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At least 1,585 records · Page 88

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NASA NTRS1995

Carrier-less, anti-backlash planetary drive system

This invention relates to a carrier-less, anti-backlash planetary gear system that has an input sun gear, a force-balancing and planet-alignment 'speeder' gear above the sun gear, a split ring gear that has a fixed lower ring gear coaxial with the sun gear and a rotating upper ring gear also coaxial with the sun gear. A preload bolt is used for securing the split ring gears together. Within the split ring gear is an even number of planet gears between the split ring gear and the sun gear. Each planet gear consists of an upper planet gear, and lower planet gear with the upper and lower planet gears splined together and pushed apart by a spring which causes separation and relative twist between the upper and lower planet gears. The lower planet gear meshes with the input sun gear and the fixed ring gear while the upper planet gear is driven by the lower planet gear and meshes with the rotating ring gear.

Vranish, John M.↗

NASA NTRS2001

Did the Eruption of the Mt. Pinatubo Volcano Affect Cirrus Properties?

Some observations suggest that the volcanic aerosols produced by the Mt. Pinatubo eruption may have altered cirrus properties. We look for evidence that such modification of cirrus is extensive enough to be climatically significant by comparing three satellite-based cirrus datasets produced by the ISCCP (International Satellite Cloud Climatology Project) analysis, the 'split-window' analysis, and 3I analysis. Since the former two have not been compared in detail before, we conduct such a comparison here. When applied to AVHRR (Advanced Very High Resolution Radiometer) data, both the ISCCP and split-window analyses identify about 0.2 - 0.3 cirrus cloud amount in tropical latitudes; however, there are detailed differences of classification for about half of these clouds. The discrepancies are attributed to the simplified assumptions made by both methods. The latter two datasets are derived from infrared radiances, so they are much less sensitive to volcanic aerosols than the ISCCP analysis. After the Mt. Pinatubo eruption, the ISCCP results indicate a dramatic decrease of thin cirrus (cloud top pressure less than 440 mb and visible optical thickness less than 1.3) over ocean, accompanied by a comparable increase of altocumulus and cumulus clouds; over land, there are no significant changes. In contrast, results from the split-window and 3I analyses show little change in thin cirrus amount over either ocean or land that is associated with the volcanic eruption. The ISCCP results can, therefore, be understood as a misclassification of thin cirrus because the additional reflected sunlight by the volcanic aerosol makes the cirrus clouds appear to be optically thicker. Examination of the split-window signature and the infrared emissivities from 3I show no significant change in infrared emissivity (or optical thickness). These results indicate that the Mt. Pinatubo volcanic aerosol did not have a significant systematic effect on tropical cirrus properties, but rather produced only temporary, local effects. Hence, these results indicate that there was no significant climate feedback produced by aerosol-cirrus-radiative interactions.

Luo, Zhengzhao↗

NASA NTRS2005

Turbulent Vortex-Flow Simulation Over a 65 deg Sharp and Blunt Leading-Edge Delta Wing at Subsonic Speeds

Turbulent thin-layer, Reynolds-Averaged Navier-Stokes solutions, based on a multi-block structured grid, are presented for a 65 deg delta wing having either a sharp leading edge (SLE) or blunt leading edge (BLE) geometry. The primary objective of the study is to assess the prediction capability of the method for simulating the leading-edge flow separation and the ensuing vortex flow characteristics. Computational results are obtained for two angles of attack of approximately 13 and 20 deg, at free-stream Mach number of 0.40 and Reynolds number of 6 million based on the wing mean aerodynamic chord. The effects of two turbulence models of Baldwin-Lomax with Degani-Schiff (BL/DS) and the Spalart-Allmaras (SA) on the numerical results are also discussed. The computations also explore the effects of two numerical flux-splitting schemes, i.e., flux difference splitting (fds) and flux vector splitting (fvs), on the solution development and convergence characteristics. The resulting trends in solution sensitivity to grid resolution for the selected leading-edge geometries, angles of attack, turbulence models and flux splitting schemes are also presented. The validity of the numerical results is evaluated against a unique set of experimental wind-tunnel data that was obtained in the National Transonic Facility at the NASA Langley Research Center.

Ghaffari, Farhad↗

NASA NTRS2010

Sub-Aperture Interferometers

Sub-aperture interferometers -- also called wavefront-split interferometers -- have been developed for simultaneously measuring displacements of multiple targets. The terms "sub-aperture" and "wavefront-split" signify that the original measurement light beam in an interferometer is split into multiple sub-beams derived from non-overlapping portions of the original measurement-beam aperture. Each measurement sub-beam is aimed at a retroreflector mounted on one of the targets. The splitting of the measurement beam is accomplished by use of truncated mirrors and masks, as shown in the example below

Zhao, Feng↗

NASA NTRS2010

Hematite at Meridiani Planum, Mars, Investigated by Simultaneous Fitting of MER Mossbauer Spectra

The Mars Exploration Rover Opportunity encountered sedimentary outcrop rocks at its landing site. Spherules with diameters in the millimeter range were found to weather from the outcrop rocks. With Opportunity s miniaturised M ssbauer spectrometer MIMOS II, hematite was detected in spherules and in the outcrop matrix [1,2]. Figure 1 shows the target Berry Bowl, where brushed outcrop and an accumulation of spherules could be investigated on sols 46 and 48 of Opportunity s mission. Hematite undergoes a transition from a weakly ferromagnetic above to an antiferromagnetic state below the Morin temperature (T(sub M) approx.265 K for chemically pure, crystalline hematite). The magnetic hyperfine splitting (B(sub hf)) shows a general decrease with increasing temperature and a drop of approx.0.8 T at T(sub M). The quadrupole splitting ((Delta)EQ) changes its sign at T(sub M), with negative values above and positive values below the transition. Crystallinity and particle size influence the magnitude and temperature dependence of the magnetic splitting and the quadrupole splitting [3].

Fleischer, I.↗

NASA NTRS2017

Vibrational Dependence of Line Coupling and Line Mixing in Self-Broadened Parallel Bands of NH3

Line coupling and line mixing effects have been calculated for several self-broadened NH3 lines in parallel bands involving an excited v2 mode. It is well known that once the v2 mode is excited, the inversion splitting quickly increases as this quantum number increases. In the present study, we have shown that the v2 dependence of the inversion splitting plays a dominant role in the calculated line-shape parameters. For the v2 band with a 36 cm-1 splitting, the intra-doublet couplings practically disappear and for the 2v2 and 2v2 - v2 bands with much higher splitting values, they are completely absent. With respect to the inter-doublet coupling, it becomes the most efficient coupling mechanism for the v2 band, but it is also completely absent for bands with higher v2 quantum numbers. Because line mixing is caused by line coupling, the above conclusions on line coupling are also applicable for line mixing. Concerning the check of our calculated line mixing effects, while the present formalism has well explained the line mixing signatures observed in the v1 band, there are large discrepancies between the measured Rosenkranz mixing parameters and our calculated results for the v2 and 2v2 bands. In order to clarify these discrepancies, we propose to make some new measurements. In addition, we have calculated self-broadened half-widths in the v2 and 2v2 bands and made comparisons with several measurements and with the values listed in HITRAN 2012. In general, the agreements with measurements are very good. In contrast, the agreement with HITRAN 2012 is poor, indicating that the empirical formula used to predict the HITRAN 2012 data has to be updated.

Parallel bands↗

NASA NTRS2019

Connections Between the Stratosphere and Surface Weather Associated with the Stratospheric Sudden Warming in Early 2018

A major Stratospheric Sudden Warming (SSW) occurred on 11 February 2018. This was the first major SSW since January 2013 and the first split-vortex SSW since January 2009. We examine the SSW and the tropospheric connections using the NASA MERRA-2 reanalysis (1980-2018) and the NASA GEOS Forward Processing (FP) system. A strong tropospheric wave forcing event in January 2018 displaced the stratospheric vortex off the pole. This displaced vortex persisted until the major SSW vortex split in February. At the time of the major SSW split vortex event the MERRA-2 100 hPa meridional heat flux, a measure of the tropospheric forcing on the stratosphere, attained record high values, associated with a strong tropospheric ridge over the US west coast and wave disturbances over the North Atlantic and Asia. The near-real-time GEOS-FP system forecasted the major SSW event with high skill out to 10 days. The analyses also show that after, the SSW, a steady circulation anomaly persisted over the European sector and the transient weather systems were concentrated over the North American continent, under the stronger of the two split vortices. The propagation of these synoptic-scale vortices around the deep, quasi-stationary vortex that extended from the surface into the stratosphere, is well illustrated in animations of extreme temperature changes near the surface over North America. A quantitative analysis of these synoptic waves and their propagation will examine their signatures in potential vorticity and other fields.

Pawson, S.↗

NASA NTRS2018

Characterizing Microfluidic Operations Underlying an Electrowetting Heat Pipe on the International Space Station

Electrowetting heat pipes (EHPs) are a newly conceptualized class of heat pipes, wherein the adiabatic wick section is replaced by electrowetting-based pumping of the condensate (as droplets) to the evaporator. Specific advantages include the ability to transport high heat loads over long distances, low thermal resistance and power consumption, and the absence of moving mechanical parts. In this work, we describe characterization of key microfluidic operations (droplet motion and splitting) underlying the EHP on the International Space Station (ISS). The testing was performed under the Advanced Passive Thermal eXperiment (APTx) project, a project to test a suite of passive thermal control devices funded by the ISS Technology Demonstration Office at NASA JSC (Johnson Space Center). A rapid manufacturing method was used to fabricate the electrowetting device on a printed circuit board. Key device-related considerations were to ensure reliability and package the experimental hardware within a confined space. Onboard the ISS, experiments were conducted to study electrowetting-based droplet motion and droplet splitting, by imaging droplet manipulation operations via pre-programmed electrical actuation sequences. An applied electric field of 36 Volts per micron resulted in droplet speeds approaching 10 millimeters per second. Droplet splitting dynamics were observed and the time required to split droplets was quantified. Droplet motion data was analyzed to estimate the contact line friction coefficient. Overall, this demonstration is the first-ever electrowetting experiment in space. The obtained results are useful for future design of the EHP and other electrowetting-based systems for microgravity applications.

Electrowetting↗

NASA NTRS2019

Analysis Ready Data in Analytics Optimized Data Stores for Analysis of Big Earth Data in the Cloud

Cloud computing offers the possibility of making the analysis of Big Data approachable for a wider community due to affordable access to computing power, an ecosystem of usable tools for parallel processing, and migration of many large datasets to archives in the cloud, allowing data-proximal computing. Generally, data analysis acceleration in the cloud comes from running multiple nodes in a split-combine-apply strategy. Data systems such as the Earth Observing System Data and Information System are in a position to "pre-split" the data by storing them in a data store that is optimized for data parallel computing, i.e., an Analytics-Optimized Data Store (AODS). A variety of approaches to AODS are possible, from highly scalable databases to scalable filesystems to data formats optimized for cloud access (e.g., zarr and cloud-optimized datasets), with the optimal choice dependent on both the types of analysis and the geospatial structure of the data. A key question is how much preprocessing of the data to do, both before splitting and as the first part of the apply step. Again, the geospatial structure of the data and the analysis type influence the decision, with the added complexity of the user type. Trans-disciplinary users who are not well-versed in the nuances of quality-filtering and georeferencing of remote sensing orbit/swath/scene data tend to ask for more highly processed data, relying on the data provider to make sensible decisions on preprocessing parameters. (This accounts for the popularity of "Level 3" gridded data, despite the lower spatial resolution it provides.) In this case, data can be preprocessed before the split, resulting in higher performance in the rest of the "apply" step, which can be transformative for use cases such as interactive data exploration at scale. Discipline researchers who are experienced with remote sensing data often prefer more flexibility in customizing the preprocessing data into Analysis Ready Data, resulting in more need for on-the-fly preprocessing.

Lynnes, Christopher↗

NASA NTRS2023

Launch Complex 39B, SWMU 009 Air Sparging System Expansion Implementation Work Plan Kennedy Space Center, Florida

This Implementation Work Plan (IWP) for expansion of the Air Sparging (AS) system at Launch Complex 39B (LC39B), presents the design and coordination specifics to expand the existing AS Interim Measure (IM) at LC39B located at Kennedy Space Center (KSC), Florida. The existing AS system at LC39B was installed in 2017 and included 279 AS wells. LC39B has been designated as Solid Waste Management Unit (SWMU) 009 under the KSC Resource Conservation and Recovery Act (RCRA) Corrective Action Program. Expansion of the AS IM will include installation of an additional five AS wells to depths of approximately 13 and 17 feet below land surface (bls) to remediate contaminated groundwater identified northwest of the launch pad, near the liquid oxygen (LOX) tank. The expansion will target concentrations of cis-1,2-dichloroethene (cDCE) and vinyl chloride (VC) greater than Florida Department of Environmental Protection (FDEP) Natural Attenuation Default Concentrations (NADCs) that were identified during direct push technology (DPT) sampling events between 2019-2022 in shallow intervals between 8 and 16 feet bls. The objective for this expansion is to remediate contaminated groundwater within the treatment zone to below NADCs to support transition to monitored natural attenuation (MNA) through a long-term monitoring (LTM) program. This expansion will treat approximately 0.07-acres of residual groundwater contamination. The IWP design for this expansion will utilize the existing AS system trailer that is already onsite and operating. The five new AS expansion wells will be integrated into the existing Zone Z4 distribution manifold to deliver compressed air to the new AS wells. To deliver airflow, three existing lateral lines will be split in the field at a lateral split junction point (using 2-way or 3-way splits). Each split lateral will supply air to AS wells at the same depth interval to minimize preferential pathways. The trenching layout for the new AS wells was developed to minimize ground disturbance due to the amount of utilities in the area. One new monitoring well will also be installed and added to LC39B’s performance monitoring program to evaluate the effectiveness of the AS system expansion. This well will be sampled on a semi-annual basis for volatile organic compounds, with results evaluated to determine if system adjustments may be required. The main components of this IWP were presented to the KSC Remediation Team (KSCRT) at the October 2022 Meeting (Meeting 2210-M05). DPT delineation data from the LOX area were also presented, which included some inferred boundaries due to physical restrictions of the LOX tank and associated concrete pad and infrastructure. Planned monitoring well sampling in this area will help determine if back-diffusion may be occurring from beneath the pad. Additionally, based on potential petroleum odors and staining identified at two DPT locations during the January 2022 DPT event in the 10-16 feet bls range, a KSCRT action item was assigned during the October 2022 meeting to collect soil samples for petroleum compounds if similar odors or staining are identified during IM implementation. Construction completion and performance monitoring will be incorporated into LC39B’s groundwater monitoring reports, which are currently submitted on an annual basis to FDEP to document operation and maintenance activities and results from the AS IM.

Deborah M. Wilson↗

NASA NTRSDate not supplied

Impact of Sleep Shifting Strategies on the International Space Station

Astronaut crews have historically averaged around six hours of sleep per night, especially during missions that required a high tempo work environment, confined spacecraft without crew quarters, and frequent sleep schedule changes. In recent years, crew aboard the ISS have had much more stable schedules, with a consistent bedtime at 2130 and wake time at 0600 Greenwich Mean Time. Despite these improvements to sleep conditions on the ISS, sleep schedules are disrupted by visiting vehicles that arrive or leave the ISS or when uncontrollable operational events require the crewmembers to shift their sleep. We characterized the approaches to sleep shifting, including shifting sleep earlier and later and split sleep to determine the impact on sleep duration and quality. METHODS Data were gathered though the Spaceflight Standard Measures protocol. These consisted of objective measures of sleep duration (calculated via a wrist-worn accelerometer) collected by 19 crewmembers (7 females; mean age 46 ± 7 years) throughout their tenure aboard the ISS. We first categorized episodes of “split sleep” whereby a person attempts sleep on two separate occasions in a 24-hour period that are similar in length. For example, they might have a 4-hour sleep opportunity followed by a night awake, followed by another 4-hour sleep opportunity the next morning. RESULTS Out of the 19 crewmembers, a total of 8 engaged in 11 episodes of split sleep while inflight. These periods all surrounded visiting vehicle events that interfered with their nominal sleep window, including docking, relocation, and undocking events. The first sleep opportunity typically took place during the afternoon before the disrupting event (all sleep periods were contained between 1151 and 2009), while the second episode took place the following morning (between 0343 and 1325) On average, the time in bed of the first sleep opportunity was shorter than the second (M1=2.89±0.82 vs. M2=4.30±1.41). DISCUSSION Next in our analysis, we will compare the crewmembers’ split sleep outcomes to those from other strategies (e.g., phase delays). We aim to determine which strategies yield the best sleep outcomes and to determine whether the sleep shifting strategy has consequences to subsequent sleep. Understanding these impacts will aid in decision making for future ISS operations and will also help us better understand the impacts of various strategies to adjust sleep and help guide scheduling in future missions where consistent schedules may not be possible.

sleep↗

DOE OSTI2023

2023 American Society for Mass Spectrometry (ASMS) 71st Annual Conference on Mass Spectrometry and Allied Topics

Title (20 words): The investigation of the mechanism for the water splitting by holmium oxide nitrate complex in gas-phase Introduction (120 words): The studies for hydrogen from water splitting is important for clean energy economy as molecular hydrogen is a potential energy carrier. Therefore, understanding the fundamental chemistry of water splitting is essential. The water splitting activated by [Ho(NO3)4]- was previously studied. The suggested mechanism was to first eliminate •NO2 from [Ho(NO3)4]- to make [HoO(NO3)3]-. Then, water was added to form [HoO(NO3)3(H2O)]-, followed by eliminating the •OH to form [HoOH(NO3)3]-. However, we proposed a new mechanism with the formation of [Ho(NO3)3]- prior to the water addition. Once water is added to this intermediate to make [Ho(NO3)3(H2O)]-, the •H is eliminated to form [HoOH(NO3)3]-. Here we have used a labeled experiments with 18-O nitrates. The results to support the new mechanism are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Mechanistic Insights on Permeation of Water over Iron Cations in Nanoporous Silicon Oxide Films for Selective H 2 and O 2 Evolution

Electrocatalysts encapsulated by an ultrathin and semipermeable oxide layer offer a promising avenue for efficient, selective, and cost-effective production of hydrogen through photoelectrochemical water splitting. This architecture is especially attractive for Z-scheme water splitting, for which a nanoporous oxide film can be leveraged to mitigate undesired, yet kinetically facile, reactions involving redox shuttles, such as aqueous iron cations, by limiting transport of these species to catalytically active sites. In this work, molecular dynamics simulations were combined with electrochemical measurements to provide a mechanistic understanding of permeation of water and Fe(III)/Fe(II) redox shuttles through nanoporous SiO 2 films. It is shown that even for SiO 2 pores with a width as small as 0.8 nm, water does not experience any energy barrier for permeating into the pores due to a favorable interaction with hydrophilic silanol groups on the oxide surface. In contrast, permeation of Fe(III) and Fe(II) into microporous SiO 2 pores is limited due to high energy barriers, which stem from a combination of distortion and dehydration of the second and third ion solvation shells. Furthermore, our simulations and experimental results show that SiO 2 coatings can effectively mitigate undesired Fe(III)/Fe(II) redox reactions at underlying electrodes by attenuating permeation of iron cations, while allowing water to permeate and thus participate in water splitting reactions. In a broader context, our study demonstrates that selectivity of solvated cations can be manipulated by controlling the pore size and surface chemistry of oxide films.

14 SOLAR ENERGY↗

DOE OSTI2026

HydroGEN Consortium: Advancements in Hydrogen Production

HydroGEN Energy Materials Network (EMN) is an U.S. Department of Energy (DOE) EERE Hydrogen and Fuel Cell Technologies Office (HFTO)-funded consortium that aims to accelerate the discovery and development of advanced water splitting materials (AWSM) for clean, low-cost hydrogen production. Materials innovations are key to enhancing performance, durability, and cost of hydrogen generation technologies. HydroGEN is focused on low technology readiness level AWS technologies, including low- (alkaline exchanged membrane electrolysis) and high-temperature electrolysis (proton-conducting solid oxide electrolysis), photoelectrochecmical (PEC) and thermochemical (TCH) water splitting. The AWS technologies in this consortium study proton conduction in solid oxide electrolysis and hydroxide conduction in polymer electrolysis, and proton transport in photoelectrochemical water splitting. This presentation will provide an overview of the HydroGEN EMN and technical highlights of a few lab-led and DOE-awarded "seedling" R&D projects. HydroGEN continues to grow its community of industry, university, and national laboratories, forming a national innovation ecosystem focused on renewable hydrogen production.

08 HYDROGEN↗

DOE OSTI2026

HydroGEN Consortium

08 HYDROGEN↗

DOE OSTI2023

Optimizing shift selection in multilevel Monte Carlo for disconnected diagrams in lattice QCD

The calculation of disconnected diagram contributions to physical signals is a computationally expensive task in Lattice QCD. To extract the physical signal, the trace of the inverse Lattice Dirac operator, a large sparse matrix, must be stochastically estimated. Because the variance of the stochastic estimator is typically large, variance reduction techniques must be employed. Multilevel Monte Carlo (MLMC) methods reduce the variance of the trace estimator by utilizing a telescoping sequence of estimators. Frequency Splitting is one such method that uses a sequence of inverses of shifted operators to estimate the trace of the inverse lattice Dirac operator, however there is no a priori way to select the shifts that minimize the cost of the multilevel trace estimation. Here we present a sampling and interpolation scheme that is able to predict the variances associated with Frequency Splitting under displacements of the underlying space time lattice. The interpolation scheme is able to predict the variances to high accuracy and therefore chooses shifts that correspond to an approximate minimum of the cost for the trace estimation. We show that Frequency Splitting with the chosen shifts displays significant speedups over multigrid deflation, and that these shifts can be used for multiple configurations within the same ensemble with no penalty to performance.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2017

Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures

Solar water splitting via multi-junction semiconductor photoelectrochemical cells provides direct conversion of solar energy to stored chemical energy as hydrogen bonds. Economical hydrogen production demands high conversion efficiency to reduce balance-of-systems costs. For sufficient photovoltage, water-splitting efficiency is proportional to the device photocurrent, which can be tuned by judicious selection and integration of optimal semiconductor bandgaps. Here, we demonstrate highly efficient, immersed water-splitting electrodes enabled by inverted metamorphic epitaxy and a transparent graded buffer that allows the bandgap of each junction to be independently varied. Voltage losses at the electrolyte interface are reduced by 0.55 V over traditional, uniformly p-doped photocathodes by using a buried p-n junction. Lastly, advanced on-sun benchmarking, spectrally corrected and validated with incident photon-to-current efficiency, yields over 16% solar-to-hydrogen efficiency with GaInP/GaInAs tandem absorbers, representing a 60% improvement over the classical, high-efficiency tandem III-V device.

14 SOLAR ENERGY↗

DOE OSTI2018

(Invited) HydroGEN: An AWSM Energy Materials Network

The HydroGEN (https://www.h2awsm.org/) energy materials network (EMN) aims to accelerate the research and development (R&D) of advanced water splitting (AWS) technologies for clean, sustainable hydrogen production. Announced in October 2016, the HydroGEN EMN comprises six core National Laboratories and focuses on four AWS pathways: low- and high-temperature electrolysis, photoelectrochemical, and solar thermochemical water splitting. The HydroGEN consortium offers an extensive collection of materials research capabilities for addressing R&D challenges in discovery and design, efficacy and efficiency, durability and cost. Leveraging the HydroGEN Consortium's technical experts and broad collection of unique resource capabilities is expected to advance the maturity and technology readiness levels in each advanced water splitting technology pathway.

08 HYDROGEN↗