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At least 163 records · Page 9

All sources NASA NTRS DOE OSTI

NASA NTRS1993

Lightweight linear alternators with and without capacitive tuning

Permanent magnet excited linear alternators rated tens of kW and coupled to free-piston Stirling engines are presently viewed as promising candidates for long term generation of electric power in both space and terrestrial applications. Series capacitive cancellation of the internal inductive reactance of such alternators was considered a viable way to both increase power extraction and to suppress unstable modes of the thermodynamic oscillation. Idealized toroidal and cylindrical alternator geometries are used for a comparative study of the issues of specific mass and capacitive tuning, subject to stability criteria. The analysis shows that the stator mass of an alternator designed to be capacitively tuned is always greater than the minimum achievable stator mass of an alternator designed with no capacitors, assuming equal utilization of materials ratings and the same frequency and power to a resistive load. This conclusion is not substantially altered when the usually lesser masses of the magnets and of any capacitors are added. Within the reported stability requirements and under circumstances of normal materials ratings, this study finds no clear advantage to capacitive tuning. Comparative plots of the various constituent masses are presented versus the internal power factor taken as a design degree of freedom. The explicit formulas developed for stator core, coil, capacitor, and magnet masses and for the degree of magnet utilization provide useful estimates of scaling effects.

Niedra, Janis M.↗

NASA NTRS1993

Temperature and pressure effects on capacitance probe cryogenic liquid level measurement accuracy

The inaccuracies of liquid nitrogen and liquid hydrogen level measurements by use of a coaxial capacitance probe were investigated as a function of fluid temperatures and pressures. Significant liquid level measurement errors were found to occur due to the changes in the fluids dielectric constants which develop over the operating temperature and pressure ranges of the cryogenic storage tanks. The level measurement inaccuracies can be reduced by using fluid dielectric correction factors based on measured fluid temperatures and pressures. The errors in the corrected liquid level measurements were estimated based on the reported calibration errors of the temperature and pressure measurement systems. Experimental liquid nitrogen (LN2) and liquid hydrogen (LH2) level measurements were obtained using the calibrated capacitance probe equations and also by the dielectric constant correction factor method. The liquid levels obtained by the capacitance probe for the two methods were compared with the liquid level estimated from the fluid temperature profiles. Results show that the dielectric constant corrected liquid levels agreed within 0.5 percent of the temperature profile estimated liquid level. The uncorrected dielectric constant capacitance liquid level measurements deviated from the temperature profile level by more than 5 percent. This paper identifies the magnitude of liquid level measurement error that can occur for LN2 and LH2 fluids due to temperature and pressure effects on the dielectric constants over the tank storage conditions from 5 to 40 psia. A method of reducing the level measurement errors by using dielectric constant correction factors based on fluid temperature and pressure measurements is derived. The improved accuracy by use of the correction factors is experimentally verified by comparing liquid levels derived from fluid temperature profiles.

Edwards, Lawrence G.↗

NASA NTRS2001

System for Measuring Capacitance

A system has been developed for detecting the level of a liquid in a tank wherein a capacitor positioned in the tank has spaced plates which are positioned such that the dielectric between the plates will be either air or the liquid, depending on the depth of the liquid in the tank. An oscillator supplies a sine wave current to the capacitor and a coaxial cable connects the capacitor to a measuring circuit outside the tank. If the cable is very long or the capacitance to be measured is low, the capacitance inherent in the coaxial cable will prevent an accurate reading. To avoid this problem, an inductor is connected across the cable to form with the capacitance of the cable a parallel resonant circuit. The impedance of the parallel resonant circuit is infinite, so that attenuation of the measurement signal by the stray cable capacitance is avoided.

McNichol, Randal S.↗

NASA NTRS2011

One Dimensional Capacitive Loading in a Frequency Selective Surface for Low Profile Antenna Applications

In this paper, the impact of adding discrete capacitive loading along one dimension of a frequency selective surface for low profile antenna applications is presented for the first time. The measured data demonstrates comparable performance between a non-loaded and a capacitively-loaded FSS with a significant reduction in the number of cells and/or cell geometry size. Additionally, the provision of discrete capacitive loads reduces the FSS susceptibility to fabrication tolerances based on placement of a fixed grid capacitance. The bandwidth increased from 1.8% to 7.3% for a total antenna thickness of approx. lambda/22, and from 1.5% to 9.2% for a thickness of approx. lambda/40. The total antenna area for each case was reduced by 55% and 12%, respectively.

Cure, David↗

NASA NTRS2011

A Fractal Model for the Capacitance of Lunar Dust and Lunar Dust Aggregates

Lunar dust grains and dust aggregates exhibit clumping, with an uneven mass distribution, as well as features that span many spatial scales. It has been observed that these aggregates display an almost fractal repetition of geometry with scale. Furthermore, lunar dust grains typically have sharp protrusions and jagged features that result from the lack of aeolian weathering (as opposed to space weathering) on the Moon. A perfectly spherical geometry, frequently used as a model for lunar dust grains, has none of these characteristics (although a sphere may be a reasonable proxy for the very smallest grains and some glasses). We present a fractal model for a lunar dust grain or aggregate of grains that reproduces (1) the irregular clumpy nature of lunar dust, (2) the presence of sharp points, and (3) dust features that span multiple scale lengths. We calculate the capacitance of the fractal lunar dust analytically assuming fixed dust mass (i.e. volume) for an arbitrary number of fractal levels and compare the capacitance to that of a non-fractal object with the same volume, surface area, and characteristic width. The fractal capacitance is larger than that of the equivalent non-fractal object suggesting that for a given potential, electrostatic forces on lunar dust grains and aggregates are greater than one might infer from assuming dust grains are sphericaL Consequently, electrostatic transport of lunar dust grains, for example lofting, appears more plausible than might be inferred by calculations based on less realistic assumptions about dust shape and associated capacitance.

Collier, Michael R.↗

NASA NTRS2013

Electrical Capacitance Volume Tomography for the Packed Bed Reactor ISS Flight Experiment

Fixed packed bed reactors are compact, require minimum power and maintenance to operate, and are highly reliable. These features make this technology a highly desirable unit operation for long duration life support systems in space. NASA is developing an ISS experiment to address this technology with particular focus on water reclamation and air revitalization. Earlier research and development efforts funded by NASA have resulted in two hydrodynamic models which require validation with appropriate instrumentation in an extended microgravity environment. To validate these models, the instantaneous distribution of the gas and liquid phases must be measured.Electrical Capacitance Volume Tomography (ECVT) is a non-invasive imaging technology recently developed for multi-phase flow applications. It is based on distributing flexible capacitance plates on the peripheral of a flow column and collecting real-time measurements of inter-electrode capacitances. Capacitance measurements here are directly related to dielectric constant distribution, a physical property that is also related to material distribution in the imaging domain. Reconstruction algorithms are employed to map volume images of dielectric distribution in the imaging domain, which is in turn related to phase distribution. ECVT is suitable for imaging interacting materials of different dielectric constants, typical in multi-phase flow systems. ECVT is being used extensively for measuring flow variables in various gas-liquid and gas-solid flow systems. Recent application of ECVT include flows in risers and exit regions of circulating fluidized beds, gas-liquid and gas-solid bubble columns, trickle beds, and slurry bubble columns. ECVT is also used to validate flow models and CFD simulations. The technology is uniquely qualified for imaging phase concentrations in packed bed reactors for the ISS flight experiments as it exhibits favorable features of compact size, low profile sensors, high imaging speed, and flexibility to fit around columns of various shapes and sizes. ECVT is also safer than other commonly used imaging modalities as it operates in the range of low frequencies (1 MHz) and does not radiate radioactive energy. In this effort, ECVT is being used to image flow parameters in a packed bed reactor for an ISS flight experiment.

Tomography↗

DOE OSTI2014

Capacitive chemical sensor

A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

47 OTHER INSTRUMENTATION↗

DOE OSTI2019

Cross-Plane Acquisitions in Electrical Capacitance Volume Tomography

Electrical capacitance tomography (ECT) is a widely used imaging modality to image two-dimensional cross sections of multiphase flows. Recent developments in electrical capacitance volume tomography (ECVT) have made it possible to directly obtain volumetric images from measured data. An ECVT is instrumental for obtaining accurate phase hold up information and velocity information that are needed for the optimization of certain flow processes. However, compared to ECT, the high correlation between the measurements in ECVT exacerbates the ill-conditioning of the associated image reconstruction problem. Previous studies have suggested that neglecting mutual capacitance data between the ECVT electrodes located at cross-planes that are well separated along the sensor axis can be done without significantly affecting the reconstructed image. In addition, this may help constrain the ill-conditioning of the reconstruction problem. Here, we examine in detail and quantify the effect of reduced cross-plane acquisition strategies for optimizing the image reconstruction and constraining the ill-conditioning of typical ECVT settings.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2020

3D‐Printed Structure Boosts the Kinetics and Intrinsic Capacitance of Pseudocapacitive Graphene Aerogels

Abstract The performance of pseudocapacitive electrodes at fast charging rates are typically limited by the slow kinetics of Faradaic reactions and sluggish ion diffusion in the bulk structure. This is particularly problematic for thick electrodes and electrodes highly loaded with active materials. Here, a surface‐functionalized 3D‐printed graphene aerogel (SF‐3D GA) is presented that achieves not only a benchmark areal capacitance of 2195 mF cm −2 at a high current density of 100 mA cm −2 but also an ultrahigh intrinsic capacitance of 309.1 µF cm −2 even at a high mass loading of 12.8 mg cm −2 . Importantly, the kinetic analysis reveals that the capacitance of SF‐3D GA electrode is primarily (93.3%) contributed from fast kinetic processes. This is because the 3D‐printed electrode has an open structure that ensures excellent coverage of functional groups on carbon surface and facilitates the ion accessibility of these surface functional groups even at high current densities and large mass loading/electrode thickness. An asymmetric device assembled with SF‐3D GA as anode and 3D‐printed GA decorated with MnO 2 as cathode achieves a remarkable energy density of 0.65 mWh cm −2 at an ultrahigh power density of 164.5 mW cm −2 , outperforming carbon‐based supercapacitors operated at the same power density.

asymmetric supercapacitors↗

DOE OSTI2018

3D-Printed, Superelastic Polypyrrole–Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage

Disruptive custom electronics require a transformation in energy storage systems from traditional thin-film units to shape conformable 3D components. However, current thick electrodes suffer from uncontrollable geometries and architectures, which lead to ion diffusion limitations, and poor mechanical properties. Here, designed, superelastic polypyrrole (PPy)-coated graphene aerogel (GA) electrodes are fabricated via 3D printing and polymer self-assembly methods. This resilient GA template (up to 90% compression) can be printed into any desired shape including engineered 3D architectures with periodic macropores, which promote the uniform deposition and adhesion of PPy onto the support. Additionally, the coated PPy thin film increases the specific gravimetric capacitance of the GA electrode from 14 to 395 F g -1 with 90% retention after 5000 charging–discharging cycles. The capacitance remains the same value after 100 times compression cycles. It also improves the compressive strength by one order of magnitude from 0.14 to 2.4 MPa. Areal capacitance and energy density of the PPy–GA electrode are 2 F cm -2 and 0.78 mWh cm -2 , respectively, which to the best of the knowledge break the record for compressible electrodes, respectively. This approach enables the fabrication of complex architectured energy storage modules with enhanced compressibility, ultrahigh areal electrochemical performance, and excellent cyclability.

25 ENERGY STORAGE↗

DOE OSTI2020

The polymeric conformational effect on capacitive deionization performance of graphene oxide/polypyrrole composite electrode

Exploitation of novel faradic materials is an alternative implementation for solving the problem of poor specific electrosorption capacity that conventional carbon materials are encountered in capacitive deionization. Particularly, composite electrode is just a suitable choice because of its potentially high ion-storage ability. Herein, a cyclic voltammetric treatment method with different low limit of potential window was used to manipulate the polymeric conformation and doping level of graphene oxide/polypyrrole (GO/PPy) composite electrode. Based on it, the effect of polymeric structure on the electrosorption performance was systematically studied. When the low limit of potential window is shifted negatively enough, the irreversible polymeric conformational shrinks of GO/PPy are promoted, which not only hinders the insertion process of ions, but also decreases the doping level of polymer due to the intensive interchain-action produced by more entangled polymeric chain. Thus, the number of intercalated ions should decrease, which is expressed by electrochemical impedance spectroscopy (EIS) results and is proportional to the electrosorption capacity of GO/PPy composite electrode in membrane capacitive deionization (MCDI) process. Finally, our work suggests that the less packing density, higher doping level and more charge delocalization on PPy backbone in electrode are beneficial to enhance its capacitive deionization performance.

42 ENGINEERING↗

DOE OSTI2013

In situ fabrication of Ni(OH){sub 2} nanofibers on polypyrrole-based carbon nanotubes for high-capacitance supercapacitors

Highlights: ► Facile surface decoration approach to highly porous Ni(OH){sub 2}/CNT composites. ► Polypyrrole-based CNTs form three-dimensional electron-transport channels. ► A high capacitance of 1118 F g{sup −1} at 50 mA cm{sup −2} is delivered. ► Ni(OH){sub 2}/CNT composites exhibit high discharge capability. - Abstract: Large-scale nickel hydroxide–carbon [Ni(OH){sub 2}/CNT] networks with three-dimensional electron-transport channels are synthesized via a facile and general surface-decoration approach, using polypyrrole-derived CNTs as the support. Flexible Ni(OH){sub 2} nanofibers with a diameter of 5–10 nm and a length of 50–120 nm are intertwined and wrapped homogenously on carbon networks, leading to the formation of more complex networks. When used as supercapacitor electrodes, this designed architecture with large surface area, abundant pores and good electrical conductivity is very important in technology. It can promote the bulk accessibility of electrolyte OH{sup −} and diffusion rate within the redox phase. Consequently, an unusual specific capacitance of 1745 F g{sup −1} can be obtained for Ni(OH){sub 2}/CNT composite at 30 mA cm{sup −2}. Even at a high rate (50 mA cm{sup −2}), the composite can also deliver a specific capacitance as high as 1118 F g{sup −1}, exhibiting the potential application for supercapacitors.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Performance of a triple-GEM detector with capacitive-sharing 3-coordinate (X–Y–U)-strip anode readout

The concept of capacitive-sharing readout, described in detail in a previous study, offers the possibility for the development of high-performance three-coordinates (X--Y--U)-strip readout for Micro Pattern Gaseous Detectors (MPGDs) using simple standard PCB fabrication techniques. Capacitive-sharing (X--Y--U)-strip readout allows simultaneous measurement of the Cartesian coordinates x and y of the position of the particles together with a third coordinate u along the diagonal axis in a single readout PCB. This provides a powerful tool to address multiple-hit ambiguity and enable pattern recognition capabilities in moderate particle flux environment of collider or fixed target experiments in high energy physics HEP) and nuclear physics (NP). We present in this paper the performance of a 10 cm × 10 cm triple-GEM detector with capacitive-sharing (X--Y--U)-strip anode readout. Spatial resolutions of the order of $\sigma_{x}^{res}$ = 71.6 $\pm$ 0.8 $\mu$m for X-strips, $\sigma_{y}^{res}$ = 56.2 $\pm$ 0.9 $\mu$m for Y-strips and $\sigma_{u}^{res}$ = 75.2 $\pm$ 0.9 $\mu$m for U-strips have been obtained at a beam test at Thomas Jefferson National Accelerator Facility (Jefferson Lab). Modifications of the readout design of future prototypes to improve the spatial resolution and challenges in scaling to large-area MPGDs are discussed.

(X-Y-U) strip↗

DOE OSTI2018

Charging and Transport Dynamics of a Flow-Through Electrode Capacitive Deionization System

We present a study of the interplay among electric charging rate, capacitance, salt removal, and mass transport in “flow-through electrode” capacitive deionization (CDI) systems. We develop two models describing coupled transport and electro-adsorption/desorption which capture salt removal dynamics. The first model is a simplified, unsteady zero-dimensional volume-averaged model which identifies dimensionless parameters and figures of merits associated with cell performance. The second model is a higher fidelity area-averaged model which captures both spatial and temporal responses of charging. We further conducted an experimental study of these dynamics and considered two salt transport regimes: (1) advection-limited regime and (2) dispersion-limited regime. We use these data to validate models. The study shows that, in the advection-limited regime, differential charge efficiency determines the salt adsorption at the early stage of the deionization process. Subsequently, charging transitions to a quasi-steady state where salt removal rate is proportional to applied current scaled by the inlet flow rate. In the dispersion-dominated regime, differential charge efficiency, cell volume, and diffusion rates govern adsorption dynamics and flow rate has little effect. In both regimes, the interplay among mass transport rate, differential charge efficiency, cell capacitance, and (electric) charging current governs salt removal in flow-through electrode CDI.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Bipolar Membrane Capacitive Deionization for pH-Assisted Ionic Separations

Selective ionic separations represent an increasingly important technical area for the strategic interests of the U.S. economy–for example, securing critical minerals and materials and circular economy aspirations that include recovering organic acids from processed biomass. This work disseminates bipolar membrane (BPM) capacitive deionization for selective ionic separations from multicomponent, ionic species mixtures. The selective separations are guided by the Pourbaix diagram and acid–base equilibria principles. BPM capacitive deionization was demonstrated to generate alkaline or acidic process streams depending upon the location of the BPM in the electrochemical cell. The role of system operating parameters, such as the cell voltage, residence time, and feed concentration on effluent stream pH was studied. It was observed that the pH adjustment in BPM-CDI/MCDI (MCDI, membrane capacitive deionization) was more sensitive to the cell voltage when compared to the process stream residence time and salt feed concentration. The BPM-MCDI gave over 6 times higher percentage of copper(II) removal when compared to sodium ion removal from brine mixtures. Lastly, BPM-MCDI demonstrated over 40% greater removal for copper ions from brine mixtures and fivefold higher removal for itaconic acid from brine mixtures when benchmarked against a traditional flow-by-MCDI setup.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2011

Measurement of the sheath capacitance of a planar probe

The sheath capacitance was measured on a planar probe dc-biased with respect to the plasma potential using the phase sensitive detection method in the region separated from the rf discharge plasmas by an immersed grid. It was observed that the sheath capacitance was negative when the collecting electrode of the probe was positioned downward toward the grid and biased near the plasma potential. This indicates that a double sheath had built up near the probe electrode. This tendency can be explained by the sheath capacitance, which is calculated using Poisson's equation with a non-zero electrical field and an ion velocity condition at the sheath edge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2012

A compact and miniaturized high resolution capacitance dilatometer for measuring thermal expansion and magnetostriction

We describe the design, construction, calibration, and two different applications of a miniature capacitance dilatometer. The device is suitable for thermal expansion and magnetostriction measurements from 300 K down to about 25 mK, with a resolution of 0.02 A at low temperatures. The main body of the dilatometer is fabricated from a single block of a Be-Cu alloy by electrical discharge milling. This creates an extremely compact high-resolution measuring cell. We have successfully tested and operated dilatometers of this new type with the commonly used physical property measurement system by quantum design, as well as with several other cryogenic refrigeration systems down to 25 mK and in magnetic fields up to 20 T. Here, the capacitance is measured with a commercially available capacitance bridge. Using a piezoelectric rotator from Attocube Systems, the cell can be rotated at T= 25 mK inside of an inner vacuum chamber of 40 mm diameter. The miniaturized design for the one-axis rotation setup allows a rotation of 360 Degree-Sign .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2013

Probing the local surface potential and quantum capacitance in single and multi-layer graphene

We report on local measurements of the surface potential and quantum capacitance in single layer graphene as well as multilayers thereof as a function of the carrier density by using frequency-modulated Kelvin probe force microscopy. We find excellent agreement to tight-binding calculations reported for graphene monolayers and extract the minimum quantum capacitance from density sweeps at room temperature. The surface potential of graphene multilayers is found to depend linearly on the carrier density, which suggests treating them as two-dimensional electron gases. In addition, we demonstrate that the simultaneously detected second harmonic of the Kelvin modulation, proportional to |∂{sup 2}C/∂z{sup 2}|, is directly sensitive to local changes in the quantum capacitance of graphene.

77 NANOSCIENCE AND NANOTECHNOLOGY↗