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At least 1,585 records · Page 88
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

NASA research on refractory compounds.

The behavior and properties of the refractory carbides, nitrides, and borides are being investigated by NASA as part of its research aimed at developing superior heat resistant materials for aerospace applications. Studies of the zirconium-carbon-oxygen system show that zirconium oxycarbides of different compositions and lattice parameters can be formed between 1500 C and 1900 C and are stable below 1500 C. More applied studies show that hot working generally improves the microstructure and therefore the strength of TiC and NbC. Sintering studies on UN indicate that very high densities can be achieved. Hot pressing of cermets of HfN and HfC produces good mechanical properties for high temperature bearing applications. Attempts to improve the impact resistance of boride composites by the addition of a nickel or carbon yarn were not overly successful.

Gangler, J. J.↗
NASA NTRS1972

Deformation of lunar and terrestrial minerals.

The deformation substructures observed by TEM in breccia returned by the Apollo 14 mission are illustrated and their significance is discussed in the context of earlier work on mineral deformation. Shock-produced glass and heavily deformed mineral grains indicate severe shock deformation. Extensive local recovery and sub-microscopic recrystallization are evident and suggest that the coherency of the breccias is caused by a 'shock sintering' mechanism.

Christie, J. M.↗
NASA NTRS1972

Method of simultaneous measurement of radiative and lattice thermal conductivity.

A new technique of high-temperature thermal-conductivity measurement is described. A CO2 gas laser is used to generate a low-frequency temperature wave at one face of a small disk-shaped sample, and an infrared detector views the opposite face to detect the phase of the emerging radiation. A mathematical expression is derived which enables phase data at several frequencies to be used for the simultaneous determination of thermal diffusivity and mean extinction coefficient. Lattice and radiative thermal conductivities are then calculated. Test results for sintered aluminum oxide at temperatures from 530 to 1924 K are within the range of error of previously existing data.

Schatz, J. F.↗
NASA NTRS1971

NASA research on refractory compounds.

The behavior and properties of the refractory carbides, nitrides, and borides are being investigated by NASA as part of its research aimed at developing superior heat resistant materials for aerospace applications. Fundamental studies on the electronic and defect structures of the carbides indicate that there is promise for improving the strength and ductility of these materials. Studies of the zirconium-carbon-oxygen system show that zirconium oxycarbides of different compositions and lattice parameters can be formed between 1500 and 1900 C and are stable below 1500 C. More applied studies show that hot working generally improves the microstructure and therefore the strength of TiC and NbC. Sintering studies on UN indicate that very high densities can be achieved. Hot pressing of cermets of HfN and HfC produces good mechanical properties for high temperature bearing applications.

Gangler, J. J.↗
NASA NTRS1974

Silicon on sapphire for ion implantation studies

Van der Pauw or bridge samples are ultrasonically cut from silicon on sapphire wafers. Contact pad regions are implanted with moderately heavy dose of ions. Ion of interest is implanted into sample; and, before being annealed in vacuum, sample is sealed with sputtered layer of silicon dioxide. Nickel or aluminum is sputtered onto contact pad areas and is sintered in nitrogen atmosphere.

Pisciotta, B. P.↗
NASA NTRS1973

Heat-sterilized silver oxide-zinc cells: Cycle life studies

A JPL study was conducted to evaluate the cell design parameters that contribute to the cycle life of sealed, heat-sterilized silver oxide-zinc cells. Test cells having a rated capacity of 4.2 A-h were fabricated using zinc oxide electrodes prepared by the sintered Teflon process. Two separator variations were evaluated, one having acrylic acid and the other methacrylic acid grafted to irradiated polyethylene film. Significant results of this study include the following: (1) cycle life in excess of 300 cycles was attained; (2) a zinc oxide/silver stoichiometric ratio of 1.5 resulted in greater cycle life than a ratio of 1.1, and similar cycle life to cells having a ratio of 2; (3) cells having methacrylic acid grafted separators suffered somewhat less in capacity loss due to zinc electrode shape change than cells having acrylic acid type; (4) use of acrylic acid grafted separators was slightly superior to the methacrylic acid type in respect to silver penetration; and (5) the inclusion of a layer of potassium titanate paper adjacent to the zinc electrodes resulted in cells that achieved higher cycle life before any of the group failed than that reached by cells of any other construction.

Arms, J. T.↗
NASA NTRS1972

Study, selection, and preparation of solid cationic conductors

Crystal chemical principles and transport theory were used to predict structures and specific compounds which might find application as solid electrolytes in rechargeable high energy and high power density batteries operating at temperatures less than 200 C. More than twenty compounds were synthesized or obtained and screened by nuclear magnetic resonance and conductivity. Many were densified by sintering or hot pressing. Encouraging results were obtained for nine of these materials but none have yet been good ionic conductors at low temperature.

Roth, W. L.↗
NASA NTRS1973

Mariner Mars 1971 sun sensor model development and simulation

The sun sensor flight performance data were analyzed along with the results of a newly developed cruise sensor life in order to better understand cadmium sulfide sun sensor performance. A set of mathematical models was constructed which closely approximated the observed sun sensor flight and laboratory test results. These models revealed, among other things, that (1) the aging phenomena in the sintered cadmium sulfide light detector varies across the detector width in proportion to the illumination history, (2) the current cruise sun sensor design is extremely sensitive to changes in the reflected illumination within the sensor housing, (3) the reflected illumination within the detector housing is proportional to the area and intensity of the solar disk observed at the spacecraft, and (4) the acquisition sun sensor becomes a low impedance path across the sensor bridge when in the vicinity of a large-angular-diameter, low-intensity light source.

Schumacher, L.↗
NASA NTRS1973

Fluorine lubricated bearing technology

An experimental program was conducted to evaluate and select materials for ball bearings intended for use in liquid fluorine and/or FLOX. The ability of three different ball-separator materials, each containing nickel, to form and transfer a nickel fluoride film to provide effective lubrication at the required areas of a ball bearing operating in liquid fluorine was evaluated. In addition, solid lubrication of a ball bearing operating in liquid fluorine by either a fused fluoride coating applied to all surfaces of the ball separator or by a fluoride impregnation of porous sintered material ball separators was evaluated. Less bearing wear occurred when tests were conducted in the less reactive FLOX. Bearings fabricated from any of the materials tested would have relatively short wear lives and would require frequent replacement in a reusable engine.

Mallaire, F. R.↗
NASA NTRS1973

Development and Characterization of CPI Surface Insulation

A new type of reusable surface material that could find application as a component of the thermal protection system of the space shuttle orbiter is discussed. These materials consist of 20-30% dense closed cell high emittance glass ceramic foams formulated by sintering an intimate mixture of fly ash cenospheres with 4-12 wt % cobalt oxide. These unique ceramic foams exhibit: (1) High mechanical strengths; (2) no need for waterproof coating due to the non-interconnecting cell network; (3) high emissivities; (4) ability to withstand space shuttle thermal environments with no loss of reuse capability; and (5) a machinable ceramic with capability of maintaining the close tolerances required of an integrated heat shield system.

Tobin, A.↗
NASA NTRS1972

Sedimentology of clastic rocks returned from the moon by Apollo 15.

A petrographic study of eleven samples of clastic rock returned from the moon by Apollo 15 suggests that two lithologies are present. The distinction between the two lithologies is based on the glass content of the rock matrices and the morphology of the detrital particles. Group I rocks have abundant, glass-rich, porous matrices and glass particles with morphologies comparable to those of glass particles in the lunar soil. The group I rocks were probably formed by welding or sintering of surficial soil deposits by impact-generated base surges of limited extent. Group II rocks have an essentially mineralic matrix and have an abundance of rounded mineral grains. Sample 15455 is the only Apollo 15 sample assigned to this group. In its general textural features, sample 15455 is comparable with the group II rocks from the Fra Mauro Formation at the Apollo 14 site. Textural features such as shock modification and rounding of mineral grains suggest that this sample is the product of a large-scale impact-generated base surge which possibly resulted from the Imbrian event.

Lindsay, J. F.↗
NASA NTRS1972

Electron petrography of Apollo 14 and 15 rocks.

Comparative optical and high-voltage electron petrographic analyses of igneous rocks and several types of breccias the Fra Mauro and Apennine sites of Apollo 14 and 15 are reported and interpreted. The crystalline rocks are found to differ substantially from the Apollo 11 and 12 basalts. Substructures in the Apollo 14 breccias are complex. At least two bonding mechanisms can be discerned from the electron petrographic examination: (a) 'shock sintering' due to high pressures and temperatures associated with the shock waves of meteoritic impacts; and (b) lithification by glass bonding.

Lally, J. S.↗
NASA NTRS1972

Studies of the performance of W-Re type thermocouples.

The effect of exposure of bare-wire and BeO-insulated commercial W-Re thermocouple materials to high temperatures in gaseous environments was investigated. The temperature range of interest was primarily 2000 to 2400 K, and the investigations were confined to thermocouple wires of 0.25 mm diameter. Thermoelements were examined for metallurgical structural changes and chemical changes by conventional methods. In the temperature range of interest, grain growth was inhibited in the chemically doped W-3% Re alloy, and excellent room-temperature ductility was retained subsequent to the exposure. The compatibility of high purity (in excess of 99.8%), sintered BeO insulators with the thermoelements differed, depending upon whether the BeO-insulated thermoelement assemblies were self-heated electrically or heated in a furnace; in tests in argon environments, highly reliable performance occurred when the assemblies were heated in a furnace. BeO-insulated W-3% Re vs W-25% Re thermocouples, constructed with degassed and aged materials, exhibited drifts equivalent to about 3 mK/hr during 1000 hours of exposure at 2073 K in argon while in the presence of tantalum.

Burns, G. W.↗
NASA NTRS1973

High gas velocity burner tests on silicon carbide and silicon nitride at 1200 C

Specimens of silicon carbide and silicon nitride were exposed to a Mach one gas velocity burner simulating a turbine engine environment. Cyclic tests up to 100 hour duration were conducted at specimen temperatures of 1200 C. A specimen geometry was used that develops thermal stresses during thermal cycling in a manner similar to blades and vanes of a gas turbine engine. Materials were compared on a basis of weight change, dimensional reductions, metallography, fluorescent penetrant inspection, X-ray diffraction analyses, failure mode, and general appearance. One hot pressed SiC, one reaction sintered SiC, and three hot pressed Si3N4 specimens survived the program goal of 100 one-hour cycle exposures. Of the materials that failed to meet the program goal, thermal fatigue was identified as the exclusive failure mode.

Sanders, W. A.↗
NASA NTRS1974

Fused silicon-rich coatings for superalloys

Various compositions of nickel-silicon and aluminum-silicon slurries were sprayed on IN 100 specimens and fusion-sintered to form fully dense coatings. Cyclic furnace oxidation tests in 1 atm air at 1100 C showed all the coatings to be protective for at least 600 hours, and one slurry, Al-60Si, was protective for 1000 hours. This coating also protected NASA TAZ 8A and NASA-TRW VIA for 1000 hours in the same furnace test. Alloys B 1900, TD-NiCr, and Mar-M200 were protected for lesser times, while NX 188 and NASA WAZ 20 were scarcely protected at all. Limited stress-rupture testing on 0.64-cm-diam IN 100 specimens detected no degradation of mechanical properties due to silicon diffusion.

Smialek, J. L.↗
NASA NTRS1974

Petrology

Boulder 1 as a whole can be considered a complex polymict breccia consisting of lithic and breccia clasts seated in a matrix that ranges from friable and poorly sintered to densely welded. Only two of the four samples collected from boulder 1, Station 2 have been examined in detail: 72255 and 72275. Of the remaining two, only two undocumented thin sections from 72235 have been studied, while none from 72215 has been examined. Sample 72275 was collected as representative of the boulder matrix, whereas the other three samples were thought to be large clasts.

Stoeser, D. B.↗
NASA NTRS1974

Tribological properties of self-lubricating fluoride-metal composites to 900 C (1650 F): A review and some new developments

The friction and wear behavior of some fluoride-metal, self-lubricating composites are summarized. Fluoride-infiltrated sintered nickel alloy composites and plasma-sprayed, co-deposited fluoride-nickel alloy composites are described. The importance of proper surface-conditioning of the composites is stressed. Performance of fluoride-metal composites in some machine application evaluation is discussed.

Sliney, H. E.↗
NASA NTRS1973

Grain boundary mobility in anion doped MgO

Certain anions OH(-), F(-) and Gl(-) are shown to enhance grain growth in MgO. The magnitude of their effect decreases in the order in which the anions are listed and depends on their location (solid-solution, second phase) in the MgO lattice. As most anions exhibit relatively high vapor pressures at sintering temperatures, they retard densification and invariably promote residual porosity. The role of anions on grain growth rates was studied in relation to their effect on pore mobility and pore removal; the atomic process controlling the actual rates was determined from observed kinetics in conjunction with the microstructural features. With respect to controlling mechanisms, the effects of all anions are not the same. OH(-) and F(-) control behavior through creation of a defect structure and a grain boundary liquid phase while Cl(-) promotes matter transport within pores by evaporation-condensation. Studies on an additional anion, S to the minus 2nd power gave results which were no different from undoped MgO, possibly because of evaporative losses during hot pressing. Hence, the effect of sulphur is negligible or undetermined.

Kapadia, C. M.↗