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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,585 records · Page 88
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Fuzzy jets

Collimated streams of particles produced in high energy physics experiments are organized using clustering algorithms to form jets . To construct jets, the experimental collaborations based at the Large Hadron Collider (LHC) primarily use agglomerative hierarchical clustering schemes known as sequential recombination. We propose a new class of algorithms for clustering jets that use infrared and collinear safe mixture models. These new algorithms, known as fuzzy jets , are clustered using maximum likelihood techniques and can dynamically determine various properties of jets like their size. We show that the fuzzy jet size adds additional information to conventional jet tagging variables in boosted topologies. Furthermore, we study the impact of pileup and show that with some slight modifications to the algorithm, fuzzy jets can be stable up to high pileup interaction multiplicities.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

Experimental and Theoretical Research into Dynamic Loading of Tungsten Porous Alloy with Reinforcing Agent

The paper studies the behavior of ceramic porous tungsten alloy with reinforcing agents under the shock-wave loading conditions. Penetrating capacity of tungsten kinetic energy projectiles is calculated and experimentally investigated during their high-speed impacts on steel plates. It is shown that the increased penetration depth of tungsten projectiles exceeds that of the prototype with relevant weight and size, made of tungsten-nickel-iron cast alloy. A mathematical model is developed together with the design technique of the behavior of tungstennickel-iron-cobalt metal foams alloyed with boron carbide, tungsten titanium carbide and tungsten carbide during the high-speed impact interaction. The composite ceramic material is described here as a porous medium. The matrix of this medium is a homogeneous two-phase mixture of the tungsten-nickel-iron-cobalt system and reinforcing agents added in the required proportions.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Separation of sugars and phenolics from the heavy fraction of bio-oil using polymeric resin adsorbents

This work describes the equilibrium and kinetic adsorption of levoglucosan and a mixture of phenolic species from an aqueous solution on two polymeric resin adsorbents, SP207 and XAD4. The separation of sugars from phenolic species is of interest as these species comprise a product stream from a unique fractionating bio-oil recovery system. Levoglucosan is the major sugar present in this product stream, with mannose, xylose, galactose, and cellobiosan present in minor extents. The phenolic species are a complex mixture of mono- and di-substituted phenols; however, we treat them as a single group of similar chemical species that must be removed before the aqueous sugar solution can be used as fermentation substrate. Adsorption isotherms and mass transfer coefficients were determined at 22 °C. Levoglucosan isotherms were fit with linear and Langmuir models. Phenolic species isotherms were fit with both Langmuir and Freundlich models although they more clearly exhibited Langmuir adsorption behavior. Adsorption equilibria show that both polymeric resins have an order of magnitude greater mass adsorption capacity for phenolic species compared to levoglucosan when the mixture is used as the applied solution. However, the kinetics of adsorption are approximately an order of magnitude slower for phenolic species versus levoglucosan. Here, the equilibrium-dispersive model for column chromatography was applied using the determined adsorption equilibria and kinetic parameters and compared to column elution experiments. The model provided a good fit to the column data; however, the fit was improved by replacing the single component isotherms with competitive Langmuir isotherm expressions and modestly lowering the phenolics mass transfer coefficient.

09 BIOMASS FUELS↗
DOE OSTI2022

The effect of oxygen concentration on the speciation of laser ablated uranium

Abstract In order to model the fate and transport of particles following a nuclear explosion, there must first be an understanding of individual physical and chemical processes that affect particle formation. One interaction pertinent to fireball chemistry and resultant debris formation is that between uranium and oxygen. In this study, we use laser ablation of uranium metal in different concentrations of oxygen gas, either 16 O 2 or 18 O 2 , to determine the influence of oxygen on rapidly cooling uranium. Analysis of recovered particulates using infrared absorption and Raman spectroscopies indicate that the micrometer-sized particulates are predominantly amorphous UO x (am-UO x , where 3 ≤ x ≤ 4) and UO 2 after ablation in 1 atm of pure O 2 and a 1% O 2 /Ar mixture, respectively. Energy dispersive X-ray spectroscopy (EDS) of particulates formed in pure O 2 suggest an O/U ratio of ~ 3.7, consistent with the vibrational spectroscopy analysis. Both am-UO x and UO 2 particulates convert to α-U 3 O 8 when heated. Lastly, experiments performed in 18 O 2 environments show the formation of 18 O-substituted uranium oxides; vibrational frequencies for am-U 18 O x are reported for the first time. When compared to literature, this work shows that cooling timescales can affect the structural composition of uranium oxides (i.e., crystalline vs. amorphous). This indicator can be used in current models of nuclear explosions to improve our predicative capabilities of chemical speciation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Experimental study of the influence of gas puff locations on H-mode boundary plasmas with argon seeding on EAST

To investigate the optimal scenario of impurity seeding to obtain divertor plasma detachment for target protection, experiments with Ar&D 2 seeding from two different poloidal locations, the upper outer (UO) divertor target and lower outer (LO) target, were carried out on EAST. Partial energy detachment (the electron temperature near the strike point T e,spt ≤ 10 eV) were obtained with Ar&D 2 mixture puffing from the UO target and, for the first time, from the LO target into H-mode plasmas in the upper single null (USN) configuration. The peak heat flux q t on the UO target was significantly reduced (by ~80%). The rollover of ion flux density j s did not appear probably due to insufficient momentum loss, which is independent of the puff locations. The poloidal asymmetries of particle and heat fluxes on the targets have also been investigated. The UO-dominant asymmetry of particle flux was reversed, while the UO-dominant asymmetry of heat flux was mitigated but not reversed. The plasma confinement dropped by only 14% and 8.2% in the LO-puff case and UO-puff case, respectively, during detachment. The high level of C may contributed greatly to the higher radiation in the bulk plasma region and the greater decline in W MHD in the LO-puff case.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Visual Style Elements in Human–System Interface Design for Nuclear Power Operations: Does Style Affect Performance and Preference?

As the world increasingly adopts renewable and sustainable energy systems, transitionary solutions include nuclear power, which currently provides 20% of the United States’ electricity and is the largest single source of carbon-free electricity generation. Advanced reactors are a critical component of a carbon-free mixed energy portfolio that require careful design of first-of-a-kind control rooms. The application of Human Factors Engineering (HFE) is essential for scientific and iterative testing of novel human–system interface (HSI) concepts to ensure effective, efficient, and safe plant operations. Microworlds are simulators that use simplified physics models and control systems to distill nuclear power operations into essential functions. HFE scientists used the Rancor Microworld Simulator to obtain preference and performance metrics for novel and traditional static HSI design styles. Participants comprised advanced reactor company employees and nuclear industry consultants. A mixture of quantitative and qualitative data was captured. There was a preference for the basic graphical style that included high contrast and traditional color scheme elements. No single HSI design outperformed the others, and the participants did not perform better using their preferred HSI style. We report this experiment is the first in a series of HFE testing for HSIs in advanced reactor control room development. Clear user preferences emerged for elements within static displays. The cutting-edge neumorphic style was the least preferred. Future directions include tests of dynamic displays. HFE is used in evaluating and designing HSI devices that will improve the efficiency and safety of advanced nuclear power operations.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2020

Effects on Human Non-Small Lung Cancer Cell growth of Cu(II), Au(III) and Re(I) Complexes Containing N-donor Pyridyl Ligands: A Senior Undergraduate Research Project

Hands-on synthetic laboratory experiences are critically important for undergraduate chemistry majors. A senior undergraduate research experience at the College of Wooster is presented in the current work. The inorganic complexes [Cu(phenan) 2 (NO 3 ) 2 ] (1; phenan = phenanthridine) and [Au(phenan)Cl 3 ](2) were prepared by metallation of the phenan ligand in a 1:1 CH 3 OH/CH 2 Cl 2 mixture at room temperature. Complex 1 is a new inorganic coordination compound. The structures were confirmed by X-ray crystallography. Complex 1 reveals a distorted octahedral geometry around the central Cu (II) metal ion. In complex 2, the Au(III) atom exhibits a square planar geometry. In addition, we investigated [Cu(dmeobpy)(H 2 O) 2 ][NO 3 ] 2 (3; dmeobpy = 4,4’-dimethoxy-2,2’-bipyridine), [Cu(bap)(NO 3 ) 2 ](4; bap = 2,6-bis(azaindole)pyridine) and [Re(CO) 3 (dmeobpy)Cl] (5). The cytoxocities of 1-5, phenan, dmeobpy, bap and cisplatin were evaluated against several human non-small cell lung cancer cell lines (NCI-H1975, HCC827, NCI-H460, and NCI-A549). Compound 1 exhibited modest antitumor activity against the HCC827 cell line, with an IC 50 value of 19 µM. Compound 3 exhibits lower cytotoxic activity than 1. Finally, the cytotoxic activity of complex 5 (IC 50 < 11 µM) is significantly greater than 1 and 3 against the H1975 cancer cell line.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Notre Dame Geothermal Ionic Liquids Research: Ionic Liquids for Utilization of Geothermal Energy

The goal of this project was to develop ionic liquids for two geothermal energy related applications. The first goal was to design ionic liquids as high temperature heat transfer fluids. We identified appropriate compounds based on both experiments and molecular simulations. We synthesized the new ILs, and measured their thermal stability, measured storage density, viscosity, and thermal conductivity. We found that the most promising compounds for this application are aminopyridinium bis(trifluoromethylsulfonyl)imide based ILs. We also performed some measurements of thermal stability of IL mixtures and used molecular simulations to better understand the thermal conductivity of nanofluids (i.e., mixtures of ILs and nanoparticles). We found that the mixtures do not follow ideal mixture theories and that the addition of nanoparticles to ILs may well have a beneficial influence on the thermal and transport properties of IL-based heat transfer fluids. The second goal was to use ionic liquids in geothermally driven absorption refrigeration systems. We performed copious thermodynamic measurements and modeling of ionic liquid/water systems, including modeling of the absorption refrigeration systems and the resulting coefficients of performance. We explored some IL/organic solvent mixtures as candidates for this application, both with experimentation and molecular simulations. We found that the COPs of all of the IL/water systems were higher than the conventional system – LiBr/H2O. Thus, IL/water systems appear very attractive for absorption refrigeration applications.

15 GEOTHERMAL ENERGY↗
DOE OSTI2026

Handling and Properties of Methanol as a Marine Fuel

Given the increasing concern around greenhouse gas emissions and the decline in the availability of fossil fuels, there is increasing global demand to develop alternate fuels for maritime transportation that are sustainable and which have lower greenhouse gas emissions. Methanol is one such alternative fuel that has garnered considerable attention given its potential to be produced by more sustainable processes and its more favorable greenhouse gas emission profile in comparison with current fossil fuels. Understanding the physical and chemical properties of methanol under a range of conditions is essential for its development as a marine fuel. In this study, we seek to define physical and chemical properties of different methanol samples to simulate real-world storage conditions as these data are lacking in the literature. Several methanol samples were evaluated: nearly pure methanol; International Organization for Standardization (ISO) marine methanol (MM) grades A, B, and C; and methanol plus higher alcohols. We first evaluated all methanol samples for impurities, acetic acid content, density, and distillation range. We then characterized the effects of water absorption and found that methanol can easily absorb unacceptable water content from humid air within hours, necessitating storage conditions that prevent this process. In eight-week aging experiments at 20 °C and 40 °C in ambient air, we did not observe significant oxidation for any of the methanol samples; however, we did observe increases in acid number. We assessed the impact of contamination of methanol with water, marine gas oil (MGO), and an MGO–biodiesel mixture on density, viscosity, distillation range, and lubricity. Finally, we show that MGO contamination of methanol results in a slight increase in sooting tendency. In aggregate, our results provide an in-depth analysis of physical and chemical properties of methanol as well as the impacts of storage conditions and impurities on the properties of fuel methanol.

09 BIOMASS FUELS↗
NASA NTRS1973

The space shuttle payload planning working groups: Volume 9: Materials processing and space manufacturing

The findings and recommendations of the Materials Processing and Space Manufacturing group of the space shuttle payload planning activity are presented. The effects of weightlessness on the levitation processes, mixture stability, and control over heat and mass transport in fluids are considered for investigation. The research and development projects include: (1) metallurgical processes, (2) electronic materials, (3) biological applications, and (4)nonmetallic materials and processes. Additional recommendations are provided concerning the allocation of payload space, acceptance of experiments for flight, flight qualification, and private use of the space shuttle.

Source record↗
NASA NTRS1980

Depriming of arterial heat pipes: An investigation of CTS thermal excursions

Four thermal excursions of the Transmitter Experiment Package (TEP) were the result of the depriming of the arteries in all three heat pipes in the Variable Conductance Heat Pipe System which cooled the TEP. The determined cause of the depriming of the heat pipes was the formation of bubbles of the nitrogen/helium control gas mixture in the arteries during the thaw portion of a freeze/thaw cycle of the inactive region of the condenser section of the heat pipe. Conditions such as suction freezeout or heat pipe turn-on, which moved these bubbles into the active region of the heat pipe, contributed to the depriming mechanism. Methods for precluding, or reducing the probability of, this type of failure mechanism in future applications of arterial heat pipes are included.

Antoniuk, D.↗
NASA NTRS1991

Production of organic compounds in plasmas: A comparison among electric sparks, laser-induced plasmas and UV light

In order to study the production of organic compounds in plasmas (and shocks), various mixtures of N2, CH4, and H2, modeling the atmosphere of Titan, were exposed to discrete sparks, laser-induced plasmas (LIP) and ultraviolet light. The yields of HCN and simple hydrocarbons were measured and compared to those calculated from a simple quenched thermodynamic equilibrium model. The agreement between experiment and theory was fair for HCN and C2H2. However, the yields of C2H6 and other hydrocarbons were much higher than those predicted by the model. Our experiments suggest that photolysis by ultraviolet light from the plasma is an important process in the synthesis. This was confirmed by the photolysis of gas samples exposed to the light, but not to the plasma or shock waves. The results of these experiments demonstrate that, in addition to the well-known efficient synthesis of organic compounds in plasmas, the yields of saturated species, e.g., ethane, may be higher than predicted by theory and that LIP provide a convenient and clean way of simulating planetary lightning and impact plasmas in the laboratory.

Scattergood, T. W.↗
NASA NTRS1995

Unsteady planar diffusion flames: Ignition, travel, burnout

In microgravity, a thin planar diffusion flame is created and thenceforth travels so that the flame is situated at all times at an interface at which the hydrogen and oxygen meet in stoichiometric proportion. If the initial amount of hydrogen is deficient relative to the initial amount of oxygen, then the planar flame will travel further and further into the half volume initially containing hydrogen, until the hydrogen is (virtually) fully depleted. Of course, when the amount of residual hydrogen becomes small, the diffusion flame is neither vigorous nor thin; in practice, the flame is extinguished before the hydrogen is fully depleted, owing to the finite rate of the actual chemical-kinetic mechanism. The rate of travel of the hydrogen-air diffusion flame is much slower than the rate of laminar flame propagation through a hydrogen-air mixture. This slow travel facilitates diagnostic detection of the flame position as a function of time, but the slow travel also means that the time to burnout (extinction) probably far exceeds the testing time (typically, a few seconds) available in earth-sited facilities for microgravity-environment experiments. We undertake an analysis to predict (1) the position and temperature of the diffusion flame as a function of time, (2) the time at which extinction of the diffusion flame occurs, and (3) the thickness of quench layers formed on side walls (i.e., on lateral boundaries, with normal vectors parallel to the diffusion-flame plane), and whether, prior to extinction, water vapor formed by burning will condense on these cold walls.

Fendell, F.↗
NASA NTRS2003

Common Ion Effects In Zeoponic Substrates: Dissolution And Cation Exchange Variations Due to Additions of Calcite, Dolomite and Wollastonite

c1inoptilolite-rich tuff-hydroxyapatite mixture (zeoponic substrate) has the potential to serve as a synthetic soil-additive for plant growth. Essential plant macro-nutrients such as calcium, phosphorous, magnesium, ammonium and potassium are released into solution via dissolution of the hydroxyapatite and cation exchange on zeolite charged sites. Plant growth experiments resulting in low yield for wheat have been attributed to a Ca deficiency caused by a high degree of cation exchange by the zeolite. Batch-equilibration experiments were performed in order to determine if the Ca deficiency can be remedied by the addition of a second Ca-bearing, soluble, mineral such as calcite, dolomite or wollastonite. Variations in the amount of calcite, dolomite or wollastonite resulted in systematic changes in the concentrations of Ca and P. The addition of calcite, dolomite or wollastonite to the zeoponic substrate resulted in an exponential decrease in the phosphorous concentration in solution. The exponential rate of decay was greatest for calcite (5.60 wt. % -I), intermediate for wollastonite (2.85 wt.% -I) and least for dolomite (1.58 wt.% -I). Additions of the three minerals resulted in linear increases in the calcium concentration in solution. The rate of increase was greatest for calcite (3.64), intermediate for wollastonite (2.41) and least for dolomite (0.61). The observed changes in P and Ca concentration are consistent with the solubilities of calcite, dolomite and wollastonite and with changes expected from a common ion effect with Ca. Keywords: zeolite, zeoponics, common-ion effect, clinoptilolite, hydroxyapatite

Beiersdorfer, R. E.↗
NASA NTRSDate not supplied

Rotational Spectroscopy is SubLIME: Site-Specific Identification of Compounds Formed on UV-photolyzed Cosmcs Ice

A variety of organic compounds has been detected in comets, meteorites, and the cold gas enveloping infant stars. These compounds display a range of complexity and include so-called complex organic molecules that may have astrobiological implications. Laboratory studies of photolyzed and nonirradiated interstellar, planetary, and cometary ices have demonstrated many astrochemical formation routes and require sensitive analytical techniques to identify the composition of ice and gas products formed. The unique identification of organics can be challenging and often requires structure-specific techniques to identify structural isomers, conformers, and isotopologues. We present the approaches used in SubLIME, the Sublimation of Laboratory Ices Millimeter/submillimeter Experiment, which uses the structure-specificity of rotational spectroscopy to identify the composition and abundances of sublimated products of UV-photolyzed ice samples. Ices are formed and photolyzed at low temperature (~10 K) and slowly heated to 300 K to sublimate the volatile products. The gas mixture is then investigated with millimeter/submillimeter spectroscopy, and the resulting spectra compared to observational spectra collected with submillimeter/far-IR telescopes. We present the experimental set-up and results of UV-photolyzed interstellar ice analogues containing water (H O) and carbon monoxide (CO). Formation routes for identified molecules are proposed for follow-up experimental and theoretical investigations.

Olivia H. Wilkins↗
DOE OSTI2019

General Handling Calculations for the Modified Hospital Can

Containers are evaluated using a Monte-Carlo N-Particle transport code (MCNP). The code calculated keff is compared to critical experiment benchmarks to determine a bias. Additional margin of safety is added to the bias to establish an upper subcritical limit (USL). Modeled cases are considered subcritical if the neutron multiplication factor plus two sigma remains below the USL. Net weight limits allow for any amount of fissile/moderator mixture to exist so long as it meets the weight requirement, therefore all mixture types must be evaluated. Cases that exceed the USL must either be controlled against or have justification why that configuration cannot reasonably exist. Current and legacy loadings and container dimensions must be taken into consideration.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Importance of Plutonium Turnings in Criticality Safety

In criticality safety, turnings are a concern due to the fact that they leave interstitial space in which a moderator can ingress and reduce the critical mass for a fissile material. As turnings are produced when a Plutonium (Pu) items are machined, they are commonly encountered in facilities that process Pu. The intent of this paper is to establish minimum subcritical mass data points for Pu turnings based on the minimum density achievable as measured in a turnings experiment performed at Los Alamos National Laboratory (LANL). Further discussion will cover the implications of these results with concern to criticality safety during normal operations and during a glovebox fire scenario. The results of the study show that a bare homogeneous Pu turnings (at 0.252 kg/L) and water mixture has a spherical critical mass of 3.80 kg, while the fully water reflected spherical critical mass of the same Pu turnings and water mixture has a critical mass of 1.65 kg. When mixed with an idealized hydrocarbon oil rather than water, the spherical critical mass is reduced. In this case, the bare critical mass of the homogeneous Pu turnings and oil mixture is 2.57 kg while the fully water reflected spherical critical mass of the Pu turnings and oil mixture is 1.17 kg. The results of this study show that up to approximately 1000 g of Pu turnings even if mixed with an ideal hydrocarbon and flooded would not be a criticality concern during fire fighting activities. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1955

Adaptation of Combustion Principles to Aircraft Propulsion: Basic Considerations in the Combustion of Hydrocarbon Fuels with Air - Volume I

The report summarizes source material on combustion for flight-propulsion engineers. First, several chapters review fundamental processes such as fuel-air mixture preparation, gas flow and mixing, flammability and ignition, flame propagation in both homogenous and heterogenous media, flame stabilization, combustion oscillations, and smoke and carbon formation. The practical significance and the relation of these processes to theory are presented. A second series of chapters describes the observed performance and design problems of engine combustors of the principal types. An attempt is made to interpret performance in terms of the fundamental processes and theories previously reviewed. Third, the design of high-speed combustion systems is discussed. Combustor design principles that can be established from basic considerations and from experience with actual combustors are described. Finally, future requirements for aircraft engine combustion systems are examined.

THEORIES - COMBUSTION↗