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Materials Data on Rb2S2O7 by Materials Project

Rb2S2O7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.95–3.29 Å. In the second Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.96–3.14 Å. There are two inequivalent S6+ sites. In the first S6+ site, S6+ is bonded to four O2- atoms to form corner-sharing SO4 tetrahedra. There are a spread of S–O bond distances ranging from 1.45–1.69 Å. In the second S6+ site, S6+ is bonded to four O2- atoms to form corner-sharing SO4 tetrahedra. There is three shorter (1.46 Å) and one longer (1.68 Å) S–O bond length. There are seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rb1+ and two S6+ atoms. In the second O2- site, O2- is bonded in a distorted single-bond geometry to three Rb1+ and one S6+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two Rb1+ and one S6+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to one Rb1+ and one S6+ atom. In the fifth O2- site, O2- is bonded in a distorted single-bond geometry to three Rb1+ and one S6+ atom. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to three Rb1+ and one S6+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to three Rb1+ and one S6+ atom.

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Materials Data on Rb2MgH4 by Materials Project

Rb2MgH4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent H1- atoms. There are two shorter (2.84 Å) and two longer (2.88 Å) Rb–H bond lengths. In the second Rb1+ site, Rb1+ is bonded to five H1- atoms to form RbH5 trigonal bipyramids that share corners with five equivalent MgH4 tetrahedra and corners with two equivalent RbH5 trigonal bipyramids. There are a spread of Rb–H bond distances ranging from 2.77–3.06 Å. Mg2+ is bonded to four H1- atoms to form MgH4 tetrahedra that share corners with five equivalent RbH5 trigonal bipyramids. There is two shorter (1.84 Å) and two longer (1.89 Å) Mg–H bond length. There are three inequivalent H1- sites. In the first H1- site, H1- is bonded in a distorted linear geometry to one Rb1+ and one Mg2+ atom. In the second H1- site, H1- is bonded in a 1-coordinate geometry to two equivalent Rb1+ and one Mg2+ atom. In the third H1- site, H1- is bonded in a 4-coordinate geometry to three Rb1+ and one Mg2+ atom.

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Materials Data on Rb2Ge2O5 by Materials Project

Rb2Ge2O5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Rb–O bond distances ranging from 2.77–3.11 Å. In the second Rb1+ site, Rb1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Rb–O bond distances ranging from 2.75–3.43 Å. There are two inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.70–1.80 Å. In the second Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.71–1.81 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a linear geometry to two Ge4+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Rb1+ and two Ge4+ atoms. In the third O2- site, O2- is bonded in a 1-coordinate geometry to three Rb1+ and one Ge4+ atom. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to three Rb1+ and one Ge4+ atom. In the fifth O2- site, O2- is bonded in a 2-coordinate geometry to two equivalent Rb1+ and two equivalent Ge4+ atoms. In the sixth O2- site, O2- is bonded in a 2-coordinate geometry to two equivalent Rb1+ and two equivalent Ge4+ atoms.

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Materials Data on RbH2SNO3 by Materials Project

RbNH2SO3 crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to one H1+ and seven O2- atoms. The Rb–H bond length is 3.09 Å. There are a spread of Rb–O bond distances ranging from 3.00–3.18 Å. N5+ is bonded in a distorted trigonal non-coplanar geometry to two H1+ and one S2- atom. Both N–H bond lengths are 1.03 Å. The N–S bond length is 1.68 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N5+ atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one Rb1+ and one N5+ atom. S2- is bonded in a tetrahedral geometry to one N5+ and three O2- atoms. There is two shorter (1.47 Å) and one longer (1.48 Å) S–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one S2- atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Rb1+ and one S2- atom.

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Materials Data on Rb2O by Materials Project

Rb2O is Baddeleyite-like structured and crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to four equivalent O2- atoms to form a mixture of corner and edge-sharing RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.91–2.98 Å. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.83–2.92 Å. O2- is bonded to seven Rb1+ atoms to form a mixture of distorted corner and edge-sharing ORb7 pentagonal bipyramids.

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Materials Data on Rb2MgH12(SeO7)2 by Materials Project

Rb2MgH12(SeO7)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rb1+ is bonded in a 9-coordinate geometry to one H1+ and eight O2- atoms. The Rb–H bond length is 3.11 Å. There are a spread of Rb–O bond distances ranging from 2.93–3.41 Å. Mg2+ is bonded in an octahedral geometry to six O2- atoms. There are a spread of Mg–O bond distances ranging from 2.07–2.11 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.68 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one Rb1+ and one O2- atom. The H–O bond length is 1.00 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. Se6+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of Se–O bond distances ranging from 1.67–1.69 Å. There are seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to one Mg2+ and two H1+ atoms. In the second O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Rb1+ and one Se6+ atom. In the third O2- site, O2- is bonded in a distorted water-like geometry to one Rb1+, one Mg2+, and two H1+ atoms. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+, one H1+, and one Se6+ atom. In the fifth O2- site, O2- is bonded in a distorted single-bond geometry to one Rb1+ and one Se6+ atom. In the sixth O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to one Rb1+, one Mg2+, and two H1+ atoms. In the seventh O2- site, O2- is bonded in a distorted single-bond geometry to one Rb1+ and one Se6+ atom.

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Materials Data on Rb2CoO3 by Materials Project

Rb2CoO3 crystallizes in the orthorhombic Cmce space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Rb–O bond distances ranging from 2.92–3.03 Å. In the second Rb1+ site, Rb1+ is bonded to seven O2- atoms to form distorted RbO7 pentagonal bipyramids that share corners with four equivalent RbO7 pentagonal bipyramids, a cornercorner with one CoO4 tetrahedra, edges with three equivalent RbO7 pentagonal bipyramids, and edges with four equivalent CoO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.92–3.01 Å. Co4+ is bonded to four O2- atoms to form CoO4 tetrahedra that share a cornercorner with one RbO7 pentagonal bipyramid, corners with two equivalent CoO4 tetrahedra, and edges with four equivalent RbO7 pentagonal bipyramids. There are a spread of Co–O bond distances ranging from 1.77–1.87 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Rb1+ and two equivalent Co4+ atoms. In the second O2- site, O2- is bonded in a distorted single-bond geometry to five Rb1+ and one Co4+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to five Rb1+ and one Co4+ atom.

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Materials Data on Rb2Sn2O3 by Materials Project

Rb2Sn2O3 crystallizes in the trigonal R-3m space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a hexagonal planar geometry to six equivalent O2- atoms. All Rb–O bond lengths are 3.12 Å. In the second Rb1+ site, Rb1+ is bonded in a hexagonal planar geometry to six equivalent O2- atoms. All Rb–O bond lengths are 3.13 Å. Sn2+ is bonded in a distorted T-shaped geometry to three equivalent O2- atoms. All Sn–O bond lengths are 2.08 Å. O2- is bonded to four Rb1+ and two equivalent Sn2+ atoms to form a mixture of distorted corner and face-sharing ORb4Sn2 octahedra. The corner-sharing octahedra tilt angles range from 0–60°.

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Materials Data on Rb3As by Materials Project

Rb3As is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a distorted single-bond geometry to four equivalent As3- atoms. There are one shorter (3.58 Å) and three longer (4.03 Å) Rb–As bond lengths. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent As3- atoms. All Rb–As bond lengths are 3.57 Å. As3- is bonded to eleven Rb1+ atoms to form a mixture of distorted edge and face-sharing AsRb11 trigonal bipyramids.

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Materials Data on Rb3PdF5 by Materials Project

Rb3PdF5 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a distorted q6 geometry to ten F1- atoms. There are two shorter (3.27 Å) and eight longer (3.29 Å) Rb–F bond lengths. In the second Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.79–3.03 Å. Pd2+ is bonded in a square co-planar geometry to four equivalent F1- atoms. All Pd–F bond lengths are 1.99 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 6-coordinate geometry to five Rb1+ and one Pd2+ atom. In the second F1- site, F1- is bonded to six Rb1+ atoms to form corner-sharing FRb6 octahedra. The corner-sharing octahedra tilt angles range from 0–33°.

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Materials Data on RbNaSnF6 by Materials Project

RbNaSnF6 crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.89–3.15 Å. In the second Rb1+ site, Rb1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Rb–F bond distances ranging from 3.03–3.30 Å. Na1+ is bonded to six F1- atoms to form NaF6 octahedra that share corners with four equivalent SnF6 octahedra and an edgeedge with one SnF6 octahedra. The corner-sharing octahedra tilt angles range from 29–49°. There are a spread of Na–F bond distances ranging from 2.23–2.49 Å. Sn4+ is bonded to six F1- atoms to form SnF6 octahedra that share corners with four equivalent NaF6 octahedra and an edgeedge with one NaF6 octahedra. The corner-sharing octahedra tilt angles range from 29–49°. There are a spread of Sn–F bond distances ranging from 2.00–2.03 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one Na1+, and one Sn4+ atom. In the second F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one Na1+, and one Sn4+ atom. In the third F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Rb1+, one Na1+, and one Sn4+ atom. In the fourth F1- site, F1- is bonded in a 2-coordinate geometry to two Rb1+, one Na1+, and one Sn4+ atom. In the fifth F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+, one Na1+, and one Sn4+ atom. In the sixth F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+, one Na1+, and one Sn4+ atom.

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Materials Data on Rb2Li2SiO4 by Materials Project

Rb2Li2SiO4 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Rb–O bond distances ranging from 2.93–3.26 Å. In the second Rb1+ site, Rb1+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Rb–O bond distances ranging from 2.80–3.37 Å. There are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Li–O bond distances ranging from 1.90–2.16 Å. In the second Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 tetrahedra that share corners with two equivalent SiO4 tetrahedra, an edgeedge with one LiO4 tetrahedra, and an edgeedge with one SiO4 tetrahedra. There are a spread of Li–O bond distances ranging from 1.96–2.02 Å. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with two equivalent LiO4 tetrahedra and an edgeedge with one LiO4 tetrahedra. There are a spread of Si–O bond distances ranging from 1.63–1.69 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to four Rb1+, two Li1+, and one Si4+ atom. In the second O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Rb1+, three Li1+, and one Si4+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to six Rb1+ and one Si4+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+, three Li1+, and one Si4+ atom.

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Materials Data on Rb2Li2GeO4 by Materials Project

Rb2Li2GeO4 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 2-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.91–3.43 Å. In the second Rb1+ site, Rb1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Rb–O bond distances ranging from 2.83–3.37 Å. There are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Li–O bond distances ranging from 1.91–2.20 Å. In the second Li1+ site, Li1+ is bonded to four O2- atoms to form distorted LiO4 trigonal pyramids that share corners with two equivalent GeO4 tetrahedra, an edgeedge with one GeO4 tetrahedra, and an edgeedge with one LiO4 trigonal pyramid. There are a spread of Li–O bond distances ranging from 1.96–2.04 Å. Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share corners with two equivalent LiO4 trigonal pyramids and an edgeedge with one LiO4 trigonal pyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.82 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to four Rb1+, two Li1+, and one Ge4+ atom. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+, three Li1+, and one Ge4+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to six Rb1+ and one Ge4+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+, three Li1+, and one Ge4+ atom.

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Materials Data on Rb2Zr2O5 by Materials Project

Rb2Zr2O5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to eight equivalent O2- atoms to form distorted RbO8 hexagonal bipyramids that share corners with eight equivalent RbO12 cuboctahedra, edges with four equivalent RbO8 hexagonal bipyramids, edges with eight equivalent ZrO5 square pyramids, and faces with two equivalent RbO12 cuboctahedra. All Rb–O bond lengths are 2.96 Å. In the second Rb1+ site, Rb1+ is bonded to twelve O2- atoms to form RbO12 cuboctahedra that share corners with four equivalent RbO12 cuboctahedra, corners with eight equivalent RbO8 hexagonal bipyramids, faces with four equivalent RbO12 cuboctahedra, faces with two equivalent RbO8 hexagonal bipyramids, and faces with eight equivalent ZrO5 square pyramids. There are four shorter (2.91 Å) and eight longer (3.21 Å) Rb–O bond lengths. Zr4+ is bonded to five O2- atoms to form distorted ZrO5 square pyramids that share corners with five equivalent ZrO5 square pyramids, edges with four equivalent RbO8 hexagonal bipyramids, and faces with four equivalent RbO12 cuboctahedra. There are one shorter (2.05 Å) and four longer (2.10 Å) Zr–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to four Rb1+ and two equivalent Zr4+ atoms. In the second O2- site, O2- is bonded to four equivalent Rb1+ and two equivalent Zr4+ atoms to form a mixture of distorted edge and corner-sharing ORb4Zr2 octahedra. The corner-sharing octahedral tilt angles are 0°.

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Materials Data on Rb2Pu2O5 by Materials Project

Rb2Pu2O5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Rb–O bond lengths are 2.98 Å. In the second Rb1+ site, Rb1+ is bonded to twelve O2- atoms to form RbO12 cuboctahedra that share corners with four equivalent RbO12 cuboctahedra, faces with four equivalent RbO12 cuboctahedra, and faces with eight equivalent PuO5 square pyramids. There are four shorter (3.07 Å) and eight longer (3.28 Å) Rb–O bond lengths. Pu4+ is bonded to five O2- atoms to form PuO5 square pyramids that share corners with five equivalent PuO5 square pyramids and faces with four equivalent RbO12 cuboctahedra. There are one shorter (2.17 Å) and four longer (2.19 Å) Pu–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to four Rb1+ and two equivalent Pu4+ atoms. In the second O2- site, O2- is bonded to four equivalent Rb1+ and two equivalent Pu4+ atoms to form a mixture of distorted corner and edge-sharing ORb4Pu2 octahedra. The corner-sharing octahedral tilt angles are 0°.

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Materials Data on RbLiH12Se3N4 by Materials Project

RbLiN4H12Se3 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two RbLiN4H12Se3 sheets oriented in the (0, 0, 1) direction. Rb1+ is bonded in a 11-coordinate geometry to three H1+ and eight Se2- atoms. There are a spread of Rb–H bond distances ranging from 3.26–3.29 Å. There are a spread of Rb–Se bond distances ranging from 3.52–3.80 Å. Li1+ is bonded in a tetrahedral geometry to four N2- atoms. There are a spread of Li–N bond distances ranging from 2.14–2.20 Å. There are four inequivalent N2- sites. In the first N2- site, N2- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N2- site, N2- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the third N2- site, N2- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the fourth N2- site, N2- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. There are twelve inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one Rb1+ and one N2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one Rb1+ and one N2- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one Rb1+ and one N2- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. There are three inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 2-coordinate geometry to two equivalent Rb1+ and two Se2- atoms. Both Se–Se bond lengths are 2.39 Å. In the second Se2- site, Se2- is bonded in a 4-coordinate geometry to three equivalent Rb1+ and one Se2- atom. In the third Se2- site, Se2- is bonded in a 2-coordinate geometry to three equivalent Rb1+ and one Se2- atom.

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Materials Data on RbUAuSe3 by Materials Project

RbAuUSe3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to two equivalent Au1- and eight Se2- atoms. Both Rb–Au bond lengths are 3.85 Å. There are a spread of Rb–Se bond distances ranging from 3.55–3.70 Å. U6+ is bonded to four equivalent Au1- and six Se2- atoms to form a mixture of corner and face-sharing UAu4Se6 octahedra. The corner-sharing octahedral tilt angles are 22°. All U–Au bond lengths are 3.49 Å. All U–Se bond lengths are 2.88 Å. Au1- is bonded in a 4-coordinate geometry to two equivalent Rb1+, four equivalent U6+, and four Se2- atoms. There are two shorter (2.57 Å) and two longer (2.70 Å) Au–Se bond lengths. There are two inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 6-coordinate geometry to three equivalent Rb1+, two equivalent U6+, and one Au1- atom. In the second Se2- site, Se2- is bonded in a 6-coordinate geometry to two equivalent Rb1+, two equivalent U6+, and two equivalent Au1- atoms.

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Materials Data on RbUTe3Au by Materials Project

RbAuUTe3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to two equivalent Au1- and eight Te2- atoms. Both Rb–Au bond lengths are 4.11 Å. There are a spread of Rb–Te bond distances ranging from 3.77–3.99 Å. U6+ is bonded to six Te2- atoms to form distorted UTe6 octahedra that share corners with two equivalent UTe6 octahedra, edges with two equivalent UTe6 octahedra, and edges with four equivalent AuRb2Te4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are two shorter (3.08 Å) and four longer (3.10 Å) U–Te bond lengths. Au1- is bonded to two equivalent Rb1+ and four Te2- atoms to form distorted AuRb2Te4 tetrahedra that share edges with four equivalent UTe6 octahedra and edges with two equivalent AuRb2Te4 tetrahedra. There are two shorter (2.77 Å) and two longer (2.82 Å) Au–Te bond lengths. There are two inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a 6-coordinate geometry to three equivalent Rb1+, two equivalent U6+, and one Au1- atom. In the second Te2- site, Te2- is bonded in a 6-coordinate geometry to two equivalent Rb1+, two equivalent U6+, and two equivalent Au1- atoms.

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