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At least 1,585 records · Page 88

Mitigating Structural Defects in Droop-Minimizing InGaN/GaN Quantum Well Heterostructures

Modern commercial InGaN/GaN blue LEDs continue to suffer from efficiency droop, a reduction in efficiency with increasing drive current. External quantum efficiency (EQE) typically peaks at low drive currents (< 10 A cm 2 ) and drops monotonically at higher current densities, falling to <85% of the peak EQE at a drive current of 100 A cm 2 . Mitigating droop-related losses will yield tremendous gains in both luminous efficacy (lumens/W) and cost (lumens/$). Such improvements are critical for continued large-scale market penetration of LED technologies, particularly in high-power and high flux per unit area applications. However, device structures that reduce droop typically require higher indium content and are accompanied by a corresponding degradation in material quality which negates the droop improvement via enhanced Shockley-Read-Hall (SRH) recombination. In this work, we use advanced characterization techniques to identify and classify structural defects in InGaN/GaN quantum well (QW) heterostructures that share features with low-droop designs. Using aberration-corrected scanning transmission electron microscopy (C s -STEM), we find the presence of severe well width fluctuations (WWFs) in a number of low droop device architectures. However, the presence of WWFs does not correlate strongly with external quantum efficiency nor defect densities measured via deep level optical spectroscopy (DLOS). Hence, performance losses in the heterostructures of interest are likely dominated by nanoscale point or interfacial defects rather than large-scale extended defects.

36 MATERIALS SCIENCE↗

Minimizing Grating Slope Errors in the IEX Monochromato at the Advanced Photon Source

The IEX beamline at the APS is currently in the commissioning phase. The energy resolution of the beamline was not meeting original specifications by several orders of magnitude. The monochromator, an in-focus VLS-PGM, is currently configured with a high and a medium-line-density grating. Experimental results indicated that both gratings were contributing to the poor energy resolution and this led to venting the monochromator to investigate. The initial suspicion was that a systematic error had occurred in the ruling process on the VLS gratings, but that proved to not be the case. Instead the problem was isolated to mechanical constraints used to mount the gratings into their respective side-cooled holders. Modifications were made to the holders to eliminate problematic constraints without compromising the rest of the design. Metrology performed on the gratings in the original and modified holders demonstrated a 20-fold improvement in the surface profile error which was consistent with finite element analysis performed in support of the modifications. Two gratings were successfully reinstalled and subsequent measurements with beam show a dramatic improvement in energy resolution.

Fisher, M. V.↗