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At least 1,567 records · Page 87

Theory and Computation of Optimal Low- and Medium- Thrust Orbit Transfers

This report presents new theoretical results which lead to new algorithms for the computation of fuel-optimal multiple-burn orbit transfers of low and medium thrust. Theoretical results introduced herein show how to add burns to an optimal trajectory and show that the traditional set of necessary conditions may be replaced with a much simpler set of equations. Numerical results are presented to demonstrate the utility of the theoretical results and the new algorithms. Two indirect methods from the literature are shown to be effective for the optimal orbit transfer problem with relatively small numbers of burns. These methods are the Minimizing Boundary Condition Method (MBCM) and BOUNDSCO. Both of these methods make use of the first-order necessary conditions exactly as derived by optimal control theory. Perturbations due to Earth's oblateness and atmospheric drag are considered. These perturbations are of greatest interest for transfers that take place between low Earth orbit altitudes and geosynchronous orbit altitudes. Example extremal solutions including these effects and computed by the aforementioned methods are presented. An investigation is also made into a suboptimal multiple-burn guidance scheme. The FORTRAN code developed for this study has been collected together in a package named ORBPACK. ORBPACK's user manual is provided as an appendix to this report.

Goodson, Troy D.↗

Evaluation of Rapid for a UNF cask benchmark problem

To ensure criticality safety and maintain a high level of security of Used Nuclear Fuel (UNF), it is necessary to perform detailed Particle Transport simulations. The commonly used technique is the 3-D, continuous energy Monte Carlo method that is time-consuming and, for eigenvalue calculations, may have difficulties with the source convergence. Wenner and Haghighat and Dufek demonstrated that in criticality problems with high dominance ratio and/or under-sampling possibilities, the fission matrix (FM) methodology should be used in order to be able to obtain unbiased solution. The RAPID (Real-time Analysis for Particle transport and In-situ Detection) code system is based on the Multi-stage Response-function Transport (MRT) methodology, and uses the FM formulation to determine eigenvalue, subcritical multiplication and fission density distribution of nuclear systems. This paper uses a benchmark problem similar to the GBC-32 Cask to evaluate the accuracy and performance of RAPID against the results of a reference MCNP solution. We performed a detailed sensitivity analysis on a single-assembly model in order to determine the MCNP eigenvalue parameters necessary to obtain a reliable reference solution. These results provided a guide for the selection of an appropriate set of parameters for the eigenvalue calculation for the whole cask. The paper is organized as follows: initially, the RAPID code system is briefly discussed; then, the benchmark problem is introduced. The methodology used to analyze results is proposed and some of the results of different cases are analyzed to identify the best set of eigenvalue parameters for a reference MCNP calculation. The selected case is then compared with the RAPID calculation for both a single assembly and a full cask model. In the end some conclusions and future work perspectives are drawn.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Computation of optimal low- and medium-thrust orbit transfers

This paper presents the formulation of the optimal low- and medium-thrust orbit transfer control problem, numerical methods for solution, and numerical solutions of the problem. The problem formulation is for final mass maximization and allows for second-harmonic oblateness, atmospheric drag, and 3D noncoplanar nonaligned elliptic terminal orbits. We set up examples to demonstrate the ability of two indirect methods to solve the resulting two point boundary value problems (TPBVP). The methods demonstrated are the multiple point shooting method as formulated in Oberle's (1987) subroutine BOUNDSCO, and the minimizing boundary-condition method (MBCM). We find that although both methods can converge solutions, there are tradeoffs to using either method. We present numerical solutions of planar transfers in which both the initial orbit exit and final orbit entry points have been optimized. These solutions include two- and three-burn transfers. The methods used show an ability to handle thrust down to at least T/W(o) = O(10 exp -3). They also show similar convergence abilities with or without the oblateness and drag terms. We discuss the issue of maximizing with respect to the final time and provide evidence that implies a local optimum at a maximum final time for a given number of burns.

Chuang, C.-H.↗

Practical Aspects of Multiple-Input Design for Aircraft System Identification Flight Tests

Practical aspects of multiple-input design methods for aircraft system identification flight tests are discussed. The orthogonal optimized multisine multiple-input design technique is explained and demonstrated, along with useful variations. Practical implementation and application issues associated with applying orthogonal optimized multisine inputs in flight are explained, and solutions are demonstrated using flight data from full-scale and subscale aircraft, as well as simulated flight data from an F-16 nonlinear simulation. Topics include truncated and extended excitation inputs, variations for control effectors with limited movement capabilities, aircraft dynamic response to excitation inputs, pilot implementation, statistical uncertainty quantification, multiple-input efficiency and effectiveness, flight testing with active feedback control, frequency-response estimation, control actuator modeling, and control interaction effects. Examples demonstrate that the orthogonal optimized multisine input design method is a practical, versatile, and effective approach for designing multiple excitation inputs for aircraft system identification flight tests.

Multiple-Input Design↗

Nondestructive evaluation of resistance spot-welded Al-steel joints

With increasing demand for better fuel economy for automobiles, multimaterial solutions are increasingly being utilized in the automotive industry for reducing weight in the vehicle body structure. This poses challenges in terms of joining dissimilar metals, especially those with vastly different properties such as aluminum to steel joining. General Motors has developed a new resistance spot-welding technique for dissimilar materials using a multi-ring domed (MRD) electrode and multiple solidification weld schedules to address this challenge. Originally developed for aluminum to aluminum resistance spot welding, this technology is being enabled as the mainstream aluminum joining solution to leverage existing infrastructure and workforce competency in resistance spot welding. With the recent expansion of MRD technology to aluminum to steel resistance spot welding, there is an ever-greater need to experimentally verify the quality of each aluminum to steel resistance spot-weld application with limited time and resources. Nondestructive evaluation (NDE) would allow the transfer of resistance spot-welding technology to dissimilar aluminum to steel joints. This article describes the current state of the art of aluminum to steel resistance spot welding and the challenges in developing a robust NDE process for this technology.

36 MATERIALS SCIENCE↗

Argumentation for coordinating shared activities

an increasing need for space missions to be able to collaboratively (and competitively) develop plans both within and across missions. In addition, interacting spacecraft that interleave onboard planning and execution must reach consensus on their commitments to each other prior to execution. In domains where missions have varying degrees of interaction and different constraints on communication and computation, the missions will require different coordination protocols in order to efficiently reach consensus with in their imposed deadlines. We describe a Shared Activity Coordination (SHAC) framework that provides a decentralized algorithm for negotiating the scheduling of shared activities over the lifetimes of multiple agents and a foundation for customizing protocols for negotiating planner interactions. We investigate variations of a few simple protocols based on argumentation and distributed constraints satisfaction techniques and evaluate their abilities to reach consistent solutions according to computation, time, and communication costs in an abstract domain where spacecraft propose joint measurements.

Mars↗

Nearly two-dimensional solutions of Euler's equations

Motivated by a stretched version of the Taylor-Green initial-value problem for the Euler and Navier-Stokes equations, nearly two-dimensional incompressible flows are considered involving a single direction of slow spatial variation. A multiple-scale formulation of the problem leads by contour averaging to a system that determines the slow development in space and time. It is shown that the latter system is equivalent to an axisymmetric problem with nonstandard connection between circulation, cylindrical radius, and angular velocity component. Special solutions of the system in the exact axisymmetric case suggest that near-two-dimensionality is lost in finite time.

Childress, Stephen↗

60 Years of Betaine 30–From Solvatochromic Discovery to Future Frontiers

Betaine-30 (B30) was reported by Karl Dimroth and Christian Reichardt et al. in 1963 as a solvatochromic probe that can be easily synthesized, shows good solubility, and remains stable in various organic solvents and solutions. Its strongly negatively solvatochromic behavior arises from differential solvation between its electronic ground and excited states, making it a valuable tool for assessing solvent polarity using the E T (30) polarity scale, also devised by Dimroth and Reichardt. In addition, advancements in femtosecond laser spectroscopy in the 1990s greatly improved the understanding of B30’s relaxation dynamics following photoexcitation. In solvents capable of hydrogen bonding, such as alcohols, intermolecular hydrogen-bond rearrangement contributes to the multiple relaxation components observed. Since the 1990s, the applications of B30 have expanded beyond simple organic solvents to include complex solvent mixtures, such as electrolyte solutions for battery technologies and eutectic solvent mixtures. Furthermore, given the growing importance of these complex solvent mixtures, B30 is becoming an increasingly valuable tool for studying previously unexplored solvation properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Holographic thermalization in a quark confining background

We study holographic thermalization of a strongly coupled theory inspired by two colliding shock waves in a vacuum confining background. Holographic thermalization means a black hole formation, in fact, a trapped surface formation. As the vacuum confining background, we considered the well-know bottom-up AdS/QCD model that provides the Cornell potential and reproduces the QCD β-function. We perturb the vacuum background by colliding domain shock waves that are assumed to be holographically dual to heavy ions collisions. Our main physical assumption is that we can make a restriction on the time of trapped surface formation, which results in a natural limitation on the size of the domain where the trapped surface is produced. This limits the intermediate domain where the main part of the entropy is produced. In this domain, we can use an intermediate vacuum background as an approximation to the full confining background. We find that the dependence of the multiplicity on energy for the intermediate background has an asymptotic expansion whose first term depends on energy as E{sup 1/3}, which is very similar to the experimental dependence of particle multiplicities on the colliding ion energy obtained from the RHIC and LHC. However, this first term, at the energies where the approximation of the confining metric by the intermediate background works, does not saturate the exact answer, and we have to take the nonleading terms into account.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Multiple Mechanisms Mapped in Aryl Alkyl Ether Cleavage via Aqueous Electrocatalytic Hydrogenation over Skeletal Nickel

We present here detailed mechanistic studies of electrocatalytic hydrogenation (ECH) in aqueous solution over skeletal nickel cathodes to probe the various paths of reductive catalytic C–O bond cleavage among functionalized aryl ethers relevant to energy science. Heterogeneous catalytic hydrogenolysis of aryl ethers is important both in hydrodeoxygenation of fossil fuels and in upgrading of lignin from biomass. The presence or absence of simple functionalities such as carbonyl, hydroxyl, methyl, or methoxyl groups is known to cause dramatic shifts in reactivity and cleavage selectivity between sp3 C–O and sp2 C–O bonds. Specifically, reported hydrogenolysis studies with Ni and other catalysts have hinted at different cleavage mechanisms for the C–O ether bonds in α-keto and α-hydroxy β-O-4 type aryl ether linkages of lignin. Our new rate, selectivity, and isotopic labeling results from ECH reactions confirm that these aryl ethers undergo C–O cleavage via distinct paths. For the simple 2-phenoxy-1-phenylethane or its alcohol congener, 2-phenoxy-1-phenylethanol, the benzylic site is activated via Ni C–H insertion, followed by beta elimination of the phenoxide leaving group. But in the case of the ketone, 2-phenoxyacetophenone, the polarized carbonyl π system apparently binds directly with the electron rich Ni cathode surface without breaking the aromaticity of the neighboring phenyl ring, leading to rapid cleavage. Substituent steric and electronic perturbations across a broad range of β-O-4 type ethers create a hierarchy of cleavage rates that supports these mechanistic ideas while offering guidance to allow rational design of the catalytic method. Furthermore, on the basis of the new insights, the usage of cosolvent acetone is shown to enable control of product selectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fixture for multiple-FCC chemical stripping and plating

For chemical stripping, lead tape applied near ends to be stripped protects insulation. Taped ends are submerged half way in stripping solution. For electroplating, both ends of FCC are stripped - top ends for electric contact, others for submersion in electroplating solution.

Angele, W.↗

A perturbation solution for transverse pressure-sensitive combustion instability in an annulus

A method for analysis of combustion instability in rocket motors based on a combination of the Galerkin method and the two-variable (or multiple-scales) perturbation method is developed. The method is illustrated by applying it to the problem of pressure-sensitive combustion instability in a liquid-fuel annular combustion chamber. To the order of approximation inherent in the method it is found that the complete linear stability analysis and most of the nonlinear stability analysis can be carried out in closed form. The results thus obtained are used to clarify several aspects of the interpretation of numerical solutions obtained by previous investigators.

Googerdy, A.↗

Unconditionally stable, second-order schemes for gradient-regularized, non-convex, finite-strain elasticity modeling martensitic phase transformations

In the setting of continuum elasticity martensitic phase transformations are characterized by a non-convex free energy density function that possesses multiple wells in strain space and includes higher-order gradient terms for regularization. Metastable martensitic microstructures, defined as solutions that are local minimizers of the total free energy, are of interest and are obtained as steady state solutions to the resulting transient formulation of Toupin’s gradient elasticity at finite strain. This type of problem poses several numerical challenges including stiffness, the need for fine discretization to resolve microstructures, and following solution branches. Accurate time-integration schemes are essential to obtain meaningful solutions at reasonable computational cost. Here in this work we introduce two classes of unconditionally stable second-order time-integration schemes for gradient elasticity, each having relative advantages over the other. Numerical examples are shown highlighting these features.

42 ENGINEERING↗

Smarter building start – A distributed solution

A significant focus of research and new technologies for reducing energy use in buildings is on operating the systems more efficiently during the times when the systems are active. However, there is a large potential for energy savings in determining the periods when the systems should or should not be active. This scheduling aspect of operation is often overlooked even though relatively simple solutions can unlock substantial energy savings. In this paper we describe a smart building start (SBS) algorithm that considers multiple zones in a building to determine individual schedules for room controllers as well as the central systems based on solving a simple optimization problem. Application of the SBS algorithm to multiple interconnected systems enables a staggered start-up that minimizes peak loads and also ensures comfort is within a target range with minimal system run time. The SBS algorithm extends the capability of traditional optimal start and is designed to be simple to deploy and robust. Simulation results as well as results from tests in a real building with a VAV system are presented. The presented algorithm is applicable to any type of building with a zonal or multi-zone HVAC system. To function, it needs to be able to change setpoints in rooms and monitor room temperatures, as well as, if desired, turn the central system on or off.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Robust Approaches to Handling Complex Geometries with Galerkin Difference Methods

The Galerkin difference (GD) basis is a set of continuous, piecewise polynomials defined using a finite-difference-like grid of degrees of freedom. The one dimensional GD basis functions are naturally extended to multiple dimensions using a tensor product construction on quadrilateral elements. The GD basis can be used to define the solution space for a discontinuous Galerkin finite element discretization of partial differential equations. In this work we propose two approaches to handling complex geometries within this setting: (1) using nonconforming, curvilinear GD elements and (2) coupling affine GD elements with curvilinear simplicial elements. In both cases the (semidiscrete) discontinuous Galerkin method is provably energy stable even when variational crimes are committed. Additionally, for both element types a weight-adjusted mass matrix is used, which ensures that only the reference mass matrix must be inverted. We also present sufficient conditions on the treatment of metric terms for the curvilinear, nonconforming GD elements to ensure that the scheme is both constant preserving and conservative. Numerical experiments confirm the stability results and demonstrate the accuracy of the coupled schemes.

97 MATHEMATICS AND COMPUTING↗

Solvent Selection for the Separation of Lignin-Derived Monomers Using the Conductor-like Screening Model for Real Solvents

The separation of desired monomers from a liquid-phase mixture of lignin depolymerization products is necessary to facilitate their upscaling and upgrading for industrial applications. One effective method to separate multiple liquid-phase products is countercurrent chromatography (CCC), which is a common liquid chromatography technique that separates target solutes based on differences in their partitioning in a biphasic solvent system. Effective CCC separation requires the selection of solvent compositions to tune solute partition coefficients. Here, to alleviate the experimental burden of selecting optimal solvent systems, we apply the conductor-like screening model for real solvents (COSMO-RS) method to compute partition coefficients of representative lignin monomers from four currently used depolymerization strategies in standard solvent systems. We further design new ternary and quaternary solvent systems that are predicted to further improve separation efficacy. On the basis of these predicted partition coefficients and empirical solvent selection criteria for CCC measurements, we suggest a range of solvent systems that would be suitable for the effective separation of aromatic lignin-derived products via CCC or similar liquid–liquid extraction methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Scenarios of energy efficiency and CO 2 emissions reduction potential in the buildings sector in China to year 2050

As China’s rapid urbanization continues and urban dwellers become more affluent, energy use in buildings is expected to grow. To understand how this growth can be slowed, here we explore four scenarios for Chinese buildings, ranging from a high-energy-demand scenario with no new energy policies to lowest energy demand under a techno-economic-potential scenario that assumes full deployment of cost-effective efficient and renewable technologies by 2050. We show that, in the high energy demand scenario, building energy demand has an average annual growth rate of about 2.8%, with slower growth rates in the other three scenarios. In all scenarios, CO 2 emissions grow slower than energy, with building CO 2 peaking around 2045 in the high energy demand scenario, and as early as 2030 in the techno-economic-potential scenario. We show that although various technological solutions, systems and practices can be very effective in minimizing building energy use, rigorous policies are needed to overcome multiple implementation barriers.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗