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At least 163 records · Page 9

Modeling of hydrogen liquefaction using magnetocaloric cycles with permanent magnets

Hydrogen (H 2 ) is promising alternative to replace fossil fuels, but its transport and storage has been challenging. As H 2 fuel cell vehicles are gaining traction, the infrastructure for storing large amounts of liquid H 2 is needed. However, liquid H 2 would suffer from boil-off loss, and traditional vapor compression refrigeration systems would not be able to economically recover the lost H 2 due to the low efficiencies at cryogenic temperature. Magnetocaloric (MC) refrigeration systems could possess much higher coefficient of performance (COP) at cryogenic temperature compared to the vapor compression ones. Previous work on cryogenic MC systems, however, have only focused on large scale applications which use superconducting magnets to provide a large magnetic field but are prohibitively expensive to operate for small scale applications, such as that of a H 2 refilling station. In this work, we model the performance of a MC refrigeration cycle using 1-Tesla permanent magnets for H 2 liquefaction, with the objective of cooling H 2 from 80 K (using liquid nitrogen as the heat sink) to 20 K (boiling point of hydrogen). We evaluate main performance metrics including the total work input to the refrigeration system, COP, total MCM mass in the system, and total volume of the permanent magnets, etc. Our modeling results indicate that such a permanent magnet-based MC cooling system is feasible for small-scale H 2 liquefaction, with projected COP values significantly higher than those of vapor compression systems. In conclusion, this work provides design guidelines for future experimental efforts on permanent magnet MC cooling systems for cryogenic cooling.

08 HYDROGEN↗

Analysis of basic airflow configurations for separate sensible and latent cooling systems with indoor air recirculation

Separate sensible and latent cooling (SSLC) is a technology with efficiency and comfort advantages over conventional cooling systems used for space conditioning of buildings. Using multiple cooling processes at different temperatures allows SSLC to save energy by raising the evaporation temperature of the sensible cooling process. In this paper, all possible airflow configurations of SSLC systems are enumerated under the following constraints: exactly two heat exchangers are used, and air is recirculated to the conditioned space (no exhaust or outdoor air treatment). Seven designs are identified, with varying free operating variables, and each is modeled. Analysis reveals that several configurations are equivalent, and there is only one unique basic airflow SSLC configuration: the one with the sensible and latent heat exchangers placed in series. The efficiency of the SSLC system is compared against that of the conventional system. Under standard conditions, an SSLC system can improve the coefficient of performance by 14.8%. In addition to the numerical simulation, the optimal operating condition of the basic air configuration of the SSLC system is derived analytically. The basic SSLC system is shown to offer the highest performance improvement when the outdoor temperature is relatively cool and the space sensible heat ratio is high.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Electrochemically driven phase transformation for high-efficiency heat pumping

To reduce energy consumption and improve energy utilization in space conditioning, advanced heat pumping technologies are needed. The chemical looping heat pump (CLHP) is a promising thermodynamic cycle that has theoretically shown the potential to achieve a cooling coefficient of performance (COP c ) increase of over 20% relative to conventional vapor compression systems. In this paper, the key process of the CLHP is experimentally demonstrated, and the system performance and non-ideal behavior are predicted using the component-level models. The results show the feasibility of electrochemical phase change of a working fluid; the peak COP c was 7.64 with a cooling capacity of 3.6 mW (cooling density of 2.57 W m -2 ) at both sink and source temperature of 23°C based on laboratory experiments. The COP c can theoretically reach up to 13 at a temperature lift of 15°C as long as an electrochemical cell can achieve a greater degree of conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessment of integral models for non-Boussinesq lazy plumes using numerical simulations

Integral modelling of turbulent buoyant plumes is crucial for rapid predictions of plume characteristics. While the governing equations are typically derived using self-similarity and a Boussinesq approximation, these assumptions may not hold for plumes originating from finite-area sources with large density ratios. Here, this work evaluates the accuracy of integral-scale models for non-Boussinesq lazy plumes using high-fidelity numerical simulations of turbulent helium plumes. We analyse the plume kinematics by computing vertical fluxes, plume radius and radial profiles, establishing some disparities between common practice and physical accuracy. We identify how the definition of the plume radius changes the perception of the plume structure when the flow is not self-similar and derive a relationship between the flux-based and threshold-based definitions without requiring self-similarity. We then examine the plume dynamics by evaluating the source terms from the governing plume equations. Our results support neglecting diffusive and viscous effects but emphasise the importance of the mean pressure gradient, even in the self-similar regime. Two coefficients need to be modelled: the well-known entrainment coefficient and the lesser-known momentum correction coefficient, which is a correction required for the momentum equation to account for self-similar and slender approximations. The momentum correction coefficient is found to be approximately constant and slightly greater than the assumed value of 1. The standard entrainment coefficient models perform well up to a local Richardson number three times the asymptotic value but overpredict entrainment for larger Richardson numbers. We propose a correction using the known finite limit of entrainment at infinite Richardson number.

Meehan, Michael Alexander [Sandia National Laborat↗

Autonomous quantum absorption refrigerators

Here, we propose a quantum absorption refrigerator using the quantum physics of resonant tunneling through quantum dots. The cold and hot reservoirs are fermionic leads, tunnel coupled via quantum dots to a central fermionic cavity, and we propose configurations in which the heat absorbed from the (very hot) central cavity is used as a resource to selectively transfer heat from the cold reservoir on the left to the hot reservoir on the right. Heat transport in the device is particle-hole symmetric; we find two regimes of cooling as a function of the dot energies—symmetric with respect to the Fermi energy of the reservoirs—and we associate them with heat transfer by electrons above the Fermi level and holes below the Fermi level. We also discuss optimizing the cooling effect by fine-tuning the energy of the dots as well as their linewidth and characterize regimes where the transport is thermodynamically reversible such that the Carnot coefficient of performance is achieved with zero cooling power delivered.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Cyclic superconducting refrigerators using guided fluxon propagation

We propose cyclic refrigeration in solid state, employing a gas of magnetic field vortices in a type-II superconductor—also known as fluxons—as the cooling agent. Refrigeration cycles are realized by envisioning a racetrack geometry consisting of both adiabatic and isothermal arms, etched into a type-II superconductor. The guided propagation of fluxons in the racetrack is achieved by applying an external electrical current, in a Corbino geometry, through the sample. A gradient of magnetic field is set across the racetrack allowing one to adiabatically cool down and heat up the fluxons, which subsequently exchange heat with the cold and hot reservoirs, respectively. We characterize the steady state of refrigeration cycles thermodynamically for both s -wave and d -wave pairing symmetries, and present their figures of merit such as the cooling power delivered, and the coefficient of performance. Our cooling principle can offer significant cooling for on-chip microrefrigeration purposes, by locally cooling below the base temperatures achievable in a conventional dilution refrigerator. We estimate n W / m m 2 of cooling power per unit area assuming a tunnel coupling with ∼ M Ω µ m 2 specific resistance. Integrating the fluxon fridge to quantum circuits can enhance their coherence time by locally suppressing thermal fluctuations, and improve the efficiency of single photon detectors and charge sensors. Published by the American Physical Society 2024

Karmakar, Tathagata (ORCID:0000000187812017)↗

Multijunction Electroluminescent Cooling

We propose a multijunction configuration for an electroluminescent cooling system, incorporating multiple semiconductor layers with different band gaps. Through theoretical analysis focusing on cooling power density and coefficient of performance, we show that increasing the number of semiconductor layers results in an enhanced performance of electroluminescent cooling. We highlight the reduction of operating voltage as a pivotal factor contributing to this improvement. Furthermore, we show that the enhancement can persist in the presence of nonradiative recombination. Our work indicates the potential of multijunction configurations in advancing the capabilities of electroluminescent cooling. Published by the American Physical Society 2024

14 SOLAR ENERGY↗

Quantum-State-Controlled Collisions of Ultracold Polyatomic Molecules

Collisions between ultracold calcium monohydroxide (CaOH) molecules are realized and studied. Inelastic collision rate constants are measured for CaOH prepared in ground and excited vibrational states, and the electric field dependence of these rates is measured for molecules in single quantum states of the parity-doubled bending mode. Theoretical calculations of collision rate coefficients are performed and found to agree with measured values. The lowest collisional loss rates are for states with repulsive long-range potentials that shield ultracold molecules from loss channels at short distance. These results unveil the collisional behavior of parity-doublet molecules in the ultracold regime and lay the foundation for future experiments to evaporatively cool polyatomic molecules to quantum degeneracy.

Vilas, Nathaniel B. [Harvard University, Cambridge↗

Theoretical Analysis of a Single-Stage Gas-Fired Ejector Heat Pump Water Heater

Ejector driven systems have the ability to operate at high efficiencies, utilizing recycled thermal energy as a power source. For a typical ejector heat pump system, the increase of the condenser temperature reduces the coefficient of performance (COP). In addition, if the condenser temperature is higher than the critical temperature, the ejector may not function. In this situation, the condenser temperature must be reduced, and an additional heater will be utilized to heat the production water from the condenser temperature to the desired temperature. In this investigation, a single-stage gas-fired ejector heat pump (EHP) is investigated and thermodynamically modeled in order to optimize the system COP for the purpose of heating water by utilizing the thermal energy from the ambient air. The effects of the high-temperature evaporator (HTE) and low-temperature evaporator (LTE) temperatures on the ejector critical back pressure and the EHP system performance are examined for a HTE temperature range of 120–180 °C and LTE temperatures of 15.5, 17.5, and 19.5 °C. Results show that an optimized COP of the EHP system exists which depends on HTE and LTE temperatures, primary nozzle throat diameters. In addition, it is found that the EHP COP is independent of the ejector COP. From this investigation a maximum EHP COP of 1.31 is able to be achieved for a HTE temperature of 160 °C and a LTE temperature of 19.5 °C with a total heat capacity of 15.98 kW.

Spitzenberger, Jeremy↗

Pinch Heat Integration Tool (PIT) v0.9

The pinch heat integration tool (PIT) is a multi-module tool designed for identifying and analyzing thermal energy integration at facilities. It generates pinch and grand composite curves to identify optimal streams for heat exchange and industrial heat pumps. Users input heating and cooling stream data via an Excel sheet. The tool comprises four modules: 1. 'Main Pinch' for creating a pinch diagram using user-provided data. 2. 'GCC' for generating a grand composite curve to identify utility optimization opportunities. 3. 'Heat Exchanger' for analyzing stream combinations for heat exchange. 4. 'Heat Pump' for evaluating streams as sources and sinks for heat pumps and calculating the heat pump's coefficient of performance based on the selected refrigerant.

Karki, Unique [Lawrence Berkeley National Laborato↗

Design and execution of a verification, validation, and uncertainty quantification plan for a numerical model of left ventricular flow after LVAD implantation

Left ventricular assist devices (LVADs) are implantable pumps that act as a life support therapy for patients with severe heart failure. Despite improving the survival rate, LVAD therapy can carry major complications. Particularly, the flow distortion introduced by the LVAD in the left ventricle (LV) may induce thrombus formation. While previous works have used numerical models to study the impact of multiple variables in the intra-LV stagnation regions, a comprehensive validation analysis has never been executed. The main goal of this work is to present a model of the LV-LVAD system and to design and follow a verification, validation and uncertainty quantification (VVUQ) plan based on the ASME V&V40 and V&V20 standards to ensure credible predictions. The experiment used to validate the simulation is the SDSU cardiac simulator, a bench mock-up of the cardiovascular system that allows mimicking multiple operation conditions for the heart-LVAD system. The numerical model is based on Alya, the BSC’s in-house platform for numerical modelling. Alya solves the Navier-Stokes equation with an Arbitrary Lagrangian-Eulerian (ALE) formulation in a deformable ventricle and includes pressure-driven valves, a 0D Windkessel model for the arterial output and a LVAD boundary condition modeled through a dynamic pressure-flow performance curve. The designed VVUQ plan involves: (a) a risk analysis and the associated credibility goals; (b) a verification stage to ensure correctness in the numerical solution procedure; (c) a sensitivity analysis to quantify the impact of the inputs on the four quantities of interest (QoIs) (average aortic root flow $Q^{avg}_{Ao}$, maximum aortic root flow $Q^{max}_{Ao}$, average LVAD flow $Q^{avg}_{VAD}$, and maximum LVAD flow $Q^{max}_{VAD}$; (d) an uncertainty quantification using six validation experiments that include extreme operating conditions. Numerical code verification tests ensured correctness of the solution procedure and numerical calculation verification showed a grid convergence index (GCI)95% <3.3%. The total Sobol indices obtained during the sensitivity analysis demonstrated that the ejection fraction, the heart rate, and the pump performance curve coefficients are the most impactful inputs for the analysed QoIs. The Minkowski norm is used as validation metric for the uncertainty quantification. It shows that the midpoint cases have more accurate results when compared to the extreme cases. The total computational cost of the simulations was above 100 [core-years] executed in around three weeks time span in Marenostrum IV supercomputer. This work details a novel numerical model for the LV-LVAD system, that is supported by the design and execution of a VVUQ plan created following recognised international standards. We present a methodology demonstrating that stringent VVUQ according to ASME standards is feasible but computationally expensive.

59 BASIC BIOLOGICAL SCIENCES↗

Updated U.S. Low-Temperature Heating and Cooling Demand by County and Sector

This dataset includes U.S. low-temperature heating and cooling demand at the county level in major end-use sectors: residential, commercial, manufacturing, agricultural, and data centers. Census division-level end-use energy consumption, expenditure, and commissioned power database were dis-aggregated to the county level. The county-level database was incorporated with climate zone, numbers of housing units and farms, farm size, and coefficient of performance (COP) for heating and cooling demand analysis. This dataset also includes a paper containing a full explanation of the methodologies used and maps. Residential data were updated from the latest Residential Energy Consumption Survey (RECS) dataset (2015) using 2020 census data. Commercial data were baselined off the latest Commercial Building Energy Consumption Survey (CBECS) dataset (2012). Manufacturing data were baselined off the latest Manufacturing Energy Consumption Survey (MECS) dataset (2021).

15 GEOTHERMAL ENERGY↗

Minimizing Auxiliary Heat Use for Cold Climate Operation of Air-Source Heat Pumps

This paper investigates the auxiliary heat use for air-source heat pumps (ASHPs) operating in cold climate conditions. Twelve variable-capacity, central ducted ASHPs installed in single-family homes in cold climate regions (eleven in northwest United States and one in Denver suburb) were monitored for an entire winter season to collect data at cold temperatures. The methodology employed airside and power measurements that were taken every five-seconds, to calculate heat pump's capacity, coefficient of performance (COP), and auxiliary heat energy consumption. This paper provides valuable insights into the practical implications of auxiliary heat utilization in centrally ducted ASHPs and suggests opportunities to mitigate the usage of auxiliary heat, improving the overall system efficiency during cold climate operation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Experimental Characterization of an Additively Manufactured Inconel 718 Heat Exchanger for High-Temperature Applications

This work presents the experimental results of a novel, air-to-air, additively manufactured manifold-microchannel heat exchanger with straight fins on both sides. The heat exchanger was made of Inconel 718 using a direct metal laser sintering technique. The overall core size of the heat exchanger was 94 mm × 87.6 mm × 94.4 mm, with a fin thickness of 0.220 mm on both the hot and cold sides. The heat exchanger was tested with pressurized nitrogen gas at 300 °C and 340 kPa for the hot side, while air at an ambient condition was used for the cold side. An overall heat transfer of 276 W/m2K was obtained for Reynolds number values of 132 and 79 for the cold and hot sides, respectively. A gravimetric heat transfer density (Q/m∆T) of 4.7–6.7 W/kgK and a volumetric heat transfer density (Q/V∆T) of 6.9–9.8 kW/m3K were recorded for this heat exchanger with a coefficient of performance value that varied from 42 to 52 over the operating conditions studied here. The experimental pressure drop results were within 10% of the numerical values, while the corresponding heat transfer results were within 17% of the numerical results, mainly due to imperfections in the fabrication process. Despite this penalty, the performance of the tested heat exchanger was superior to the conventional plate-fin heat exchangers: more than 60% of improvements in both gravimetric and volumetric heat transfer densities were recorded for the entire range of experimental data.

42 ENGINEERING↗

Compatibility of LaFe13−x−yMnxSiyH1.6 and Eutectic Liquid GaInSn Alloy

The heat transfer rate of magnetocaloric regenerators is a topic of extensive research and the cyclability of these regenerators is critical to the operation of systems with a high coefficient of performance (e.g., potentially >22, significantly higher than typical vapor compression cooling technologies). To enable a high operating frequency that will result in a high specific cooling power, the heat transfer fluid should have high thermal conductivity and lower specific heat, i.e., higher thermal diffusivity. Eutectic metal alloys possess these qualities, such as gallium–indium–tin (Galinstan), whose thermal diffusivity has been found to be approximately an order of magnitude higher than water. For this study, the effects of eutectic liquid Galinstan exposure on the phase stability of LaFe13−x−yMnxSiyH1.6 magnetocaloric powders in an active magnetic regenerator device were investigated. The powders were characterized before and after exposure to Galinstan using X-ray diffraction, in which the phases were determined using the Rietveld refinement technique and X-ray fluorescence. It was found that after Galinstan exposure, hydrogen containing phases were present in the powder, suggesting that the hydrogen was lost from the magnetocaloric phase. The magnetocaloric phase degradation indicates that the powder was incompatible with the Galinstan metal in an environment with moisture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Computer extension and analytic continuation of Stokes' expansion for gravity waves

Stokes' infinitesimal-wave expansion for steady progressive free-surface waves has been extended to high order using a computer to perform the coefficient arithmetic. Stokes' expansion has been found to be incapable of yielding the highest wave for any value of the water depth since convergence is limited by a square-root branch-point some distance short of the maximum. By reformulating the problem using a different independent parameter, the highest waves are obtained correctly. Series summation and analytic continuation are facilitated by the use of Pade approximants. The method is valid in principle for any finite value of the wavelength and solutions of high accuracy can be obtained for most values of the wave height and water depth.

Schwartz, L. W.↗

Computerized data collection and reduction from an X-ray diffractometer

A series of computer programs written for use with a Philips X-ray diffractometer and a Hewlett Packard 9825A desk top computer is described. These programs permit the collection and storage on disk of the number of x-ray counts and the associated 2-thera angles across line profiles. Automatic background subtraction, integrated intensity, correction for the angular dependance of the Lorentz, polarization, and atomic scattering factors, peak location, K-alpha 2 removal, and calculation of Fourier coefficients are performed. The programs are written for a computer configured with a disk drive, but they can be easily modified to run from the cassette tape drive that is integral to the 9825A computer.

Mcclure, J. C.↗