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At least 1,603 records · Page 89

Temperature and Chemical Species Distributions in the Middle Atmosphere Observed during Titan's Late Northern Spring to Early Summer

We present a study of the seasonal evolution of Titan’s thermal field and distributions of haze, C2H2, C2H4, C2H6, CH3C2H, C3H8, C4H2, C6H6, HCN, and HC3N from March 2015 (Ls = 66°) to September 2017 (Ls = 93°) (i.e., from the last third of northern spring to early summer). We analyzed thermal emission of Titan’s atmosphere acquired by the Cassini Composite Infrared Spectrometer with limb and nadir geometry to retrieve the stratospheric and mesospheric temperature and mixing ratios pole-to-pole meridional cross sections from 5 mbar to 50 μbar (120–650 km). The southern stratopause varied in a complex way and showed a global temperature increase from 2015 to 2017 at high-southern latitudes. Stratospheric southern polar temperatures, which were observed to be as low as 120 K in early 2015 due to the polar night, showed a 30 K increase (at 0.5 mbar) from March 2015 to May 2017 due to adiabatic heating in the subsiding branch of the global overturning circulation. All photochemical compounds were enriched at the south pole by this subsidence. Polar cross sections of these enhanced species, which are good tracers of the global dynamics, highlighted changes in the structure of the southern polar vortex. These high enhancements combined with the unusually low temperatures (<120 K) of the deep stratosphere resulted in condensation at the south pole between 0.1 and 0.03 mbar (240–280 km) of HCN, HC3N, C6H6 and possibly C4H2 in March 2015 (Ls = 66°). These molecules were observed to condense deeper with increasing distance from the south pole. At high-northern latitudes, stratospheric enrichments remaining from the winter were observed below 300 km between 2015 and May 2017 (Ls = 90°) for all chemical compounds and up to September 2017 (Ls = 93°) for C2H2, C2H4, CH3C2H, C3H8, and C4H2. In September 2017, these local enhancements were less pronounced than earlier for C2H2, C4H2, CH3C2H, HC3N, and HCN, and were no longer observed for C2H6 and C6 H6, which suggests a change in the northern polar dynamics near the summer solstice. These enhancements observed during the entire spring may be due to confinement of this enriched air by a small remaining winter circulation cell that persisted in the low stratosphere up to the northern summer solstice, according to predictions of the Institut Pierre Simon Laplace Titan Global Climate Model (IPSL Titan GCM). In the mesosphere we derived a depleted layer in C2H2, HCN, and C2H6 from the north pole to mid-southern latitudes, while C4H2, C3H4, C2H4, and HC3N seem to have been enriched in the same region. In the deep stratosphere, all molecules except C2H4 were depleted due to their condensation sink located deeper than 5 mbar outside the southern polar vortex. HCN, C4H2, and CH3C2H volume mixing ratio cross section contours showed steep slopes near the mid-latitudes or close to the equator, which can be explained by upwelling air in this region. Upwelling is also supported by the cross section of the C2H4 (the only molecule not condensing among those studied here) volume mixing ratio observed in the northern hemisphere. We derived the zonal wind velocity up to mesospheric levels from the retrieved thermal field. We show that zonal winds were faster and more confined around the south pole in 2015 (Ls = 67−72°) than later. In 2016, the polar zonal wind speed decreased while the fastest winds had migrated toward low-southern latitudes.

S Vinatier↗

Effects of Heating Configuration and Operating Parameters on Heat Transfer and Interfacial Physics of Microgravity Flow Boiling With Subcooled Inlet Conditions –Experiments Onboard the International Space Station

This study is part of the Flow Boiling and Condensation Experiment (FBCE), a collaborative effort between the Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) and the NASA Glenn Research Center. The FBCE fitted with the Flow Boiling Module (FBM) was launched to the International Space Station (ISS) in August 2021 and experiments were successfully performed from February to July 2022 to amass a large microgravity-flow-boiling database. This study is focused on heat transfer and flow visualization of microgravity flow boiling of n-Perfluorohexane in a rectangular channel of 5.0 mm height, 2.5 mm width (heated), and 114.6 mm length, with subcooled inlet conditions. High-speed-video photography is utilized to present flow patterns and temporal interfacial behavior. Heat transfer results are presented in the form of flow boiling curves and both parametric curves and streamwise profiles of wall temperature and heat transfer coefficient. Firstly, the parametric effects of mass velocity (199.4 – 3200.0 kg/m 2 s), inlet subcooling (0.2 – 46.0°C), and inlet pressure (124.2 – 176.7 kPa), on the aforementioned aspects are assessed for double-sided heating to establish them for a microgravity environment. Of these three parameters, mass velocity and inlet subcooling mostly determine the microgravity flow boiling behavior, while inlet pressure plays an insignificant role. Flow patterns for double-sided heating are more complex than those for single-sided heating due to interaction between the two vapor layers. Vapor interaction is minimized at high subcoolings and high mass velocities due to strong condensation offered by the subcooled bulk liquid layer separating them. Despite the different flow patterns, both single- and double-sided heating generally result in similar parametric trends and local heat transfer coefficients for similar operating conditions. Flow instabilities manifest as temporal flow anomalies and temperature oscillations, and their severity increases with increasing boiling number. Secondly, the effects of heating configuration are analyzed by comparing and contrasting several aspects of single- and double-sided heating data. The heat fluxes at which onset of nucleate boiling degradation (ONBD) and critical heat flux (CHF) occur are distinctly different for single- and double-sided heating. There exists a threshold inlet subcooling demarcating the dominance of flow acceleration and condensation effects in vapor removal from the near-wall region and replenishment of fresh liquid for boiling. Above the threshold, condensation from the near-wall region is dominant and single-sided heating yields higher heat fluxes, and below it, acceleration is dominant and double-sided yields higher heat fluxes. At mass velocity in the range of 200 – 2400 kg/m 2 s, the threshold inlet subcooling lies in the approximate range of 20 – 30°C (corresponding inlet quality of roughly -0.40 – -0.20).

Microgravity↗

Method and apparatus for reduction of water re-evaporation in a dedicated dehumidifier/water heater

An apparatus that includes a refrigeration circuit that includes an evaporator, a first condenser and a compressor. The apparatus includes a refrigerant-water heat exchanger that includes a second condenser fluidly coupled to the refrigeration circuit. A control valve is operatively connected to the refrigeration circuit to direct flow of refrigerant through at least one of the first condenser during a dehumidification mode and the second condenser during a water heating mode. A damper is disposed on an upwind side of the evaporator, the damper being operable to reduce airflow across the evaporator during a ventilation mode.

42 ENGINEERING↗

PWR decay heat removal system in which steam from the pressurizer drives a turbine which drives a pump to inject water into the reactor pressure vessel

In conjunction with a pressurized water reactor (PWR) and a pressurizer configured to control pressure in the reactor pressure vessel, a decay heat removal system comprises a pressurized passive condenser, a turbine-driven pump connected to suction water from at least one water source into the reactor pressure vessel; and steam piping configured to deliver steam from the pressurizer to the turbine to operate the pump and to discharge the delivered steam into the pressurized passive condenser. The pump and turbine may be mounted on a common shaft via which the turbine drives the pump. The at least one water source may include a refueling water storage tank (RWST) and/or the pressurized passive condenser. A pressurizer power operated relief valve may control discharge of a portion of the delivered steam bypassing the turbine into the pressurized passive condenser to control pressure in the pressurizer.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

PWR decay heat removal system in which steam from the pressurizer drives a turbine which drives a pump to inject water into the reactor pressure vessel

In conjunction with a pressurized water reactor (PWR) and a pressurizer configured to control pressure in the reactor pressure vessel, a decay heat removal system comprises a pressurized passive condenser, a turbine-driven pump connected to suction water from at least one water source into the reactor pressure vessel; and steam piping configured to deliver steam from the pressurizer to the turbine to operate the pump and to discharge the delivered steam into the pressurized passive condenser. The pump and turbine may be mounted on a common shaft via which the turbine drives the pump. The at least one water source may include a refueling water storage tank (RWST) and/or the pressurized passive condenser. A pressurizer power operated relief valve may control discharge of a portion of the delivered steam bypassing the turbine into the pressurized passive condenser to control pressure in the pressurizer.

Graham, Thomas G.↗

Method and apparatus for reduction of water re-evaporation in a dedicated dehumidifier/water heater

An apparatus that includes a refrigeration circuit that includes an evaporator, a first condenser and a compressor. The apparatus includes a refrigerant-water heat exchanger that includes a second condenser fluidly coupled to the refrigeration circuit. A control valve is operatively connected to the refrigeration circuit to direct flow of refrigerant through at least one of the first condenser during a dehumidification mode and the second condenser during a water heating mode. A damper is disposed on an upwind side of the evaporator, the damper being operable to reduce airflow across the evaporator during a ventilation mode.

Uselton, Robert B.↗

Control rod drive mechanism with heat pipe cooling

A representative cooling system for a nuclear reactor control rod drive mechanism (CRDM) includes an evaporation section located within or next to the CRDM and a condensation section fluidly coupled to the evaporation section. The cooling system includes a set of heat fins coupled to drive coils in the CRDM and heat pipes that extend through the drive coils and heat fins. A fluid evaporates while in the evaporation section of the heat pipes from heat generated by the CRDM and moves out of the evaporation section into the condensation section in the heat fins. The fluid cools and condensates while in the condensation section, recirculating back into the evaporation section. This passive natural circulation cooling system reduces or eliminates the number of water hoses, piping, and other water pumping equipment typically used for cooling a CRDM thereby increasing nuclear reactor reliability and simplifying nuclear reactor operation and maintenance.

Lobscheid, Christian↗

Experimental study of steam-driven ejector heat pump

Ejector-driven systems have been shown to be promising for heating applications. Most of the research works have been devoted to cooling purposes, while little attention has been focused on heating applications. An experimental steam ejector heat pump system (EHP) was designed and constructed to assess its applicability to water heating applications. The effect of the primary nozzle exit position (NXP) on the performance of the steam ejector system was investigated for primary nozzle throat diameter of 1.5 mm and 2.0 mm. The ejector system was run for high-temperature evaporator (HTE) temperatures of 120, 130, and 140 °C and low-temperature evaporator (LTE) temperatures of 10, 15, and 20 °C. The target of this investigation was to attain the highest condensing temperature to be able to use the proposed system for water heating purposes. The ejector heat pump coefficient of performance (EHP COP) was used to determine the system efficiency. Larger LTE temperatures were found to result in higher EHP COPs and condensing temperatures. A maximum EHP COP of 2.02 was attained for a HTE and LTE temperatures of 120 °C and 20 °C, respectively; however only resulted in a condensing temperature of 22.88 °C. Higher HTE temperatures were found to result in higher condensing temperatures but at the cost of EHP COP.

Spitzenberger, Jeremy↗

Secure hierarchical processing using a secure ledger

Disclosed is a system and method for processing data using blockchain technology. The system includes a memory having programmable instructions stored thereon that, when executed by a processor, cause the system to: authenticate one or more sensors in anticipation of receiving component data; receive component data, upon successful authentication; store the component data locally or to a cloud-based server and/or calculate a root value for the component data; store or embed the root value with the stored component data; condense the component data and link the condensed component data to the stored component data via the root value. The system further includes instructions to log the condensed data, including the root value, to a ledger, and to identify a tag or transaction id corresponding to the logging event for subsequent retrieval of the condensed data using the tag or transaction id.

Zhao, Wenbing↗

Nuclear Power Fault Diagnostics and Preventative Maintenance Optimization

Operation and maintenance costs for nuclear power plants are very large. Reactors are starting to shut down even after their operating licenses have been extended, because they are not price competitive compared to other energy sources. The nuclear industry is witnessing early closure of nuclear power plants due to economic reasons despite excellent safety records. Therefore, it is imperative to reduce costs to prevent these early closures. This paper showcases recent research into advanced fault diagnostics techniques and preventative maintenance optimization to reduce these maintenance costs. This report focuses on the condensate and feedwater system for both pressurized and boiling water reactor systems. The computerized maintenance management system, which contains the plant’s digital record of all the corrective- and preventative-maintenance work orders, was used as a ground truth to locate potential faults and label the process data as healthy or faulty. Various feature extraction techniques were utilized to further differentiate the faults from the healthy data. Support vectors machines were used to categorize other test sets of process data as healthy or faulty through a cross validation procedure. Similar faults were not found within this system leading to preventative maintenance optimization. Unnecessary amounts of preventative maintenance lead to inflated maintenance costs. This paper summarizes the steps for preventative maintenance optimization from component health determination to recommendation for action. This optimization was completed for condensate pumps, condensate booster pumps, and the respective motors that drive them.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Fracton phases via exotic higher-form symmetry-breaking

We study p-string condensation mechanisms for fracton phases from the viewpoint of higher-form symmetry, focusing on the examples of the X-cube model and the rank-two symmetric-tensor scalar charge theory. This work is motivated by questions of the relationship between fracton phases and continuum quantum field theories, and also provides general principles to describe p-string condensation independent of specific lattice model constructions. We give a perspective on higher-form symmetry in lattice models in terms of cellular homology. Applying this perspective to the coupled-layer construction of the X-cube model, we identify a foliated 1-form symmetry that is broken in the X-cube phase, but preserved in the phase of decoupled toric code layers. Similar considerations for the scalar charge theory lead to a framed 1-form symmetry. These symmetries are distinct from standard 1-form symmetries that arise, for instance, in relativistic quantum field theory. Here, we also give a general discussion on interpreting p-string condensation, and related constructions involving gauging of symmetry, in terms of higher-form symmetry.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Heat and mass transfer during a sudden loss of vacuum in a liquid helium cooled tube - Part III: Heat deposition in He II

A sudden loss of vacuum can be catastrophic for superconducting particle accelerators. In such an event, air leaks into the liquid-helium-cooled accelerator beamline tube and condenses on its inner surface, causing rapid boiling of the helium and dangerous pressure build-up. Understanding the coupled heat and mass transfer processes is important for the design of the beamline cryogenic system. Our past experimental study on nitrogen gas propagating in a copper tube cooled by normal liquid helium (He I) has revealed a nearly exponential slowing down of the gas front. A theoretical model that accounts for the interplay of the gas dynamics and the condensation was developed, which successfully reproduced various key observations. However, since many accelerator beamlines are actually cooled by superfluid helium (He II) in which the heat transfer is via a non-classical thermal counterflow mode, we need to extend our work to the He II cooled tube. This paper reports our systematic measurements using He II and the numerical simulations based on a modified model that accounts for the He II heat-transfer characteristics. By tuning the He II peak heat-flux parameter in our model, we have reproduced the observed gas dynamics in all experimental runs. The fine-tuned model is then utilized to reliably evaluate the heat deposition in He II. Finallly, this work not only advances our understanding of condensing gas dynamics but also has practical implications to the design codes for beamline safety.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Water Uptake by Silica Nanopores: Impacts of Surface Hydrophilicity and Pore Size

Water uptake at 298 K by two mesoporous silicas with different pore sizes was studied using volumetric vapor sorption. Here, through variation of sample pretreatment temperature and time, the number of surface hydroxyl groups was varied, leading to marked changes in the water sorption behavior. With increasing surface hydroxyl density, the adsorption of water to the pore surfaces increases, leading to formation of a thicker and denser water sorption layer. The BET model was used to measure surface hydroxyl density from low pressure parts of water adsorption isotherms. Adsorption of water molecules scales with the number density of surface hydroxyl groups, and monolayer coverage is reached at reduced pressure of ca. 0.3. The onset of adsorption pore condensation of water shifts to lower reduced pressure with increasing surface hydroxyl density, indicating growing thickness of adsorption layers. However, the water pore condensation step of the desorption branch shifts to smaller reduced pressure with increasing surface hydroxylation, reducing the adsorption-desorption hysteresis width. An adsorbed phase model is utilized to calculate the distribution of pore water molecules between adsorbed and pore condensation phases, and characterize the density and thickness of the water sorption phase. In the smaller pores, the adsorbed phase forms a sparse monolayer, while approximately a bilayer is formed in the wider pores. The previously reported silica nanopore underfilling by water is confirmed and rationalized by a significantly reduced water density in the adsorbed phase with respect to bulk, while the pore core is filled with water of approximately bulk density.

36 MATERIALS SCIENCE↗

Experiments on the Capillary Condensation/Evaporation Hysteresis of Pure Fluids and Binary Mixtures in Cylindrical Nanopores

Here, a new experimental method, i.e., isochoric cooling/heating cycle measurement using differential scanning calorimeter (DSC), is applied to investigate the hysteretic phenomenon of pure components and mixtures confined in two different types of cylindrical nanopores (SBA-15 and KIT-6). The capillary condensation/evaporation hysteresis end point (T he ) for a specific system is determined by performing a series of measurements with different densities by increasing initial temperature and pressure. We confirm that for a pure component, T he is lower when confined in smaller nanopores, whereas T he for CH 4 /CO 2 and CH 4 /C 2 H 6 mixtures at the specific composition investigated are higher than that of pure CO 2 and C 2 H 6 , respectively, when confined in the same nanopores. To the best of our knowledge, this is the first time that T he of fluid mixture is experimentally studied, which further demonstrates that binary mixtures behave similarly to pure fluids when confined in nanoporous media. At low temperatures where hysteresis is observed, the shape as well as the duration of the exothermic peak (due to capillary condensation) and endothermic peak (due to capillary evaporation) indicate that capillary condensation, rather than capillary evaporation, takes place at/near a thermodynamic equilibrium. Within the accuracy of the measurements, we find that the total heat of capillary condensation is identical to that of capillary evaporation for all systems examined, regardless of the presence of hysteresis. By comparing the heat per unit volume among different systems, we also find that the heat per unit volume of the phase transition of confined pure fluid is lower than that of bulk, which further demonstrates that the molar density of confined pure liquid is less than that of bulk pure liquid at saturation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Phase Transition and Criticality of Methane Confined in Nanopores

For the first time, the phase transition and criticality of methane confined in nanoporous media are measured. The measurement is performed by establishing an experimental setup utilizing a differential scanning calorimeter (DSC) capable of operating under very low temperatures as well as high pressures to detect the capillary phase transition of methane inside nanopores. By performing experiments along isochoric cooling paths, both the capillary condensation and the bulk condensation of methane are detected. Here, the pore critical point (PCP) of nanoconfined methane is also determined and then used to derive the parameters of a previously developed self-consistent equation of state based on the Generalized van der Waals (vdW) partition function. Using this parameter, the equation of state can predict the capillary-condensation curves that agree well with the experimental data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Designer membraneless organelles sequester native factors for control of cell behavior

Subcellular compartmentalization of macromolecules increases flux and prevents inhibitory interactions to control biochemical reactions. Inspired by this functionality, we sought to build designer compartments that function as hubs to regulate the flow of information through cellular control systems. Here we report a synthetic membraneless organelle platform to control endogenous cellular activities through sequestration and insulation of native proteins. We engineer and express a disordered protein scaffold to assemble micron size condensates and recruit endogenous clients via genomic tagging with high-affinity dimerization motifs. By relocalizing up to ninety percent of a targeted enzymes to synthetic condensates, we efficiently control cellular behaviors, including proliferation, division, and cytoskeletal organization. Further, we demonstrate multiple strategies for controlled cargo release from condensates to switch cells between functional states. These synthetic organelles offer a powerful and generalizable approach to modularly control cell decision-making in a variety of model systems with broad applications for cellular engineering.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Revealing reaction intermediates in one-carbon elongation by thiamine diphosphate/CoA-dependent enzyme family

2-Hydroxyacyl-CoA lyase/synthase (HACL/S) is a thiamine diphosphate (ThDP)-dependent versatile enzyme originally discovered in the mammalian α-oxidation pathway. HACL/S natively cleaves 2-hydroxyacyl-CoAs and, in its reverse direction, condenses formyl-CoA with aldehydes or ketones. The one-carbon elongation biochemistry based on HACL/S has enabled the use of molecules derived from greenhouse gases as biomanufacturing feedstocks. We investigated several HACL/S family members with high activity in the condensation of formyl-CoA and aldehydes, and distinct chain-length specificities and kinetic parameters. Our analysis revealed the structures of enzymes in complex with acyl-CoA substrates and products, several covalent intermediates, bound ThDP and ADP, as well as the C-terminal active site region. One of these observed states corresponds to the intermediary α–carbanion with hydroxymethyl-CoA covalently attached to ThDP. This research distinguishes HACL/S from related sub-families and identifies key residues involved in substrate binding and catalysis. These findings expand our knowledge of acyloin-condensation biochemistry and offer attractive prospects for biocatalysis using carbon elongation.

2-hydroxyacyl-CoA lyase↗

BCS-BEC crossover in a (t 2g ) 4 excitonic magnet

The condensation of spin-orbit-induced excitons in t 2 g 4 electronic systems is attracting considerable attention. At large Hubbard U , antiferromagnetism was proposed to emerge from the Bose-Einstein Condensation (BEC) of triplons ( J eff = 1 ). Furthermore, we show that even at intermediate U regimes, the spin-orbit exciton condensation is possible leading also to staggered magnetic order. The canonical electron-hole excitations (excitons) transform into local triplon excitations at large U , and this BEC strong coupling regime is smoothly connected to the intermediate U excitonic insulator region. We solved the degenerate three-orbital Hubbard model with spin-orbit coupling ( λ ) in one dimension using the density matrix renormalization group, while in two dimensions we use the Hartree-Fock approximation (HFA). Employing these techniques, we provide the full λ versus U phase diagrams for both one- and two-dimensional lattices. Our main result is that at intermediate Hubbard U , increasing λ at fixed U the system transitions from an incommensurate spin-density-wave metal to a Bardeen-Cooper-Schrieffer (BCS) excitonic insulator, with coherence length r coh of O ( a ) and O ( 10 a ) in 1 d and 2 d , respectively, with a being the lattice spacing. Further increasing λ , the system eventually crosses over to the BEC limit (with r coh ≪ a ).

1-dimensional systems↗