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At least 1,585 records · Page 88

Interfacial Solar Evaporation by a 3D Graphene Oxide Stalk for Highly Concentrated Brine Treatment

In this study, we demonstrate a 3-dimensional graphene oxide (3D GO) stalk that operates near the capillary wicking limit to achieve an evaporation flux of 34.7 kg m -2 h -1 under 1 sun conditions (1 kW/m 2 ). This flux represents nearly a 100 times enhancement over a conventional solar evaporation pond. Interfacial solar evaporation traditionally uses 2D evaporators to vaporize water using sunlight, but their low evaporative water flux limits their practical applicability for desalination. Some recent studies using 3D evaporators demonstrate potential for more efficient water transfer, but the flux improvement has been marginal because of a low evaporation area index (EAI), which is defined as the ratio of the total evaporative surface area to the projected ground area. By using a 3D GO stalk with an ultrahigh EAI of 70, we achieved nearly a 20-fold enhancement over a 2D GO evaporator. The 3D GO stalk also exhibited additional advantages including omnidirectional sunlight utilization, a high evaporation flux under dark conditions from more efficient utilization of ambient heating, a dramatic increase of the evaporation rate by introducing wind, and scaling resistance in evaporating brines with a salt content of up to 17.5 wt %. This performance makes the 3D GO stalk well suited for the development of a low-cost, reduced footprint technology for zero liquid discharge in brine management applications.

3D evaporator↗

The need for isotopic data on refractory elements in the solar wind

The Sun accounts for the bulk of material in the solar system. Information on the isotopic composition of elements in the solar wind is therefore essential for an understanding of the contribution made by each nucleogenetic component that has been identified in meteorites. Recent work suggests that isotopic data on the solar wind may also help us to understand the physical process that is concentrating light elements at the solar surface. Refractory and volatile elements would behave alike under the conditions of solar fractionation. Prolonged exposure of foils at 1AU from the sun would be a relatively inexpensively way to collect the quantity of solar wind implanted refractory elements needed to test this hypothesis.

Manuel, O. K.↗

Transmissive concentrated photovoltaic module with cooling system

A spectrum splitting, transmissive concentrating photovoltaic (tCPV) module is proposed and designed for a hybrid photovoltaic-solar thermal (PV/T) system. The system may be able to fully utilize the full spectrum of incoming sunlight. By utilizing III-V triple junction solar cells with bandgaps of approximately 2.1 eV, 1.7 eV, and 1.4 eV in the module, ultraviolet (UV) and visible light (in-band light) are absorbed and converted to electricity, while infrared (IR) light (out-of-band light) passes through and is captured by a solar thermal receiver and stored as heat. The stored heat energy may be dispatched as electricity or process heat as needed. The tCPV module may have an overall power conversion efficiency exceeding 43.5% for above bandgap (in-band) light under a standard AM1.5D solar spectrum with an average concentration ratio of 400 suns. Passive and/or active cooling methods may be used to keep cells below 110° C. while transmitting >75% of out-of-band light to the thermal receiver, which may attain thermal energy capture at temperatures as high as 500° C. or more. A transparent active cooling system may improve the CPV module efficiency by about 1% (absolute) relative to a passive cooling system by reducing the maximum cell working temperature by about 16° C.

Escarra, Matthew David↗

The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition

Abstract. In this study, we present and analyze the first continuous time series of relevant aerosol precursor vapors from the central Arctic (north of 80° N) during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. These precursor vapors include sulfuric acid (SA), methanesulfonic acid (MSA), and iodic acid (IA). We use FLEXPART simulations, inverse modeling, sulfur dioxide (SO2) mixing ratios, and chlorophyll a (chl a) observations to interpret the seasonal variability in the vapor concentrations and identify dominant sources. Our results show that both natural and anthropogenic sources are relevant for the concentrations of SA in the Arctic, but anthropogenic sources associated with Arctic haze are the most prevalent. MSA concentrations are an order of magnitude higher during polar day than during polar night due to seasonal changes in biological activity. Peak MSA concentrations were observed in May, which corresponds with the timing of the annual peak in chl a concentrations north of 75° N. IA concentrations exhibit two distinct peaks during the year, namely a dominant peak in spring and a secondary peak in autumn, suggesting that seasonal IA concentrations depend on both solar radiation and sea ice conditions. In general, the seasonal cycles of SA, MSA, and IA in the central Arctic Ocean are related to sea ice conditions, and we expect that changes in the Arctic environment will affect the concentrations of these vapors in the future. The magnitude of these changes and the subsequent influence on aerosol processes remains uncertain, highlighting the need for continued observations of these precursor vapors in the Arctic.

Boyer, Matthew↗

The Surface Chemical Composition of Lunar Samples and Its Significance for Optical Properties

The surface iron, titanium, calcium, and silicon concentration in numerous lunar soil and rock samples was determined by Auger electron spectroscopy. All soil samples show a large increase in the iron to oxygen ratio compared with samples of pulverized rock or with results of the bulk chemical analysis. A solar wind simulation experiment using 2 keV energy alpha -particles showed that an ion dose corresponding to approximately 30,000 years of solar wind increased the iron concentration on the surface of the pulverized Apollo 14 rock sample 14310 to the concentration measured in the Apollo 14 soil sample 14163, and the albedo of the pulverized rock decreased from 0.36 to 0.07. The low albedo of the lunar soil is related to the iron + titanium concentration on its surface. A solar wind sputter reduction mechanism is discussed as a possible cause for both the surface chemical and optical properties of the soil.

Gold, T.↗

Design for On-Sun Evaluation of Evaporator Receivers

A heat pipe designed for operation as a solar power receiver should be optimized to accept the solar energy flux and transfer this heat into a reactor. Optical properties of the surface, thermal conductance of the receiver wall, contact resistance of the heat pipe wick, and other heat pipe wick properties ultimately define the maximum amount of power that can be extracted from the concentrated sunlight impinging on the evaporator surface. Modeling of solar power receivers utilizing optical and physical properties provides guidance to their design. On-sun testing is another important means of gathering information on performance. A test rig is being designed and built to conduct on-sun testing. The test rig is incorporating a composite strip mirror concentrator developed as part of a Small Business Innovative Research effort and delivered to NASA Glenn Research Center. In the strip concentrator numerous, lightweight composite parabolic strips of simple curvature were combined to form an array 1.5 m x 1.5 m in size. The line focus of each strip is superimposed in a central area simulating a point of focus. A test stand is currently being developed to hold the parabolic strip concentrator, track the sun, and turn the beam downward towards the ground. The hardware is intended to be sufficiently versatile to accommodate on-sun testing of several receiver concepts, including those incorporating heat pipe evaporators. Characterization devices are also being developed to evaluate the effectiveness of the solar concentrator, including a receiver designed to conduct calorimetry. This paper describes the design and the characterization devices of the on-sun test rig, and the prospect of coupling the concentrated sunlight to a heat pipe solar power receiver developed as part of another Small Business Innovative Research effort.

Jaworske, Donald A.↗

Sputtered p-Type Cu x Zn 1– x S Back Contact to CdTe Solar Cells

As thin-film cadmium telluride (CdTe) solar cells gain prominence, one particular challenge is optimizing contacts and their interfaces to transfer charge without losses in efficiency. Back contact recombination is still significant and will prevent CdTe solar technology from reaching its full potential in device efficiency, and transparent back contacts have not been developed for bifacial solar technology or multijunction solar cells. To address these challenges, here we investigate sputtered Cu x Zn 1– x S as a p-type semi-transparent back contact material to thin-film polycrystalline CdTe solar cells at Cu concentrations x = 0.30, 0.45, and 0.60. This material is selected for its high hole conductivity (160–2120 S cm –1 ), wide optical band gap (2.25–2.75 eV), and variable ionization potential (approximately 6–7 eV) that can be aligned to that of CdTe. We report that without device optimization, CdTe solar cells with these Cu x Zn 1– x S back contacts perform as well as control cells with standard ZnTe:Cu back contacts. We observe no reduction in external quantum efficiency, low contact barrier heights of approximately 0.3 eV, and carrier lifetimes on par with those of baseline CdTe. These cells are relatively stable over one year in air, with V OC and efficiency of the x = 0.30 cell decreasing by only 1 and 3%, respectively. Using scanning electron microscopy and scanning transmission electron microscopy to investigate the Cu x Zn 1– x S/CdTe interface, we demonstrate that the Cu x Zn 1– x S layer segregates into a bilayer of Cu-Te-S and Zn-Cd-S, and thermodynamic reaction calculations support these findings. Despite its bilayer formation, the back contact still functions well. This investigation explains some of the physical mechanisms governing the device stack, inspires future work to understand interfacial chemistry and charge transfer, and elicits optimization to achieve higher-efficiency CdTe cells.

14 SOLAR ENERGY↗

Solar dynamic power for space station freedom

The Space Station Freedom Program is presently planned to consist of two phases. At the completion of Phase 1, Freedom's manned base will consist of a transverse boom with attached manned modules and 75 kW of available electric power supplied by photovoltaic (PV) power sources. In Phase 2, electric power available to the manned base will be increased to 125 kW by the addition of two solar dynamic (SD) power modules, one at each end of the transverse boom. Power for manned base growth beyond Phase 2 will be supplied by additional SD modules. Studies show that SD power for the growth eras will result in life cycle cost savings of $3 to $4 billion when compared to PV-supplied power. In the SD power modules for Space Station Freedom, an offset parabolic concentrator collects and focuses solar energy into a heat receiver. To allow full power operation over the entire orbit, the receiver includes integral thermal energy storage by means of the heat of fusion of a salt mixture. Thermal energy is removed from the receiver and converted to electrical energy by a power conversion unit (PCU) which includes a closed brayton cycle (CBC) heat engine and an alternator. The receiver/PCU/radiator combination will be completely assembled and charged with gas and cooling fluid on Earth before launch to orbit. The concentrator subassemblies will be pre-aligned and stowed in the orbiter bay before launch. On orbit, the receiver/PCU/radiator assembly will be installed as a unit. The pre-aligned concentrator panels will then be latched together and the total concentrator attached to the receiver/PCU/radiator by the astronauts. After final electric connections are made and checkout is complete, the SD power module will be ready for operation.

Labus, Thomas L.↗

Solar dynamic power for Space Station Freedom

The Space Station Freedom Program is presently planned to consist of two phases. At the completion of Phase 1, Freedom's manned base will consist of a transverse boom with attached manned modules and 75 kW of available electric power supplied by photovoltaic (PV) power sources. In Phase 2, electric power available to the manned base will be increased to 125 kW by the addition of two solar dynamic (SD) power modules, one at each end of the transverse boom. Power for manned base growth beyond Phase 2 will be supplied by additional SD modules. Studies show that SD power for the growth eras will result in life cycle cost savings of $3 to $4 billion when compared to PV-supplied power. In the SD power modules for Space Station Freedom, an offset parabolic concentrator collects and focuses solar energy into a heat receiver. To allow full power operation over the entire orbit, the receiver includes integral thermal energy storage by means of the heat of fusion of a salt mixture. Thermal energy is removed from the receiver and converted to electrical energy by a power conversion unit (PCU) which includes a closed brayton cycle (CBC) heat engine and an alternator. The receiver/PCU/radiator combination will be completely assembled and charged with gas and cooling fluid on earth before launch to orbit. The concentrator subassemblies will be pre-aligned and stowed in the orbiter bay before launch. On orbit, the receiver/PCU/radiator assembly will be installed as a unit. The pre-aligned concentrator panels will then be latched together and the total concentrator attached to the receiver/PCU/radiator by the astronauts. After final electric connections are made and checkout is complete, the SD power module will be ready for operation.

Labus, Thomas L.↗

Preliminary Error Budget for the Reflected Solar Instrument for the Climate Absolute Radiance and Refractivity Observatory

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) plans to observe climate change trends over decadal time scales to determine the accuracy of climate projections. The project relies on spaceborne earth observations of SI-traceable variables sensitive to key decadal change parameters. The mission includes a reflected solar instrument retrieving at-sensor reflectance over the 320 to 2300 nm spectral range with 500-m spatial resolution and 100-km swath. Reflectance is obtained from the ratio of measurements of the earth s surface to those while viewing the sun relying on a calibration approach that retrieves reflectance with uncertainties less than 0.3%. The calibration is predicated on heritage hardware, reduction of sensor complexity, adherence to detector-based calibration standards, and an ability to simulate in the laboratory on-orbit sources in both size and brightness to provide the basis of a transfer to orbit of the laboratory calibration including a link to absolute solar irradiance measurements. The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe high-accuracy, long-term climate change trends and to use decadal change observations as the most critical method to determine the accuracy of climate change projections such as those in the IPCC Report. A rigorously known accuracy of both decadal change observations as well as climate projections is critical in order to enable sound policy decisions. The CLARREO Project will implement a spaceborne earth observation mission designed to provide rigorous SI traceable observations (i.e., radiance, reflectance, and refractivity) that are sensitive to a wide range of key decadal change variables, including: 1) Surface temperature and atmospheric temperature profile 2) Atmospheric water vapor profile 3) Far infrared water vapor greenhouse 4) Aerosol properties and anthropogenic aerosol direct radiative forcing 5) Total and spectral solar irradiance 6) Broadband reflected and emitted radiative fluxes 7) Cloud properties 8) Surface albedo There are two methods the CLARREO mission will rely on to achieve these critical decadal change benchmarks: direct and reference inter-calibration. A quantitative analysis of the strengths and weaknesses of the two methods has led to the recommended CLARREO mission approach. The project consists of two satellites launched into 90-degree, precessing orbits separated by 90 degrees. The instrument suite receiver on each spacecraft includes one emitted infrared spectrometer, two reflected solar spectrometers: dividing the spectrum from ultraviolet through near infrared, and one global navigation receiver for radio occultation. The measurements will be acquired for a period of three years minimum, with a five-year lifetime goal, enabling follow-on missions to extend the climate record over the decades needed to understand climate change. The current work concentrates on the reflected solar instrument giving an overview of its design and calibration approach. The calibration description includes the approach to achieving an SI-traceable system on orbit. The calibration overview is followed by a preliminary error budget based on techniques currently in place at the National Institute of Standards and Technology (NIST).

Thome, Kurtis↗

Power System Options Evaluated for the Radiation and Technology Demonstration Mission

The Radiation and Technology Demonstration (RTD) Mission is under joint study by three NASA Centers: the NASA Johnson Space Center, the NASA Goddard Space Flight Center, and the NASA Glenn Research Center at Lewis Field. This Earth-orbiting mission, which may launch on a space shuttle in the first half of the next decade, has the primary objective of demonstrating high-power electric thruster technologies. Secondary objectives include better characterization of Earth's Van Allen trapped-radiation belts, measurement of the effectiveness of the radiation shielding for human protection, measurement of radiation effects on advanced solar cells, and demonstration of radiation-tolerant microelectronics. During the mission, which may continue up to 1 year, the 2000-kg RTD spacecraft will first spiral outward from the shuttle-deployed, medium-inclination, low Earth orbit. By the phased operation of a 10-kW Hall thruster and a 10-kW Variable Specific Impulse Magneto-Plasma Rocket, the RTD spacecraft will reach a low-inclination Earth orbit with a radius greater than five Earth radii. This will be followed by an inward spiraling orbit phase when the spacecraft deploys 8 to 12 microsatellites to map the Van Allen belts. The mission will conclude in low Earth orbit with the possible retrieval of the spacecraft by the space shuttle. A conceptual RTD spacecraft design showing two photovoltaic (PV) array wings, the Hall thruster with propellant tanks, and stowed microsatellites is presented. Early power system studies assessed five different PV array design options coupled with a 120-Vdc power management and distribution system (PMAD) and secondary lithium battery energy storage. Array options include (1) state-of-the-art 10-percent efficient three-junction amorphous SiGe thin-film cells on thin polymer panels deployed with an inflatable (or articulated) truss, (2) SCARLET array panels, (3) commercial state-of-the-art, planar PV array rigid panels with 25-percent efficient, three-junction GaInP2/GaAs/Ge solar cells, (4) rigid panels with 25-percent efficient, three-junction GaInP2/GaAs/Ge solar cells, in a 2 -concentrator trough configuration, and (5) thin polymer panels with 25-percent efficient, three-junction GaInP2/GaAs/Ge solar cells deployed with an inflatable (or articulated) truss. To assess the relative merits of these PV array design options, the study group developed a dedicated Fortran code to predict power system performance and estimate system mass. This code also modeled Earth orbital environments important for accurately predicting PV array performance. The most important environmental effect, solar cell radiation degradation, was calculated from electron-proton fluence input from the industry standard AE8/AP8 trapped radiation models and the concept of damage equivalence. Power systems were sized to provide 10 kW of thruster power and approximately 1 kW of spacecraft power at end of life. Of the five PV array design options, the option 1 (thin-film cells) power system was the most massive 590 kg, whereas the option 4 (trough concentrator) power system was the lightest 260 kg. Arguably, the lowest cost would come from the option 3 (commercial array panels) power system with an acceptable, albeit greater, system mass of 320 kg. Predicted power system performance during the spiral-out mission phase is shown the preceding graph for the option 5 (flexible-panel) array. From the results, the radiation-induced power loss over time is evident as the spacecraft slowly spirals outward through the trapped proton belt. The importance of the spiral trip time is also evident in the two curves representing 74-day and 182-day spiral-out periods. The longer spiral time introduces a beginning-of-life power oversizing penalty greater than 1 kW. Future studies will analyze power system performance and mass with a 50-Vdc power management and distribution architecture favorable to the VASIMR thruster and longer missions.

Kerslake, Thomas W.↗

Thermal response of solar receiver aperture plates during sun walk-off

The tracking mechanism for a point-focusing concentrator may be subject to failure. If this should occur, the solar image will travel across the aperture plate, and it may also impinge on the adjacent support structure. Such an event is called 'sun walk-off'. The present investigation is concerned with the transient response of different aperture plate materials to the intense heating produced in a typical walk-off situation for parabolic dish concentrators. Receivers for two solar module systems are considered, including a high-temperature receiver that utilizes a 2-milliradian (mrad) concentrator, and a lower-temperature receiver which is coupled with a 4-mrad concentrator. It is found that during a walk-off situation the solar image travels in a straight line in the radial direction. The results obtained for a copper aperture plate were disappointing. It appears that passive metallic plates without cooling or other protective support cannot withstand the intense heating.

Wen, L.↗

Multi-junction solar cells paving the way for super high-efficiency

In order to realize a clean energy society by using renewable energies, high-performance solar cells are a very attractive proposition. The development of high-performance solar cells offers a promising pathway toward achieving high power per unit cost for many applications. As state-of-the-art of single-junction solar cells are approaching the Shockley–Queisser limit of 32%–33%, an important strategy to raise the efficiency of solar cells further is stacking solar cell materials with different bandgaps to absorb different colors of the solar spectrum. The III–V semiconductor materials provide a relatively convenient system for fabricating multi-junction solar cells providing semiconductor materials that effectively span the solar spectrum as demonstrated by world record efficiencies (39.2% under one-sun and 47.1% under concentration) for six-junction solar cells. This success has inspired attempts to achieve the same with other materials like perovskites for which lower manufacturing costs may be achieved. Recently, Si multi-junction solar cells such as III–V/Si, II–VI/Si, chalcopyrite/Si, and perovskite/Si have become popular and are getting closer to economic competitiveness. Here, we discuss the perspectives of multi-junction solar cells from the viewpoint of efficiency and low-cost potential based on scientific and technological arguments and possible market applications. In addition, this article provides a brief overview of recent developments with respect to III–V multi-junction solar cells, III–V/Si, II–VI/Si, perovskite/Si tandem solar cells, and some new ideas including so-called 3rd generation concepts.

14 SOLAR ENERGY↗

High-performance solar collector

Evacuated all-glass concentric tube collector using air or liquid transfer mediums is very efficient at high temperatures. Collector can directly drive existing heating systems that are presently driven by fossil fuel with relative ease of conversion and less expense than installation of complete solar heating systems.

Beekley, D. C.↗

Characterization of deliberately nickel-doped silicon wafers and solar cells

Microstructural and electrical evaluation tests were performed on nickel-doped p-type silicon wafers before and after solar cell fabrication. The concentration levels of nickel in silicon were 5 x 10 to the 14th power, 4 x 10 to the 15th power, and 8 x 10 to the 15th power atoms/cu cm. It was found that nickel precipitated out during the growth process in all three ingots. Clumps of precipitates, some of which exhibited star shape, were present at different depths. If the clumps are distributed at depths approximately 20 micron apart and if they are larger than 10 micron in diameter, degradation occurs in solar cell electrical properties and cell conversion efficiency. The larger the size of the precipitate clump, the greater the degradation in solar cell efficiency. A large grain boundary around the cell effective area acted as a gettering center for the precipitates and impurities and caused improvement in solar cell efficiency. Details of the evaluation test results are given.

Salama, A. M.↗

Coronal mass ejections and major solar flares: The great active center of March 1989

The solar flare and coronal mass ejection (CME) events associated with the large and complex March 1989 active region are discussed. This active region gave us a chance to study the relation of CME with truly major solar flares. The work concentrates on questions of the relation of CMEs and flares to one another and to other types of activity on the Sun. As expected, some major (X-3B class) flares had associated CMEs. However, an unexpected finding is that others did not. In fact, there is strong evidence that the X4-4B flare of March 9th had no CME. This lack of a CME for such an outstanding flare event has important implications to theories of CME causation.Apparently, not all major flares cause CMEs or are caused by CMEs. The relations between CMEs and other types of solar activity are also discussed. No filament disappearances are reported for major CMEs studied here. Comparing these results with other studies, CMEs occur in association with flares and with erupting prominences, but neither are required for a CME. The relation between solar structures showing flaring without filament eruptions and structures showing filament eruptions without flares becomes important. The evolutionary relation between an active flaring sunspot region and extensive filaments without sunspots is reviewed, and the concept of an 'evolving magnetic structure' (EMS) is introduced. It is suggested that all CMEs arise in EMSs and that CMEs provide a major path through which azimuthal magnetic fields escape form the Sun during the solar cycle.

Feynman, Joan↗

Solar-wind interactions with the moon - Role of oxygen ions

The role of oxygen ions in the solar-wind interactions with the lunar surface due to tenuous atmosphere and magnetic field is examined. The interaction results in an absorption of the solar-wind corpuscles producing no upstream bowshock but a cavity downstream, and the oxygen ionic species undergo a set of reactions with the lunar minerals and the solar-wind derived trapped gases. The oxygen concentrations in the lunar surface material and the solar-wind species flux are discussed, noting that for the contributions of oxygen from the lunar surface grains to the atmosphere, the diffusion coefficients of oxygen atom and molecules should be known. The coefficients are calculated by using the apparent lifetimes of oxygen in the lunar material, and the atmospheric concentration of oxygen atoms and molecules near the lunar surface were compared with the Apollo 17 lunar orbital data.

Mukherjee, N. R.↗