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At least 1,567 records · Page 87

Compact in situ probe for magnetotransport measurements of 2D materials under variable tensile strain

The recent development of freestanding oxide membranes has opened new opportunities for strain engineering of transition metal oxides beyond values accessible in bulk samples. While a number of studies have been performed with fixed strain, the ability to dynamically control the strain state during measurement would be greatly enabling. To this end, we present an in situ uniaxial strain probe optimized for transport measurements of tensile-strained 2D or quasi-2D materials down to 2 K. Utilizing a flexible polyimide substrate as the stress transfer medium, our platform simplifies the sample preparation process and allows precise alignment of strain fields relative to the crystalline axes. An in situ optical microscope monitors the macroscopic strain state operando and makes it possible to complete an entire magnetotransport study at cryogenic temperatures under continuous strain variations. We demonstrate the capabilities of the probe on a freestanding LaNiO 3 membrane, where we induce tensile strain up to 8% and observe a corresponding strong transport anisotropy. In view of the rapid developments in low-dimensional materials synthesis and the plethora of novel quantum phenomena they exhibit, this strain probe provides general instrumentation for examining and controlling these properties via strain.

2D materials↗

Response of marine post-frontal clouds to Gulf Stream variability

Understanding how Gulf Stream variation influences cloud morphology is critical for evaluating cloud feedback in the western North Atlantic Ocean and beyond, where mesoscale air-sea interactions dominate. This study investigates the impact of altered mean sea surface temperature (SST) and SST gradients on post-frontal cloud characteristics during cold-air outbreaks, using the Weather Research and Forecasting (WRF) model. Three sensitivity experiments are conducted: a control simulation (default SST), Plus4 (uniform SST increase of 4 K), and Gradplus (SST gradient enhanced by 25 %, centered around mean SST). Results reveal distinctly different responses in boundary layer dynamics and cloud macro-physics. In Plus4, a warmer and moister boundary layer reduces total cloud cover but promotes larger cloud sizes and elongated cloud streets, with diminished liquid water and enhanced ice-phase hydrometeors. Conversely, Gradplus amplifies impacts in the upwind colder SST regions, yielding a drier, colder boundary layer, weaker energy transport, and higher liquid water path but reduced ice water content and cloud lines. Tracer analysis highlights that SST modifications alter airmass sources near cloud tops due to the entrainment of ambient air, with Plus4 amplifying boundary layer contributions to cloud-top regions. These findings underscore the spatially varying effects of SST gradients and mean SST on cloud organization and microphysics, emphasizing the need to resolve ocean-atmosphere coupling in global models to improve the prediction of marine cloud feedback under warming scenarios.

AIR-SEA INTERACTION↗

Delineating Variabilities of Groundwater Level Prediction Across the Agriculturally Intensive Transboundary Aquifers of South Asia

We report the groundwater depletion in South Asia’s Himalayan, transboundary Indus-Ganges-Brahmaputra-Meghna (IGBM) rivers basin is among the highest globally. Given the high irrigation demand and population, groundwater sustainability requires an improved understanding of groundwater systems for the accurate prediction of groundwater levels (GWLs). However, the prediction of groundwater system behaviors is a significant challenge since it is dominated by spatiotemporal and subsurface depth-dependent drivers. Earlier studies that address the challenges are mainly based on the short spatial and temporal extent and/or do not separate the renewable (i.e., shallow) vs nonrenewable (i.e., deeper) groundwater signals. Here, we first identified the variable importance of spatial and depth-dependent drivers on GWL in the IGBM basin. Our results indicate a greater influence of anthropogenic factors (i.e., widespread pumping and increased population) in most parts of the IGBM basin, except in the precipitation-dominated basin of the Brahmaputra. Our next purpose was to delineate a multifactorial approach for GWL prediction using the two most used machine learning models (i.e., support vector machine and feed-forward neural network) in the literature. In general, the machine learning model outputs show a good match in comparison to the GWL from the observation wells (n = 2303 distributed across India and Bangladesh) with some limitations in areas with increased groundwater irrigation. We separately compared the results from shallow (<35 m) and deep (>35 m) observation wells, emphasizing the significance of deep groundwater pumping. Our approach highlights the importance of spatiotemporal to multidepth factors in GWL prediction and can be adopted in other parts of the globe to predict GWLs.

54 ENVIRONMENTAL SCIENCES↗

Causal Directions Matter: How Environmental Factors Drive Convective Cloud Detrainment Heights

This study investigates how environmental factors influence the level of maximum detrainment (LMD) in deep convective clouds. Through a novel application of the Linear Non‐Gaussian Acyclic Model (LiNGAM), we discover causal structures between environmental variables and LMD, observed at six tropical sites operated by the Atmospheric Radiation Measurement (ARM) user facility. LiNGAM effectively identifies causal directions among variables of interest, revealing robust relationships such as those among the lifting condensation level (LCL), level of free convection (LFC), and convective inhibition (CIN), aligning with prior knowledge. Relative humidity is shown to directly influence LMD; however, this relationship exhibits strong nonlinearity and becomes difficult to detect when the contrast between oceanic and continental environments is excluded from the analysis. This study highlights the importance of establishing causal relationships before performing statistical inference.

54 ENVIRONMENTAL SCIENCES↗

Combined Effects of Stream Hydrology and Land Use on Basin‐Scale Hyporheic Zone Denitrification in the Columbia River Basin

Abstract Denitrification in the hyporheic zone (HZ) of river corridors is crucial to removing excess nitrogen in rivers from anthropogenic activities. However, previous modeling studies of the effectiveness of river corridors in removing excess nitrogen via denitrification were often limited to the reach‐scale and low‐order stream watersheds. We developed a basin‐scale river corridor model for the Columbia River Basin with random forest models to identify the dominant factors associated with the spatial variation of HZ denitrification. Our modeling results suggest that the combined effects of hydrologic variability in reaches and substrate availability influenced by land use are associated with the spatial variability of modeled HZ denitrification at the basin scale. Hyporheic exchange flux can explain most of spatial variation of denitrification amounts in reaches of different sizes, while among the reaches affected by different land uses, the combination of hyporheic exchange flux and stream dissolved organic carbon (DOC) concentration can explain the denitrification differences. Also, we can generalize that the most influential watershed and channel variables controlling denitrification variation are channel morphology parameters (median grain size (D50), stream slope), climate (annual precipitation and evapotranspiration), and stream DOC‐related parameters (percent of shrub area). The modeling framework in our study can serve as a valuable tool to identify the limiting factors in removing excess nitrogen pollution in large river basins where direct measurement is often infeasible.

54 ENVIRONMENTAL SCIENCES↗

Standardising the “Gregory method” for calculating equilibrium climate sensitivity

The equilibrium climate sensitivity (ECS) – the equilibrium global mean temperature response to a doubling of atmospheric CO 2 – is a high-profile metric for quantifying the Earth system's response to human-induced climate change. A widely applied approach to estimating the ECS is the “Gregory method” (Gregory et al., 2004), which uses an ordinary least squares (OLS) regression between the net radiative flux, N, and surface air temperature anomalies, ΔT, from a 150 year experiment in which atmospheric CO 2 concentrations are quadrupled. The ECS is determined by extrapolating the linear fit to N=0, i.e. the ΔT-intercept, indicating the point at which the system is back in equilibrium. This method has been used to compare ECS estimates across the CMIP5 and CMIP6 ensembles and will likely be a key diagnostic for CMIP7. Despite its widespread application, there is little consistency or transparency between studies in how the climate model data is processed prior to the regression, leading to potential discrepancies in ECS estimates. We identify 32 alternative data processing pathways, varying by differences in global mean weighting, net radiative flux variable, anomaly calculation method, and linear regression fit. Using 44 CMIP6 models, we systematically assess the impact of these choices on ECS estimates and calculate uncertainty ranges using two bootstrap approaches. While the inter-model ECS range is insensitive to the data processing pathway, individual outlier models exhibit notable differences. Approximating a model's native grid cell area (if irregular) with cosine of the latitude can decrease the ECS by 11 %, the choice of N-variable can change the ECS by 6 %, and some anomaly calculation methods can introduce spurious temporal correlations in the processed data. Beyond data processing choices, we also evaluate an alternative linear regression method – total least squares (TLS) – which has a more statistically robust basis than OLS. However, for consistency with previous literature, and given TLS may reduce the ECS compared to OLS (by up to 24 %), thereby making a known bias in the Gregory method worse, we do not feel there is sufficient clarity to recommend a transition to TLS in all cases. To improve reproducibility and comparability in future studies, we recommend a standardised Gregory method: weighting the global mean by cell area, using the top of the atmosphere (as opposed to the top of model) N-variable, and calculating anomalies by first applying a rolling average to the preindustrial control timeseries then subtracting from the raw CO 2 quadrupling experiment. This approach accounts for model drift while reducing noise in the data to best meet the pre-conditions of the linear regression. While CMIP6 results of the multi-model mean ECS appear insensitive to these processing choices, similar assumptions may not hold for CMIP7, underscoring the need for standardised data preparation in future climate sensitivity assessments.

Geosciences↗

Implementation of Sub‐Grid Scale Temperature Perturbations Induced by Non‐Orographic Gravity Waves in WACCM6

Abstract Atmospheric gravity waves can play a significant role on atmospheric chemistry through temperature fluctuations. A recent modeling study introduced a method to implement subgrid‐scale orographic gravity‐wave‐induced temperature perturbations in the Whole Atmosphere Community Climate Model (WACCM). The model with a wave‐induced temperature parameterization was able to reproduce for example, the influence of mountain wave events on atmospheric chemistry, as highlighted in previous literature. Here we extend the subgrid‐scale wave‐induced temperature parameterization to also include non‐orographic gravity waves arising from frontal activity and convection. We explore the impact of these waves on middle atmosphere chemistry, particularly focusing on reactions that are strongly sensitive to temperature. The non‐orographic gravity waves increase the variability of chemical reaction rates, especially in the lower mesosphere. As an example, we show that this, in turn, leads to increases in the daytime ozone variability. To demonstrate another impact, we briefly investigate the role of non‐orographic gravity waves in cirrus cloud formation in this model. Consistent with findings from the previous study focusing on orographic gravity waves, non‐orographic waves also enhance homogeneous nucleation and increase cirrus clouds. The updated method used enables the global chemistry‐climate model to account for both orographic and non‐orographic gravity‐wave‐induced subgrid‐scale dynamical perturbations in a consistent manner.

Yook, Simchan [Department of Earth Atmospheric and↗

The inclusion of uncertainty in circularity transition modeling: A case study on wind turbine blade end-of-life management

The transition to a more circular economy (CE) is complex and hard to predict, including in sustainable energy technologies. Many sources of uncertainty make it challenging to model CE scenarios and their potential benefits. As an example, the high variability in costs and revenues of different recycling options makes future wind turbine blade recycling highly uncertain. To better understand this challenge, the circular economy, life cycle assessment and visualization (CELAVI) framework - a discrete event simulation and life cycle assessment framework - is modified to incorporate uncertainty analysis capabilities. Moreover, a 3-step procedure that covers different aspects of uncertainty in CE studies and includes a Monte-Carlo analysis is proposed. The procedure is tested in a case study on wind turbine blade recycling using CELAVI. Results highlight that grinding and landfilling costs are the most influential parameters for wind power circularity. The model's output coefficients of variation (when input parameter uncertainties are propagated) are between 92% and 384% depending on the indicator. The approach developed in this study may help researchers and decision-makers who study circularity prioritize their data collection effort. Finally, our method contributes to a mounting yet critical body of research: the measurement of uncertainty in circularity transitions.

17 WIND ENERGY↗

Sparse Control Synthesis for Uncertain Responsive Loads With Stochastic Stability Guarantees

In this report, recent studies have demonstrated the potential of flexible loads in providing frequency response services, predominantly due to their availability and cost-effectiveness. However, uncertainty and variability in various weather-related and end-use behavioral factors often impact the reliability of demand-side control performance. This work addresses this problem with the design of a demand-side control to achieve frequency response under load uncertainties. Our approach involves modeling the load uncertainties via stochastic processes that appear as both multiplicative and additive in the power system dynamics. Recently developed mean square exponential stability (MSES) results for continuous-time linear stochastic systems are applied to pose the control synthesis problem which results in an LMI-based optimization problem. Additional costs and constraints are added to the LMI-based controller synthesis to ensure MSES, improve closed-loop transient performance, maximize tolerable uncertainties, and promote sparsity in the controller. Additionally, the fundamental limitations between the tolerable uncertainties and control efforts while ensuring MSES are discussed. Further, the control synthesis problem for the case of the full-state measurement is generalized to the case of partial-state measurements. The proposed control synthesis is illustrated on an IEEE 39 bus system with rigorous studies to demonstrate the role of sparsity, closed-loop transient performance, tolerable uncertainties, and control efforts while ensuring MSES and achieving frequency response.

42 ENGINEERING↗

Indications of a Decrease in the Depth of Deep Convective Cores with Increasing Aerosol Concentration during the CACTI Campaign

Abstract An aerosol indirect effect on deep convective cores (DCCs), by which increasing aerosol concentration increases cloud-top height via enhanced latent heating and updraft velocity, has been proposed in many studies. However, the magnitude of this effect remains uncertain due to aerosol measurement limitations, modulation of the effect by meteorological conditions, and difficulties untangling meteorological and aerosol effects on DCCs. The Cloud, Aerosol, and Complex Terrain Interactions (CACTI) campaign in 2018–19 produced concentrated aerosol and cloud observations in a location with frequent DCCs, providing an opportunity to examine the proposed aerosol indirect effect on DCC depth in a rigorous and robust manner. For periods throughout the campaign with well-mixed boundary layers, we analyze relationships that exist between aerosol variables (condensation nuclei concentration > 10 nm, 0.4% cloud condensation nuclei concentration, 55–1000-nm aerosol concentration, and aerosol optical depth) and meteorological variables [level of neutral buoyancy (LNB), convective available potential energy, midlevel relative humidity, and deep-layer vertical wind shear] with the maximum radar-echo-top height and cloud-top temperature (CTT) of DCCs. Meteorological variables such as LNB and deep-layer shear are strongly correlated with DCC depth. LNB is also highly correlated with three of the aerosol variables. After accounting for meteorological correlations, increasing values of the aerosol variables [with the exception of one formulation of aerosol optical depth (AOD)] are generally correlated at a statistically significant level with a warmer CTT of DCCs. Therefore, for the study region and period considered, increasing aerosol concentration is mostly associated with a decrease in DCC depth.

54 ENVIRONMENTAL SCIENCES↗

Quantification of energy and cost reduction from decreasing dissolved oxygen levels in full‐scale water resource recovery facilities

Abstract Aeration systems often lack the efficiency to maintain a desired residual dissolved oxygen (DO) concentration in the tank in part because little consideration is given to the dynamic daily and seasonal loading conditions. Although advanced aeration controllers exist, the majority of plants have DO set points typically based on common practice and literature values rather than site‐specific conditions, which can result in DO set points higher than those necessary to meet treatment objectives. DO set point reduction strategies have primarily been proposed through either static or dynamic simulations. In this study, the substantial improvements associated with DO set point reduction are demonstrated at full scale. A yearlong characterization of full‐scale aeration dynamics captured the effect of diurnal and seasonal fluctuations on oxygen transfer and energy demand and so facilitated the estimation of the potential savings of DO reduction strategies. Full‐scale validation provided direct evidence of DO reduction strategies inducing an overall enhancement of oxygen transfer efficiency along the different bioreactors, while confirming that energy savings as high as 20% were feasible. This study quantifies the influence of oxygen transfer efficiency on operating choices and site‐specific conditions (control strategy, loading conditions, and influent flow variability). Practitioner points We quantified the energy reduction and cost savings associated with a DO reduction in an aeration tank. For each 0.2 mg/L of DO decreased, the average power demand reduction per unit water treated exceeded 17%. Field measurements of dynamic alpha values eliminate the uncertainty in estimating aeration energy and cost savings from DO variations.

Pasini, Federico↗

Mouse models of Ebola virus tolerance and lethality: characterization of CD-1 mice infected with wild-type, guinea pig-adapted, or mouse-adapted virus

Development of lethal models of Ebola virus disease has been achieved by the serial passage of virus isolates from human cases in mice and guinea pigs. Use of mice infected with non-adapted virus has been limited due to the absence of overt clinical disease. In recent years, newly recognized sequelae identified in human cases has highlighted the importance of continued investigations of non-lethal infection both in humans and animal models. Here, we revisit the use of rodent-adapted and non-adapted Ebola virus (EBOV) in mice to investigate infection tolerance and future utility of these models in pathogenesis and therapeutic intervention studies. We found that like non-adapted wild-type EBOV, guinea pig-adapted EBOV resulted in widespread tissue infection, variably associated with tissue pathology, and alterations in clinical and immunological analytes in the absence of overt disease. Notably, infection with either non-lethal variant did not greatly differ from lethal mouse-adapted EBOV until near the time end-point criteria are reached in these mice. Furthermore, these data support future investigations of pathogenesis, convalescence, and sequelae in mouse models of virus tolerance.

60 APPLIED LIFE SCIENCES↗

Properties and reaction mechanism of phosphoric acid activated metakaolin geopolymer at varied curing temperatures

Reaction mechanism of phosphoric activated metakaolin is studied by techniques of calorimetry, ICP-OES, FTIR and NMR taking curing temperature and [H{sub 3}PO{sub 4}] as variables. A two-stage curing method including pre-curing at 40 °C for 24 h and second curing at 60/80 °C for another 24 h effectively mitigates thermal-cracking of the obtained silico-aluminate phosphate (SAP) samples, whose maximum compressive strength reaches 120 MPa. Dealumination of metakaolin in H{sub 3}PO{sub 4} solution produces low aluminate-containing silicate units and subsequently condensation of silicate tetrahedrons occurs. Higher temperature and H{sub 3}PO{sub 4} concentration accelerate the two processes. After complete reaction, A{sub VI} structure from metakaolin disappears and the dissolved Al preferably forms Al{sub VI}-O-P units. During reaction, metastable P-O-P intermediate appears in SAPs with higher P/Al ratio and finally transforms into Al-O-P structure upon PO{sub 4}{sup 3−} consumption. Phosphate units as P(OAl){sub x}(H{sub 2}O){sub 4-x} are connected with Si or Al structure units. Major structural units of the SAPs include Al-O-P, Si-O-P, Si-O-Si, and Si-O-Al.

36 MATERIALS SCIENCE↗

Parallel derivative-free optimization for simulation-based design of behind-the-meter energy systems

In this work, the integrated design and dispatch of behind-the-meter or distributed resources (e.g. stationary battery storage and solar PV generation) is considered. A simulation-based framework is employed, generating high-fidelity results with closed-loop predictive control at a fine resolution, at the expense of high computational cost (several minutes to a few hours per design point). To address this challenge, parallel derivative-free design methods are considered. Four methods are compared, including state-of-the-art surrogate-based methods (Radial-Basis Functions and Gaussian processes) and sampling strategies, an evolutionary-based method, and a simple sequential grid refinement method. As a case study, two types of design problem with increasing complexity are considered, namely, the design of behind-the-meter resources (three design variables) and the inclusion of grid capacity (four design variables). The second yields a constrained design problem for which violations can only be determined after solving the computationally expensive simulation. For the three-dimensional case, all methods present a good performance, achieving a solution within 1% of the optimum after the first iteration, with the sequential grid refinement exhibiting the fastest convergence and achieving the best final objective value. This indicates that the parallel evaluation of multiple sampling points may be more important than the choice of method for small decision spaces. For the four-dimensional constrained case, the Genetic Algorithm presents the best tradeoff between performance and computational effort, while the rough objective function terrain generated by constraint violation penalties reduces the performance of surrogate-based methods. Contour plots with flat regions indicate flexibility in the optimal design and highlight the importance of characterizing the solution space.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Predictive dynamic wetting, fluid–structure interaction simulations for braze run-out

Brazing and soldering are metallurgical joining techniques that use a wetting molten metal to create a joint between two faying surfaces. Here, the quality of the brazing process depends strongly on the wetting properties of the molten filler metal, namely the surface tension and contact angle, and the resulting joint can be susceptible to various defects, such as run-out and underfill, if the material properties or joining conditions are not suitable. In this work, we implement a finite element simulation to predict the formation of such defects in braze processes. This model incorporates both fluid–structure interaction through an arbitrary Eulerian–Lagrangian technique and free surface wetting through conformal decomposition finite element modeling. Upon validating our numerical simulations against experimental run-out studies on a silver-Kovar system, we then use the model to predict run-out and underfill in systems with variable surface tension, contact angles, and applied pressure. Finally, we consider variable joint/surface geometries and show how different geometrical configurations can help to mitigate run-out. This work aims to understand how brazing defects arise and validate a coupled wetting and fluid–structure interaction simulation that can be used for other industrial problems.

36 MATERIALS SCIENCE↗

Numerical assessment of triply periodic minimal surfaces for direct air capture of carbon dioxide

Direct air capture (DAC) systems often consist of packing material wetted by a capture fluid that reacts with CO 2 in the airstream. The efficiency of the contactor is determined by a complex relationship of fluid dynamics, heat and mass transfer, contactor geometry, and chemical properties. The efficiency of the contactor must be balanced with other factors, primarily pressure drop through the system. Triply periodic minimal surfaces (TPMS) are a class of differential surfaces that have been explored in multiple engineering applications and have been shown to exhibit excellent performance when used in heat exchangers. Their tortuous path provides a high surface-to-volume ratio and favorable trade-off between contact area and pressure drop. In this work, a gyroid-type TPMS contactor was evaluated using computational fluid dynamics for a variety of geometric parameters to explore the potential benefit of TPMS shapes for DAC applications. A thin-film model was employed to model the flow and distribution of the capture solvent, allowing efficient simulations of TPMS structures at scale by eliminating the need for a computationally intensive interface capturing method. A liquid-gas mass transfer model was implemented in the commercial software STAR-CCM+ and used to predict the CO 2 capture efficiency and study the trade-off between capture performance and pressure drop through analysis of capture rates, mass transfer coefficients, and other relevant variables. TPMS contactors with a variety of geometric parameters and two capture solvent options were investigated to determine the effect of design choices on the operational performance of DAC systems. In conclusion, results showed that while contactor geometry is the dominant factor in efficiency and pressure drop, the physiochemical properties of the solvent are an important secondary influence on the contactor performance.

CFD↗

Life cycle assessment of co-firing biomass at coal-fired power plants with carbon capture and storage toward net-zero emissions

Co-firing biomass with carbon capture and storage (BECCS) offers a technological option to decarbonize coal-fired power plants toward net-zero emissions. This study estimates the life cycle emissions of co-firing biomass at coal-fired power plants with CCS and quantifies its variability and uncertainty. Deployment of co-firing BECCS at coal-fired power plants can significantly reduce the life cycle emissions toward the net-zero target but lower the power plant performance, which vary with numerous factors, including coal type, biomass type, co-firing level, and CO 2 capture rate. The breakeven co-firing levels required for biomass at coal-fired power plants with 90 % CO 2 capture to reach net-zero emissions fall with a range roughly from 15 % to 25 % on an energy basis, depending on coal and biomass types. Increasing the CO 2 capture rate from 90 % to 95 % can lower the breakeven co-firing levels by about 5 to 8 percentage points for the biomass resources of interest, which can lower reliance on biomass resources and facilitate large-scale deployment of co-firing BECCS in fossil-rich regions but with limited biomass resources. Furthermore, findings improve the understanding of the techno-environmental performance of co-firing BECCS and inform strategic planning decisions on net-zero emissions in the coal-fired power sector.

Breakeven co-firing level↗