Corrosion of Al 2 O 3 /Cr and Ti 2 O 3 /Cr composites in flowing air and CO 2 at 750°C
Hot-pressed Al 2 O 3 /Cr and Ti 2 O 3 /Cr composites were exposed to synthetic air or CO 2 at 750 °C. The Al 2 O 3 /Cr composites formed external Cr 2 O 3 scales, and exhibited slow parabolic oxidation kinetics, in both gases. The Cr 2 O 3 scales formed in CO 2 possessed finer grains, and thickened at a faster rate, than Cr 2 O 3 scales formed in air. The Ti 2 O 3 /Cr composites formed thick external TiO 2 scales with internal oxidation zones that also contained Cr 2 O 3 scales on subsurface Cr grains. After 20 h at 750 °C, the Ti 2 O 3 /Cr composites exhibited parabolic oxidation kinetics in both gases, although the oxidation rates were significantly higher than for the Al 2 O 3 /Cr composites.