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At least 1,585 records · Page 88

The reaction H + C4H2 - Absolute rate constant measurement and implication for atmospheric modeling of Titan

The absolute rate constant for the reaction H + C4H2 has been measured over the temperature (T) interval 210-423 K, using the technique of flash photolysis-resonance fluorescence. At each of the five temperatures employed, the results were independent of variations in C4H2 concentration, total pressure of Ar or N2, and flash intensity (i.e., the initial H concentration). The rate constant, k, was found to be equal to 1.39 x 10 to the -10th exp (-1184/T) cu cm/s, with an error of one standard deviation. The Arrhenius parameters at the high pressure limit determined here for the H + C4H2 reaction are consistent with those for the corresponding reactions of H with C2H2 and C3H4. Implications of the kinetic carbon chemistry results, particularly those at low temperature, are considered for models of the atmospheric carbon chemistry of Titan. The rate of this reaction, relative to that of the analogous, but slower, reaction of H + C2H2, appears to make H + C4H2 a very feasible reaction pathway for effective conversion of H atoms to molecular hydrogen in the stratosphere of Titan.

Nava, D. F.↗

Research in lightning swept-stroke attachment patterns and flight conditions with the NASA F-106B airplane

Data on 637 direct lightning strikes and 117 close flashes observed by the NASA instrumented F-106B aircraft as part of the Storm Hazards Program at NASA Langley during 1980-1984 are compiled and analyzed, updating the report of Fisher and Plumer (1983). The airborne and ground-based measurement and recording apparatus and the flight and data-reduction procedures are described, and the results are discussed in terms of lightning-strike-conducive flight conditions and lightning attachment patterns. A peak strike rate of 2.1/min is found at altitude 38,000-40,000 ft and temperature below -40 C, with very few strikes below 20,000 ft. Four categories of swept-flash attachment pattern are identified, but it is pointed out that all exterior surfaces of the F-106B are potential attachment sites.

Fisher, B. D.↗

Measuring Specific Heats at High Temperatures

Flash apparatus for measuring thermal diffusivities at temperatures from 300 to 1,000 degrees C modified; measures specific heats of samples to accuracy of 4 to 5 percent. Specific heat and thermal diffusivity of sample measured. Xenon flash emits pulse of radiation, absorbed by sputtered graphite coating on sample. Sample temperature measured with thermocouple, and temperature rise due to pulse measured by InSb detector.

Vandersande, Jan W.↗

On the Theory of Type 1 X-Ray Bursts: The Energetics of Bursts and the Nuclear Fuel Reservoir in the Envelope

The observed properties of type 1 X-ray bursts from 4U/MXB 1636-53 and those of models of thermonuclear flashes on accreting neutron stars are compared. Ways to explain variations in the burst recurrence properties without an apparent correlation with the accretion rate, including the rapid succession of bursts at intervals 10 min are discussed. The strongest X-ray bursts, which occur after a very long interval, are well described by thermonuclear flash models with simple accumulation of accreted fuel, and a spherically symmetric structure in the burning shell. The majority of observed bursts, however, occur after much shorter intervals, and radiate much smaller amounts of energy, by a factor of up to 10 times that predicted by the spherical models. An ignition mechanism of the bursts is proposed in terms of elemental mixing and dissipative heating associated with hydrodynamical instabilities in the neutron star envelope caused by angular momentum carried inward by accreted gas.

Fujimoto, Masayuki Y.↗

A study of starting time in great hard X-ray flares

An analysis of the starting time in ten great hard X-ray bursts observed with the X-Ray Burst Spectrometer (HXRBS) is presented. It is shown that the impulsive phase of nine of them is composed of a preflash phase, during which the burst is observed up to an energy limit ranging from some tens of keV to 200 keV, followed ten to some tens of seconds afterwards by a flash phase, where the count rate rises simultaneously in all detector channels. For two events strong gamma-ray line emission is observed and is shown to start close to the onset of the flash phase.

Klein, K. L.↗

Photorefractor ocular screening system

A method and apparatus for detecting human eye defects, particularly detection of refractive error is presented. Eye reflex is recorded on color film when the eyes are exposed to a flash of light. The photographs are compared with predetermined standards to detect eye defects. The base structure of the ocular screening system is a folding interconnect structure, comprising hinged sections. Attached to one end of the structure is a head positioning station which comprises vertical support, a head positioning bracket having one end attached to the top of the support, and two head positioning lamps to verify precise head positioning. At the opposite end of the interconnect structure is a camera station with camera, electronic flash unit, and blinking fixation lamp, for photographing the eyes of persons being evaluated.

Richardson, John R.↗

Lightning in the Jovian water cloud

The vertical location of the lightning superbolts seen on the Voyager images of Jupiter has been determined using a comparison between the measured spot sizes for single flashes with the intensity distributions calculated from various assumptions about the altitude of the flash. A Monte Carlo model was used to describe the light scattering in the clouds, aerosols, and gases of the Jupiter atmosphere. Best agreement between the measurements and the model predictions was obtained when the lightning activity was assumed to occur in a lower cloud centered at the 5-bar pressure level, whereas the width predicted for lightning in the ammonia cloud was much smaller than the measured widths. The results imply that the lightning observed by the Voyager must be in a cloud much deeper than the ammonia cloud. The lower cloud is expected to be composed of water or a mixture of water and ammonium hydrosulfide.

Borucki, W. J.↗

Summary of NASA storm hazards lightning research, 1980-1985

Lightning swept-flash attachment patterns and the associated flight conditions were recorded from 1980-1985 during 1378 thunderstorm penetrations and 690 direct strikes with a NASA F-106B research airplane. The individual lightning attachment spots, along with crew comments and onboard photographic data have been used to identify lightning swept-flash attachment patterns and the orientations of the lightning channels with respect to the airplane. The altitudes, ambient temperatures, and the relative turbulence and precipitation levels at which the strikes occurred also are summarized and discussed, with an emphasis on the differences between high and low altitude strikes.

Fisher, B. D.↗

Temperature dependence of the NO3 absorption spectrum

The absorption spectrum of the gas-phase NO3 radical has been studied between 220 and 700 nm by using both flash photolysis and discharge flow reactors for the production of NO3. In the flash photolysis method, cross sections at the peak of the (0,0) band at 661.9 nm were measured relative to the cross section of ClONO2 at several different wavelengths. From the best current measurements of the ClONO2 spectrum, the NO3 cross section at 661.9 nm was determined to be (2.28 + or 0.34) x 10 to the -17th sq cm/molecule at 298 K. Measurements at 230 K indicated that the cross section increases by a factor of 1.18 at the peak of the (0,0) band. The discharge flow method was used both to obtain absolute cross sections at 661.9 nm and to obtain relative absorption spectra between 300 and 700 nm at 298 and 230 K. A value of (1.83 + or - 0.27) x 10 to the -17th sq cm/molecule was obtained for sigma NO3 at 661.9 nm at 298 K. Upper limits to the NO3 cross sections were also measured between 220 and 260 nm with the discharge flow method.

Sander, Stanley P.↗

Searches for low-energy counterparts of gamma-ray bursters

The results of six studies concerning the identification of low-energy counterparts of gamma-ray bursters (GRBs) are reported. From these results, it is concluded that the near-infrared observations of GRBs from IRAS pose serious difficulties for several GRB models. No precedent or plausible explanation is found for the optical flash detected on February 8, 1984 by Pedersen et al. (1984) other than that the flash originated on a GRB. The star in the middle of the 1944 optical transient error box has an ultraviolet excess which is significant at the 95 percent confidence level, a result which strongly suggests that the object is indeed the quiescent GRB optical counterpart. If true, then GRBs are probably low-mass contact binaries caused by thermonuclear or accretion instabilities at distances of roughly 1 kpc.

Schaefer, B. E.↗

Search for X-rays from the region of the Aries-Perseus flasher

The region containing the Perseus flasher was observed for 5.4 h with the Exosat observatory. Upper limits to a point source with a steady X-ray flux were 2 x 10 to the -12th erg/sq cm s and 6 x 10 to the 12th erg/sq cm s. Upper limits to X-ray flashes of about 1 s duration were 4 x 10 to the 9th erg/sq cm s and 7 x 10 to the -10th erg/sq cm s. In view of the growing number of negative optical observations, it appears that either the optical flashes do not have a celestial origin, or that the flasher has a transient character and turns off for extended periods of time.

Lewin, Walter H. G.↗

Rate constant for the reaction of atomic oxygen with phosphine at 298 K

The rate constant for the reaction of atomic oxygen with phosphine has been measured at 298 K using flash photolysis combined with time-resolved detection of O(3P) via resonance fluorescence. Atomic oxygen was produced by flash photolysis of N2O or NO highly diluted in argon. The results were shown to be independent of (PH3), (O), total pressure and the source of O(3P). The mean value of all the experiments is k1 = (3.6 + or -0.8) x 10 to the -11th cu cm/s (1 sigma). Two previous measurements of k1 differed by more than an order of magnitude, and the results support the higher value obtained in a discharge flow-mass spectrometry study. A comparison with rate data for other atomic and free radical reactions with phosphine is presented, and the role of these reactions in the aeronomy or photochemistry of Jupiter and Saturn is briefly considered.

Stief, L. J.↗

Short-term forecasting of lightning based on the surface wind field at Kennedy Space Center

Cloud-to-ground lightning is related in time and space to surface convergence for 244 days during the summer over a 790 sqkm network. The method uses surface convergence, particularly the average over the area, to identify the potential for new, local thunderstorm growth, and can be used to specify the likely time and location of lightning during the life cycle of the convection. A threshold of 0.0000075/sec change in divergence is used to define a convergence event, and a separation of 30 min between flashes defines a lightning event. Time intervals are found to be on the order of 1 hr from beginning convergence to first flash, and (CH110) 2 hr from beginning convergence to the end of lightning. Major differences between the convergence-lightning relationships based on low-level mean onshore and offshore flow are noted.

Watson, Andrew I.↗

Hard X-ray and radio emission at the onset of great solar flares

A study of the onset phase of ten great hard X-ray bursts is presented. It is shown from hard X-ray and radio observations in different wavelength ranges that the energization of the electrons proceeds on a global time-scale for some tens of seconds. In nine of the bursts, two phases of emission can be distinguished during the onset phase: the preflash phase (during which emission up to an energy limit ranging from some tens of keV to 200 keV is observed) followed ten to some tens of seconds later by the flash phase (where the count rate in all detector channels rises simultaneously to within some seconds). For two of the events, strong gamma-ray line emission is observed and is shown to start close to the onset of the flash phase.

Klein, K.-L.↗

Optical observations of lightning from a high-altitude airplane

Near-infrared optical measurements of about 1300 optical pulses produced by 79 lightning flashes were obtained by a NASA U-2 high-altitude airplane. Ninety percent of the flashes produced peak radiant energy densities of 4.7 microJ/sq m per sr or greater relative to the full field of view of the instrument. A median pulse rise time of 240 microsec and FWHM of 370 microsec are found, and these slow optical rise times and broad pulse widths are suggested to be due to multiple scattering within the cloud. The spectral characteristics in the near-infrared of the neutral emission lines noted above the clouds are shown to be similar to those found with ground-based measurements.

Christian, H. J.↗

Interiors of the giant planets

This theoretical/observational project constrains interior structure of Jovian planets through observational data. Researchers continue to concentrate on Neptune in support of the 1989 Voyager encounter. Occultations of stars by Neptune are observed from the Tucson area and from Chile to obtain information about Neptune's atmosphere and to continue to search for Neptune arcs. Occultations by other solar system objects are also observed as part of collaborative efforts from time to time. New results on the structure of scintillations in the central flash occultation by Neptune on 20 August 1985 were derived. Analysis shows that scintillations are present throughout the lightcurve, both near the half-intensity points (at a pressure of 1 microbar) and near the central flash (at 0.4 mbar). Near the planetary limb, the scintillations are extended parallel to the limb; near the shadow center, they are extended parallel to the limb; near the shadow center, they are extended in a radial direction. Researchers collaborated with Ramesh Narayan to derive a theory relating the scintillations to density fluctuations in Neptune's atmosphere. The theory will ultimately enable researchers to test whether the scintillations are caused by internal gravity waves in Neptune's upper atmosphere.

Hubbard, W. B.↗

Lightning and precipitation history of a microburst-producing storm

Quantitative measurements of the lightning and precipitation life cycle of a microburst-producing storm are discussed. The storm, which occurred on July 20, 1986 at Huntsville, Alabama, was studied using Doppler radar data. The storm produced 116 flashes, 6 of which were discharges to the ground. It is suggested that an abrupt decrease in the total flash rates is associated with storm collapse, and serves as a precursor to the arrival of the maximum microburst outflows at the surface. Ice-phase precipitation is shown to be an important factor in both the formation of the strong downdraft and the electrification of the storm.

Goodman, Steven J.↗

Comparison of fast electric field changes from subsequent return strokes of natural and triggered lightning

Fast electric field changes from subsequent return strokes of natural and triggered lightning with propagation paths almost entirely over water are compared. Data were collected at the Kennedy Space Center, Florida. Comparisons have been made of the average shape, the rise time and the spectrum of the electric field changes. The electric field changes from the triggered flashes tend to rise to peak faster and decay faster than do their counterparts in natural cloud-to-ground flashes.

Le Vine, D. M.↗