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At least 1,567 records · Page 87

Optically Stimulated Luminescence Based Optical Data Storage

We design, built, and demonstrated a photocathode based pulsed electron system to produce optically stimulated luminescence (OSL) for next generation data storage. We successfully demonstrated 10ps pulses of up to 10 6 electrons and used those pulses to form OSL patterns in LiF without causing mechanical damage. By adjusting the accelerating voltage, we were able to vary the ratio of red to green optical emission, demonstrating a potential path for increasing storage density using orthogonal encoding. We also modeled a new approach to reading data that exploits the unique nature of OSL based data storage where the writing and reading processes have different size scales. Based on the technical demonstrations, we developed a roadmap to increase the storage density beyond 50TB using a standard 5.25” optical storage disc.

36 MATERIALS SCIENCE↗

FY18 Status Report: SNL Research into Stress Corrosion Cracking of SNF Interim Storage Canisters

This progress report describes work done in FY18 at Sandia National Laboratories (SNL) to assess the localized corrosion performance of container/cask materials used in the interim storage of spent nuclear fuel (SNF). The work focuses on stress corrosion cracking (SCC), the only mechanism by which a through-wall crack could potentially form in a canister outer wall over time intervals that are shorter than possible dry storage times. Work in FY18 continued several studies initiated in FY17 that are aimed at refining the understanding of the chemical and physical environment on canister surfaces, and evaluating the relationship between chemical and physical environment and the form and extent of corrosion that occurs. The SNL canister environment work focused on evaluating the stability of sea-salt deliquescent brines on the heated canister surface; an additional opportunity to analyze dusts sampled from an inservice spent nuclear fuel storage canister also arose. The SNL corrosion work focused predominantly on pitting corrosion, a necessary precursor for SCC, and process of pit-to-crack transition. SNL is collaborating with several university partners to investigate SCC crack growth experimentally, providing guidance for design and interpretation of experiments. The scope of these efforts targets near-marine Independent Spent Fuel Storage Installation environments which are generally considered to be most aggressive for pitting and SCC. Work to define the chemical and physical environment that could develop on storage canister surfaces in near-marine environments included experiments to evaluate the thermal stability of magnesium chloride brines, representative of the first brines to form when sea-salts deliquesce, with the specific goal of understanding and interpreting results of sea-salt and magnesium chloride corrosion experiments carried out under accelerated conditions. The experiments showed that magnesium chloride brines, and by extension, low RH sea-salt deliquescent brines, are not stable at elevated temperatures, losing chloride via degassing of HC1 and conversion to Mg-hydroxychlorides and carbonates. The experiments were carried out on an inert substrate to eliminate the effects of corrosion reactions, simulating brine stabilities in the absence of, or prior to, corrosion. Moreover, analysis of salts recovered from actively corroding metal samples shows that corrosion also supports or drives conversion of magnesium chloride or sea-salt brines to less deliquescent salts. This process has significant implications on corrosion, as the secondary phases are less deliquescent than magnesium chloride; the conversion reaction results in decreases in brine volume, and potentially results in brine dry-out. The deliquescence properties of these reaction products will be a topic of active research in FY19.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Comparative Analysis of Transport and Storage Options from a CO 2 Source Perspective

This analysis evaluated integrated CCS costs (i.e., capture, transport, and storage) from the perspective of a CO 2 source. Capture costs for sources with annual CO 2 capture rates from 0.65 to 3.90 Mt were based on two NETL reports. Transportation costs from source to storage reservoir were modeled for two pipelines systems (dedicated and trunkline) using the FE/NETL CO 2 Transport Cost Model. Storage costs were modeled in dome and regional dip structural settings for two reservoirs in the Rose Run Formation, three within the Mt. Simon, one in the Lower Tuscaloosa, and one in the Frio using the FE/NETL CO 2 Saline Storage Cost Model. A paper with the same name and information as well as additional details on this analysis was published in The International Journal of Greenhouse Gas Control along with a supplementary document that provides additional material (i.e., key parameters used in the models for obtaining transport and storage costs and CCS cost and pipeline results).

03 NATURAL GAS↗

Induction Heating for Tritium Storage Beds (FY19 PDRD Project Summary Report)

Metal hydride beds used for storing hydrogen isotopes at the Savannah River Site are conductively heated and cooled to desorb and absorb gases during storage cycling. While several storage bed configurations have been utilized over the years, many achieve heating by utilizing electric cartridge heaters positioned laterally along the longest axis of the storage bed (FACE Gen 2 Beds). Others achieve heating and cooling through hot and cold nitrogen flow (Gen 1 Beds). While these beds/heating configurations are well-designed for storage cycling operations, it is unclear if they can be regenerated to operating conditions once too much helium has accumulated in them. Full regeneration of hydride beds occurs around 625 - 650 °C. It is unclear if the currently employed electric cartridge heaters in Gen 2 beds can reach these temperatures. Furthermore, since swelling can occur during routine heating operations, it is unclear if existing cartridge heaters in Gen 2 beds can be swapped for higher-power cartridges that can reach 625 - 650 °C . Similarly, nitrogen air flow (to the best of our knowledge) cannot cause Gen 1 beds to reach these temperatures. Thus, existing Gen 1 and Gen 2 beds need to be heated through an alternative method to removal helium, so the beds can either return to normal operation or be disposed of. The goal of this PDRD was to investigate if induction heating can be used for various heating processes involving hydride storage beds (e.g. regeneration, gas cycling, helium heel removal). In the original call for proposals, this PDRD fell under "Gas Processing" area of interest # 3: "Develop methods to deploy alternate ways to heat existing process equipment to minimize impact to glove box environment."

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advanced Concepts for Dry Storage Cask Thermal-Hydraulic Testing

The purpose of this report is to review technical issues relevant to the performance evaluation of dry storage systems during vacuum drying and long-term storage operations. It also provides updates on experimental components under development that are vital for pursuing advanced studies. Validation of the extent of water removal in a multi-assembly dry storage system using an industrial vacuum drying procedure is needed, as operational conditions leading to incomplete drying may have potential impacts on the fuel, cladding, and other components in the system. Water remaining in canisters/casks upon completion of vacuum drying can lead to cladding corrosion, embrittlement, and breaching, as well as fuel degradation. Therefore, additional information is needed to evaluate the potential impacts of water retention on extended long-term dry storage. A general lack of data and experience modeling the drying process necessitates the testing of advanced concepts focused on the simulation of industrial vacuum drying. Smaller-scale tests that incorporate relevant physics and well-controlled boundary conditions are necessary to provide insight and guidance to the modeling of prototypic systems undergoing drying processes. This report describes the development and testing of waterproof, electrically-heated spent fuel rod simulators as a proof of concept to enable experimental simulation of the entire dewatering and drying process. This report also describes the preliminary development of specially-designed, unheated mock fuel rods for monitoring internal rod pressures and studying water removal from simulated failed fuel rods. A variety of moisture monitoring instrumentation is also being considered and will be downselected for the tracking of dewpoints of gas samples. The effects of cladding oxidation and crud on water retention in dry storage systems can be explored via separate effects tests (SETs) that would measure chemisorbed and physisorbed water content on cladding samples. The concepts listed above will be incorporated into an advanced dry cask simulator with multiple fuel assemblies in order to account for important inter-assembly heat-transfer physics. Plans are described for harvesting up to five full-length 5x5 laterally truncated assemblies from commercial 17x17 PWR skeleton components with the goal of constructing this simulator.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Update: Structural Uncertainty of Used Nuclear Fuel in Dry Storage Canisters

The Structural Uncertainty research task uses numerical modeling to help close knowledge gaps associated with extended dry storage of used nuclear fuel. Modeling helps to predict the expected range of mechanical loading on used nuclear fuel and dry storage system components, which is needed to help guide materials research. Knowledge of expected loads helps the materials researchers prioritize their research and focus only on the relevant material degradation phenomena that can have an effect on the ability of dry storage systems to function. The primary loading conditions considered in this task are dry storage cask (DSC) tip-over, handling drops of the multipurpose fuel canister, and seismic loading of DSC systems while situated on the concrete pad of a storage facility. Loads related to normal conditions

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Carbon Storage Atlas (Fifth Edition)

The Carbon Storage Atlas contains the following sections: (1) Introduction to CCS; (2) DOE’s Carbon Storage Activities; (3) National Perspectives; (4) Large-Scale Field Projects; (5) Small-Scale Field Projects; and (6) American Recovery and Reinvestment Act (ARRA) Site Characterization Projects. The Introduction to CCS section is an overview of CCS. The DOE’s Carbon Storage Activities section is a summary of CCS activities including information on DOE’s Carbon Capture and Storage Programs, NETL’s Research and Development, DOE’s Systems Analysis Activities, and DOE’s Interagency and Global Collaborations, and Knowledge Sharing Efforts. The National Perspectives section contains maps showing the number, location, and magnitude of CO 2 stationary sources in the United States and other portions of North America, as well as the areal extent and estimated CO 2 prospective storage resource available in RCSP-evaluated geologic formations. The Large-Scale Field Projects section provides detailed information on various aspects of the large-scale injections conducted by the RCSPs. The Small-Scale Field Projects and Site Characterization Projects sections provide summaries of field project activities that augment the efforts of the large-scale field projects.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Carbon Storage Atlas, Fifth Edition - Updated Information on Geological Sinks and CO 2 Sources

The Carbon Storage Atlas contains the following sections: (1) Introduction to CCS; (2) DOE’s Carbon Storage Activities; (3) National Perspectives; (4) Large-Scale Field Projects; (5) Small-Scale Field Projects; and (6) American Recovery and Reinvestment Act (ARRA) Site Characterization Projects. The Introduction to CCS section is an overview of CCS. The DOE’s Carbon Storage Activities section is a summary of CCS activities including information on DOE’s Carbon Capture and Storage Programs, NETL’s Research and Development, DOE’s Systems Analysis Activities, and DOE’s Interagency and Global Collaborations, and Knowledge Sharing Efforts. The National Perspectives section contains maps showing the number, location, and magnitude of CO 2 stationary sources in the United States and other portions of North America, as well as the areal extent and estimated CO 2 prospective storage resource available in RCSP-evaluated geologic formations. The Large-Scale Field Projects section provides detailed information on various aspects of the large-scale injections conducted by the RCSPs. The Small-Scale Field Projects and Site Characterization Projects sections provide summaries of field project activities that augment the efforts of the large-scale field projects.

54 ENVIRONMENTAL SCIENCES↗

Fiberboard Properties and Degradation Rates for Storage of 9975 Shipping Packages in KAC (2021 Status Report)

Thermal, mechanical, and physical properties have been measured on fiberboard samples following accelerated aging for up to 16 years. The aging environments include elevated temperature up to 250 ºF (the maximum allowed service temperature for fiberboard in 9975 packages) and elevated humidity. Accelerated aging results have been analyzed and used to build aging models. Correlations relating several properties (thermal conductivity, energy absorption, weight, dimensions, and density) to their rate of change in potential storage environments have been developed. Combined with an estimate of the actual conditions the fiberboard experiences in K-Area Complex (KAC), these models allow development of service life predictions. KAC completed calculations that supported extending the service life of 9975 packages with 3013 and non3013 containers in storage from 15 years to 20 years. These calculations addressed the potential for degraded fiberboard properties following 20 years in storage using degradation models developed previously. The updated degradation models developed in this report have been compared to the assumptions in these calculations, and the current results for fiberboard dimensions, density, radial thermal conductivity, and energy absorption remain consistent with those calculations. The axial thermal conductivity degradation rate slightly exceeds calculations estimate of 0.5% per year between 130 and 160 °F. Additional data will continue to be collected to permit future refinements to the models and assumptions. Some of the predicted degradation rates presented in this report are extreme. However, these relate to environments that do not exist within KAC or would be postulated only as upset conditions that would not likely persist for an extended period. For a typical package stored in KAC with approximately 10-12 watts internal heat load or less, and ambient temperatures below 90 ºF, the fiberboard assemblies experience storage conditions less severe than any of the aging environments. Fiberboard in conforming packages with lower internal heat loads should experience little or no degradation and is expected to provide a service life beyond the currently approved 20 year storage period. Packages with higher internal heat loads may not continue to perform their required safety functions beyond 20 years. Ultimately, service life will be determined by the cumulative effect of degradation from all the conditions these packages might encounter. The results and model predictions presented in this report are applicable to 9975 packages with cane or softwood fiberboard overpack assemblies. These degradation models do not address the effects of nonconforming conditions such as the presence of excess moisture and mold or beetle infestations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Recommended Practices for Managing Induced Seismicity Risk Associated with Geologic Carbon Storage

The geologic storage of carbon dioxide (CO 2 ) is one method to help reduce or eliminate atmospheric CO 2 emissions. The sequestered CO 2 is originally captured from the atmosphere or from a stationary industrial source and subsequently injected into a deep subsurface porous rock formation. To facilitate the successful deployment of field scale carbon storage projects, the U.S. Department of Energy (DOE) is developing tools and protocols for defensible, science-based frameworks to quantify and mitigate risks associated with the long-term storage of CO 2 . This protocol specifically addresses the risk of induced seismicity due to injection in a geologic carbon storage (GCS) site. This integrated and risk-based protocol is a product of the U.S. DOE Fossil Energy’s National Risk Assessment Partnership (NRAP), a multi-year collaborative research effort of Los Alamos National Laboratory (LANL), Lawrence Berkeley National Laboratory (LBNL), Lawrence Livermore National Laboratory (LLNL), National Energy Technology Laboratory (NETL), and Pacific Northwest National Laboratory (PNNL). These recommended practices describe a set of 7 steps to evaluate, manage, communicate, and mitigate the risk of induced seismicity at GCS sites. The base methodology of the recommended practices follows a framework similar to the Protocol for Addressing Induced Seismicity Associated with Enhanced Geothermal Systems (Majer et al., 2012), developed for the Geothermal Technology Office of the U.S. DOE. These recommended practices present a framework to systematically assess the induced seismicity risk and quantify the associated uncertainties. These recommendations are based on current research and are sufficiently general to allow for modification and application to a variety of different types of sites. The substance of the recommended practices contained herein includes both technical and non-technical issues, and covers all operational stages of the GCS project lifecycle. They start at the preliminary risk assessment phase, continue through site assessment and characterization, include best practice communication and seismic monitoring plan methodologies, discuss the evaluation and mitigation of seismic hazard and risk, and closes with an exploration of operational management plans, which conclude when the induced seismicity risk abates back to background level. The focus of these recommendations is on actively managing the risks associated with induced seismicity by developing an actionable risk management plan that starts at the project proposal stage and continues through site closure through an iterative assessment and improvement process. The audience of this document is expected to include all interested stakeholders (e.g., operators, project developers, regulators, and the general public) and is expressly written to be accessible to this broad range of partners. This document is intended to disseminate knowledge gained through recent advances in the science of induced seismicity hazard and risk assessments, to provide updates based on recent experience gained by similar corollary injection-induced seismicity cases, and most importantly to establish a uniform framework to carry out a successful induced seismicity risk management plan for carbon storage projects in the future. These recommendations do not directly address any domestic or international regulations or standards. A complementary NRAP report makes recommendations for the assessment and management of environmental subsurface risks associated with unwanted fluid migration at GCS sites (Thomas et al., 2021) and should be referred to in order to address those additional GCS site risks.

54 ENVIRONMENTAL SCIENCES↗

Recommended Practices for Managing Induced Seismicity Risk Associated with Geologic Carbon Storage

The geologic storage of carbon dioxide (CO 2 ) is one method to help reduce or eliminate atmospheric CO 2 emissions. The sequestered CO 2 is originally captured from the atmosphere or from a stationary industrial source and subsequently injected into a deep subsurface porous rock formation. To facilitate the successful deployment of field scale carbon storage projects, the U.S. Department of Energy (DOE) is developing tools and protocols for defensible, science-based frameworks to quantify and mitigate risks associated with the long-term storage of CO 2 . This protocol specifically addresses the risk of induced seismicity due to injection in a geologic carbon storage (GCS) site. This integrated and risk-based protocol is a product of the U.S. DOE Fossil Energy’s National Risk Assessment Partnership (NRAP), a multi-year collaborative research effort of Los Alamos National Laboratory (LANL), Lawrence Berkeley National Laboratory (LBNL), Lawrence Livermore National Laboratory (LLNL), National Energy Technology Laboratory (NETL), and Pacific Northwest National Laboratory (PNNL). These recommended practices describe a set of 7 steps to evaluate, manage, communicate, and mitigate the risk of induced seismicity at GCS sites. The base methodology of the recommended practices follows a framework similar to the $\textit{Protocol for Addressing Induced Seismicity Associated with Enhanced Geothermal Systems}$ (Majer et al., 2012), developed for the Geothermal Technology Office of the U.S. DOE. These recommended practices present a framework to systematically assess the induced seismicity risk and quantify the associated uncertainties. These recommendations are based on current research and are sufficiently general to allow for modification and application to a variety of different types of sites. The substance of the recommended practices contained herein includes both technical and non-technical issues, and covers all operational stages of the GCS project lifecycle. They start at the preliminary risk assessment phase, continue through site assessment and characterization, include best practice communication and seismic monitoring plan methodologies, discuss the evaluation and mitigation of seismic hazard and risk, and closes with an exploration of operational management plans, which conclude when the induced seismicity risk abates back to background level. The focus of these recommendations is on actively managing the risks associated with induced seismicity by developing an actionable risk management plan that starts at the project proposal stage and continues through site closure through an iterative assessment and improvement process. The audience of this document is expected to include all interested stakeholders (e.g., operators, project developers, regulators, and the general public) and is expressly written to be accessible to this broad range of partners. This document is intended to disseminate knowledge gained through recent advances in the science of induced seismicity hazard and risk assessments, to provide updates based on recent experience gained by similar corollary injection-induced seismicity cases, and most importantly to establish a uniform framework to carry out a successful induced seismicity risk management plan for carbon storage projects in the future. These recommendations do not directly address any domestic or international regulations or standards. A complementary NRAP report makes recommendations for the assessment and management of environmental subsurface risks associated with unwanted fluid migration at GCS sites (Thomas et al., 2021) and should be referred to in order to address those additional GCS site risks

58 GEOSCIENCES↗

Probabilistic Modeling of Climate Change Impacts on Renewable Energy and Storage Requirements for NM's Energy Transition Act (SAND Report)

This report provides a study of the potential impacts of climate change on intermittent renewable energy resources, battery storage, and resource adequacy in Public Service Company of New Mexico’s Integrated Resource Plan for 2020 – 2040. Climate change models and available data were first evaluated to determine uncertainty and potential changes in solar irradiance, temperature, and wind speed in NM in the coming decades. These changes were then implemented in solar and wind energy models to determine impacts on renewable energy resources in NM. Results for the extreme climate-change scenario show that the projected wind power may decrease by ~13% due to projected decreases in wind speed. Projected solar power may decrease by ~4% due to decreases in irradiance and increases in temperature in NM. Uncertainty in these climate-induced changes in wind and solar resources was accommodated in probabilistic models assuming uniform distributions in the annual reductions in solar and wind resources. Uncertainty in battery storage performance was also evaluated based on increased temperature, capacity fade, and degradation in round-trip efficiency. The hourly energy balance was determined throughout the year given uncertainties in the renewable energy resources and energy storage. The loss of load expectation (LOLE) was evaluated for the 2040 No New Combustion portfolio and found to increase from 0 days/year to a median value of ~2 days/year due to potential reductions in renewable energy resources and battery storage performance and capacity. A rank-regression analyses revealed that battery round-trip efficiency was the most significant parameter that impacted LOLE, followed by solar resource, wind resource, and battery fade. An increase in battery storage capacity to ~25,000 – 30,000 MWh from a baseline value of ~14,000 MWh was required to reduce the median value of LOLE to ~0.2 days/year with consideration of potential climate impacts and battery degradation.

54 ENVIRONMENTAL SCIENCES↗

Thermal Modeling of Advanced Test Reactor Fuel in a Generalized Dry Storage System Under Hypothetical Accident Conditions

Work was performed to investigate the thermal behavior of a sealed aluminum-clad spent nuclear fuel (ASNF) dry storage configuration under hypothetical accident conditions during long-term storage. The considered system consists of a concrete dry storage overpack; a welded over canister, backfilled with argon; and nine Department of Energy (DOE) standardized canisters (DOESCs) loaded with ASNF, backfilled with helium gas. One technical concern associated with the long-term storage of ASNF includes radiolytic hydrogen generation. The yield of large quantities of hydrogen could lead to DOESC over pressurization or a flammable internal atmosphere. While flammability concerns can be resolved by preventing the ingress of oxygen, the canister pressure is partially controlled by the atmosphere temperature. This memorandum summarizes the results of modeling and simulation (M&S) work completed with Star CCM+ (a computational fluid dynamics [CFD] software) considering the thermal effects of a fully engulfing flame and another scenario with the vent ports of the concrete dry storage overpack completely blocked. The goal was to determine the bounding maximum temperature of the DOESC internal atmosphere to evaluate a worst-case pressure scenario, as well as the critical vent port blockage durations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Pumped Storage Hydro Model Evaluation Report Task 1: Tool Assessment

Pumped storage hydro (PSH) projects support various aspects of power system operations. However, determining the value of PSH projects and the many services and contributions to the system they provide can be a challenge. The PSH techno-economic studies being carried out by a 5-lab consortium are defining extensive modeling approaches for evaluating the economic benefits of PSH projects. To enhance the impact of the valuation approach and follow-on techno-economic studies, Pacific Northwest National Laboratory (PNNL) will be developing a set of online tools that industry could adopt and use to advance PSH projects in the US. The problem is that the research team is not entirely clear on the features of the tools that would offer the most significant impact to industry. Thus, year one of this effort is designed to first define the needs of industry before developing the PSH valuation tool. The first step in defining industry needs is to evaluate existing tool packages, including those created by DOE and those by industry groups, to both measure usage levels and define tool attributes that maximize industry impact. The second step in this process will be to hold a workshop designed to elicit direct industry input. Given the breadth and nature of the task, which is to define ideal model attributes, the research team did not constrain the assessment to storage valuation tools. Several tools were assessed, and their characteristics compared against a list of “ideal” attributes that included ease of use, generalizability of results, and analytical flexibility. Information regarding usage and impact were then compared to specific model attributes to define which attributes appear to drive success. The following key lessons and implications can be drawn from the analysis: Models with high ease of use were often the most adopted by industry, though they did not necessarily have high publication reference records, meaning a published article made direct reference to the tool. For example, REScheck TM and COMcheck TM , two tools which share a site, have seen a high amount of web traffic and usage. Similarly, Storage Value Estimate Tool (StorageVET®), an energy storage valuation model, has a large number of organizations using it despite a low publication reference record. A common feature between these models is that they are web-hosted, theoretically making them more easily accessible with graphic user interfaces (GUIs) that are more navigable; Models with higher usage statistics were typically free and/or open source. While it may be unsurprising that this attribute could be considered a draw for users, there is the potential for overestimating the tool's value based on popularity due to the fact that some users may have used the model simply because it was free and not because it is the best model; Models that offer more in-depth analysis and a wide coverage of applications (e.g. VOLTTRON™, GridLAB-D™, and Integrated Valuation of Ecosystem Services and Tradeoffs (InVest)) have shown a high number of publication references as well as showing a high number of downloads in the case of GridLAB-D™. It should be noted that the figure below does not include the model with the highest number of publication references (EnergyPlus™) as it has been removed to show clearer distinction between the remaining tools; The most popular model within the evaluation list was EnergyPlus™. This tool has the highest number of publication references (2,034) of all models considered and contains both a high ease of use level as well as broad application flexibility. Its high usage may be correlated, however, with the presumed wider audience conducting energy consumption modeling compared to the audiences for some of the other tools in this list; Models that were low in both general usage and publication reference generally did not exhibit characteristics considered ideal by the research team. Some of these models offered a narrower range of analytical applications or lower generalizability of results. This would automatically restrict the pool of potential users to those who fall within a narrow range of specific technologies or applications. This report also explores two model structures for the PSH tool: decision tree-based, which would guide the user through the valuation methods defined in the PSH techno-economic studies currently being carried out by DOE, and an all-inclusive comprehensive model. The strengths of each were explored and a hybrid approach was defined that would embed a price taker model into the decision tree approach. Such an approach would provide a comprehensive approach for modeling small-scale PSH while recognizing the challenges associated with implementing a price-maker approach in an all-inclusive model. Insight gained in this analysis of other models can aid in narrowing down the list of effective and sought-after attributes, and in defining model structure. Next steps toward developing a model for storage valuation will be to gain direct industry input through workshops.

13 HYDRO ENERGY↗

Polar Bear™ – Innovative Capture of Storage Tank Vapors

Polar Bear™ is a patented technology developed by the Energy & Environmental Research Center (EERC) to capture storage tank vapors and eliminate methane emissions from upstream oil- and gas-producing facilities. Sparked by early commercial investment, the EERC licensed the technology and extended the intellectual property to storage tanks. Polar Bear™ is uniquely engineered and adapted to individual lower-producing facilities where there is otherwise no economic alternative for capturing tank vapors. A high number of small producing oil and gas wells are distributed across the country. The aggregate contributes to a significant volume of emissions. Because of the lack of economy of scale, gas volumes from these facilities are typically not recovered and contribute to methane emissions. Polar Bear™ provides a fit-for-purpose compression solution that addresses cost by reducing complexity with respect to conventional vapor recovery units and eliminating oil changes. Unique to Polar Bear™ is the capability to separate oxygenated gas from storage tank vapors. Storage tanks are designed to “breathe,” allowing gas to enter and escape during internal level and temperature changes. This infiltration of air into the tank headspace imparts undesirable oxygen content with respect to pipeline gathering. Polar Bear™ separates the vapor stream, allowing oxygen-rich gas to be used as fuel on-site while recovering the liquids-rich portion of the gas where oxygen content is minimized. A prototype system was tested to verify process models, evaluate operational performance, and advance the technology readiness level from 5 to 6. Results provide a good match between experimental measurements and process models, indicating the models are useful for future scale-up and field design. Various mixtures of nitrogen and liquefied petroleum gas were tested to understand the mass balance of nitrogen and how it relates to the potential control of oxygen content. Findings indicate that less than 2000 ppm of oxygen is likely to remain in the liquid portion of the gas in field applications. The research and development prepare the technology for field implementation to eliminate routine and fugitive methane emissions from storage tanks.

02 PETROLEUM↗

Geomechanical Study for Stacked Carbon Dioxide Storage in North Dakota

Conference presentation at American Association of Petroleum Geologists (AAPG) Carbon Capture, Utilization, and Storage (CCUS) Conference, Houston, Texas, April 25–27, 2023. When multiple carbon dioxide (CO 2 ) storage targets are present in the subsurface at the same geographic location, a CO 2 storage project may pursue a stacked storage approach. This study focused on assessing geomechanical effects on dedicated storage in stacked saline aquifers during a 20-year CO 2 injection project life.

01 COAL, LIGNITE, AND PEAT↗

Williston basin associated co 2 storage field laboratory

The Williston Basin Associated CO 2 Storage Field Laboratory (WBCFL), led by the Energy & Environmental Research Center (EERC) in partnership with Denbury (now ExxonMobil), was established to advance understanding of CO 2 enhanced oil recovery (EOR) and associated geologic CO 2 storage in the Williston Basin. The specific objective of the WBCFL was to conduct field and laboratory activities to inform decisionmakers regarding the 1) efficacy of associated storage in stacked geologic reservoirs during EOR operations; 2) CO 2 injectivity, oil production, and storage in residual oil zones (ROZs); 3) use of a novel CO 2 storage monitoring, verification, and accounting (MVA) technology (active seismoelectric [ASE] monitoring), and 4) life cycle and techno-economic factors for EOR development scenarios targeting ROZs. The project location was the Pennel Field in southeast Montana, which is part of the Cedar Creek Anticline (CCA) geologic structure within the Williston Basin.

02 PETROLEUM↗