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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Approach to using 3D laser-induced breakdown spectroscopy (LIBS) data to explore the interaction of FLiNaK and FLiBe molten salts with nuclear-grade graphite

Nuclear graphite has historically been a key component of many nuclear reactor designs and has emerged as key to numerous advanced nuclear reactor design concepts. Molten salt reactors (MSRs) are one broad group of advanced reactor designs currently being pursued by industry for commercialization. Several MSR designs under consideration use graphitic materials that directly interface with a molten salt, whether it is a fuel salt, coolant salt, or both. Therefore, the interaction of graphite materials with molten salts must be understood. To gain this required understanding, a range of data is needed including porosity, strength, and composition as a function of different salt exposure parameters. In this study, a laser-induced breakdown spectroscopy (LIBS) measurement and data analysis methodology was developed to obtain spatially resolved elemental composition information for graphite samples exposed to a molten fluoride salt. Traditional univariate emission line analysis of atomic, ionic, and molecular optical emission signals was coupled via correlation analysis with spectral decomposition of the data using principal component analysis. Elemental depth profiling and elemental mapping were also performed to visualize salt–graphite interactions. LIBS was demonstrated to be useful for measuring key analytes such as fluorine and hydrogen, which are troublesome for other analysis techniques. Evidence for complex behavior was found, thereby demonstrating the usefulness of the developed approach for future systematic studies.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2024

Absolute nuclear charge radius by Na-like spectral line separation in high-Z elements

Abstract We describe a novel technique to determine absolute nuclear radii of high- Z nuclides. Utilizing accurate theoretical atomic structure calculations together with precise measurements of extreme ultraviolet transitions in highly charged ions this method allows for precise determinations of absolute nuclear charge radii based upon the well-known nuclear radii of their neighboring elements. This method can work for elements without stable isotopes, and its accuracy may be competitive with current methods (electron scattering and muonic x-ray spectroscopy).

Hosier, A. (ORCID:0000000328366605)↗
NASA NTRS1972

Electric discharges in air - Near infrared emission spectrum.

The emission from glow discharges in flowing air has been investigated in the 1- to 5-micron wavelength region with a vacuum spectrometer. Most of the spectral features observed in the pressure range of .5 to 10 torr are identified, including atomic lines of OI, NI, and HI and molecular bands of N2, NO, N2O, CO2, and CO. The spectra are presented as a function of pressure and a table compiled of the atomic lines. Of particular interest are the contrasts between the emission of the air discharge and that of the pure gases, nitrogen and oxygen. In addition, the results of studies of several discharge modes, employing steady voltages and pulsed, provide data on details of the energy flow within the plasma.

Benesch, W. M.↗
NASA NTRS1994

VUV shock layer radiation in an arc-jet wind tunnel experiment

Measurements were made of the radiating gas cap of a blunt body in a NASA-Ames 20 MW arc-jet wind tunnel. The test gas was air. Spectra of the flux incident on a small aperture centered at the stagnation region were obtained. A helium-cooled, magnesium fluoride window transmitted the flux into an evacuated collimating system that focused the aperture onto the entrance slit of a spectrometer. Data were obtained with films and by photomultipliers. The spectral ranges covered were the vacuum ultraviolet, VUV, (120 nm to 200 nm) and the ultraviolet to near infrared (200 nm to 900 nm) with resolutions from 0.05 nm to 0.5 nm. This paper presents the preliminary VUV results from the experiment. Results from the 200 nm to 900 nm spectral range have been presented elsewhere. Representative spectral records from 120 nm to 200 nm are shown. The intense atomic oxygen and nitrogen lines which are of concern to hypersonic flight are measured. Carbon lines are are also seen. These results will be used to help develop and validate aerothermodynamic computational models of arc-jet wind tunnel performance and help to assess the importance of VUV heating to entering spacecraft.

Craig, Roger A.↗
NASA NTRS2001

Spectroscopic Determination of the Physical Conditions in Hot, Optically Thin Sources

This annual report covers the period from Oct 1, 2000 to Sep 30, 2001. The Astrophysics Plasma Emission Code and Database (APEC/APED), developed in part under this grant, have been upgraded to Version 1.1 and are now beginning to be used outside our research group in applications to X-ray spectral data from Chandra and XMM-Newton. These models represent the best theoretical data currently available and are reasonably complete below about 30 angstroms. Stellar coronae are being used to benchmark the atomic data in APED as part of the Emission Line Project. Initial results suggest that the models for most of the strongest lines are in good agreement with the observations, including the H-like and He-like emission from dominant elements and the Fe L shell emission, both near 1 keV and in the extreme ultraviolet near 100 eV. At this point in time, we define 'good agreement' at the level of accuracy expected from the atomic physics, approximately 20-30%. In order to benchmark the spectral models beyond the canonical theoretical accuracy, we are working closely with the Chandra gratings calibration group to ensure that we are using the optimal calibration, primarily effective areas and line response functions.

Brickhouse, N.↗
NASA NTRS1983

Theoretical studies of chromospheres and winds in cool stars

The formation of spectral lines in expanding spherical atmospheres was determined in a physically realistic way, taking into account multilevel atomic processes, partial frequency redistribution, and other non-LTE transfer effects that affect the formation of optically thick lines. The formation of MgII and Ca II circumstellar absorption lines in late type giants and supergiants is investigated. The radiative cooling rate as a function of density and temperature was calculated from the results of plane parallel chromospheric models and these results were used to approximate the radiative cooling in an extended wind. The run of temperature was calculated along with the density and velocity profiles. The most important prediction of these models is that a warm zone in the wind must exist as a result of the wave heating. Within this zone, the Ca II and Mg II atoms can be ionized to Ca III and Mg III, so that the gas is transparent in the resonance transitions.

Dupree, A.↗
NASA NTRS1994

Discovery of an obscured low luminosity active nucleus in the spiral galaxy NGC 4258

The spectra and images of the nearby jet galaxy NGC 4258 (M106) obtained with ASCA indicate presence of several distinct X-ray emission components. The emission above 3 keV is pointlike and coincident in position with the optical nucleus, exhibiting a hard (photon index approximately 1.78) and absorbed N(sub H) approximately 1.5 x 10(exp 23) cm(exp -2) spectrum. This provides clear evidence that NGC 4258 hosts an obscured active nucleus of low luminosity, about 4 x 10(exp 40) ergs s(exp -1) in 2-10 keV after removing the absorption. Iron K-line emission with an equivalent width 0.25 +/- 0.10 keV was detected. The emission below 1 keV is dominated by an extended approximately 4 min thin-thermal component with a temperature approximately 0.5 keV exhibiting atomic emission lines, possibly associated with the jet. There exists a third continuum component with an intermediate spectral hardness, which is brightest at approximately 1 min south-east of the nucleus.

Makishima, Kazuo↗
NASA NTRS2020

Eta Carinae & the Homunculus: Far Infrared Sub-millimeter Spectral Lines detected with the Herschel Space Observatory

The evolved massive binary star η Carinae underwent eruptive mass loss events that formed the complex bi-polar “Homunculus” nebula harboring tens of solar masses of unusually nitrogen-rich gas and dust. Despite expectations for the presence of a significant molecular component to the gas, detections have been observationally challenged by limited access to the far-infrared and the intense thermal continuum. A spectral survey of the atomic and rotational molecular transitions was carried out with theHerschel Space Observatory, revealing a rich spectrum of broad emission lines originating in the ejecta. Velocity profiles of selected PACS lines correlate well with known substructures: Hi in the central core; NH and weak [Cii] within the Homunculus; and [Nii] emissions in fast-moving structures external to the Homunculus.We have identified transitions from [Oi], Hi, and 18 separate light C- and O-bearing molecules including CO, CH, CH+, and OH, and a wide set of N-bearing molecules,NH, NH+, N2H+, NH2, NH3, HCN, HNC, CN, and N2H+. Half of these are new detections unprecedented for any early-type massive star environment. A very low ratio[12C/13C]≤4 is estimated from five molecules and their isotopologues. We demonstrate that non-LTE effects due to the strong continuum are significant. Abundance patterns are consistent with line formation in regions of carbon and oxygen depletions with nitrogen enhancements, reflecting an evolved state of the erupting star with efficient transport of CNO-processed material to the outer layers. The results offer many opportunities for further observational and theoretical investigations of the molecular chemistry under extreme physical and chemical conditions around massive stars in their final stages of evolution.

T. R. Gull↗
NASA NTRS2023

Prospects of Detecting Nonthermal Protons in Solar Flares via Lyman Line Spectroscopy: Revisiting the Orrall-Zirker Effect

Solar flares are efficient particle accelerators, with a substantial fraction of the energy released manifesting as nonthermal particles. While the role that nonthermal electrons play in transporting flare energy is well studied, the properties and importance of nonthermal protons are rather less well understood. This is in large part due to the paucity of diagnostics, particularly at the lower-energy (deka-keV) range of nonthermal proton distributions in flares. One means to identify the presence of deka-keV protons is by an effect originally described by Orrall & Zirker. In the Orrall–Zirker effect, nonthermal protons interact with ambient neutral hydrogen, and via charge exchange produce a population of energetic neutral atoms (ENAs) in the chromosphere. These ENAs subsequently produce an extremely redshifted photon in the red wings of hydrogen spectral lines. We revisit predictions of the strength of this effect using modern interaction cross sections, and numerical models capable of self-consistently simulating the flaring nonequilibrium ionization stratification, and the nonthermal proton distribution (and, crucially, their feedback on each other). We synthesize both the thermal and nonthermal emission from Ly α and Ly β, the most promising lines that may exhibit a detectable signal. These new predictions are weaker and more transient than prior estimates, but the effects should be detectable in fortuitous circumstances. We degrade the Ly β emission to the resolution of the Spectral Imaging of the Coronal Environment (SPICE) instrument on board Solar Orbiter, demonstrating that though likely difficult, it should be possible to detect the presence of nonthermal protons in flares observed by SPICE.

Solar flares↗
NASA NTRS2008

Uncertainty Analysis of Air Radiation for Lunar Return Shock Layers

By leveraging a new uncertainty markup technique, two risk analysis methods are used to compute the uncertainty of lunar-return shock layer radiation predicted by the High temperature Aerothermodynamic Radiation Algorithm (HARA). The effects of epistemic uncertainty, or uncertainty due to a lack of knowledge, is considered for the following modeling parameters: atomic line oscillator strengths, atomic line Stark broadening widths, atomic photoionization cross sections, negative ion photodetachment cross sections, molecular bands oscillator strengths, and electron impact excitation rates. First, a simplified shock layer problem consisting of two constant-property equilibrium layers is considered. The results of this simplified problem show that the atomic nitrogen oscillator strengths and Stark broadening widths in both the vacuum ultraviolet and infrared spectral regions, along with the negative ion continuum, are the dominant uncertainty contributors. Next, three variable property stagnation-line shock layer cases are analyzed: a typical lunar return case and two Fire II cases. For the near-equilibrium lunar return and Fire 1643-second cases, the resulting uncertainties are very similar to the simplified case. Conversely, the relatively nonequilibrium 1636-second case shows significantly larger influence from electron impact excitation rates of both atoms and molecules. For all cases, the total uncertainty in radiative heat flux to the wall due to epistemic uncertainty in modeling parameters is 30% as opposed to the erroneously-small uncertainty levels (plus or minus 6%) found when treating model parameter uncertainties as aleatory (due to chance) instead of epistemic (due to lack of knowledge).

Kleb, Bil↗
NASA NTRS1979

Electron impact study of potassium hydroxide

An attempt is made to measure the sum of the elastic, rotational and vibrational scattering of electrons by KOH at low impact energies (5 to 20 eV) at angles from 10 to 120 deg. Energy loss spectra taken in the 0 to 18 eV range using an electron impact spectrometer are used to identify the species contributing to electric scattering. At temperatures between 300 and 500 C, only inelastic spectral features belonging to water are detected, while at temperatures from 500 to 800 C strong atomic K lines, indicative of molecular dissociation, and H2 energy loss features become prominent. No features attributable to KOH, the KOH dimer, O2 or potassium oxides were observed, due to the effects of the dissociation products, and it is concluded that another technique will have to be developed in order to measure electron scattering by KOH.

Vuskovic, L.↗
NASA NTRS1985

An ultraviolet line list for O star spectra

Archival high dispersion UV spectra obtained by the IUE satellite, together with laboratory data for the Fe peak ions, reveal more than 550 identifiable spectral features in the far-UV region in the cases of the O subdwarfs BD +75 deg 325 and BD +28 deg 4211, as well as the sharp lined main sequence star HD 46202. The wide range of effective temperatures of the selected stars makes this spectral line identification list suitable for use with all stars of spectral type O. The most numerous of the features identified are those of the lines attributed to iron atoms, with each of the spectra studied exhibiting three levels of ionization that range from Fe III to Fe V for the coolest O star, HD 46202, and Fe IV through Fe VI for the hottest O star, BD +28 4211.

Dean, C. A.↗
NASA NTRS1995

New model of iron spectra in the extreme ultraviolet and application to SERTS and EUV observations: A solar active region and capella

We report new predictions for the EUV spectral emission of FeIX-FeXXIV, based on data now available from the Solar EUV Rocket Telescope and Spectrograph (SERTS) and the Extreme Ultraviolet Explorer (EUVE) spectrometers. The iron spectral emission model is the first result of a larger effort to revise the Raymond & Smith model and to update the atomic rates. We present here predicted emissivities for selected densities and temperatures applicable to various astrophysical plasmas. Comparisons of our predicted spectra with two recent observations provide important tests of the atomic data. They also test to some extent some basic assumptions of coronal emission codes: optically thin spectral lines and ionization equilibrium.

Brickhouse, N. S.↗
DOE OSTI2020

Panning for Gold: New Emission Lines from UV–VIS Spectroscopy of Au i and Au ii

The recent detection of a neutron star merger by the LIGO collaboration has renewed interest in laboratory studies of r-process elements. Accurate modeling and interpretation of the electromagnetic transients following the mergers requires computationally expensive calculations of both the structure and opacity of all trans-iron elements. To date, the necessary atomic data to benchmark structure codes are incomplete or, in some cases, absent entirely. Within the available laboratory studies, the literature on Au i and Au ii provides incomplete reports of the emission lines and level structures. We present a new study of Au i and Au ii lines and levels by exposing a solid gold target to plasma in the Compact Toroidal Hybrid (CTH) experiment at Auburn University. A wavelength range from 187 to 800 nm was studied. In Au i, 86 lines are observed, 43 of which are unreported in the literature, and the energies of 18 $5{d}^{9}6s6p$ levels and 16 of the 18 known $5{d}^{9}6s6d$ levels are corroborated by a least-squares level energy optimization. In Au ii, 76 emission lines are observed, and 51 of the lines are unreported in the literature. For both Au i and Au ii, the new lines predominantly originate from the most energetic of the known levels, and over half of the new Au ii lines have wavelengths longer than 300 nm. For the estimated electron parameters of CTH plasmas at the gold target (ne ~ 10 12 cm -3 , T e ~ 10 eV), two-electron transitions are similar in intensity to LS-allowed one-electron transitions.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1996

Spectroscopic Diagnostics and an Arc Jet Heated Air Plasma

Spectral radiation measurements were made in the range of 200 to 900 nm across a section of the plenum of an arc jet wind tunnel using a series of optical fibers. The spectra contained line radiation from Oxygen and Nitrogen atoms and molecular radiation from N2(+), N2, and NO. Abel inversion technique is used to obtain radial distribution of the spectra. The analysis yielded radial profiles of the electronic excitation, vibrational and rotational temperatures of the flow field. Spectral fitting yielded branching ratios for different vibrational and rotational bands. Relatively mild flow conditions, i.e. enthalpy and mass flow rate, were used for prolonged measurements of up to and over two hours to establish the best experimental methods of temperature determinations. Signal to noise was improved by at least an order of magnitude enabling the molecular vibrational band heads of N2(+) (first negative system), N2 (second positive system), and NO (beta, gamma, delta, and epsilon systems) to be resolved in the lower ultraviolet wavelength regions. The increased signal to noise ratio also enabled partial resolution of the rotational lines of N2(+) and N2 in certain regions of minimal overlap. Comparison of the spectra with theoretical models such as the NEQAIR2 code are presented and show potential for fitting the spectra when reliable calibration is performed for the complete wavelength range.

Mack, Larry Howard, Jr.↗
DOE OSTI2023

Long-slit spectral study of the unusual post-interacting galaxy Arp 263

ABSTRACT Arp 263 is a single irregularly shaped galaxy with intense star formation. Its short tidal features of low brightness visible in both optics and the H i line, as well as the strong non-circular motion of atomic gas in the outskirts, give pieces of evidence of a recent merging with some intruder, non-observed directly. We carried out spectral observations of this galaxy at the 6 m telescope of the Special Astrophysical Observatory. The spectra for three positions of the spectral slit were obtained: two of them cross the central region of the galaxy and the third one runs along the nearly straight narrow chain of clumps of emission gas with a length of 4–5 kpc. We derived the profiles of velocity, fluxes, and oxygen abundances (O/H) along the slits. We confirm that within the radius of several kpc the galaxy rotates regularly. The maximal value of the rotational velocity allows us to conclude that the dark mass of the galaxy prevails over the mass of its visible components. The observed velocity profile along the peripheral star-forming chain gives pieces of evidence that it is located outside of the plane of the disc, and the gas that formed the chain is probably falling back on to the disc after being ejected from the galaxy. We discuss that the observed chain of clumps is the result of gravitational instability of the gaseous filament.

Astronomy & Astrophysics↗
NASA NTRS1981

Lyman-alpha fluorescence from hydrogen photofragments of CH4 and H2O

The process of H-Lyman-alpha fluorescence produced through photodissociation of CH4 and H2O provides an example for the usefulness of the detection of fluorescence of dissociation fragments as an aid in identifying some high lying Rydberg states. In the first experiment reported, an electron storage ring synchrotron radiation source was used. The fluorescence produced was detected with a solar blind photomultiplier and a Cs photocathode with a spectral sensitivity in the wavelength range from 1050 to 1950 A. In the second experiment considered, an intense atomic line source was employed.

Wu, C. Y. R.↗
NASA NTRS1990

Calculation of polarization and anisotropy of resonant and fluorescent scattering

Formulas are derived for the swift calculation of the angular intensity distribution and the degree of polarization associated with the resonant and fluorescent scattering of radiation by atoms which occurs in the rarefied upper atmospheres of planets during sunlit airglow phenomena. Attention is given to spectral lines with hyperfine structure, which are indicative of nuclear spin processes. The method employed involves summations over Zeeman components, allowing an evaluation of polarization through the addition of underlying simple resonant and fluorescent scattering channels.

Chamberlain, Joseph W.↗