Structural and morphological characteristics of CuMe2O4 spinels in reductive atmosphere depending on the chemical nature of Me(III) cations
Highlights: • CuCr{sub 1}Fe{sub 1}O{sub 4}, CuFe{sub 1}Al{sub 1}O{sub 4} and CuCr{sub 1}Al{sub 1}O{sub 4} samples of a spinel structure, prepared by thermal decomposition of common hydroxycarbonates at 650°C have nonuniforn atomic distribution in the spinel nanoparticles. • The extent of copper reduction and structural features of Cu{sup 0} produced upon reduction of CuMe{sub 2}O{sub 4} spinels depend on the chemical nature of Me{sup 3+}. • The nature of Me{sup 3+} makes it possible to control the structural characteristics, particularly in the reduced state. - Abstract: Mixed copper-containing spinel-type compounds CuCr{sub 1}Fe{sub 1}O{sub 4}, CuCr{sub 1}Al{sub 1}O{sub 4} and CuFe{sub 1}Al{sub 1}O{sub 4} were studied by means of XRD and HREM after calcination at 650 °C in the air and treatments in a hydrogen-containing medium at 270–210 °C (H{sub 2}:He = 5:95; H{sub 2}:CO:H{sub 2}O = 50:7:43). The effect of the chemical nature of Me{sup 3+} cation on the structural-morphological characteristics of oxide systems and their transformations in a reducing medium was investigated. It was shown that the nature of Me{sup 3+} cation makes it possible to control the structural characteristics, particularly in the reduced state.