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At least 163 records · Page 9

A well-posed and stable stochastic Galerkin formulation of the incompressible Navier–Stokes equations with random data

We present a well-posed stochastic Galerkin formulation of the incompressible Navier–Stokes equations with uncertainty in model parameters or the initial and boundary conditions. The stochastic Galerkin method involves representation of the solution through generalized polynomial chaos expansion and projection of the governing equations onto stochastic basis functions, resulting in an extended system of equations. A relatively low-order generalized polynomial chaos expansion is sufficient to capture the stochastic solution for the problem considered. We derive boundary conditions for the continuous form of the stochastic Galerkin formulation of the velocity and pressure equations. The resulting problem formulation leads to an energy estimate for the divergence. With suitable boundary data on the pressure and velocity, the energy estimate implies zero divergence of the velocity field. Based on the analysis of the continuous equations, we present a semi-discretized system where the spatial derivatives are approximated using finite difference operators with a summation-by-parts property. With a suitable choice of dissipative boundary conditions imposed weakly through penalty terms, the semi-discrete scheme is shown to be stable. Numerical experiments in the laminar flow regime corroborate the theoretical results and we obtain high-order accurate results for the solution variables and the velocity divergence converges to zero as the mesh is refined.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Linearized stability analysis and design of a flyback dc-dc boost regulator.

Analytic expressions for the small-signal power-stage describing functions of a switched dc-dc boost regulator are derived from an approximate continuous circuit model which is developed by a time-averaging technique. Closed-loop stability is attained through the design of frequency compensation of the loop gain. Open- and closed-loop regulator output impedances are derived from the linearized models for the given configuration. The analysis and design are compared with and confirmed by breadboard measurements.

Wester, G. W.↗

Pilot-Scale Studies of Lignin-Derived Ionic Liquids for Biomass Pretreatment

The polymers found in plant cell walls represent the largest reserves of renewable carbon on Earth - it has been estimated that the United States has approximately 1.3 billion tons of plant biomass available per year. Ionic liquids (ILs) are salts with melting points less than 100oC, typically containing organic cations, that possess a wide range of extraordinary properties as compared to traditional organic solvents. The unusual catalytic and solvation properties of ionic liquids have attracted the biofuel and biomass communities because IL-pretreatment provides higher fermentable sugar yields than those obtained by acid- or alkali-pretreatment under similar severities. This research used lignin, a major by-product of the biofuel and pulping industries, as raw material for IL synthesis. The goal is to lower the cost of IL production, and enable a more "closed-loop" biorefinery. The lignin is oxidatively depolymerized, purified, and used to prepare a new class of renewable ILs. Biomass pretreatment was the target application for the lignin-derived ILs, while we continue to investigate additional applications within the growing IL market - process chemistry, biotechnology and materials recycling. When comparing our corn stover pretreatment data to recently published reports, we have shown comparable glucose and xylose yields by using neat and 10% aqueous solutions of lignin-derived ILs.

09 BIOMASS FUELS↗

Comparison of a discrete steepest ascent method with the continuous steepest ascent method for optimal programing

A discrete steepest ascent method which allows controls which are not piecewise constant (for example, it allows all continuous piecewise linear controls) was derived for the solution of optimal programming problems. This method is based on the continuous steepest ascent method of Bryson and Denham and new concepts introduced by Kelley and Denham in their development of compatible adjoints for taking into account the effects of numerical integration. The method is a generalization of the algorithm suggested by Canon, Cullum, and Polak with the details of the gradient computation given. The discrete method was compared with the continuous method for an aerodynamics problem for which an analytic solution is given by Pontryagin's maximum principle, and numerical results are presented. The discrete method converges more rapidly than the continuous method at first, but then for some undetermined reason, loses its exponential convergence rate. A comparsion was also made for the algorithm of Canon, Cullum, and Polak using piecewise constant controls. This algorithm is very competitive with the continuous algorithm.

Childs, A. G.↗

Multi-disciplinary optimization of aeroservoelastic systems

The purpose of the research project was to continue the development of new methods for efficient aeroservoelastic analysis and optimization. The main targets were as follows: to complete the development of analytical tools for the investigation of flutter with large stiffness changes; to continue the work on efficient continuous gust response and sensitivity derivatives; and to advance the techniques of calculating dynamic loads with control and unsteady aerodynamic effects. An efficient and highly accurate mathematical model for time-domain analysis of flutter during which large structural changes occur was developed in cooperation with Carol D. Wieseman of NASA LaRC. The model was based on the second-year work 'Modal Coordinates for Aeroelastic Analysis with Large Local Structural Variations'. The work on continuous gust response was completed. An abstract of the paper 'Continuous Gust Response and Sensitivity Derivatives Using State-Space Models' was submitted for presentation in the 33rd Israel Annual Conference on Aviation and Astronautics, Feb. 1993. The abstract is given in Appendix A. The work extends the optimization model to deal with continuous gust objectives in a way that facilitates their inclusion in the efficient multi-disciplinary optimization scheme. Currently under development is a work designed to extend the analysis and optimization capabilities to loads and stress considerations. The work is on aircraft dynamic loads in response to impulsive and non-impulsive excitation. The work extends the formulations of the mode-displacement and summation-of-forces methods to include modes with significant local distortions, and load modes. An abstract of the paper,'Structural Dynamic Loads in Response to Impulsive Excitation' is given in appendix B. Another work performed this year under the Grant was 'Size-Reduction Techniques for the Determination of Efficient Aeroservoelastic Models' given in Appendix C.

Karpel, Mardechay↗

A PC program to optimize system configuration for desired reliability at minimum cost

High reliability is desired in all engineered systems. One way to improve system reliability is to use redundant components. When redundant components are used, the problem becomes one of allocating them to achieve the best reliability without exceeding other design constraints such as cost, weight, or volume. Systems with few components can be optimized by simply examining every possible combination but the number of combinations for most systems is prohibitive. A computerized iteration of the process is possible but anything short of a super computer requires too much time to be practical. Many researchers have derived mathematical formulations for calculating the optimum configuration directly. However, most of the derivations are based on continuous functions whereas the real system is composed of discrete entities. Therefore, these techniques are approximations of the true optimum solution. This paper describes a computer program that will determine the optimum configuration of a system of multiple redundancy of both standard and optional components. The algorithm is a pair-wise comparative progression technique which can derive the true optimum by calculating only a small fraction of the total number of combinations. A designer can quickly analyze a system with this program on a personal computer.

Hills, Steven W.↗

Improvement of Raman lidar algorithm for quantifying aerosol extinction

Aerosols are particles of different composition and origin and influence the formation of clouds which are important in atmospheric radiative balance. At the present there is high uncertainty on the effect of aerosols on climate and this is mainly due to the fact that aerosol presence in the atmosphere can be highly variable in space and time. Monitoring of the aerosols in the atmosphere is necessary to better understanding many of these uncertainties. A lidar (an instrument that uses light to detect the extent of atmospheric aerosol loading) can be particularly useful to monitor aerosols in the atmosphere since it is capable to record the scattered intensity as a function of altitude from molecules and aerosols. One lidar method (the Raman lidar) makes use of the different wavelength changes that occur when light interacts with the varying chemistry and structure of atmospheric aerosols. One quantity that is indicative of aerosol presence is the aerosol extinction which quantifies the amount of attenuation (removal of photons), due to scattering, that light undergoes when propagating in the atmosphere. It can be directly measured with a Raman lidar using the wavelength dependence of the received signal. In order to calculate aerosol extinction from Raman scattering data it is necessary to evaluate the rate of change (derivative) of a Raman signal with respect to altitude. Since derivatives are defined for continuous functions, they cannot be performed directly on the experimental data which are not continuous. The most popular technique to find the functional behavior of experimental data is the least-square fit. This procedure allows finding a polynomial function which better approximate the experimental data. The typical approach in the lidar community is to make an a priori assumption about the functional behavior of the data in order to calculate the derivative. It has been shown in previous work that the use of the chi-square technique to determine the most likely functional behavior of the data prior to actually calculating the derivative eliminates the need for making a priori assumptions. We note that the a priori choice of a model itself can lead to larger uncertainties as compared to the method that is validated here. In this manuscript, the chi-square technique that determines the most likely functional behavior is validated through numerical simulation and by application to a large body of Raman lidar measurements. In general, we show that the chi-square approach to evaluate aerosol extinction yields lower extinction uncertainty than the traditional technique. We also use the technique to study the feasibility of developing a general characterization of the extinction uncertainty that could permit the uncertainty in Raman lidar aerosol extinction measurements to be estimated accurately without the use of the chi-square technique.

Russo, Felicita↗

Universal Compiling and (No-)Free-Lunch Theorems for Continuous-Variable Quantum Learning

Quantum compiling, where a parameterized quantum circuit is trained to learn a target unitary, is an important primitive for quantum computing that can be used as a subroutine to obtain optimal circuits or as a tomographic tool to study the dynamics of an experimental system. While much attention has been paid to quantum compiling on discrete-variable hardware, less has been paid to compiling in the continuous-variable paradigm. Here we motivate several, closely related, short-depth continuous-variable algorithms for quantum compilation. We analyze the trainability of our proposed cost functions and numerically demonstrate our algorithms by learning arbitrary Gaussian operations and Kerr nonlinearities. We further make connections between this framework and quantum learning theory in the continuous-variable setting by deriving no-free-lunch theorems. These generalization bounds demonstrate a linear resource reduction for learning Gaussian unitaries using entangled coherent-Fock states and an exponential resource reduction for learning arbitrary unitaries using two-mode-squeezed states.

97 MATHEMATICS AND COMPUTING↗

The abundance of CH(+) in translucent molecular clouds - Further tests of shock models

Observations of interstellar absorption lines of CH(+) in the (0, 0) and (1, 0) bands of the A 1Pi - X 1Sigma(+) system are presented for 17 stars with reddenings up to E(B-V) about 1.5 mag. Complementary data on interstellar CH in the (0, 0) bands of the A 2Delta - X 2Pi and B 2Sigma(-) - X 2Pi systems and C2 in the A 1Pi(u) - X 1Sigma(g)(+) red system have been obtained as well. The derived CH(+) column densities continue to increase with total column density, and values up to 10 exp 14/sq cm are reported for highly-reddened lines of sight. In most cases, the CH(+) and CH absorptions are dominated by a single strong component, with weaker features displaced by a few km/s. No significant velocity difference is found between CH(+) and neutral species such as CH and CN for this sample of randomly oriented lines of sight. In contrast with CN, the CH(+) abundance does not increase with the density in the cloud as derived from the observed C2 excitation. For the two clouds with the largest density, HD 62542 and HD 94413, no CH(+) absorption is found with CH(+)/CH less than 0.03 and 0.14, respectively. The CH(+) findings do not support a single-shock origin for the formation of the ion.

Gredel, R.↗

Scaling patch analysis of planar turbulent mixing layers

Proper scales for the mean flow and Reynolds shear stress in planar turbulent mixing layers are determined from a scaling patch analysis of the mean continuity and momentum equations. By seeking an admissible scaling of the mean continuity equation, a proper scale for the mean transverse flow is determined as V ref =(dδ/dx)U ref , where dδ/dx is the growth rate of the mixing layer width and U ref =U h –U l is the difference between the velocity of the high speed stream U h and the velocity of the low speed stream U l . By seeking an admissible scaling for the mean momentum equation, a proper scale for the kinematic Reynolds shear stress is determined as R uv,ref =U avg V ref =[$\frac{1}{2A_u}$$\frac{dδ}{dx}$]$U^{2}_{ref}$ where A u $_{=}^{def}$(U h –U l )/(U h +U l ) is the normalized velocity difference that emerges naturally in the admissible scaling of the mean momentum equation. Self-similar equations for the scaled mean transverse flow V* and Reynolds shear stress $R^{*}_{uv}$=R uv /R uv,ref are derived from the mean continuity and mean momentum equations. Finally, approximate equations for V* and $R^{*}_{uv}$ are developed and found to agree well with experimental data.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Historical Greenland Climate Network (GC-Net) Curated and Augmented Level-1 Dataset

The Greenland Climate Network (GC-Net) consists of 31 automatic weather stations (AWSs) at 30 sites across the Greenland Ice Sheet. The first site was initiated in 1990, and the project has operated almost continuously since 1995 under the leadership of the late Konrad Steffen. The GC-Net AWS measured air temperature, relative humidity, wind speed, atmospheric pressure, downward and reflected shortwave irradiance, net radiation, and ice and firn temperatures. The majority of the GC-Net sites were located in the ice sheet accumulation area (17 AWSs), while 11 AWSs were located in the ablation area, and two sites (three AWSs) were located close to the equilibrium line altitude. Additionally, three AWSs of similar design to the GC-Net AWS were installed by Konrad Steffen's team on the Larsen C ice shelf, Antarctica. After more than 3 decades of operation, the GC-Net AWSs are being decommissioned and replaced by new AWSs operated by the Geological Survey of Denmark and Greenland (GEUS). Therefore, making a reassessment of the historical GC-Net AWS data is necessary. We present a full reprocessing of the historical GC-Net AWS dataset with increased attention to the filtering of erroneous measurements, data correction and derivation of additional variables: continuous surface height, instrument heights, surface albedo, turbulent heat fluxes, and 10 m ice and firn temperatures. This new augmented GC-Net level-1 (L1) AWS dataset is now available at https://doi.org/10.22008/FK2/VVXGUT (Steffen et al., 2023) and will continue to be refined. The processing scripts, latest data and a data user forum are available at https://github.com/GEUS-Glaciology-and-Climate/GC-Net-level-1-data-processing (last access: 30 November 2023). In addition to the AWS data, a comprehensive compilation of valuable metadata is provided: maintenance reports, yearly pictures of the stations and the station positions through time. This unique dataset provides more than 320 station years of high-quality atmospheric data and is available following FAIR (findable, accessible, interoperable, reusable) data and code practices.

Greenland Climate Network↗

Hydrodynamic description of an unmagnetized plasma with multiple ion species. I. General formulation

A generalization of the Braginskii ion fluid description [S. I. Braginskii, Sov. Phys. JETP 6, 358 (1958)] to the case of an unmagnetized collisional plasma with multiple ion species is presented. An asymptotic expansion in the ion Knudsen number is used to derive the individual ion species continuity, as well as the total ion mass density, momentum, and energy evolution equations accurate through the second order. Expressions for the individual ion species drift velocities with respect to the center of mass reference frame, as well as for the total ion heat flux and viscosity, which are required to close the fluid equations, are evaluated in terms of the first-order corrections to the lowest order Maxwellian ion velocity distribution functions. A variational formulation for evaluating such corrections and its relation to the plasma entropy are presented. Employing trial functions for the corrections, written in terms of expansions in generalized Laguerre polynomials, and maximizing the resulting functionals produces two systems of linear equations (for “vector” and “tensor” portions of the corrections) for the expansion coefficients. A general matrix formulation of the linear systems as well as expressions for the resulting transport fluxes are presented in forms convenient for numerical implementation. The general formulation is employed in the companion paper [A. N. Simakov and K. Molvig, Hydrodynamic description of an unmagnetized plasma with multiple ion species. II. Two and three ion species plasmas, submitted to Phys. Plasmas (2015)] to evaluate the individual ion drift velocities and the total ion heat flux and viscosity for specific cases of two and three ion species plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Unified approach for incompressible flows

An unified approach for solving both compressible and incompressible flows was investigated in this study. The difference in CFD code development between incompressible and compressible flows is due to the mathematical characteristics. However, if one can modify the continuity equation for incompressible flows by introducing pseudocompressibility, the governing equations for incompressible flows would have the same mathematical characters as compressible flows. The application of a compressible flow code to solve incompressible flows becomes feasible. Among numerical algorithms developed for compressible flows, the Centered Total Variation Diminishing (CTVD) schemes possess better mathematical properties to damp out the spurious oscillations while providing high-order accuracy for high speed flows. It leads us to believe that CTVD schemes can equally well solve incompressible flows. In this study, the governing equations for incompressible flows include the continuity equation and momentum equations. The continuity equation is modified by adding a time-derivative of the pressure term containing the artificial compressibility. The modified continuity equation together with the unsteady momentum equations forms a hyperbolic-parabolic type of time-dependent system of equations. The continuity equation is modified by adding a time-derivative of the pressure term containing the artificial compressibility. The modified continuity equation together with the unsteady momentum equations forms a hyperbolic-parabolic type of time-dependent system of equations. Thus, the CTVD schemes can be implemented. In addition, the boundary conditions including physical and numerical boundary conditions must be properly specified to obtain accurate solution. The CFD code for this research is currently in progress. Flow past a circular cylinder will be used for numerical experiments to determine the accuracy and efficiency of the code before applying this code to more specific applications.

Chang, Tyne-Hsien↗

A Characterization of the Reflected Quasipotential

Recent interest in the reflected quasipotential comes from the queueing theory literature, specifically the analysis of so-called (b,A,D) reflected Brownian motion where it is the large deviation rate function for the stationary distribution. Our purpose here is to characterize the reflected quasipotential in terms of a first-order Hamilton–Jacobi equation. Using conventional dynamic programming ideas, along with a complementarity problem formulation of the effect of the Skorokhod map on absolutely continuous paths, we will derive necessary conditions in the form of viscosity-sense boundary conditions. It turns out that even with these boundary conditions solutions are not unique. Thus a unique characterization needs to refer to some additional property of V(⋅). We establish such a characterization in two dimensions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Studies on Supercapacitor Electrode Material from Activated Lignin-Derived Mesoporous Carbon

Here, we synthesized mesoporous carbon from pre-cross-linked lignin gel impregnated with a surfactant as the pore-forming agent, and then activated the carbon through physical and chemical methods to obtain activated mesoporous carbon. The activated mesoporous carbons exhibited 1.5- to 6-fold increases in porosity with a maximum BET specific surface area of 1148 m 2 /g and a pore volume of 1.0 cm 3 /g. Slow physical activation helped retain dominant mesoporosity; however, aggressive chemical activation caused some loss of the mesopore volume fraction. Plots of cyclic voltammetric data with the capacitor electrode made from these carbons showed an almost rectangular curve depicting the behavior of ideal double-layer capacitance. Although the pristine mesoporous carbon exhibited the same range of surface-area-based capacitance as that of other known carbon-based supercapacitors, activation decreased the surface-area-based specific capacitance and increased the gravimetric-specific capacitance of the mesoporous carbons. Surface activation lowered bulk density and electrical conductivity. Warburg impedance as a vertical tail in the lower frequency domain of Nyquist plots supported good supercapacitor behavior for the activated mesoporous carbons. Our work demonstrated that biomass-derived mesoporous carbon materials continue to show potential for use in specific electrochemical applications.

36 MATERIALS SCIENCE↗

Frequency-domain stimulated and spontaneous light emission signals at molecular junctions

Using a diagrammatic superoperator formalism we calculate optical signals at molecular junctions where a single molecule is coupled to two metal leads which are held at different chemical potentials. The molecule starts in a nonequilibrium steady state whereby it continuously exchanges electrons with the leads with a constant electron flux. Expressions for frequency domain optical signals measured in response to continuous laser fields are derived by expanding the molecular correlation functions in terms of its many-body states. The nonunitary evolution of molecular states is described by the quantum master equation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Steady-State and Small-Signal Analysis of A-Source Converter

This paper presents a detailed steady-state analysis and ac small-signal modeling of the power stage of pulse-width modulated A-source converter. The voltage and current waveforms along with their corresponding expressions describing the converter operation are presented in detail. The input-to-output and input-to-capacitor dc voltage transfer functions are determined. The minimum inductance required to ensure continuous conduction mode is derived. The expressions for the semiconductor devices stresses are also presented. The dc, averaged equivalent circuit is derived using the circuit averaging technique. A complete derivation of the small-signal model including the converter parasitic resistances are presented followed by the power stage transfer functions relevant to the capacitor voltage loop, such as: 1) duty cycle-to-capacitor voltage; and 2) input-to-capacitor voltage. In addition, the expressions for the network input impedance and output impedance are derived. Finally, experimental validations of the derived small-signal models are performed, both in frequency and time domain for a laboratory prototype of an A-source converter. The theoretical predictions were in good agreement with the experimental results over a wide range of frequencies.

42 ENGINEERING↗