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At least 163 records · Page 9

Skin factor and potential formation damage from chemical and mechanical processes in a naturally fractured carbonate aquifer with implications to CO 2 sequestration

Here, in this study, we investigate formation damage due to acidization and water injection tests into the naturally fractured carbonate Middle Duperow Formation at Kevin Dome, Montana, potentially diminishing the chance of a future successful Geological Carbon Sequestration (GCS) project. Multiple well-test analytical models, correlated with core description and lithology data, are used to determine flow behavior and communication between the water injection interval and surrounding formations. An improved three-dimensional (3D) geologic model with dual-continuum matrix and fracture properties is constructed based on most recent seismic, core, and water sample measurements. Brine injection is simulated to verify the interpretation from the analytical models, followed by CO 2 injection simulation. Geochemical calculations are performed to understand the in-situ processes that led to formation damage. Our findings suggest: (1) there are two possible scenarios that could lead to a positive total effective skin factor and permeability decline: partial penetration and formation damage; (2) analytical models indicate a positive total skin factor, contradicting results of a previous study suggesting that the well was mildly stimulated; (3) numerical simulation supports the formation damage hypothesis by matching the pressure buildup observed during the latter two brine injection tests; (4) several mechanical and chemical processes may have occurred during injection to clog the matrix/fracture system: anhydrite fines migration and/or calcite precipitation. We then make preventative suggestions for future GCS projects into carbonate reservoirs and remediation recommendations for GCS operation at the Kevin Dome.

54 ENVIRONMENTAL SCIENCES↗

Reply to Comment by Peterie Et Al. on “Accelerated Fill‐Up of the Arbuckle Group Aquifer and Links to U.S. Midcontinent Seismicity”

Abstract Peterie et al. question one observation in our paper: associating pressure increases to injection volumes at distances of up to 25 km from an injection well. In this reply, we show that the comment misunderstands our analysis and the evidence that led to this conclusion. We also show that gauge‐depth‐corrected pressures, used by the authors to produce statewide pressure maps, are discrepant with the static fluid level data, provided in our original compilation and analysis. The discrepancies are a result of the pressure correction method employed, which naïvely substitutes formation pressure for bottomhole pressure to calculate wellbore fluid density. Their linearly interpolated pressure maps, based on sparse data, contain interpolation and extrapolation artifacts that contradict injection trends in the state, the Theis solution, and the superposition principle. We reiterate that pressure and static fluid level increases in Class I wells existed prior to 2013, most notably in central Kansas, where recent earthquakes are cited in the comment as evidence of a pressure plume emanating from the Kansas‐Oklahoma border, 90 km away. We show that the space‐time pattern of seismicity in this area is inconsistent with a northward propagating pressure plume and, instead, seismicity appears to be centered on and near a cluster of high‐rate injection wells, two of which are among the highest rate wells in the state. These observations, along with recent M4 + earthquakes during continued decreases in wastewater injection in southern Kansas and northern Oklahoma, question the usefulness of the comment for understanding and managing societally significant earthquakes.

Ansari, Esmail↗

Deep anoxic aquifers could act as sinks for uranium through microbial-assisted mineral trapping

Uptake of uranium (U) by secondary minerals, such as carbonates and iron (Fe)-sulfides, that occur ubiquitously on Earth, may be substantial in deep anoxic environments compared to surficial settings due to different environment-specific conditions. Yet, knowledge of U reductive removal pathways and related fractionation between 238 U and 235 U isotopes in deep anoxic groundwater systems remain elusive. Here we show bacteria-driven degradation of organic constituents that influences formation of sulfidic species facilitating reduction of geochemically mobile U(VI) with subsequent trapping of U(IV) by calcite and Fe-sulfides. The isotopic signatures recorded for U and Ca in fracture water and calcite samples provide additional insights on U(VI) reduction behaviour and calcite growth rate. The removal efficiency of U from groundwater reaching 75% in borehole sections in fractured granite, and selective U accumulation in secondary minerals in exceedingly U-deficient groundwater shows the potential of these widespread mineralogical sinks for U in deep anoxic environments.

36 MATERIALS SCIENCE↗

Genomic Features and Pervasive Negative Selection in Rhodanobacter Strains Isolated from Nitrate and Heavy Metal Contaminated Aquifer

Despite the dominance of Rhodanobacter species in the subsurface of the contaminated Oak Ridge Reservation (ORR) site, very little is known about the mechanisms underlying their adaptions to the various stressors present at ORR. Recently, multiple Rhodanobacter strains have been isolated from the ORR groundwater samples from several wells with varying geochemical properties.

59 BASIC BIOLOGICAL SCIENCES↗

Well-Log Derived Geomechanical Analysis of Microseismicity in the Mt. Simon Saline Aquifers (Illinois Basin - Decatur Project)

The Illinois Basin Decatur Project (IBDP) successfully demonstrated the safe geologic storage of carbon dioxide at a commercial scale. Within the IBDP project three deep wells (injection (CCS1), monitoring (VW1), geophysical (GM1)) were competed and geophysical logs were recorded. During injection and post-injection periods microseismic monitoring was conducted to create a miscoseismic catalog. The correlations between microseimic attributes and geomechanical well logs define major geomechanical drivers of microseismic expression to understand a reservoir response to CO2 injection in geological context. Utilizing standard sonic and density well logs, the dynamic elastic moduli were calculated and employed to correlate with microseismic pseudo-logs. A multi-dimensional Mu-rho and Lambda-rho (MRLR) hyperdimensional plots display of meaningful data and uncovered subtle relationships between elastic properties of sandstones and the seismological attributes of recorded microseismicity.

Myshakin, Evgeniy↗

Multisystem feedbacks from a changing climate: Do altered hydrological dynamics control vadose zone carbon nutrient cycling and storage in shallow aquifer systems?

The vadose zone, which extends from upper soils to the subsurface water table, consists of many distinct habitats (including the critical zone), each with its own physical characteristics. Upper soils are typically richer in organic carbon chemical diversity and concentration, while deeper portions near the water table have less labile carbon and a greater percentage of humic acids and other long-lived organics. The availability of carbon and oxygen constrain the habitability of these zones. Typically, microorganisms (bacteria, archaea, and fungi) extend throughout the vadose zone and potentially deeper into the bedrock, while higher eukaryotes (i.e., arthropods and plants) are limited to the surficial soils. An exception to this is deep taproots of some tree species that can extend tens of meters into the subsurface. In subsurface systems, microbial metabolisms are constrained by the availability of carbon (organic and inorganic) and electron acceptors.

54 ENVIRONMENTAL SCIENCES↗