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At least 1,585 records · Page 88

Tensile, Creep, and Fatigue Behaviors of 3D-Printed Acrylonitrile Butadiene Styrene

Acrylonitrile butadiene styrene (ABS) is a widely used thermoplastics in 3D printing. However, there is a lack of thorough investigation of the mechanical properties of 3D-printed ABS components, including orientation-dependent tensile strength and creep fatigue properties. In this work, a systematic characterization is conducted on the mechanical properties of 3D-printed ABS components. Specifically, the effect of printing orientation on the tensile and creep properties is investigated. The results show that, in tensile tests, the 0° printing orientation has the highest Young’s modulus of 1.81 GPa, and ultimate strength of 224 MPa. In the creep test, the 90° printing orientation has the lowest k value of 0.2 in the plastics creep model, suggesting 90° is the most creep resistant direction. In the fatigue test, the average cycle number under load of 30 N is 3796 cycles. The average cycle number decreases to 128 cycles when the load is 60 N. Using the Paris law, with an estimated crack size of 0.75 mm, and stress intensity factor is varied from 352 to 700 N√m, the derived fatigue crack growth rate is 0.0341 mm/cycle. This study provides important mechanical property data that is useful for applying 3D-printed ABS in engineering applications.

36 MATERIALS SCIENCE↗

Nonisothermal elasto-visco-plastic response of shell-type structures

A mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads is disussed. Among the system responses, which are associated with these load conditions, are thermal buckling and creep buckling. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and have been considered in the development of the mathematical model. Furthermore, this was accommodated in the solution procedures. A complete true ab-inito rate theory of kinematics and kinetics for continuum and curved thin structures, without any restriction on the magnitude of the strains or the deformation, was formulated. The time dependence and large strain behavior are incorporated through the introduction of the time rates of the metric and curvature in two coordinate systems, a fixed (spatial) one and a convected (material) coordinate system. The relations between the time derivative and the covariant derivatives (gradients) have been developed for curved space and motion, so that the velocity components supply the connection between the equations of motion and the time rate of change of the metric and curvature tensors.

Simitses, G. J.↗

Influence of severe plastic deformation on intermetallic particles in Mg-12 wt.%Zn alloy investigated using transmission electron microscopy

The in-depth microstructural characterization of intermetallic particles in an Mg-12 wt.%Zn binary alloy subjected to a severe plastic deformation is presented. The alloy was processed by four passes via equal channel angular pressing with an applied back pressure at a gradually decreasing temperature and analyzed using transmission electron microscopy techniques to observe the influence of processing on intermetallic particles. The results are compared with the initial state of the material prior to severe plastic deformation. The microstructural evolution of the α-Mg matrix and the Mg{sub 21}Zn{sub 25}, Mg{sub 51}Zn{sub 20} and MgZn{sub 2} was analyzed using bright field imaging, selected area electron diffraction, high-resolution transmission electron microscopy and high-angle annular dark field imaging in scanning mode. The plastic deformation process influenced the α-Mg matrix and each type of intermetallic particle. The α-Mg matrix consisted of two types of areas. The first type of area had a highly deformed structure, and the second type of area had a partially recrystallized structure with an average grain size of approximately 250 nm. The Mg{sub 21}Zn{sub 25} microparticles exhibited distinct forms in the α-Mg matrix that were characterized as a single-crystalline form, a nano-crystalline form and a broken up form. No evidence of Mg{sub 51}Zn{sub 20} nanoparticles within the α-Mg matrix was found in the microstructure, which indicates their dissolution or phase transformation during the deformation process. MgZn{sub 2} nanoparticles exhibited different behavior in both types of α-Mg matrix. Two orientation relationships toward the highly deformed α-Mg matrix were observed; however, there was no relationship toward the partially recrystallized α-Mg matrix. Additionally, the growth of the MgZn{sub 2} nanoparticles was different in the two types of α-Mg matrix. The Mg{sub 51}Zn{sub 20} nanoparticles inside Mg{sub 21}Zn{sub 25} microparticles exhibited a distinct behavior within the single-crystalline or nano-crystalline form of the parent Mg{sub 21}Zn{sub 25} microparticles. The Mg{sub 21}Zn{sub 25} + Mg{sub 51}Zn{sub 20} eutectic compound was confirmed for both forms of the parent Mg{sub 21}Zn{sub 25} microparticles, and the growth of Mg{sub 51}Zn{sub 20} nanoparticles is discussed. - Highlights: •Comprehensive microstructure characterization of Mg-12 wt.%Zn alloy after ECAP-BP •TEM analysis of changes of intermetallic phases caused by SPD •Mg{sub 21}Zn{sub 25} particles exhibit nano-crystalline regions with grain size below 100 nm. •MgZn{sub 2} preserved its orientation relationship toward highly deformed α-Mg after SPD. •Existence of Mg{sub 21}Zn{sub 25} + Mg{sub 51}Zn{sub 20} eutectic remained for each Mg{sub 21}Zn{sub 25} particle form.

36 MATERIALS SCIENCE↗

Understanding Variability in Mechanical Behavior of Adhesively Bonded Sandwich Joints due to Stochastic Material Damage

A mesoscale progressive damage analysis was applied to the analysis of recently tested adhesively bonded sandwich panels, in which ten nominally identical tension loaded panels failed in three different failure modes, with peakloads ranging from 13.0 –16.1 kips. A parametric finite element model for progressive damage analysis of an adhesively bonded joint (ABJ) considering matrix and fiber damage, and delamination cracks in unidirectional and fabric composite sections of the joint, as well as core crushing, and adhesive fracture was developed. The model was developed using Abaqus/Explicit and utilized continuum damage mechanics material models for intralaminar damage in the facesheet and doubler plies, cohesive elements for delamination and adhesive debonding, and discretized cells considering plasticity to model crushing of the aluminum honeycomb core. Analysis predictions obtained with a pristine model agreed well with the average experimental peak load, strain in the joint, and post-test damage states. Then, various methods to incorporate stochastic material variability into ABJ model were evaluated. These methods included simulation of pre-existing matrix damage, pre-existing adhesive porosity, and uniform modification of adhesive properties. These material and manufacturing defects changed the damage mode predictions in some cases. The analysis of stochastic strength due to the considered defects revealed unintuitive damage mode interaction in the ABJ, explaining some structure-property relationships observed experimentally.

Richard Larson↗

Effect of polycarboxylate ether on the expansion of ye'elimite hydration in the presence of anhydrite

Polycarboxylate ether (PCE), a commonly used superplasticizer, is known to influence the morphology of ettringite during the early hydration of C{sub 3}A- and ye'elimite-containing cements. According to existing theories, such morphological changes may be crucial to the expansive behavior of these cements. This paper studied the expansion of ye'elimite-anhydrite pastes and found the use of PCE to reduce expansion after 4 days of curing. Hydration studies were conducted by calorimetry, X-ray diffractometry, scanning electron microscopy, mercury intrusion porosimetry, inductively coupled plasma–optical emission spectrometry, and X-ray microtomography. The results show that the influences of PCE on the morphology of ettringite and the hydration of ye'elimite were quite small after 2 days. Based on the crystal growth theory, the range of pores in which ettringite can grow was calculated to explain the observed expansive behaviors. The presence of ettringite nano-crystals in aluminum hydroxide was also revealed and considered as a possible expansion mechanism.

36 MATERIALS SCIENCE↗

Unified Creep Plasticity Damage (UCPD) Model for Rigid Polyurethane Foams

Numerous experiments were performed to characterize the mechanical response of several different rigid polyurethane foams (FR3712, PMDI10, PMDI20, and TufFoam35) to large deformation. In these experiments, the effects of load path, loading rate, and temperature were investigated. Results from these experiments indicated that rigid polyurethane foams exhibit significant volumetric and deviatoric plasticity when they are compressed. Rigid polyurethane foams were also found to be very strain-rate and temperature dependent. These foams are also rather brittle and crack when loaded to small strains in tension or to larger strains in compression. Thus, a new Unified Creep Plasticity Damage (UCPD) model was developed and implemented into SIERRA with the name Foam Damage to describe the mechanical response of these foams to large deformation at a variety of temperatures and strain rates. This report includes a description of recent experiments and experimental findings. Next, development of a UCPD model for rigid, polyurethane foams is described. Selection of material parameters for a variety of rigid polyurethane foams is then discussed and finite element simulations with the new UCPD model are compared with experimental results to show behavior that can be captured with this model.

36 MATERIALS SCIENCE↗

A Platform-Independent X-ray Diffraction Diagnostic for Phase Transition Kinetics in Traditional and Synthetic Microstructure Materials (LDRD Project 213088 Final Report)

Pulsed-power generators using the magnetic loading technique are able to produce well-controlled continuous ramp compression of condensed matter for high-pressure equation-of-state studies. X-ray diffraction (XRD) data from dynamically compressed samples provide direct measurements of the elastic compression of the crystal lattice, onset of plastic flow, strength-strain rate dependence, structural phase transitions, and density of crystal defects such as dislocations. Here, we present a cost effective, compact X-ray source for XRD measurements on pulsed-power-driven ramp-loaded samples. This combination of magnetically-driven ramp compression of materials with single, short-pulse XRD diagnostic will be a powerful capability for the dynamic materials community. The success in fielding this new XRD diagnostic dramatically improves our predictive capability and understanding of rate-dependent behavior at or near phase transition. As Sandia plans the next-generation pulse-power driver platform, a key element needed to deliver new state-of-the-art experiments will be having the necessary diagnostic tools to probe new regimes and phenomena. These diagnostics need to be as versatile, compact, and portable as they are powerful. The development of a platform-independent XRD diagnostic gives Sandia researchers a new window to study the microstructure and phase dynamics of materials under load. This project has paved the way for phase transition research in a variety of materials with mission interest.

36 MATERIALS SCIENCE↗

Corrosion of Metal Alloys in Potassium Acetate Solutions for Liquid Desiccant Dehumidification and Air Conditioning

For commercial buildings, liquid desiccant air conditioners (LDACs) could provide up to 80% energy savings compared to high-efficiency vapor compression AC, but commonly utilized liquid desiccants are highly corrosive. This precludes the use of metallic components, necessitating specialized plastics and thereby driving up cost, weight, and limiting operational temperature and pressure ranges. Less corrosive alternatives are sought. Here, potassium acetate solutions are investigated as less-corrosive alternatives to the chloride salt solutions that are typically used in LDAC systems. Corrosion evaluations for a Cu alloy (C12200) and two Al alloys (Al3003 and Al1100) in both potassium acetate and chloride salt solutions are presented. We show that yearly corrosion rates are lower in potassium acetate solutions by up to three orders of magnitude. Active corrosion behavior is largely absent in potassium acetate solutions but is present in chloride salt solutions. Furthermore, solid corrosion products are observed in chloride salt solutions. Thus, we conclude that potassium acetate is a promising candidate as a less corrosive alternative liquid desiccant for LDAC systems with metallic components.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Kinetics of HCP-BCC Phase Transition Boundary in Magnesium at High Pressure

Under high pressures, many crystalline metals undergo solid–solid phase transformations. In order to accurately model the behavior of materials under extreme loading conditions, it is essential to understand the kinetics of phase transition. Using molecular dynamics simulations, this work demonstrates the feasibility of characterizing the speeds of a moving phase boundary using atomistic simulations employing a suitable empirical potential for single-crystal magnesium. The model can provide temperature- and tensorial stress-dependent velocity of a moving phase boundary as a rate-limiting contribution to the kinetics of phase transformation in continuum codes. Results demonstrate that a nonlinear interaction exists between plasticity and phase transition, facilitating a jump in the velocity of a moving phase boundary, facilitated by activated plastic deformation mechanisms.

36 MATERIALS SCIENCE↗

Fracture mechanics; Proceedings of the Seventeenth National Symposium, Albany, NY, August 7-9, 1984

The present conference gives attention to topics in the application of fracture mechanics, subcritical crack growth phenomena, fracture testing methods, ductile fracture behavior, and fracture mechanisms and their analysis. Specific papers treat the resistance curve approach to composite materials characterization, fracture toughness in ductile iron and cast steel, hold-time effects in elevated temperature fatigue crack propagation, creep crack growth under nonsteady conditions, viscoplastic fatigue in a superalloy at elevated temperatures, fracture testing with arc bend specimens, one-point bend impact test application, and a compact mode II fracture specimen. Also discussed are the computation of stable crack growth using the J-integral, the use of plastic energy dissipation to characterize crack growth, the extension of surface cracks under cyclic loading, the minimum time criterion for crack instability in structural materials, dynamic crack propagation and branching under biaxial loading, and boundary layer effects in cracked bodies.

Underwood, J. M.↗

Strain rate effects on the mechanical behavior of porous titanium with different pore sizes

High strain-rate (up to 6600 s –1 ) and quasi-static compression tests are conducted on a powder-sintered porous titanium with different pore sizes (mean: 30 μm and 120 μm). In situ X-ray imaging is implemented to characterize the pores-scale deformation dynamics. The yield strength as a function of strain rate exhibits two stages of rate sensitivity, and the transition occurs at 1600 s –1 . X-ray images show that pore compaction and strain localizations occur preferentially at pores oriented perpendicular to the loading direction under quasi-static loading, but become more random under high strain-rate loading as a result of higher driving force and plastic deformation nucleation rate. Here, the more homogeneous nucleation of plastic deformation contributes to the increased rate sensitivity beyond 1600 s –1 . At the same strain rate, the yield strength of porous Ti as well as strain field homogeneity decreases significantly with increasing pore size. The small pore spacing in fine-pored Ti reduces the degree of stress concentrations around pores. Therefore, the higher stress concentrations in coarse-pored Ti lead to an earlier yield of matrix around pores and thus a lower bulk yield strength.

36 MATERIALS SCIENCE↗

Linking microstructural evolution and macro-scale friction behavior in metals [Predicting the friction behavior of metals using a microstructural evolution model]

A correlation is established between the macro-scale friction regimes of metals and a transition between two dominant atomistic mechanisms of deformation. Metals tend to exhibit bi-stable friction behavior—low and converging or high and diverging. These general trends in behavior are shown to be largely explained using a simplified model based on grain size evolution, as a function of contact stress and temperature, and are demonstrated for self-mated pure copper and gold sliding contacts. Specifically, the low-friction regime (where µ < 0.5) is linked to the formation of ultra-nanocrystalline surface films (10–20 nm), driving toward shear accommodation by grain boundary sliding. Above a critical combination of stress and temperature—demonstrated to be a material property—shear accommodation transitions to dislocation dominated plasticity and high friction, with µ > 0.5. We utilize a combination of experimental and computational methods to develop and validate the proposed structure–property relationship. As a result, this quantitative framework provides a shift from phenomenological to mechanistic and predictive fundamental understanding of friction for crystalline materials, including engineering alloys.

36 MATERIALS SCIENCE↗

An atomistic survey of shear coupling in asymmetric tilt grain boundaries and interpretation using the disconnections framework

Grain Boundaries (GB) play an important role in determining the behavior of polycrystalline materials. While the mechanisms of motion and associated shear response for symmetric tilt grain boundaries (STGBs) are well studied, the same is not true for asymmetric tilt grain boundaries (ATGBs) despite their greater prevalence in polycrystals. Here, this study aims to investigate the shear response of a large collection of asymmetric tilt grain boundaries (ATGBs) using molecular dynamics (MD) simulations and interpret the data using a discrete disconnections model that works remarkably well for STGBs. MD simulations of shear-driven ATGBs show that the plastic shear (shear coupling factor) in the region swept by a GB exhibits a complex dependence on the inclination angle, and this dependence changes with the misorientation of the GB. In addition, the shear response was observed to be highly sensitive to the applied shear rate and temperature. Recognizing the spatial and temporal scale limitations of MD simulations, we extended the discrete disconnections mesoscale model of Khateret al. (2012) to calculate the nucleation barriers of disconnection modes and predict the effective shear coupling of an ATGB. We observed that the mesoscale model’s predictions of the shear coupling factor of ATGBs do not agree with those observed in MD simulations. Finally, we examine the hypotheses of our mesoscale model that contribute to disagreements between MD simulations and the mesoscale model and propose improvements to the mesoscale model for future work.

36 MATERIALS SCIENCE↗

Safety evaluation of dermal exposure to phthalates: Metabolism-dependent percutaneous absorption

Phthalates, known as reproductive toxicants and endocrine disruptors, are widely used as plasticizers in polyvinyl chloride products. The present study was conducted for risk identification of dermal exposure to phthalates. When dibutyl phthalate was applied to the skin of hairless rats and humans, only monobutyl phthalate appeared through the skin, and the permeability of the skin was higher than that after the application of the monoester directly. The inhibition of skin esterases made the skin impermeable to the metabolite following dermal exposure to dibutyl ester, whereas removal of the stratum corneum from the skin did not change the skin permeation behavior. Similar phenomena were observed for benzyl butyl phthalate. The skin permeability of monobenzyl phthalate was higher than that of monobutyl phthalate in humans, although the reverse was observed in rats. Species difference in skin permeation profile corresponded to the esterase activity of the skin homogenate. Di(2-ethylhexyl) phthalate, which was not metabolized by esterases in the skin, was not transported across the skin. These results suggest that highly lipophilic phthalates may be transported easily across the stratum corneum lipids. The water-rich viable layer may become permeable to these phthalates by their metabolism into monoesters, which are relatively hydrophilic. Skin metabolism is essential to the percutaneous absorption of phthalates. Because esterase activity has large inter-individual differences, further study will be needed for individual risk identification of dermal exposure to phthalates. - Highlights: • Monophthalate, permeated through the skin after diphthalate application. • Characteristics of human skin cannot be determined from those of rat skin. • An accurate estimation of esterase activity in the skin requires a risk assessment.

60 APPLIED LIFE SCIENCES↗

SU-E-T-526: On the Linearity, Stability and Beam Energy Dependence of CdSe Quantum Dots as Scintillating Probes

Purpose: Structure and energy transfer mechanisms confer colloidal quantum dots (cQDs) interesting properties, among them their potential as scintillators. CdSe multi-shell cQDs in powder were investigated under photons irradiation. The purpose of this work is to characterize signal to dose linearity, stability with time and to quantify the dependence of their light output with beam energy. Methods: The cQDs are placed at the extremity of a non-scintillating plastic collecting fiber, with the other extremity connected to an Apogee U2000C CCD camera. The CCD camera collects the fluorescence light from irradiated cQDs from which the delivered dose is extracted. This signal is corrected for Cerenkov contamination at MV energies using the chromatic technique. The detector was irradiated with two devices: Xstrahl 200 orthovoltage unit for 120, 180 and 220 kVp and a Varian Clinac iX for 6 and 23 MV. Results: Linear output response with varying dose is observed for all beam energies with R2 factors > 0,999. Reproducibility measurements were performed at 120 kVp: the same set-up was irradiated at different time intervals (one week and three months). The results showed only a small relative decrease of light output of 3,2 % after a combine deposited dose of approximately 95 Gy. CdSe nanocrystals response has been studied as a function of beam energy. The output increases with decreasing energy from 120 kVp to 6 MV and increase again for 23 MV. This behavior could be explained in part by the cQDs high-Z composition. Conclusion: The fluorescence light output of CdSe cQDs was found to be linear as a function of dose. The results suggest stability of the scintillation output of cQDs over time. The specific composition of cQDs is the main cause of the observed energy dependence. We will further look into particle beam dependence of the cQDs. Bourse d'excellence aux etudes graduees du CRC (Centre de Recherche sur le Cancer, Universite Laval) Bourse d'excellence aux etudes graduees du CRC (Centre de Recherche sur le Cancer, Universite Laval)

60 APPLIED LIFE SCIENCES↗

Effect of different stages of deformation on the microstructure evolution of Ti-rich NiTi shape memory alloy

The main objective of this work was to investigate the thermomechanical behavior and microstructural changes of a Ti-rich NiTi shape memory alloy (SMA). The microstructural and texture evolution of aged NiTi alloy at different degrees of deformation were elicited by transmission electron microscopy (TEM). An effort was made to correlate results obtained from the tensile test with results from microstructure studies. The undeformed sample reveals a self-accommodated morphology with straight and well defined twin boundaries. At different stages of deformation, diverse mechanisms were involved. These mechanisms include marstraining, detwinning accompanied by dislocation movement, and finally, severe plastic deformation, subdivision and amorphization of the matrix. Under increasing strains, high density lattice defects were generated and the morphology of B19’ became disordered. - Graphical abstract: The summary of microstructure changes of the martensite twins during tensile deformation in polycrystalline NiTi SMAs. - Highlights: • Initial elastic response, dislocation avalanche and deformation bands were studied. • < 011 > Type II twin accompanied by detwinned area after 2% cold work was observed. • Visible parallel fine stacking faults showed plastic flow of the material. • At higher strains, subgrains changed to recrystallized, finely amorphous structure.

36 MATERIALS SCIENCE↗

Jet Engine Fan Blade Containment Using an Alternate Geometry

With a goal of reducing jet engine weight, simulations of a fan blade containment system with an alternate geometry were tested and analyzed. A projectile simulating a fan blade was shot at two alternate geometry containment case configurations using a gas gun. The first configuration was a flat plate representing a standard case configuration. The second configuration was a flat plate with a radially convex curve section at the impact point. The curved surface was designed to force the blade to deform plastically, dissipating energy before the full impact of the blade is received by the plate. The curved case was able to tolerate a higher impact velocity before failure. The computational model was developed and correlated with the tests and a weight savings assessment was performed. For the particular test configuration used in this study the ballistic impact velocity of the curved plate was approximately 60 m/s (200 ft/s) greater than that of the flat plate. For the computational model to successfully duplicate the test, the very high strain rate behavior of the materials had to be incorporated.

Carney, K.S.↗

The Effects of Sc Addition on the Microstructure and Mechanical Properties of Be-Al Alloy Fabricated by Induction Melting

This study investigated the alloying effects of 0.4 wt.% Sc on the microstructure, mechanical properties, and fracture behavior of a cast Be-Al alloy prepared by vacuum induction melting. The micromechanics of Sc-containing secondary-phase particles (SPs) were characterized by nanoindentation, and the fracture behavior of the alloy was investigated via tensile fractography and optical metallography. The addition of 0.4 wt.% Sc significantly modified the alloy microstructure by decreasing the secondary dendritic arm spacing (SDAS), weakening the dendritic structure of Be, and producing an equiaxed/cellular alloy microstructure with refined Be grains. Sc alloying increased the Vickers hardness by 36%, elastic modulus by 28%, yield strength by 35%, ultimate strength by 52%, but decreased the elongation from 3.6 to 2.9%. Sc-containing SPs had a higher elastic modulus, yield strength, microhardness, and a lower plasticity index than the Be and Al matrices, resulting in interface separation during the fracture process. SPs located at the Be/Al interfaces did not act as microcrack sources for the matrices, whereas highly faceted SPs within the Be grains induced microcrack formation and decreased the elongation. The failure mode of the cast Be-Al-0.4Sc alloy still involved the brittle cleavage failure of Be regions and ductile dimple failure of Al regions, which was not the case with the cast Be-Al alloy.

36 MATERIALS SCIENCE↗