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At least 1,585 records · Page 88

Protonic Ceramics for Energy Storage & Electricity Generation with Ammonia (Final Report)

The commercial product resulting from this R&D project will enable cost-effective synthesis of the Carbon Neutral Liquid Fuel (CNLF) ammonia, a common chemical, at a small scale for energy and industrial applications using only intermittent renewable energy, water, and air as feedstocks. These products are also capable of producing electrical energy from the CNLF in a fuel cell mode of operation. Thus, the eventual commercial product enables both single direction production of either CLNF or electricity, or alternatively functions as a fully reversible, self-contained energy storage device. The renewed interest in developing electrolysis systems is driven, in part, by the burgeoning renewable, solar, and wind industries and the need for an energy conversion and storage technology that can convert intermittent solar and wind energy into the production of hydrogen. Electrolysis systems integrated into both distributed and central renewable power plants would utilize solar and wind energy as their primary power source to produce renewably generated hydrogen for local energy storage or chemical feedstock purposes. Ammonia is an excellent surrogate for hydrogen transportation. NH3 presents an attractive alternative to hydrogen as a working fluid in reversible devices towards a sustainable green energy-oriented future. Ammonia can be easily liquefied at room temperature at about 8 bar or at -33°C at ambient pressure. In contrast, the liquefaction temperature of hydrogen is -253°C at ambient pressure. NH3 has a significantly higher volumetric energy density (12.7 MJ/L) than compressed hydrogen (4.5 MJ/L at ~70 MPa) or liquefied hydrogen (8.5 MJ/L). Additionally, ammonia is a widely used raw material for agriculture fertilizer and thus has well-established storage, transport, and handling processes (about 180 million tons of ammonia are produced annually). Techno-economic analysis suggests ammonia is the least expensive fuel among hydrogen, gasoline, natural gas, liquefied petroleum gas, and methanol.

08 HYDROGEN↗

Revenue Analysis for Energy Storage Systems in the United States

In this work we evaluate the potential revenue from energy storage using historical electricity prices, forward-looking projections of hourly electricity prices, and actual reported revenue. This analysis examines the impact of storage characteristics, specifically duration and round-trip efficiency, as well as locational elements of storage revenue within the current and projected U.S. power system. Figure ES-1 illustrates the revenue for a 1 MW storage system in seven market regions with durations range from 1 hour to 12 hours using both historical and forward-looking price data. The historical analysis covers more than 500 price nodes for each market region, while the forward-looking analysis includes balancing areas under different 10 scenarios of the electricity generation mix. The results indicate that the revenues consistently increase with duration, though the marginal value declines as duration grows. Moreover, the range of revenue depends on the system's operational location, and the electricity generation mix changes for future years. This range also widens with increased durations. In addition, the sensitivity analysis of round-trip efficiency reveals that as efficiency improves, system revenue increases, though the value of better round-trip efficiency declines as at higher efficiency levels.

25 ENERGY STORAGE↗

Experimental Characterization of High-Surface Area Thermal Energy Storage

There is growing interest in energy storage technologies due to the expansion of renewable energy sources that are inherently intermittent and the increasing frequency of extreme weather events that disturb the power grid. Power consumption in buildings makes up approximately 76% of all electricity usage on the grid and is primarily used for thermal applications such as space conditioning, hot water, and cooking. This makes thermal energy storage (TES) an ideal solution for many of these applications. Many TES technologies rely on latent energy storage, which utilizes the melting/solidification of phase change materials (PCM) to store energy. Typically, TES designs suffer from low power density due to their low inherent thermal conductivity. This limitation makes the deployment of TES in active applications difficult as the ease of access to energy is essential for effective use. Common routes for improving power density include high thermal conductivity additives or extended features such as fins that increase cost. This study presents an alternative approach to improving performance through increasing the overall surface area to volume ratio of the device, to increase the available area for convection to occur between the working fluid and PCM. In the study a commercial PCM was selected with a transition temperature ideal for space heating applications. The heat exchanger design utilizes a unique application of triply periodic minimal surfaces (TPMS) for macro-encapsulation of the PCM. The use of TPMS for heat exchangers has been growing in interest due to their high-surface area to volume ratios, which were previously unmanufacturable until the development of additive manufacturing. A modular system was designed and manufactured with a stereolithography resin printing system that is then backfilled with PCM. An experiment test set-up is designed to test the charge and discharge performance of the thermal storage using a conditioned air stream. The pressure drop of the design is tested across a variety of flow rates. When compared to existing experimental data within literature, there is excellent agreement based on the Reynolds number at similar hydraulic diameters. Several inlet temperatures are tested at consistent temperature differences from the phase change temperature for both charging and discharging. Additionally, the volumetric flow rate is varied for each temperature set point. It was found that increasing flow rate had diminishing returns in reducing the overall charge time of the TES. The temperature delta from the melting temperature was the primary contributor to the change in average heat flux with limited variation in average heat transfer rate between charging and discharging at similar inlet temperatures and flow rates. The TPMS heat exchanger design has a high air-side pressure drop but it provides high heat transfer rates. This helps maintain a high outlet temperature during discharge, which is important to thermal comfort applications. The design, manufacturing, and experimental characterization of the TES device will be presented as part of this study.

25 ENERGY STORAGE↗

Numerical Modeling & Size Optimization of Thermal Energy Storage for Iron & Steel Production

Iron and steel production are responsible for 90 million MtCO2 per year in the United States. Hydrogen direct reduction of iron (H2DRI) is a promising pathway for a more sustainable iron production than commercially deployed technologies which rely on natural gas. The H2DRI process requires hydrogen at a temperature of up to 950 degrees C fed into a reduction furnace to produce pellets or briquettes that are used in the downstream iron and steelmaking process. In this work, we propose to use an electrical thermal energy storage (ETES) system, that can use renewable electricity to store high-temperature heat and dispatch it upon demand. Such a system can buffer the H2DRI plant from the variability of electricity prices by charging during curtailment and running the plant from storage during times of peak electricity price. We have developed heat transfer models for two different ETES systems that can be used to heat up hydrogen to the required temperatures: a particle-based ETES and a firebrick ETES. These models are used to evaluate the performance of such a system and support the sizing and preliminary cost estimation. The preliminary results using both models show that designing ETES systems for an industrial-scale H2DRI furnace is feasible. The firebrick ETES system has limited operational duration, which might limit the price buffering effect unless significantly oversized. The particle ETES system heat exchanger has industry-feasible dimensions, but its storage capacity would be decided upon the number of particle storage silos.

25 ENERGY STORAGE↗

Long Duration Energy Storage Viability Survey

Energy storage technologies that can economically store and provide electricity over multi-day and seasonal timescales are likely to be a critical component of a sustainable and resilient energy system. This analysis performs a broad survey of energy storage technologies to find storage media that are promising for these long-duration energy storage applications.

levelized cost of storage↗

Exergy Analysis of Solar Still with Sand Heat Energy Storage

This paper studies the experimental and exergy analysis of solar still with the sand heat energy storage system. The cumulative yield from solar still with and without energy storage material is found to be 3.3 and 1.89 kg/m{sup 2}, respectively for 8-h operation. Results show that the exergy efficiency of the system is higher with the least water depth of 0.02 m (m{sub w} = 20 kg). Competitive analysis of second law efficiency shows that the exergy efficiency improves the system by 30% than conventional single slope solar still without any heat storage. The maximum exergy efficiency with energy storage material is found as 13.2% and it is less than the conventional solar still without any material inside the basin.

14 SOLAR ENERGY↗

Energy Storage Improves Power Plant Flexibility and Economic Performance

Most existing coal-fired power plants were designed for sustained operation at full load to maximize efficiency, reliability, and revenue, as well as to operate air pollution control devices at design conditions. Depending on plant type and design, these plants can adjust output within a fixed range in response to plant operating or market conditions. The need for flexibility driven by increased penetration of variable and non-dispatchable power generation, such as wind and solar, is shifting the traditional mission profile of thermoelectric power plants in three ways: more frequent shutdowns when market or grid conditions warrant, more aggressive load ramp rates (rate of output change), and a lower minimum sustainable load, which provides a wider operating range and helps avoid costly plant shutdowns. Recent studies have shown that the flexibility of a coal-fired power plant can be improved by energy storage. The objective of this work was to analyze a set of energy storage options and determine their impact on the flexibility and economics of a representative coal-fired power plant. The effect of three energy storage systems integrated with a coal power plant on plant flexibility and economics was investigated. The results obtained in this project show that energy storage systems integrated with a thermal power plant improve plant flexibility and participation in the energy and ancillary services markets, which improves plant financial performance.

20 FOSSIL-FUELED POWER PLANTS↗

Africa Battery Energy Storage Systems (BESS) Capacity Building Li-Ion Battery Degradation and Performance [Slides]

This presentation is intended for power system engineers, operators, and planners who work on isolated power systems that have (or may soon have) high levels of power generation coming from wind turbines, solar farms, and battery energy storage, which are collectively referred to as inverter-based resources. It describes the basics of lithium-ion battery energy storage systems and lithium-ion battery degradation. Battery degradation at the cell-level is explained, and then the structure and degradation of battery energy storage systems is also explained. This is intended to help power system engineers, operators, and planners to understand and effectively utilize battery energy storage systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Viability of Existing INL Facilities for Dry Storage Cask Handling

This report evaluates existing capabilities at the INL to determine if a practical and cost effective method could be developed for opening and handling full-sized dry storage casks. The Idaho Nuclear Technology and Engineering Center (INTEC) CPP-603, Irradiated Spent Fuel Storage Facility, provides the infrastructure to support handling and examining casks and their contents. Based on a reasonable set of assumptions, it is possible to receive, open, inspect, remove samples, close, and reseal large bolted-lid dry storage casks at the INL. The capability can also be used to open and inspect casks that were last examined at the TAN Hot Shop over ten years ago. The Castor V/21 and REA-2023 casks can provide additional confirmatory information regarding the extended performance of low-burnup (<45 GWD/MTU) used nuclear fuel. Once a dry storage cask is opened inside CPP-603, used fuel retrieved from the cask can be packaged in a shipping cask, and sent to a laboratory for testing. Testing at the INL’s Materials and Fuels Complex (MFC) can occur starting with shipment of samples from CPP-603 over an on-site road, avoiding the need to use public highways. This reduces cost and reduces the risk to the public. The full suite of characterization methods needed to establish the condition of the fuel exists and MFC. Many other testing capabilities also exist at MFC, but when those capabilities are not adequate, samples can be prepared and shipped to other laboratories for testing. This report discusses how the casks would be handled, what work needs to be done to ready the facilities/capabilities, and what the work will cost.

INL, dry storage cask, Idaho National Lab, Long Te↗

Hydrogen Energy Storage and Power-to-Gas: Establishing Criteria for Successful Business Cases

As the electric sector evolves and increasing amounts of variable generation are installed on the system, there are greater needs for system flexibility, sufficient capacity and greater concern for overgeneration. As a result there is growing interest in exploring the role of energy storage and demand response technologies to support grid needs. Hydrogen is a versatile feedstock that can be used in a variety of applications including chemical and industrial processes, as well as a transportation fuel and heating fuel. Traditionally, hydrogen technologies focus on providing services to a single sector; however, participating in multiple sectors has the potential to provide benefits to each sector and increase the revenue for hydrogen technologies. The goal of this work is to explore promising system configurations for hydrogen systems and the conditions that will make for successful business cases in a renewable, low-carbon future. Current electricity market data, electric and gas infrastructure data and credit and incentive information are used to perform a techno-economic analysis to identify promising criteria and locations for successful hydrogen energy storage and power-to-gas projects. Infrastructure data will be assessed using geographic information system applications. An operation optimization model is used to co-optimizes participation in energy and ancillary service markets as well as the sale of hydrogen. From previous work we recognize the great opportunity that energy storage and power-to-gas but there is a lack of information about the economic favorability of such systems. This work explores criteria for selecting locations and compares the system cost and potential revenue to establish competitiveness for a variety of equipment configurations. Hydrogen technologies offer unique system flexibility that can enable interactions between multiple energy sectors including electric, transport, heating fuel and industrial. Previous research established that hydrogen technologies, and in particular electrolyzers, can respond fast enough and for sufficient duration to participate in electricity markets. This work recognizes that participation in electricity markets and integration with the gas system can enhance the revenue streams available for hydrogen storage systems and quantifies the economic competitiveness and of these systems. A few of the key results include 1) the most valuable revenue stream for hydrogen systems is to sell the produced hydrogen, 2) participation in both energy and ancillary service markets yields the greatest revenue and 3) electrolyzers acting as demand response devices are particularly favorable.

30 DIRECT ENERGY CONVERSION↗

Life Cycle Assessment for Closed-Loop Pumped Hydropower Energy Storage in the United States

The federal government has initiated an aggressive set of policies to achieve a net-zero carbon emission goal for the electricity sector by 2050. As a result, rapid growth in deployment of renewable energy technologies is expected. Most commercially mature technologies are temporally variable and do not provide grid inertia, while renewable technologies with high projected deployment have intermittent generation methods. Energy storage technologies are needed to both dispatch power on-demand and help provide the needed grid inertia. Pumped storage hydro (PSH) is a well-established technology that has gained renewed interest in recent years offering energy-balancing, grid stability, control of electrical network frequency, and large-scale storage capacity. For widespread adoption of PSH, more information is needed regarding its current life cycle environmental impacts. The objective of this study is to perform a full life cycle assessment (LCA) of new closed-loop PSH in the U.S. The functional unit for this study is 1 kWh of electrical power delivered to the grid and the base case project lifetime is 80 years. The life cycle inventory for this project accounts for all material and energy flows associated with the green-field construction, operation, maintenance, and decommissioning of a closed-loop PSH plant in the U.S. Collected data represents a range of potential PSH specifications and geographic locations coming from all prospective closed-loop PSH installations in the U.S. with data available. In addition, existing PSH installations are used to provide assumptions for inventory inputs. Results presented will include the global warming potential (GWP IPCC 100a) and Energy Return on Investment (EROI) from our base case (average PSH installation) as well as from scenario analyses and model sensitivity. These results will be compared to the impacts from existing PSH sites and alternate storage technologies. Methods align with the assumptions and guidelines put in place by previous PSH LCAs to ensure an accurate comparison with the results from this report.

ENERGY PLANNING, POLICY, AND ECONOMY,HYDRO ENERGY↗

Used fuel transportation considerations to support centralized interim storage

The deployment of a used fuel centralized interim storage facility (CISF) can offer a renewed opportunity for the U.S. to make real progress towards integrating of the back end of the fuel cycle. One of the key elements of success, and perhaps as important as the CISF project itself, is transportation-program readiness for large-scale rail shipments of spent fuel to a centralized storage facility. This paper offers an overview of the status of spent fuel transportation readiness in the U.S. The authors identify a number of technical and institutional challenges to be resolved before rail shipments of used fuel to a centralized storage facility can begin. Furthermore, 'NAC International', a transportation company, recommends a key action to ensure a safe, secure and efficient transportation system that meets stakeholder expectations is ready to meet milestone dates. NAC will address the challenges of deploying such a system, focused on leveraging existing U.S. transportation experience, capabilities and infrastructure. This paper concludes with the assertion, that spent fuel transportation to a CISF by 2021 is possible if we seriously commit resources now to address the critical institutional, operational, and system requirements implicit in a consent based transportation and storage program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Extended Storage of High Burn-up Fuel Cask R and D Project - 17145

Under contract by EPRI and DOE, AREVA Federal Services LLC (AFS) is leading a team consisting of AREVA Inc. and Dominion Virginia Power (Dominion) to develop and conduct a full-scale confirmatory Research project with HBU fuel. A test plan was developed using an existing TN Americas (TN) TN-32 bolted storage cask with a modified, specially instrumented lid to be engineered and then loaded with multiple cladding types of HBU pressurized water reactor (PWR) UNF from Dominion's North Anna Power Station (this modified cask is identified as TN-32B). Seven specially designed thermocouple lances, each containing nine detectors, will be inserted into the designated fuel assembly guide tubes through the modified cask lid. The loaded cask with the monitoring system will be placed into dry storage on the existing North Anna Independent Spent Fuel Storage Installation (ISFSI) pad for a period of extended monitoring. In addition, design modifications to the lid have been incorporated to permit periodic gas sampling of the cask internals during the storage period on the ISFSI pad. The fuel selected for this research project ranges in average assembly burnup between 50 GWD/MTU to 67 GWD/MTU. The instrumentation used to collect the thermal data is very similar to in-core thermocouple detectors used at nuclear power plants and is considered very reliable for this application. Prior to cask loading at North Anna, a series of 'fit up' tests will be performed at the fabricator to ensure proper alignment, fit and function of the modified cask and related instrumentation and equipment. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Evaluation of Neutron Flux on the Surface of a PWR Dry Storage Cask - 17574

Since the construction of a dry storage facility for spent nuclear fuel is expected in Korea, several methods have been studied for assuring the safety of pressurized-water reactor (PWR) spent fuels in dry storage casks. Existing evaluation methods are mostly based on detection technology of gamma-rays. However, the gamma-ray detection methods have high uncertainties due to background radiation. Therefore, we developed an evaluation method for the spent nuclear fuel monitoring based on neutron detection. In this study, we evaluated neutron flux on the surface of a PWR dry storage cask using computational simulation. Neutron release rate and energy spectra from a Westinghouse (WH) 17x17 type spent fuel with 10 years cooling time were calculated using ORIGEN-ARP code. MCNP code was used to simulate geometry and material properties of the spent fuel assemblies and casks. Neutron flux after 10 years of cooling time of the spent fuels was calculated on the surface of top, side, and bottom of the casks. The metal cask and the concrete cask, called as KORAD-21 casks which newly developed by Korea Radioactive Waste Agency (KORAD), were selected for this study. As a result, for the metal cask, average neutron flux were 4.79x10{sup 2} neutrons/cm{sup 2} sec, 5.29x10{sup 2} neutrons/cm{sup 2} sec, and 1.47x10{sup 3} neutrons/cm{sup 2} sec on the surface of top, side, and bottom of the cask, respectively. For the concrete cask, average neutron flux on the surface of top, side and bottom of the casks were 5.07x10{sup 1} neutrons/cm{sup 2} sec, 1.18x10{sup 1} neutrons/cm{sup 2} sec, and 1.46x10{sup 3} neutrons/cm{sup 2} sec, respectively. The study results can be applied to evaluate characteristics of PWR spent fuels and the neutron flux of dry storage cask. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Use of the underwater collimated spectrometric system for survey of storage ponds of research VVR-2 and or reactors - 15118

Spent nuclear fuel removal activities in the National Research Centre 'Kurchatov Institute' were resumed in 2004. During the last two years, removal was performed of the spent nuclear fuel from the VVR-2 and OR reactor installations, whose storage facilities are located within the Gas Plant complex. The Gas Plant complex is the experimental base of the Institute of Nuclear Reactors, which is part of the 'Kurchatov Institute'. The complex features four storage facilities for spent nuclear fuel, one in a dedicated building for storage of spent nuclear fuel and solid rad-waste and three in the reactor building. They are sub-surface vessels filled with water (the volume of water in each is about 6 m{sup 3}), closed with top shielding slabs. Some spent fuel assemblies and fuel elements stored are resized, deformed, or have defective claddings. In the course of works on removal from ponds of the spent nuclear fuel, its fragments could get to water. The bottoms of ponds storage are covered with a deposit. The bottom of ponds and water are possible to be pollution by fission products. The survey objective was to find uranium-containing materials (elements of irradiated nuclear fuel) at the bottom of the ponds and evaluation of surface activity of fission products. To solve this problem was used the underwater collimated spectrometric system on the basis of a semiconductor detector CdZnTe (volume of a crystal of 20 mm{sup 3}) and a multichannel analyzer InSpector 2000. The detector with the collimator is placed in the waterproof case on which the video camera fastens. The principle of detection of uranium-containing materials is based on the identification of the characteristic peaks in the spectra of uranium radiation measurements in the energy range 95 - 115 keV. The results of the most representative measurements at the bottom of reactor ponds are given. The received results are discussed; comparison of results between in-site pond measurements and gamma spectrometric and radiochemical analysis of the water in the lab is carried out. The received results will be used for scheduling on pond cleaning. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Defining WAC for interim storage dedicated to tritium decay - 15164

Considering the high mobility of tritium through the package in which it is contained, the new 50-year storage concepts proposed by the CEA currently provide a solution adapted to the management of waste with high tritium concentrations, associated with adapted disposal sites. The 50-year intermediate storage corresponds to 4 tritium radioactive periods i.e. a tritium reduction by a factor 16. The waste acceptance criteria (WAC) for this interim storage concept will take into account the safety of the facility, the reference scheme for the management of tritiated waste in France, and the criteria applicable at Andra disposal centers. This will lead to define a set of waste specifications that describe the generic criteria such as acceptable waste forms, general principles and specific issues, e.g. conditioning, radioactive content, tritium content, waste tracking system, and quality control. This paper details how the work by the CEA has led to a storage facility project that not only takes into account the specificity of tritium, but also the producers' needs and Andra's disposal requirements. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Thermo-Hydro-Geochemical Evolution Influences on the Concrete Cask in Long-Term Storage Facility of Spent Fuel - 16171

Due to humid environment and weather condition in Taiwan's island, as well as the acid rain environment resulting from sulfur dioxide emissions, the concrete cask might be damaged or degraded under the effect of humid, salt, acid rain, and sulfate attack on cementitious materials. These degradation factors could influence the safety design of the long-term spent fuel storage facility. Due to the long-term decay heat of spent fuel and severe environments to be encountered, the thermo-hydro-geochemical evolution could play an important role in the safety assessment of concrete-cask storage facility. The effects of humid, salt, acid rain, and sulfate attack on the degradation of cementitious materials of concrete-cask facility in thermo-hydro-geochemical evolution under rain water quality conditions have been investigated. The results show that the main processes responsible for concrete degradation are species induced from hydrogen ion, sulfate and chloride. For most storage and disposal casks and conditions, the American Concrete Institute nuclear safety code requirements (ACI-349 Appendix A) specify a bulk-concrete shield temperature limit of 150 deg. F (65.5 deg. C). However, localized temperatures at the inner walls of the shielding casks could reach 200-300 deg. F (93-149 deg. C). Simulation of geochemical degradation reactions for 100 years of cask storage under two temperature scenarios was performed. The results indicate that the hydrogen ion, sulfate anion, and chloride do not result in the dissolution of portlandite, or formation of ettringite and Friedel's salt. Therefore, these results indicate the concrete cask may remain in a durable condition. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Innovative Solutions for Loading Smaller Standardized Dry Storage Canister Systems for Used Nuclear Fuel - 16232

An integrated team lead by EnergySolutions has developed and evaluated design concepts and loading processes for standardized transportation, aging and disposal (STAD) canister systems for the dry storage of United States (US) commercial used nuclear fuel (UNF). These STADs would be smaller than the Dual Purpose Canisters (DPCs) currently in use for storage and transportation of UNF at the nuclear power plant (NPP) sites in the US, so it was necessary to study the operational requirements and impacts related to their implementation at the NPPs and develop innovative approaches to mitigate these impacts. This work was funded by the US Department of Energy (DOE) to support the DOE in evaluating the option of using standardized canister systems for storage, transport, and disposal of US commercial UNF as part of an integrated waste management system. The NPP utilities are currently placing UNF into increasingly large DPCs because this reduces loading times and associated worker dose uptake. However, whether large DPCs may be able to be directly disposed is not known at this time, and will depend in part on future geologic disposal concepts and the DPC heat content. The use of STAD canisters rather than DPCs at the NPP sites and/or at an interim storage facility could avoid a potential need to repackage the UNF for disposal but, to make STAD canisters attractive for use, ways need to be found to fill and seal them efficiently from an operational perspective. This paper describes the generic design for a small STAD canister system, the loading processes and process improvements that were identified for the small, medium and large STAD canister sizes, the methodology for, and results from, the assessment of the performance of the loading processes, and the practicality of the results versus NPP operating experience. The work that this paper reports thus reflects research and development efforts to explore technical concepts that could support future decision-making by DOE. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗