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At least 163 records · Page 9
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NASA NTRS1982

Chemisorption of CO on particulate deposits of platinum

Morphology and CO chemisorption properties are studied as a function of particle size for the case of particulate Pt films, vapor-deposited onto ultrahigh vacuum-cleaved and heat-treated mica surfaces at a 200 C substrate temperature. The particles were found to be mostly irregular in shape and randomly-oriented, with two desorption peaks after CO absorption at 60 C: (1) an alpha peak, at 120 C, attributed to smooth particle surfaces, and (2) a beta peak, at about 175 C, attributed to particle edges and steps. Transmission electron microscopy showed that major changes occur in particle morphology during absorption-desorption cycling, so that the decrease in CO desorption flux may be interpreted as due to particle restructuring, rather than contamination by CO decomposition as in the cases of Ni or Pd on mica. Auger electron spectroscopy corroborates the lack of CO decomposition, even for the case of very small Pt particles.

Doering, D. L.↗
NASA NTRS1982

Microwave spectra of terrestrial mesospheric CO

Mesospheric CO was observed in absorption against the moon in early December 1979 at a wavelength of 1.3 mm and in early December 1980 at 2.6 mm with the 10.4-m millimeter wavelength telescope at the Owens Valley Radio Observatory. No significant change in the column density of CO above about 65 km is found between the 1979 and 1980 observations. Comparison with other published spectra of mesospheric CO suggests a large seasonal variation (about a factor of 2-3) in the column density of CO above 65 km, with a maximum in winter and a minimum in summer. It is concluded that the understanding of CO in the mesosphere can be improved with earth-based microwave measurements, but data with high signal-to-noise ratios must be obtained.

Clancy, R. T.↗
NASA NTRS1983

Far-infrared and CO observations of NGC 6357 and regions surrounding NGC 6357 and NGC 6334

Two 1.7 square degree sections of the galactic plane at 70 microns have been surveyed with one-arcminute resolution. The scanned areas included the giant southern H II region complexes NGC 6357 and NGC 6334. Nineteen far-infrared sources were observed. The sources range in luminosity from 16,000 to 550,000 solar masses. Far-infared continuum and CO line observations of NGC 6357 are presented. Four far-infrared sources were found in this complex and for one of these sources the exciting stars are identified. Far-infrared and CO observations of sources in the field surrounding NGC 6357 and NGC 6334 are presented. The far-infrared sources coincide frequently with CO line temperature peaks. The CO clouds which surround the far-infrared sources have similar CO-13 column densities. Two of the far-infrared sources in the field have associated OH and H2O maser emission and compact H II regions.

Mcbreen, B.↗
NASA NTRS1985

Micron CO in the eclipse spectrum of Epsilon Aur

Two micrometer spectrum of epsilon Aur was observed at high resolution (lambda/delta lambda approx. 40000) with the KPNO 4m telescope and FTS approximately every 100 days during the recent eclipse. CO delta v=2 lines appeared in the spectrum only after mid-totality. No CO features were present JD 2445478 but weak absorption lines were present on 2445592. The CO strengthened in the spectrum and remained present until at least 2445812. CO was again absent after forth contact when the spectrum was observed on 2445912. The CO appears to originate in a cool (approx. 1000 K), turbulent region. Excitation temperatures, velocities, and column densities is presented.

Hinkle, K. H.↗
NASA NTRS1985

Modulus measurements in ordered Co-Al, Fe-Al, and Ni-Al alloys

The composition and/or temperature dependence of the dynamic Young's modulus for the ordered B2 Co-Al, Fe-Al, and Ni-Al aluminides has been investigated using the piezoelectric ultrasonic composite oscillator technique (PUCOT). The modulus has been measured in the composition interval 48.49 to 52.58 at. pct Co, 50.87 to 60.2 at. pct Fe, and 49.22 to 55.95 at. pct Ni for Co-Al, Fe-Al, and Ni-Al, respectively. The measured values for Co-Al are in the temperature interval 300 to 1300 K, while those for the other systems are for ambient temperature only. The data points show that Co-Al is stiffer than Fe-Al, which is stiffer than Ni-Al. The data points for Fe-Al and Ni-Al are slightly higher than those reported in the literature.

Harmouche, M. R.↗
NASA NTRS1985

Chemical-dynamical models of the Venus mesosphere based upon diurnal microwave CO variations

An attempt is made to explain the fact that the large variation in Venus CO abundance with planetary phase using a combination of photochemical and kinematical models. Present knowledge about the Venus mesosphere is first summarized, emphasizing the more completely measured lower and upper atmosphere. The predictions of Dickinson and Ridley's (1977) hydrodynamic modeling are compared to the results of microwave observations of CO. It is noted that the nightside CO bulge above 90-95 km altitude indicated by microwave measurements is a primary characteristic of these models, whereas the opposite phase behavior of CO between 80 and 90 km is not predicted by them. The result of diurnal photochemical models for the Venus mesosphere are presented and an attempt is made to reproduce the phase behavior of CO between 80 and 90 km in the Venus mesosphere. Possible diurnal variations due to chemistry and vertical eddy diffusion are considered.

Clancy, R. T.↗
NASA NTRS1986

Atmospheric CH4, CO and OH from 1860 to 1985

Studies have shown that atmospheric methane, CO and the gaseous OH radical are interdependent: if CH4, CO or OH is perturbed, background concentrations of the other two constituents are affected. Perturbations to OH alter photooxidation rates of numerous natural and anthropogenic trace gases and affect lifetimes of those species that pass from the earth's surface to the free troposphere and stratosphere. It is now known that global atmospheric methane concentrations are increasing; less definite data suggest that carbon monoxide is also increasing. Even before the measurements reported in nine literature references, modeling studies of CH4-CO-OH coupling had led to predictions (Chameides, Liu and Ciceronne, 1977; Sze, 1977; and Hameed, Pinto and Stewart 1979) of future increases of CH4 and CO. A photochemical model is used to look backwards in time by simulating the trace-gas composition of the unpolluted troposphere at the start of the industrial era (taken as 1860) and at intervals up to 1985. It is found that the OH concentration in the background troposphere has decreased significantly and O3 has increased due to increases of CH4 and CO; calculated changes depend on temporal trends of NOx (NOx = NO + NO2), for which no historical data are available. The calculations allow recent trace-gas trends affecting background chemistry and climate to be viewed in a longer-term context.

Thompson, A. M.↗
NASA NTRS1986

Are young stars always associated with cold massive disks? A CO and millimeter interferometric continuum survey

The results of a combined millimeter-spectral-line and continuum survey of cold far-infrared sources selected to favor embedded young stars in the Galaxy are presented. The spectral-line observations were performed with the 5 meter antenna of the University of Texas Millimeter-Wave Observatory. High resolution continuum observations were obtained with the Owens Valley (OVRO) Millimeter-Wave Interferometer. The goal of the survey was to gain insight into the mass, temperature, and distribution of cold dust which envelopes stars during the earliest stages of their evolution. The first phase of our survey involved 1.2 arcmin resolution observations of CO-12 and CO-13 emission lines toward each source. All but two sources had detectable CO emission. We found that 40% of the sources appear to be associated with star formation as evidenced by the presence of enhanced CO-12 line widths or broad wings. At least five of these objects are associated with bipolar molecular outflows. The second phase of our survey involves high resolution 2.7 mm continuum observations with 3 interferometer baselines ranging from 15 to 55 m in length. Preliminary results indicate that about 25% of the sources in our sample have detectable continuum emission on scales less than 30 arcsec. The high percentage of sources with enhanced CO-12 line widths or broad wings indicates that a significant fraction of our samples, 40%, are likely to be young stars. The lower detection percentage in the continuum observations, 25%, suggest that such objects are not always surrounded by large concentrations of gas and dust. The continuum detection percentage for actual dust emission could be lower than that given above since emission from ionized gas could be responsible for the observed 2.7 mm emission in some objects. To get an understanding of the type of object detected in our survey, a map of one of the survey sources, L1689N, has been made using the OVRO mm interferometer.

Mundy, L. G.↗
NASA NTRS1987

Chemical engineering design of CO oxidation catalysts

How a chemical reaction engineer would approach the challenge of designing a CO oxidation catalyst for pulsed CO2 lasers is described. CO oxidation catalysts have a long history of application, of course, so it is instructive to first consider the special requirements of the laser application and then to compare them to the characteristics of existing processes which utilize CO oxidation catalysts. All CO2 laser applications require a CO oxidation catalyst with the following characteristics: (1) active at stoichiometric ratios of O2 and CO, (2) no inhibition by CO2 or other components of the laser environment, (3) releases no particulates during vibration or thermal cycling, and (4) long lifetime with a stable activity. In all applications, low consumption of power is desirable, a characteristic especially critical in aerospace applications and, thus, catalyst activity at low temperatures is highly desirable. High power lasers with high pulse repetition rates inherently require circulation of the gas mixture and this forced circulation is available for moving gas past the catalyst. Low repetition rate lasers, however, do not inherently require gas circulation, so a catalyst that did not require such circulation would be favorable from the standpoint of minimum power consumption. Lasers designed for atmospheric penetration of their infrared radiation utilize CO2 formed from rare isotopes of oxygen and this application has the additional constraint that normal abundance oxygen isotopes in the catalyst must not exchange with rare isotopes in the gas mixture.

Herz, Richard K.↗
NASA NTRS1986

The infrared spectrum of M8 E - Evidence for circumstellar CO

High-resolution spectroscopic observations of the compact infrared source M8 E are reported in the region from 3 to 5 microns. Very prominent CO absorption lines are observed in the v = 1-0 band at 4.7 microns. The velocity width and rotational temperature suggest that this CO absorption occurs in a highly excited region. The high background continuum flux level and the prominent appearance of the CO features suggest that the CO line-forming region must be in front of the dust emission region. A blister model for M8 E, which places most of the dust continuum emission behind the source, satisfies this requirement. According to this picture, the observed circumstellar CO spectrum shows a high rotational temperature and a large velocity dispersion because of the combined effects of the strong stellar wind and possible shock heating near the dust zone as the wind encounters the ambient molecular cloud.

Larson, H. P.↗
NASA NTRS1986

Possible perturbations to atmospheric CO, CH4, and OH

A photochemical model is used to predict temporal trends in atmospheric CO, CH4, and OH. The model is described, including the choice of model inputs and boundary conditions for three cases: low NOx, midlatitude; high NOx, midlatitude; and low NOx, low latitude. Basic features of CO and CH4 perturbation calculations are presented. The model is used to predict CH4, CO, and OH over the next 50 years and to assess possible CH4-CO-OH perturbations from 1860 to 1985. An attempt is made to discern whether increasing global sources of CO or increasing sources of CH4, or both, are responsible for the recent apparent increases of these gases.

Thompson, A. M.↗
NASA NTRS1986

Modeling for CO poisoning of a fuel cell anode

Poisoning losses in a half-cell in the 110-190 C temperature range have been measured in 100 wt pct H3PO4 for various mixtures of H2, CO, and CO2 gases in order to investigate the polarization loss due to poisoning by CO of a porous fuel cell Pt anode. At a fixed current density, the poisoning loss was found to vary linearly with ln of the CO/H2 concentration ratio, although deviations from linearity were noted at lower temperatures and higher current densities for high CO/H2 concentration ratios. The surface coverages of CO were also found to vary linearly with ln of the CO/H2 concentration ratio. A general adsorption relationship is derived. Standard free energies for CO adsorption were found to vary from -14.5 to -12.1 kcal/mol in the 130-190 C temperature range. The standard entropy for CO adsorption was found to be -39 cal/mol per deg K.

Dhar, H. P.↗
NASA NTRS1987

Chemical and physical studies of type 3 chondrites. VIII - Thermoluminescence and metamorphism in the CO chondrites

A possible relationship between the thermoluminescence (TL) properties of CO chondrites and their metamorphic history was investigated by measuring the TL properties of seven normal CO chondrites and of the Colony and the Allan Hills A77307 (ALHA 77307) CO-related chondrites. With the exception of Colony and ALHA 77307, whose maximum induced TL emission is at approximately 350 C, the CO chondrites were found to exhibit two TL peaks: a 130 C and a 250 C peaks. Among the CO chondrites, the 130 C peak showed a 100-fold range in TL sensitivity and was found to correlate with various metamorphism-related phenomena, such as silicate heterogeneity, metal composition, and McSween's metamorphic subtypes. The peak at 250 did not show these correlations and, with exception of Colony, showed little variation.

Keck, Bradly D.↗
NASA NTRS1990

Molecular clouds without detectable CO

The clouds identified by Desert, Bazell, and Boulanger (DBB clouds) in their search for high-latitude molecular clouds were observed in the CO (J = 1-0) line, but only 13 percent of the sample was detected. The remaining 87 percent are diffuse molecular clouds with CO abundances of about 10 to the -6th, a typical value for diffuse clouds. This hypothesis is shown to be consistent with Copernicus data. The DBB clouds are shown to ben an essentially complete catalog of diffuse molecular clouds in the solar vicinity. The total molecular surface density in the vicinity of the sun is then only about 20 percent greater than the 1.3 solar masses/sq pc determined by Dame et al. (1987). Analysis of the CO detections indicates that there is a sharp threshold in extinction of 0.25 mag before CO is detectable and is derived from the IRAS I(100) micron threshold of 4 MJy/sr. This threshold is presumably where the CO abundance exhibits a sharp increase

Blitz, Leo↗
NASA NTRS1990

Observations of CO in the Magellanic irregular galaxy NGC 55

The content of molecular gas in galaxies, mainly H2, is one of the key observations necessary for the understanding of star formation processes and history. As the CO molecule is the most widely distributed molecule after H2 and has easily observable mm lines, it is used as a tracer for the molecular gas. CO was detected towards the direction where the H alpha and 6 cm radio continuum emission is strongest (Hummel et al. 1986). Here, researchers present the Gaussian line parameters in tabular form. The distribution of CO corresponds well with the intense HI cloud near the bar of NGC 55. The extent of the CO cloud is about 975 pc perpendicular to the major axis. As the radio continuum and the H alpha emission also peaks in this region, it is most probably associated with the star forming region in NGC 55. Assuming that the molecular gas is in virial equilibrium, researchers derive a mass of about 8 times 10(exp 7) solar magnitude. The molecular mass found indicates that the conversion factor for the molecular mass in Irr galaxies as inferred from CO line emission is indeed higher by up to a factor of 20 compared to the canonical value for the Galaxy.

Heithausen, Andreas↗
NASA NTRS1991

Kinetic conversion of CO to CH4 in the Solar System

Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed.

Yung, Y. L.↗
NASA NTRS1992

Three-dimensional co-culture process

The present invention relates to a 3-dimensional co-culture process, more particularly to methods or co-culturing at least two types of cells in a culture environment, either in space or in unit gravity, with minimum shear stress, freedom for 3-dimensional spatial orientation of the suspended particles and localization of particles with differing or similar sedimentation properties in a similar spatial region to form 3-dimensional tissue-like structures. Several examples of multicellular 3-dimensional experiences are included. The protocol and procedure are also set forth. The process allows simultaneous culture of multiple cell types and supporting substrates in a manner which does not disrupt the 3-dimensional spatial orientation of these components. The co-cultured cells cause a mutual induction effect which mimics the natural hormonal signals and cell interactions found in the intact organism. This causes the tissues to differentiate and form higher 3-dimensional structures such as glands, junctional complexes polypoid geometries, and microvilli which represent the corresponding in-vitro structures to a greater degree than when the cell types are cultured individually or by conventional processes. This process was clearly demonstrated for the case of two epithelial derived colon cancer lines, each co-cultured with normal human fibroblasts and with microcarrier bead substrates. The results clearly demonstrate increased 3-dimensional tissue-like structure and biochemical evidence of an increased differentiation state. With the present invention a variety of cells may be co-cultured to produce tissue which has 3-dimensionality and has some of the characteristics of in-vitro tissue. The process provides enhanced 3-dimensional tissue which create a multicellular organoid differentiation model.

Wolf, David A.↗
NASA NTRS1991

Interstellar solid CO - Polar and nonpolar interstellar ices

Observations of the solid-CO lines corresponding to particular protostars are compared with respect to peak position and width and contrasted with the solid CO bands derived experimentally for astrophysical mixtures. Most lines of sight reveal narrow and broad observational solid-CO components; the narrow band appears when nonpolar molecules are dominant. When the concentration of CO is greater than 0.3 the 'surface modes' of the protostars are responsible for the position and shape of the CO fundamental. Some variations of the parameters are related to the composition and/or morphology of the grains particularly at the interstellar 2140/cm line. Grain mantles are theorized to be composed of both a polar and a nonpolar mixtures which reflect the chemical variations associated with accretion.

Tielens, A. G. G. M.↗