 3) establishing an infrastructure for public release. The optimization of the data collection workflow is in collaboration with members of the U220 department to setup formal training on the tomography operation of the G4, through ThermoFisher Scientific, and exploring DREAM.3D, MIPAR, and VGStudioMax data processing/visualization software packages. VGStudioMax currently demonstrates the most promise for future use. Optimization of the data collection and processing workflow is still ongoing. A collaboration with INL High Performance Computing (HPC) established an open-source license for expediting the public release of FIB tomography datasets through HPC. FIB tomography data generated by the G4 will provide comprehensive data for validating 3D phase field mesoscale modelling tools within the MOOSE framework for accelerated qualification of reactor structural materials.

Copeland-Johnson, Trishelle↗
NASA NTRS1971

The relation of the European Datum to a geocentric reference system

Over 31,000 precision reduced optical observations of GEOS-1 and 2 in 70 two-day orbital arcs were used at Goddard Space Flight Center (GSFC) in a dynamical solution to determine center-of-mass coordinates for 15 tracking stations on the European Datum. Comparisons with the results obtained at Centre National d'Etudes Spatiales (CNES) give agreement of about 1.5 ppm for chord lengths. After considering a scale correction to the European Datum (ED) of 1950 to account for the absence of geoid heights at the time of its reduction, agreement to a few ppm between the CNES/GSFC and the ED chords is obtained. However, a small systematic difference between survey and satellite results remains for stations in southeastern France and Switzerland.

Marsh, J. G.↗
NASA NTRS1972

Quantitative simultaneous multi-element microprobe analysis using combined wavelength and energy dispersive systems

A combined WDS-EDS system obviates the severe X-ray peak overlap problems encountered with Na, Mg, Al and Si common to pure EDS systems. By application of easily measured empirical correction factors for pulse pile-up and peak overlaps which are normally observed in the analysis of silicate minerals, the accuracy of analysis is comparable with that expected for WDS electron microprobe analyses. The continuum backgrounds are subtracted for the spectra by a spline fitting technique based on integrated intensities between the peaks. The preprocessed data are then reduced to chemical analyses by existing data reduction programs.

Walter, L. S.↗
NASA NTRS1985

Hypervelocity impacts on Skylab 4/Apollo windows

The three largest Skylab 4 Command Module windows that were exposed for 84 days to space were optically scanned for impact features as small as 30 microns in diameter. This scanning effort which was carried out at an opptical magnification of 35x, detected features approximately three times smaller than were found in the original 5x scanning effort over the entire window surface. Some 289 features were recorded from the 35x scan for later detailed analyses. Sixty of the largest and most promising features were cored from the windows for SEM and energy-dispersive X-ray spectrometer (EDS) analysis. Twenty-six of the cores contained craters with glassy pits, and of these, fourteen were found to contain strikingly obvious liners coating the interior of the glassy pit. The six largest features cored from the windows do not have a central glassy pit which leaves their previously reported hypervelocity origin in some doubt. The remaining twenty-eight features that were cored from the windows show no clear evidence for a hypervelocity origin and evidence available at this time is insufficient to identify an origin in Earth orbit or as ground damage. The EDS analysis of six of the seven liners that were examined show detectable aluminum in the liner or lip of the glassy pit. The source of aluminum is most probably an Earth orbiting population of aluminum oxide spherules, exhaust from solid rocket motors.

Clanton, U. S.↗
NASA NTRS1986

Fluid and protein shifts after postural changes in humans

The effects of head-up, one-step, slow-graded, and rapid-graded tilt positions on blood density (BD), plasma density (PD), and erythrocyte density (ED) in male and female subjects are evaluated using a mass density detection method. The preparation of the samples and procedures for density and hematocrit measurements are described. The formula for calculating the density and volume of fluid shifted between intravascular and extravascular compartments is derived. The data reveal that ED does not change with varying tilt positions; however, PD and BD increase linearly with increasing angles of tilt, thereby resembling the time course of hemodilution and hemoconcentration.

Hinghofer-Szalkay, H.↗
NASA NTRS1986

Description of the Mast Flight System

The Mast Flight System is composed of several subsystems. Primary among these is the Deployable Mast Subsystem (DMS) which consists of a beam assembly and an associated mechanism for deploying and retracting the beam. The beam assembly is a joint dominated graphite epoxy and titanium truss as is expected of future large space structures. Integral to the beam assembly are actuators, sensors and associated electronics which are available for excitation and damping as desired by the experimenter. The beam structural characteristics can also be modified as desired by the experimenter using the Parameter Modification Device installed at the end of the beam. Data measured on the beam by the sensors and commands to the actuators are transmitted along the beam digitally at 150 Hz using a standard 1553 type bus. The Modular Distributed Information Sybsystem (MDIS) computer functions as bus master and ensures that all experimental data is saved for future analysis. The MDIS computer also performs a safing function to prevent inadvertent overexcitation of the beam. Finally, the Excitation and Damping Subsystem (EDS) computer is available to the experimenter for implementation of control algorithms or any other numerical operations as desired. Data from all system sensors can be accessed by the EDS computer.

Talcott, Ronald C.↗
NASA NTRS1990

Thin film eddy current impulse deicer

Two new styles of electrical impulse deicers has been developed and tested in NASA's Icing Research Tunnel. With the Eddy Current Repulsion Deicing Boot (EDB), a thin and flexible spiral coil is encapsulated between two thicknesses of elastomer. The coil, made by an industrial printed circuit board manufacturer, is bonded to the aluminum aircraft leading edge. A capacitor bank is discharged through the coil. Induced eddy currents repel the coil from the aluminum aircraft structure and shed accumulated ice. A second configuration, the Eddy Current Repulsion Deicing-Strip (EDS) uses an outer metal erosion strip fastened over the coil. Opposite flowing eddy currents repel the strip and create the impulse deicing force. The outer strip serves as a surface for the collection and shedding of ice and does not require any structural properties. The EDS is suitable for composite aircraft structures. Both systems successfully dispelled over 95 percent of the accumulated ice from airfoils over the range of the FAA icing envelope.

Smith, Samuel O.↗
NASA NTRS1991

Preliminary studies on NiAl/Nb2Be17 reaction and effectiveness of BeO as an interfacial reaction barrier

The interfacial reaction between NiAl and Nb2Be17 (used as a reinforcement for the alloy) was studied by measuring diffusion bonding of NiAl and Nb2Be17 plates in a hot press under a vacuum of 10 exp -5 atm. It was found that, after 2 hrs of hot pressing at 1373 K, the reaction between NiAl and Nb2Be17 was extensive. A 40 to 50-micron-thick reaction zone consisted of three distinct layers at the NiAl/Nb2Be17 interface: layer A next to Nb2Be17, layer B in the middle, and layer C next to NiAl. Results of analysis of the reaction layers using energy dispersive spectroscopy (EDS) were inconclusive because of the inabiliaty of EDS to detect Be.

Misra, Ajay K.↗
NASA NTRS1992

Tensile properties of cast titanium alloys: Titanium-6Al-4V ELI and Titanium-5Al-2.5Sn ELI

This work was performed to determine the tensile properties of cast, hot isostatic pressed (HIP'ed), and annealed titanium alloys, Ti-6Al-4V ELI and Ti-5Al-2.5Sn ELI, that are candidate materials for the space transportation main engine (STME) liquid hydrogen turbopump impeller. Samples of the cast alloys were HIP'ed, annealed, and machined into tensile specimens. The specimens were tested in air at ambient temperature (70 F) and also at -423 F in liquid hydrogen. The Ti-6Al-4V alloy had an average ultimate strength of 129.1 ksi at 70 F and 212.2 ksi at -423 F. The Ti-5Al-2.5Sn alloy had an average ultimate strength of 108.4 ksi at 70 degrees F and 185.0 ksi at -423 F. The ductility, as measured by reduction of area, for the Ti-6Al-4V averaged 15.2 percent at 70 F and 8.7 percent at -423 F, whereas for the Ti-5Al-2.5Sn alloy average reduction of area was 24.6 percent at 70 F and 11.7 percent at -423 F.

Billinghurst, E. E., Jr.↗
NASA NTRS1993

Low cycle fatigue behavior of polycrystalline NiAl at 300 and 1000 K

The low cycle fatigue behavior of polycrystalline NiAl was determined at 300 and 1000 K - temperatures below and above the brittle- to-ductile transition temperature (BDTT). Fully reversed, plastic strain-controlled fatigue tests were conducted on two differently fabricated alloy samples: hot isostatically pressed (HIP'ed) prealloyed powder and hot extruded castings. HIP'ed powder (HP) samples were tested only at 1000 K, whereas the more ductile cast-and-extruded (C+E) NiAl samples were tested at both 1000 and 300 K. Plastic strain ranges of 0.06 to 0.2 percent were used. The C+E NiAl cyclically hardened until fracture, reaching stress levels approximately 60 percent greater than the ultimate tensile strength of the alloy. Compared on a strain basis, NiAl had a much longer fatigue life than other B2 ordered compounds in which fracture initiated at processing-related defects. These defects controlled fatigue life at 300 K, with fracture occurring rapidly once a critical stress level was reached. At 1000 K, above the BDTT, both the C+E and HP samples cyclically softened during most of the fatigue tests in air and were insensitive to processing defects. The processing method did not have a major effect on fatigue life; the lives of the HP samples were about a factor of three shorter than the C+E NiAl, but this was attributed to the lower stress response of the C+E material. The C+E NiAl underwent dynamic grain growth, whereas the HP material maintained a constant grain size during testing. In both materials, fatigue life was controlled by intergranular cavitation and creep processes, which led to fatigue crack growth that was primarily intergranular in nature. Final fracture by overload was transgranular in nature. Also, HP samples tested in vacuum had a life three times longer than their counterparts tested in air and, in contrast to those tested in air, hardened continuously over half of the sample life, thereby indicating an environmentally assisted fatigue damage mechanism. The C+E samples were tested only in air. At 1000 K, NiAl exhibited a superior fatigue life when compared to most superalloys on a plastic strain basis, but was inferior to most superalloys on a stress basis.

Lerch, Bradley A.↗
NASA NTRS1993

High temperature annealing of minority carrier traps in irradiated MOCVD n(+)p InP solar cell junctions

Deep level transient spectroscopy was used to monitor thermal annealing of trapping centers in electron irradiated n(+)p InP junctions grown by metalorganic chemical vapor deposition, at temperatures ranging from 500 up to 650K. Special emphasis is given to the behavior of the minority carrier (electron) traps EA (0.24 eV), EC (0.12 eV), and ED (0.31 eV) which have received considerably less attention than the majority carrier (hole) traps H3, H4, and H5, although this work does extend the annealing behavior of the hole traps to higher temperatures than previously reported. It is found that H5 begins to anneal above 500K and is completely removed by 630K. The electron traps begin to anneal above 540K and are reduced to about half intensity by 630K. Although they each have slightly different annealing temperatures, EA, EC, and ED are all removed by 650K. A new hole trap called H3'(0.33 eV) grows as the other traps anneal and is the only trap remaining at 650K. This annealing behavior is much different than that reported for diffused junctions.

Messenger, S. R.↗
NASA NTRS1995

Image and compositional characteristics of the LDEF Big Guy impact crater

A 5.2 mm crater in Al-metal represents the largest found on LDEF. We have examined this crater by field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) and time-of-flight/secondary ion mass spectroscopy (TOF-SIMS) in order to determine if there is any evidence of impactor residue. Droplet and dome-shaped columns, along with flow features, are evidence of melting. EDS from the crater cavity and rim show Mg, C, O and variable amounts of Si, in addition to Al. No evidence for a chondritic impactor was found, and it hypothesized that the crater may be the result of impact with space debris.

Bunch, T. E.↗
NASA NTRS1989

The Wavelength-Dispersive Spectrometer and Its Proposed Use in the Analytical Electron Microscope

The Analytical Electron Microscope (AEM) equipped with a wavelength-dispersive spectrometer (WDS) should have the ability to resolve peaks which normally overlap in the spectra from an energy-dispersive spectrometer (EDS). With a WDS it should also be possible to measure lower concentrations of elements in thin foils due to the increased peak-to-background ratio compared with EDS. The WDS will measure X-ray from the light elements (4 less than Z less than 1O) more effectively. This paper addresses the possibility of interfacing a compact WDS with a focussing circle of approximately 4 cm to a modem AEM with a high-brightness (field emission) source of electrons.

Goldstein, Joseph I.↗
NASA NTRS1995

Long Duration Exposure Facility

The Long Duration Exposure Facility (LDEF) materials were useful for testing technical concepts that needed to be validated for the Cosmic Dust Collector Facility (CDCF) - a large instrument that was under study for inclusion on the upcoming Space Station. As it turned out, CDCF, which was approved at one point as an external payload, was ultimately canceled due to the scaling back of the Space Station capabilities. However, the study of cosmic dust is still a field of great interest for NASA, being the crucial part of at least one experiment that is still being considered for a Discovery mission. The optimum analysis of hypervelocity impacts is thus a continuing NASA concern. Two experiments, AO187-1 and AO187-2 were explicitly designed to measure the flux and composition of dust particles impacting LDEF. The former consisted of flat targets of Au and Al while the second comprised a set of 237 "capture cells" using Ge target plates covered by thin (2.5 microns) metallized plastic foils. The spacecraft maintained a constant orientation with respect to its velocity vector thereby defining leading and trailing edges that faced respectively into and away from the direction of motion. Both AO187-1 and AO187-2 had detectors on both the leading and trailing edges of LDEF. It was expected that interplanetary dust particles would dominate impacts on the trailing edge while the leading edge would be exposed to both cosmic dust and particles of orbital manmade debris. In AO187-1, the compositions of the impactors was determined by SEM-EDS techniques; in AO187-2 a sensitive surface analysis technique - SIMS - was used to determine both elemental and (some) isotopic compositions. In the initial analysis of AO187-2, it was found that SIMS was more sensitive for the analysis of thin impact debris layers than SEM-EDS. The present grant was made to determine if SIMS analysis could also be applied to impacts recorded in the Au surfaces of AO187-1. Success would extend the analysis of AO187-1 and would also contribute important technical information for the design of future cosmic dust space missions. The results obtained with this grant are incorporated in the attached paper presented at the Third LDEF Symposium and are briefly summarized here. In addition, we comment on the potential implications of this work for future research.

Source record↗
NASA NTRS2000

STS-99 Countdown Status Briefing

The primary objective of the STS-99 mission was to complete high resolution mapping of large sections of the Earth's surface using the Shuttle Radar Topography Mission (SRTM), a specially modified radar system. This radar system produced unrivaled 3-D images of the Earth's Surface. The mission was launched at 12:31 on February 11, 2000 onboard the space shuttle Endeavour. This tape presents a pre-launch briefing for the press held on Feb 8, 2000. Statements were given by Doug Lyons, Shuttle Test Director; Scott Higginbotham, STS-99 Payload Director and Ed Priselac, Shuttle Weather Officer. Mr. Lyons reported on the replacement of the Master Control Unit on board Endeavour, the part that had caused a delay in the launch. He reviewed the work that had to be done and the timeline for completion. Scott Higginbotham reported that there were no problems with the SRTM. Ed Priselac reported on favorable weather conditions for the launch. Discussion after the statements concerned a possible problem with a cable, and the possibility of a further delay to the launch.

Source record↗
NASA NTRS2000

STS-99 Countdown Status Briefing

The primary objective of the STS-99 mission was to complete high resolution mapping of large sections of the Earth's surface using the Shuttle Radar Topography Mission (SRTM), a specially modified radar system. This radar system produced unrivaled 3-D images of the Earth's Surface. The mission was launched at 12:31 on February 11, 2000 onboard the space shuttle Endeavour. This tape presents a pre-launch briefing for the press held on Jan. 28, 2000. Statements were given by Doug Lyons, Shuttle Test Director; Scott Higginbotham, STS-99 Payload Director and Ed Priselac, Shuttle Weather Officer. Doug Lyons reported on the checkout of the equipment. Scott Higgenbotham reviewed the steps required to assemble and test the SRTM instrumentation and equipment. Ed Priselac gave the weather forecast for the expected launch day. The questions concerned a possible problem with a part onboard the shuttle and the likely impact this might have on the launch.

Source record↗