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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Size-Resolved Chemical Composition of Particles Collected Using STAC at the Ground Site During the SAIL Campaign in Gunnison, Colorado

Aerosol particles were collected using a four-stage Size and Time-resolved Aerosol Collector (STAC) during the SAIL field campaign. Each stage of STAC separates particles into distinct aerodynamic size fractions with 50% cut-off diameters: Stage A: 2.27 µm Stage B: 0.615 µm Stage C: 0.421 µm Stage D: 0.119 µm Each stage provides both size- and time-resolved sampling, enabling investigation of particle composition across different atmospheric regimes. Only a subset of samples was selected for analysis based on prevailing meteorological conditions (e.g., temperature, humidity, and air-mass influence) to capture representative aerosol types under distinct weather patterns. Collected substrates were first examined under Scanning Electron Microscopy (SEM) to evaluate particle loading, morphology, and spatial distribution. Subsequently, Computer-Controlled Scanning Electron Microscopy with Energy-Dispersive X-ray Spectroscopy (CCSEM/EDX) was performed to obtain size-resolved elemental composition of individual particles. A rule-based classification scheme was applied to categorize particles into major compositional groups (e.g., biological, carbonaceous, dust, sulfate, Na-rich, and mixed types). This dataset provides high-resolution morphological and chemical information on atmospheric particles collected during the SAIL campaign, offering insights into the influence of meteorology on aerosol composition and mixing state.

Size and Time-resolved Aerosol Collector↗
NASA NTRS1981

Chemical composition of the SiO2/InSb interface as determined by X-ray photoelectron spectroscopy

In connection with the relatively poor insulating characteristics of the native oxides of most III-V compound semiconductors, there has been interest in the development of deposited dielectric layers for surface passivation and MOS device fabrication on III-V compound semiconductor substrates. The chemical system of SiO2 deposited on single-crystal InSb substrates has been proposed for the fabrication of IR CCD. The considered investigation is concerned with a detailed examination of the chemical nature of the interactions between deposited and native oxides using X-ray photoelectron spectroscopy (XPS) in conjunction with a chemical-etching technique for depth profiling. The compositional structure of the interfaces obtained in the SiO2/native oxide/InSb system is derived on the basis of an intensity analysis of XPS spectra. Thermal oxidation of the InSb substrate is found to result in an In-rich native oxide and excess elemental Sb at the native oxide/substrate interface.

Vasquez, R. P.↗
DOE OSTI2021

Evolution of the structure and chemical composition of the interface between multi-component silicate glasses and yttria-stabilized zirconia after 40,000 h exposure in air at 800 °C

The chemical and structural stability of two commercial multicomponent silicate glasses (SCN and G6) in contact with yttria-stabilized zirconia (YSZ) was investigated after exposure times of up to 40,000 h in air at 800 °C. With exposure time, interfacial layers develop at the SCN-YSZ and G6-YSZ interfaces, which were characterized in detail using both quantitative chemical analysis and atomic-resolution imaging. At the SCN-YSZ interface, a Ca-Ba-Si-O reaction phase was found to grow by diffusion control. In G6-YSZ, Raman spectroscopy and electron microscopy revealed a disorganized interfacial reaction later between G6 and YSZ, and the occurrence of cubic to tetragonal to monoclinic phase transformations in YSZ. Finally, this microstructural evolution is discussed in terms of devitrification resistance of glass and diffusion processes at interfaces.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Filter measurements of chemical composition during the airborne Antarctic ozone experiment

During the Airborne Antarctic Ozone Experiment campaign, a filter sampler was flown to measure the bulk composition of aerosol and gas phases. The background sulfate aerosol was measured in regions inside and outside of the chemically perturbed region (CPR) of the polar vortex. The mass ratio of sulfate outside to inside was 2.8. This is indicative of a cleansing mechanism effecting the CPR or of a different air mass inside versus outside. The absolute value of the sulfate mixing ratio shows that the background aerosol has not been influenced by recent volcanic eruptions. The sulfate measured on the ferry flight returning to NASA Ames shows a decrease towards the equator with increasing concentrations in the northern hemisphere. Nitrate in the aerosol phase was observed on two flights. The largest amount of nitrate measured in the aerosol was 44 percent of the total amount of nitrate observed. Other samples on the same flights show no nitrate in the aerosol phase. The presence of nitrate in the aerosol is correlated with the coldest temperatures observed on a given flight. Total nitrate (aerosol plus acidic vapor nitrate) concentrations were observed to increase at flight altitude with increasing latitude north and south of the equator. Total nitrate was lower inside the CPR than outside. Chloride and flouride were not detected in the aerosol phase. From the concentrations of acidic chloride vapor, the ratio of acidic vapor Cl to acidic vapor F and a summing of the individual chloride containing species to yield a total chloride concentration, there is a suggestion that some of the air sampled was dechlorinated. Acidic vapor phase fluoride was observed to increase at flight altitude with increasing latitude both north and south of the equator. The acidic vapor phase fluoride was the only compound measured with the filter technique that exhibited larger concentrations inside the CPR than outside.

Grandrud, B. W.↗
NASA NTRS1991

The chemical composition of the dust-free Martian atmosphere - Preliminary results of a two-dimensional model

This paper describes a two-dimensional model of the Martian atmosphere, in which chemical, radiative and dynamical processes are treated interactively. The model is developed for a carbon dioxide-hydrogen-oxygen-nitrogen atmosphere and provides estimates of concentrations for 19 chemical species. The dynamical equations are expressed in the transformed Eulerian coordinates. The wave driving and eddy mixing coefficients resulting from gravity and Rossby wave absorption are computed consistently with the evolving distribution of the mean zonal wind. The net diabatic heating/cooling rate is derived from a detailed radiative scheme including the contributions of CO2, O3, H2O and O2, and is computed consistently with the calculated distribution of temperature and trace species quantities. The computed temperature field as well as the meridional and seasonal variations of ozone column abundance are in good agreement with the distributions observed by Mariner 9 and Viking spacecrafts and the results obtained by previous studies. The present version of the model does not include the effects of dust, clouds and polar hood and only the chemistry in a dust-free atmosphere is considered.

Moreau, D.↗
DOE OSTI2023

HPTLC Analysis and Chemical Composition of Selected Melaleuca Essential Oils

Tea tree oil (TTO) is a volatile essential oil obtained by distillation, mainly from the Australian native plant Melaleuca alternifolia (Maiden & Betche) Cheel (Myrtaceae). In this study, a comparative analysis of the chemical constituents of seven tea tree oils (M. alternifolia) and four other Melaleuca spp. oils (M. cajuputi, (M Ca ), two chemotypes of M. quinquenervia, (M Ne and M Ni ), and M. ericifolia (M Ro )) was carried out using gas chromatography–mass spectrometry (GC-MS) and high-performance thin-layer chromatography (HPTLC). Among the seven TTOs, terpinen-4-ol (37.66–44.28%), γ-terpinene (16.42–20.75%), α-terpinene (3.47–12.62%), α-terpineol (3.11–4.66%), and terpinolene (2.75–4.19%) were the most abundant compounds. On the other hand, the most abundant compounds of the other Melaleuca oils varied, such as 1,8-cineole (64.63%) in M Ca oil, (E)-nerolidol (48.40%) and linalool (33.30%) in M Ne oil, 1,8-cineole (52.20%) in M Ni oil, and linalool (38.19%) and 1,8-cineole (27.57%) in M Ro oil. HPTLC fingerprinting of Melaleuca oils enabled the discrimination of TTO oils from other Melaleuca spp. oils. Variation was observed in the profile of the R f values among EOs. The present study shows that HPTLC is one of the best ways to identify and evaluate the quality control in authenticating TTOs, other Melaleuca EOs, or EOs from other species within the Myrtaceae.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Chemical composition of sawdust from lunar rock 12013 and comparison of a Java tektite with the rock.

Abundances of 11 major and minor elements and 11 trace elements have been determined by instrumental neutron activation analysis of two Apollo 12013 rock fragments, a sample of rock 12013,17 sawdust, and a Java tektite (J2). Although the abundances of major elements in tektite J2 are similar to those of rock 12013, comparison of the minor and trace elements shows that no fragment of sawdust or rock 12013 that has been analyzed to date is chemically similar to tektite glass. Rock sawdust is representative of ?whole rock' composition only if the amount of contamination from the sawing process is known. After appropriate correction for saw wire contamination, analyses of sawdust yield fairly accurate averaged elemental compositions of complex clastic lunar and other rocks.

Showalter, D. L.↗
NASA NTRS1993

Chemical composition of new Acapulcoites and Lodranites

The bulk compositions of two Antarctic Lodranites, MAC 88177 and FRO 90011, and two Acapulcoites, ALH 81261 and Monument Draw, were determined with instrumental neutron activation analysis. Acapulcoites have essentially chondritic major and trace element abundances but achondritic texture. They consist of entirely recrystallized, fine grained mineral assemblages. Chondrules are extremely rare; one relict radiating pyroxene chondrule was described in Monument Draw (MD). The coarse grained Lodranites also have achondritic textures, but they are different compositionally with depletions in Al, Na, and incompatible elements probably a result of separation of partial, feldspar-rich melt. MAC 88177 is significantly more depleted in incompatible elements than FRO 90011 suggesting a higher degree of partial melting for the MAC-Lodranite. The chemical data support a genetic relationship between Lodranites and Acapulcoites inferred earlier from oxygen isotopes, petrology, and mineral composition.

Zipfel, J.↗
NASA NTRS1999

Synoptic Mapping of Chemical Composition, Thermal Structure, and Air Motion from UARS Observations

An operational mapping algorithm was developed to process measurements of individual species observed by different satellite instruments on board UARS. Based on Fast Fourier Synoptic Mapping (FFSM), the algorithm accounts for the precessing orbit of UARS, the error of individual instruments, and gaps associated with instrument duty cycle and the satellite yaw maneuver. It provides synoptic structure and evolution on periods as short as 1 day, derived collectively from all observations of an individual species. The algorithm was applied to synoptically map temperature, thickness, and several chemical constituents observed by the instruments: MLS, CLAES, ISAMS, and HALOE. Each field variable observed by these instruments was mapped twice-daily in continuous global time series several months long. Mapped behavior produced via FFSM was compared against standard archived products generated via Kalman filtering. The standard map products reveal similar behavior, but are limited to features of larger scale. Tracer structure that develops through flow deformation and attending transport is therefore represented in those products more coarsely, eventually being sheared down to scales that are no longer represented properly. The synoptic time series also reveal a diurnal cycle for several of the constituents, one that emerges clearly in their space-time spectra. The zonal and meridional structure of diurnal variability was mapped by filtering the space-time spectrum, an intermediate product of FFSM, to those scales resolved by the UARS sampling. Geographical variations of the diurnal cycle have also been evaluated in its seasonal-mean structure by compositing distributions at individual local times. Both were compared to diurnal variations in chemical models and in dynamical models that account for transport by the diurnal tide. Diurnal variations were found to introduce spurious behavior into the archived products generated via Kalman filtering, behavior that is misrepresented in those synoptic time series. Aliasing by under-sampled diurnal variations introduces a bias into the time-mean structure of archived products. That systematic error is manifested as anomalous wave structure in the time-mean fields. By contrast, synoptic time series generated via FFSM faithfully represent such behavior as varying diurnally, so it does not corrupt time-mean structure. Tracer structure mapped via the above algorithm was being applied to determine the Brewer-Dobson circulation of the stratosphere through Lagrangian considerations. Preliminary results are encouraging: They reveal diabatic ascent in the tropics, balanced by diabatic descent over the winter hemisphere. This Lagrangian description of transport derived from UARS tracer measurements would be potentially valuable for diagnosing interannual changes of transport, specifically, in relation to interannual changes of total ozone. Regrettably, support was reduced to 50% of the approved funding level, leaving this component incomplete.

Salby, Murry L.↗
NASA NTRS1980

The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

The present review deals with the importance of three distinct classes of precipitation which directly deposit energy into the middle atmosphere, viz. galactic cosmic radiation, energetic solar protons and relativistic electron precipitation from the earth's radiation belts. Chemical considerations during particle precipitation are discussed, with special emphasis on the relative production rate of odd nitrogen and odd hydrogen species during ionizing particle precipitation. The long residence time of NO in the upper stratosphere, where catalytic interaction with O3 is most effective, requires that this mechanism be included in future modeling of global distribution of O3. Other situations causing O3 depletion are also identified.

Thorne, R. M.↗
DOE OSTI2020

Atmospheric clusters to nanoparticles: Recent progress and challenges in closing the gap in chemical composition

Aerosol nanoclusters (AN), defined here as molecular aggregates suspended in a gas with dimensions between 2 and 10 nm, are the link between substances that we think of as molecules, or the “gas phase,” and those that we consider as particles, or the “condensed phase.” The ability to measure and model the physical and chemical properties of size-resolved AN, which at present is rudimentary at best, is crucial for understanding how particles form and evolve in a number of environments that are natural or influenced by human activities. This review describes the current state-of-the-art for measuring and modeling the size-resolved composition of atmospheric AN. We focus specifically on instruments, many relying on mass spectrometry, that show promise for closing the measurement gap under atmospherically relevant conditions by increasing the size of measurable gas-phase clusters (bottom-up approaches) and by decreasing the size of measurable nanoparticles (top-down approaches). Theoretical methods for predicting AN composition have similarly relied on bottom-up approaches that extend the accuracy of quantum chemistry calculations to larger molecular systems, as well as top-down approaches that correct bulk composition aerosol models for size-dependent properties such as viscosity and volatility. Finally, current measurement and modeling challenges that must be overcome in order to close the gap are discussed.

42 ENGINEERING↗
NASA NTRS2003

Aerosol Chemical Composition in Asian Continental Outflow during the TRACE-P Campaign: Comparison with PEM-West B

Aerosol associated soluble ions and the radionuclide tracers (7)Be and (210)Pb were quantified in 414 filter samples collected in spring 2001 from the DC-8 during the Transport and Chemical Evolution over the Pacific (TRACE-P) campaign. Binning the data into near Asia (flights from Hong Kong and Japan) and remote Pacific (all other flights) revealed large enhancements of NO3(-), SO4(-), C2O4(-), NH4(+), K(+), Mg2(+), and Ca2(+) near Asia. The boundary layer and lower troposphere were most strongly influenced by continental outflow, and the largest enhancements were seen in Ca2(+) (a dust tracer) and NO3(-) (reflecting uptake of HNO3 onto the dust). Comparing the TRACE P near Asia bin with earlier results from the same region during PEM-West B (in 1994) shows at least twofold enhancements during TRACE P in most of the ions listed above. Calcium and NO3(-) were most enhanced in this comparison as well (more than sevenfold higher in the boundary layer and threefold higher in the lower troposphere). Independent estimation of Asian emissions of gaseous precursors of the aerosol-associated ions suggest only small changes between the two missions, and precipitation fields do not suggest any significant difference in the efficiency of the primary sink, precipitation scavenging. It thus appears that with the possible exception of dust, the enhancements of aerosol-associated species during TRACE P cannot be explained by stronger sources or weaker sinks. We argue that the enhancements largely reflect the fact that TRACE P focused on characterizing Asian outflow, and thus the DC-8 was more frequently flown into regions that were influenced by well-organized flow off the continent.

Dibb, Jack E.↗
NASA NTRS2011

Dependences of Ratio of the Luminosity to Ionization on Velocity and Chemical Composition of Meteors

On the bases of results simultaneous photographic and radio echo observations, the results complex radar and television observations of meteors and also results of laboratory modeling of processes of a luminescence and ionization, correlation between of luminous intensity Ip to linear electronic density q from of velocities and chemical structure are investigated. It is received that by increasing value of velocities of meteors and decrease of nuclear weight of substance of particles, lg Ip/q decreased more than one order.

Narziev, M.↗
NASA NTRS1980

On the chemical composition of L-chondrites

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl, and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L group is unusually variable and may represent at least 2 subgroups differing in formation history. Chemical trends in the S/Fe rich subgroup support textural evidence indicating late loss of a shock formed Fe-Ni-S melt; the S/Fe poor subgroup seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock induced loss from L chondrites. However, contrasting chemical trends in several L chondrite sample sets indicate that these meteorites constitute a more irregular sampling of, or more heterogeneous parent material than do carbonaceous or enstatite chondrites. Data for 15 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.

Neal, C. W.↗
NASA NTRS1976

The Surface Chemical Composition of Lunar Samples and Its Significance for Optical Properties

The surface iron, titanium, calcium, and silicon concentration in numerous lunar soil and rock samples was determined by Auger electron spectroscopy. All soil samples show a large increase in the iron to oxygen ratio compared with samples of pulverized rock or with results of the bulk chemical analysis. A solar wind simulation experiment using 2 keV energy alpha -particles showed that an ion dose corresponding to approximately 30,000 years of solar wind increased the iron concentration on the surface of the pulverized Apollo 14 rock sample 14310 to the concentration measured in the Apollo 14 soil sample 14163, and the albedo of the pulverized rock decreased from 0.36 to 0.07. The low albedo of the lunar soil is related to the iron + titanium concentration on its surface. A solar wind sputter reduction mechanism is discussed as a possible cause for both the surface chemical and optical properties of the soil.

Gold, T.↗
NASA NTRS1985

Effects of breaking gravity waves on the chemical composition of the mesosphere and lower thermosphere

Eddy diffusion and momentum forcing in the mesosphere and lower thermosphere arise principally from the effects of breaking gravity and waves. The propagation and dissipation of gravity waves depend strongly on season and latitude because of its relationship to the background zonal wind. These processes have significant effects on the transport of chemical species in that region, so that observations of variations in chemical constituents provide useful tracers for dynamical theory. A parameterization of gravity wave propagation and dissipation was incorporated in the coupled dynamical-chemical model to study these effects. Several easily observable airglow features of the mesosphere-thermosphere region are shown to provide sensitive indications of gravity wave influence. In particular, theoretical predictions of large seasonal and latitudinal variations in the atomic oxygen green line, the Meinal bands of excited OH, and the O3 densities inferred from O2 (delta supra 1 sub g) emission at altitudes from 75 to 90 km are shown to be in remarkably good agreement with observations. Implications of these sensitive chemical tracers for the dynamics of the mesosphere-lower thermosphere region and its relationship to gravity waves are discussed.

Solomon, S.↗