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Tremendous efforts by Fluxnet scientists over the past few decades have made thousands of site-years of carbon flux observations available for advancing our understanding of carbon cycling in terrestrial ecosystems. One of key Fluxnet measurements is net ecosystem exchange (NEE) as it is directly related to carbon budget of terrestrial ecosystems. However, carbon flux estimation studies using satellite remote sensing have focused mainly on daily Gross Primary Production (GPP). The satellite based carbon flux estimation used the polar orbiting satellite sensors (e.g., Moderate Resolution Imaging Spectroradiometer (MODIS)), which allow us to observe target regions only once during the day. Because daily NEE is close to zero value, the carbon flux models using the polar orbiting satellite data have not been well used for NEE estimation. The new generation of geostationary satellite sensors (e.g., GOES Advanced Baesline Imager (ABI) and Himawari Advanced Himawari Imager (AHI)) provide frequent observations, often less than every 10 minutes. Here, we use GOES ABI data to estimate hourly NEE over the conterminous USA. We used the Terrestrial Observation Prediction System (TOPS) model for estimating hourly NEE. TOPS is a diagnostic ecosystem process model that simulates the fluxes of carbon and water through vegetation in response to climate variability. For the climate input, we developed hourly climate data using the same algorithm with NASA Earth Exchange Gridded Daily Meteorology (NEX-GDM) datasets based on machine learning techniques. The hourly climate data includes precipitation, maximum temperature, minimum temperature, dew point temperature, and, in particular, solar radiation that is directly derived from the Geostationary observations. The spatial patterns of ecosystem parameters used in TOPS are optimized using satellite Solar Induced Fluorescence (SIF) data. The high frequency GPP estimations from geostationary satellite sensors make it comparable to the instantaneous SIF data than daily GPP. We also used Fluxnet data for optimization of model parameters and the validation of the output. The derived data addresses the diurnal dynamics of carbon cycling at large scales and should help in reducing the uncertainties in carbon budget studies.