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At least 1,603 records · Page 89

Remote sensing of earth terrain

In remote sensing, the encountered geophysical media such as agricultural canopy, forest, snow, or ice are inhomogeneous and contain scatters in a random manner. Furthermore, weather conditions such as fog, mist, or snow cover can intervene the electromagnetic observation of the remotely sensed media. In the modelling of such media accounting for the weather effects, a multi-layer random medium model has been developed. The scattering effects of the random media are described by three-dimensional correlation functions with variances and correlation lengths corresponding to the fluctuation strengths and the physical geometry of the inhomogeneities, respectively. With proper consideration of the dyadic Green's function and its singularities, the strong fluctuation theory is used to calculate the effective permittivities which account for the modification of the wave speed and attenuation in the presence of the scatters. The distorted Born approximation is then applied to obtain the correlations of the scattered fields. From the correlation of the scattered field, calculated is the complete set of scattering coefficients for polarimetric radar observation or brightness temperature in passive radiometer applications. In the remote sensing of terrestrial ecosystems, the development of microwave remote sensing technology and the potential of SAR to measure vegetation structure and biomass have increased effort to conduct experimental and theoretical researches on the interactions between microwave and vegetation canopies. The overall objective is to develop inversion algorithms to retrieve biophysical parameters from radar data. In this perspective, theoretical models and experimental data are methodically interconnected in the following manner: Due to the complexity of the interactions involved, all theoretical models have limited domains of validity; the proposed solution is to use theoretical models, which is validated by experiments, to establish the region in which the radar response is most sensitive to the parameters of interest; theoretically simulated data will be used to generate simple invertible models over the region. For applications to the remote sensing of sea ice, the developed theoretical models need to be tested with experimental measurements. With measured ground truth such as ice thickness, temperature, salinity, and structure, input parameters to the theoretical models can be obtained to calculate the polarimetric scattering coefficients for radars or brightness temperature for radiometers and then compare theoretical results with experimental data. Validated models will play an important role in the interpretation and classification of ice in monitoring global ice cover from space borne remote sensors in the future. We present an inversion algorithm based on a recently developed inversion method referred to as the Renormalized Source-Type Integral Equation approach. The objective of this method is to overcome some of the limitations and difficulties of the iterative Born technique. It recasts the inversion, which is nonlinear in nature, in terms of the solution of a set of linear equations; however, the final inversion equation is still nonlinear. The derived inversion equation is an exact equation which sums up the iterative Neuman (or Born) series in a closed form and, thus, is a valid representation even in the case when the Born series diverges; hence, the name Renormalized Source-Type Integral Equation Approach.

Yueh, Herng-Aung↗

Estimation of Lower-Body Kinetics from Loading Profile and Kinematics Alone, Without Measured Ground Reaction Forces

Biomechanical models of human motion can estimate kinetic outcomes, such as joint moments, joint forces and muscle forces. Typically, one performs an inverse dynamics (ID) analysis to compute joint moments from joint angles and measured external forces. Sometimes it is impractical to measure ground reaction forces and moments (GRF&M). We devised an empirical method for performing ID analysis of resistance exercises without measured GRF&M. The method solves the multibody dynamics equations of motion with four key assumptions about the GRF&M that reduce the number of unknowns. The assumptions are 1) negligible ground reaction moments, 2) fixed lateral/medial location of the center of pressure (COP), 3) equal fore/aft location of the COP between the feet, and 4) constant angle of the GRF vector relative to the vertical axis in the frontal plane. We used evaluation trials from a spaceflight countermeasure resistance training device to test this approach. Four participants performed squat and deadlift exercises at various loads. We compared results from traditional ID analysis to results without measured GRF&M using our method. We found that joint moment trajectories in the sagittal plane were qualitatively similar in shape between the two methods, and the amount of root mean squared error (RMSE), measured by difference in joint moment impulse, was typically under 10 percent. Non-sagittal joint moment trajectories, which are much lower in overall magnitude, were not qualitatively similar in shape between the two methods. Non-sagittal moments displayed much higher RMSE, with typical values well over 50 percent. These findings were further supported by validation metrics (Sprague and Geers' P and M metrics, Pearson's r correlation coefficient). Based on these findings, we concluded that useful kinetic results are obtained from ID analysis of squat and deadlift exercises, even when GRF&M are not measured, as long as the outcomes of interest lie in the sagittal plane.

computational modeling↗

A Mechanism-Based Reaction–Diffusion Model for Accelerated Discovery of Thermoset Resins Frontally Polymerized by Olefin Metathesis

Frontal ring-opening metathesis polymerization (FROMP) involves a self-perpetuating exothermic reaction, which enables the rapid and energy-efficient manufacturing of thermoset polymers and composites. Current state-of-the-art reaction–diffusion FROMP models rely on a phenomenological description of the olefin metathesis kinetics, limiting their ability to model the governing thermo-chemical FROMP processes. Furthermore, the existing models are unable to predict the variations in FROMP kinetics with changes in the resin composition and as a result are of limited utility toward accelerated discovery of new resin formulations. In this work, we formulate a chemically meaningful model grounded in the established mechanism of ring-opening metathesis polymerization (ROMP). Our study aims to validate the hypothesis that the ROMP mechanism, applicable to monomer-initiator solutions below 100 °C, remains valid under the nonideal conditions encountered in FROMP, including ambient to >200 °C temperatures, sharp temperature gradients, and neat monomer environments. Through extensive simulations, we demonstrate that our mechanism-based model accurately predicts the FROMP behavior across various resin compositions, including polymerization front velocities and thermal characteristics (e.g., T max ). Additionally, we introduce a semi-inverse workflow that predicts FROMP behavior from a single experimental data point. Notably, the physiochemical parameters utilized in our model can be obtained through DFT calculations and minimal experiments, highlighting the model’s potential for rapid screening of new FROMP chemistries in pursuit of thermoset polymers with superior thermo-chemo-mechanical properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A fast and accurate radiance algorithm for application to inversion of limb measurements

A method is devised to accurately calculate broad band limb radiance based on a precalculated data base consisting of homogeneous path emissivity as a function of mass path data for various temperatures and pressures. Accurately estimating limb radiance by splicing together interpolated information from the emissivity curves requires no temperature or pressure weighting, and only two interpolations per layer path. The emissivity growth approximation (EGA) technique is applied in a simulated inversion study to the inference of O3, H2O, NO2 and HNO3, and it is found to have comparable accuracies to more sophisticated many-degree band models. The EGA technique is also found to be two orders of magnitude faster, while requiring one second per inversion for one constituent at one-km resolution, allowing a completely nonlinear relaxation time inversion to be done at linear speeds. The technique is also expected to work well for nadir calculations, and prove adequate for estimating occultation radiances.

Gordley, L. L.↗

Inversion of Gravity Fields From the Spacecraft Orbital Data Using an Adjoint Operator Approach

In perturbation approximation, the forward problem of orbital dynamics (equations with initial conditions) is linear with respect to variations of coordinates and/or velocities of the spacecraft and to corresponding variations of the gravity field in the models used. The linear operator adjoint to the linear operator of such forward problem turns out to be instrumental in inversion of differences between observed and predicted coordinates/velocities in terms of the updates of harmonics in the initial gravity field model. Based on this approach, the solution of resulting adjoint problem of orbital dynamics can be used to directly evaluate the matrix of partial derivatives of observable differences with respect to the gravity field harmonics. General discussion of the adjoint problem of orbital dynamics is given and an example of a mathematical formalism for the practical retrieval algorithm is presented.

Ustinov, E. A.↗

Mercury and Radiocesium Accumulation and Associations With Sublethal Endpoints in the Florida Green Watersnake ( Nerodia floridana )

Mercury (Hg) and radiocesium ( 137 Cs) are well-known environmental contaminants with the potential to impact the health of humans and wildlife. Snakes have several characteristics conducive to studying environmental contamination but have rarely been included in the monitoring of polluted sites. We investigated the bioaccumulation of Hg and 137 Cs and associations with sublethal effects (standard metabolic rate [SMR] and hemoparasite infections) in Florida green watersnakes (Nerodia floridana). We captured 78 snakes from three former nuclear cooling reservoirs on the US Department of Energy's Savannah River Site in South Carolina (USA). For captured snakes, we (1) determined whole-body 137 Cs, (2) quantified total Hg (THg) using snake tail clips, (3) conducted hemoparasite counts, and (4) measured the SMR. We used multiple regression models to determine associations among snake body size, capture location, sex, tail THg, whole-body 137 Cs, Hepatozoon spp. prevalence and parasitemia, and SMR. Average whole-body 137 Cs (0.23 ± 0.08 Becquerels [Bq]/g; range: 0.00–1.02 Bq/g) was correlated with snake body size and differed significantly by capture site (Pond B: 0.67 ± 0.05 Bq/g; Par Pond: 0.10 ± 0.02 Bq/g; Pond 2: 0.03 ± 0.02 Bq/g). Tail THg (0.33 ± 0.03 mg/kg dry wt; range: 0.16–2.10 mg/kg) was significantly correlated with snake body size but did not differ by capture site. We found no clear relationship between SMR and contaminant burdens. However, models indicated that the prevalence of Hepatozoon spp. in snakes was inversely related to increasing whole-body 137 Cs burdens. Our results indicate the bioaccumulation of Hg and 137 Cs in N. floridana and further demonstrate the utility of aquatic snakes as bioindicators. Furthermore, our results also suggest a decrease in Hepatozoon spp. prevalence related to increased burdens of 137 Cs. Although the results are intriguing, further research is needed to understand the dynamics between 137 Cs and Hepatozoon spp. infections in semiaquatic snakes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhanced neutrino polarizability

We point out that neutrinos can have enhanced couplings to photons, if light (pseudo)scalar mediators are present, resulting in a potentially measurable neutrino polarizability. We show that the expected suppression from small neutrino masses can be compensated by the light mediator mass, generating dimension 7 Rayleigh operators at low scales. We explore the rich phenomenology of such models, computing in detail the constraints on the viable parameter space, spanned by the couplings of the mediator to neutrinos and photons. Finally, we build several explicit models that lead to an enhanced neutrino polarizability by modifying the inverse see-saw majoron, i.e., the pseudo-Nambu-Goldstone boson of the U(1) L global lepton number responsible for generating small neutrino masses.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Impact of Changing Winds on the Mauna Loa CO 2 Seasonal Cycle in Relation to the Pacific Decadal Oscillation

Abstract Long‐term measurements at the Mauna Loa Observatory (MLO) show that the CO 2 seasonal cycle amplitude (SCA) increased from 1959 to 2019 at an overall rate of 0.22 0.034 ppm decade −1 while also varying on interannual to decadal time scales. These SCA changes are a signature of changes in land ecological CO 2 fluxes as well as shifting winds. Simulations with the TM3 tracer transport model and CO 2 fluxes from the Jena CarboScope CO 2 Inversion suggest that shifting winds alone have contributed to a decrease in SCA of −0.10 0.022 ppm decade −1 from 1959 to 2019, partly offsetting the observed long‐term SCA increase associated with enhanced ecosystem net primary production. According to these simulations and MIROC‐ACTM simulations, the shorter‐term variability of MLO SCA is nearly equally driven by varying ecological CO 2 fluxes (49%) and varying winds (51%). We also show that the MLO SCA is strongly correlated with the Pacific Decadal Oscillation (PDO) due to varying winds, as well as with a closely related wind index (U‐PDO). Since 1980, 44% of the wind‐driven SCA decrease has been tied to a secular trend in the U‐PDO, which is associated with a progressive weakening of westerly winds at 700 mbar over the central Pacific from 20°N to 40°N. Similar impacts of varying winds on the SCA are seen in simulations at other low‐latitude Pacific stations, illustrating the difficulty of constraining trend and variability of land CO 2 fluxes using observations from low latitudes due to the complexity of circulation changes.

54 ENVIRONMENTAL SCIENCES↗

Optically induced umklapp shift currents in striped cuprates

Motivated by recent experiments that observed low-frequency second-order optical responses in doped striped superconductors, here we investigate the nonlinear electrodynamics of systems exhibiting a charge density wave (CDW) order parameter. Due to the Bragg scattering off the CDW order, an incoming spatially homogeneous electric field in addition to zero momentum current generates umklapp currents that are modulated in space at momenta of the reciprocal CDW lattice. In particular, here we predict and microscopically evaluate the umklapp shift current, a finite momentum analog of the regular shift current which represents the second-order optical process that downconverts homogeneous AC electric field into low-frequency, zero momentum current. Specifically, we evaluate real-time response functions within mean-field theory via the Keldysh technique and use the Peierls substitution to compute observables at finite momenta in lattice models. We find that systems with certain lattice symmetries (such as inversion symmetry), where the regular shift current is disallowed, may give rise to the umklapp one. We apply our framework to investigate lattice symmetries in layered materials with helical-like stripes and show that both types of shift currents provide insight into the nature of intertwined phases of matter. Finally, we discuss the relation of our findings to recent experiments in striped superconductors. Published by the American Physical Society 2024

Materials Science↗

Large critical fields in superconducting Ti 4 ⁢Ir 2⁢ O from spin-orbit coupling

The recently synthesized 𝜂-carbide-type superconductors exhibit large critical fields. A notable example is Ti 4 ⁢Ir2⁢ O, for which the upper critical field strongly violates the Pauli paramagnetic limit, a behavior that is unusual for cubic materials that preserve inversion symmetry. Here, by combining density functional theory (DFT) and analytic modeling, we provide an explanation for this enhanced Pauli limiting field. We show that the nonsymmorphic Fd⁢-3 ⁢m symmetry implies that the electronic states near the X points exhibit strong spin-orbit coupling (SOC), which leads to a vanishing effective 𝑔 factor and enables the enhanced Pauli limiting field. Furthermore, our DFT results reveal a Van Hove singularity peak near the X points, accounting for ∼65% of the total density of states (DOS), occurring near the chemical potential. We propose that the strong SOC and enhanced DOS in the vicinity of the X points provide the origin of the observed enhancement of the critical field. This leads to a prediction that the magnetic field will lead to a strongly momentum-dependent gap suppression. As a result, the gap due to electronic states away from (near to) the X points will be rapidly (slowly) suppressed by fields.

Critical field↗

Spectroscopy of 33 Mg with knockout reactions

In this work, the structure of 33 Mg was investigated by means of two knockout reactions, one-neutron removal from 34 Mg and one-proton removal from 34 Al. Using comparative analysis of the population of observed excited states in the residual 33 Mg, the nature of these states can be deciphered. In addition, the long-standing controversy about the parity of the 33 Mg ground state is resolved using momentum distribution analysis, showing a clear signature for negative parity. Partial cross section measurements are compared with the results of eikonal reaction theory combined with large-scale shell model calculations of this complex nucleus located in the island of inversion, where configuration mixing plays a major role.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Sparse measurement medical CT reconstruction using multi-fused block matching denoising priors

A major challenge for medical X-ray CT imaging is reducing the number of X-ray projections to lower radiation dosage and reduce scan times without compromising image quality. However these under-determined inverse imaging problems rely on the formulation of an expressive prior model to constrain the solution space while remaining computationally tractable. Traditional analytical reconstruction methods like Filtered Back Projection (FBP) often fail with sparse measurements, producing artifacts due to their reliance on the Shannon-Nyquist Sampling Theorem. Consensus Equilibrium, which is a generalization of Plug and Play, is a recent advancement in Model-Based Iterative Reconstruction (MBIR), has facilitated the use of multiple denoisers are prior models in an optimization free framework to capture complex, non-linear prior information. However, 3D prior modelling in a Plug and Play approach for volumetric image reconstruction requires long processing time due to high computing requirement. Instead of directly using a 3D prior, this work proposes a BM3D Multi Slice Fusion (BM3D-MSF) prior that uses multiple 2D image denoisers fused to act as a fully 3D prior model in Plug and Play reconstruction approach. Our approach does not require training and are thus able to circumvent ethical issues related with patient training data and are readily deployable in varying noise and measurement sparsity levels. In addition, reconstruction with the BM3D-MSF prior achieves similar reconstruction image quality as fully 3D image priors, but with significantly reduced computational complexity. We test our method on clinical CT data and demonstrate that our approach improves reconstructed image quality.

Hossain, Maliha [ORNL]↗

Far-field thermal imaging below diffraction limit

Non-uniform self-heating and temperature hotspots are major concerns compromising the performance and reliability of submicron electronic and optoelectronic devices. At deep submicron scales where effects such as contact-related artifacts and diffraction limits accurate measurements of temperature hotspots, non-contact thermal characterization can be extremely valuable. In this work, we use a Bayesian optimization framework with generalized Gaussian Markov random field (GGMRF) prior model to obtain accurate full-field temperature distribution of self-heated metal interconnects from their thermoreflectance thermal images (TRI) with spatial resolution 2.5 times below Rayleigh limit for 530nm illumination. Finite element simulations along with TRI experimental data were used to characterize the point spread function of the optical imaging system. In addition, unlike iterative reconstruction algorithms that use ad hoc regularization parameters in their prior models to obtain the best quality image, we used numerical experiments and finite element modeling to estimate the regularization parameter for solving a real experimental inverse problem.

42 ENGINEERING↗

Inviscid to turbulent transition of trailing vortices

The characteristics of the plateau region in the vortex system which trails from a lifting wing are discussed. The decay of the vortex due to viscous or turbulent shear is very slow in the plateau so that the maximum tangential speed in the vortices remains nearly constant for some distance downstream of roll-up and then begins to decrease, becoming inversely proportional to the square root of the distance downstream. Mathematical models are developed to analyze the structure of the plateau area. Solutions are obtained for both constant and variable eddy viscosity models.

Iversen, J. D.↗

Venus - Vertical structure of stratospheric hazes from Mariner 10 pictures

An 'optical barometer' technique for determining the altitudes of haze in the stratosphere of Venus is presented wherein the Rayleigh-scattering component is derived by comparing orange and UV brightness profiles for nearby Mariner 10 television-picture pairs. The derived scale height for CO2 gas is 4.2 km, corresponding to a temperature of 200 K, in good agreement with radio occultation data. The optical barometer yields a pressure of 4 mb for the level at which the slant-path optical depth at the limb is unity. This level corresponds to a distance from the center of Venus equal to 6131 km, which is accurate to within 1 km provided that there is no appreciable contribution to the brightness by Rayleigh-scattering aerosols which mimic CO2 gas. It is possible that the limb haze layering observed between 6130 and 6140 km could be correlated with temperature inversions detected by the Mariner 5 radio-occultation experiment. A model is proposed wherein the concentration of particles increases rapidly with an effective scale height of about 2 km as one descends about 10 km from the limb haze to the main polarization cloud deck.

Oleary, B.↗

Further studies of trace elements in C3 chondrites

Five carbonaceous chondrites (Renazzo C2V, Allende C3V, Ornans C3O, Warrenton C3O, and Orgueil C1) were analyzed by radiochemical neutron activation analysis for 20 elements. Elements condensing between approximately 700 and 420 K are systematically more depleted than those condensing between 1000 and 900 K, and the depletion correlates inversely with matrix content and directly with degree of metamorphism. A model of gas-dust fractionation during condensation, by settling of dust to the median plane of the nebula, is proposed. Gas/dust ratios relative to the cosmic ratio ranged from 0.7 at 1000 K to 0.5 at 700 K for C3O chondrites that accreted first and from 1.3 to 0.6 for the last. No further gas/dust fractionation was indicated below 700 K

Takahashi, H.↗