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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,585 records · Page 88
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States

Here we confirm pyrolysis gases from prescribed burns conducted inpine forests with a shrub understory captured using a manual extraction device. The device selectively sampled emissions ahead of the flame front,minimizing the collection of oxidized gases, with the captured gases analyzed in the laboratory using infrared (IR) absorption spectroscopy. Results show that emission ratios (ERs) relative to CO for ethene and acetylene were significantly greater than in previous fire studies, suggesting that the sample device was able to collect gases predominantly generated prior to ignition. Additional evidence that ignition had not begun was corroborated by novel IR detections of several species, in particular naphthalene. With regards to oxygenated species, several aldehydes (acrolein, furaldehyde, acetaldehyde,formaldehyde) and carboxylic acids (formic, acetic) were all observed;results show that ERs for acetaldehyde were noticeably greater, while ERs for formaldehyde and acetic acid were lower compared to other studies. The acetylene-to-furan ratio also suggests that high-temperature pyrolysis was the dominant process generating the collected gases.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Seasonal variations in fire conditions are important drivers in the trend of aerosol optical properties over the south-eastern Atlantic

Abstract. From June to October, southern Africa produces one-third of the global biomass burning (BB) emissions by widespread fires. BB aerosols are transported westward over the south-eastern Atlantic with the mid-tropospheric winds, resulting in significant radiative effects. Ascension Island (ASI) is located midway between Africa and South America. From June 2016 to October 2017, a 17-month in situ observation campaign on ASI found a low single-scattering albedo (SSA) as well as a high mass absorption cross-section of black carbon (MACBC), demonstrating the strong absorbing marine boundary layer in the south-eastern Atlantic. Here we investigate the monthly variations of critical optical properties of BB aerosols, i.e. SSA and MACBC, during the BB seasons and the driving factors behind these variations. Both SSA and MACBC increase from June to August and decrease in September and October. The average SSA during the BB seasons is 0.81 at 529 nm wavelength, with the highest mean ∼ 0.85 in October and the lowest ∼ 0.78 in August. The absorption enhancement (Eabs) derived from the MACBC shows similar trends with SSA, with the average during the whole of the BB seasons at ∼ 1.96 and ∼ 2.07 in 2016 and 2017, respectively. As the Eabs is higher than the ∼ 1.5 commonly adopted value by climate models, this result suggests the marine boundary layer in the south-eastern Atlantic is more absorbing than model simulations. We find the enhanced ratio of BC to CO (ΔBC/ΔCO, equal to BC/ΔCO as the BC background concentration is considered to be 0) is well correlated with SSA and MACBC, providing a simple way to estimate the aerosol optical characteristics in the south-eastern Atlantic. The exponential function we proposed can approximate SSA and MACBC with BC/ΔCO, and when BC/ΔCO is small it can capture the rapid growth of SSA as BC/ΔCO decreases. BC/ΔCO is influenced by combustion conditions and aerosol scavenging. From the analysis of the location of BB, the primary source fuel, the water content in the fuel, combined with the mean cloud cover and precipitation in the transport areas of the BB plume, we conclude that the increase in BC/ΔCO from June to August is likely to be caused by burning becoming more flaming. The reduction in the water content of fuels may be responsible for the change in the burning conditions from June to August. The decrease in BC/ΔCO in September and October may be caused by two factors, one being a lower proportion of flaming conditions, possibly associated with a decrease in mean surface wind speed in the burning area, and the other being an increase in precipitation in the BB transport pathway, leading to enhanced aerosol scavenging, which ultimately results in an increase in SSA and MACBC.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Identification of gas-phase pyrolysis products in a prescribed fire: first detections using infrared spectroscopy for naphthalene, methyl nitrite, allene, acrolein and acetaldehyde

Volatile organic compounds (VOCs) are emitted from many sources, includingwildland fire. VOCs have received heightened emphasis due to such gases'influential role in the atmosphere, as well as possible health effects. Wehave used extractive infrared (IR) spectroscopy on recent prescribed burnsin longleaf pine stands and herein report the first detection of fivecompounds using this technique. The newly reported IR detections includenaphthalene, methyl nitrite, allene, acrolein and acetaldehyde. We discussthe approaches used for detection, particularly the software methods neededto fit the analyte and multiple (interfering) spectral components within theselected spectral micro-window(s). We also discuss the method's detectionlimits and related parameters such as spectral resolution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Data and code from: Multivariate bayesian regression model for predicting disposed ash composition at U.S. coal fired power stations

This dataset contains the code and data files needed for implementation of a Multivariate Bayesian Regression model, described in Jin et al. (2025), for the historical prediction of the chemical composition of disposed coal ash at U.S. coal fired power plants as a function of annualized coal purchase data. The integrated coal supply data file (CoalSupplyDataset.csv) represents a compilation of monthly fuel purchase records for the period 1973-2022 at major U.S. power stations. These records were obtained from the U.S. Energy Information Administration. The CSV file also contains, for each coal purchase record, the coal region of the mine as defined by the U.S. Geological Survey. Data entry errors and data gaps in the EIA records were corrected as described in Jin et al. This CSV file represents the integrated coal supply data after corrections were made. The model structure and fitting parameters are encoded in pickle file format (Bayesian.pkl). The model was developed with the coal supply data and coal ash composition data, apportioned according to the Stratified Shuffle Split for training and testing subsets. The model was built using Python and the PyMC library. Reference Publication: Jin, Z.; Huang, J.; Hower, J.C.; Hsu-Kim, H.(2025). Predictive Assessment of the Chemical Composition of Coal Ash in Reserve at U.S. Disposal Sites. Environmental Science & Technology.

Coal ash composition↗
NASA NTRS1964

Effects of Atmospheric Environment on Electrical Fire Hazards

In general, the problem of electrical fires involves the ignition and flammability parameters relating to the metallic conductor as well as to the insulating materials. The recent study of Klein has approached the problem by using three basic tests: (1) Determining the amount of current that causes wire to burn in various atmospheres, (2) measuring the effect of various atmospheres in propagating flame from a shorted wire to adjacent wires, and (3) measuring the effect of various atmospheres when extreme current is passed through wire.

Roth, Emanuel M.↗
NASA NTRS1964

Problems of Fire Prevention and Extinguishment in Space Cabins

The problems of prevention and extinguishment of fires in space cabins are, except for a few specific situations, not much different from those at sea level or in aircraft conditions. The unusual atmospheric environment and limitations of space and firefighting equipment compound the general problem. The zero-gravity environment modifies firefighting procedures in a rather profound way and will be given detailed treatment in this report.

CHEMICAL EXTINGUISHER↗
NASA NTRS1966

Infrared Television Used to Detect Hydrogen Fires

Standard, commercially available closed circuit television system detects hydrogen fires in test facilities. It sees in the infrared and displays on a standard cathode ray monitor screen.

Proffitt, Robert T.↗
NASA NTRS1966

Emergency escape system protects personnel from explosion and fire

Elevator-type emergency escape system evacuates personnel from tall structures, especially when the possibility of explosion or fire exists. The system consists of a spike shaped rescue cabin which descends along a vertical guide cable, penetrates the dome shaped roof of an underground blast shelter and stops in a deceleration bed of granular material.

Offik, W. G.↗