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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Solar wind dynamic pressure variations and possible ground signatures of flux transfer events

The effects of a series of solar wind dynamic pressure pulses are followed through the solar wind, across the bow shock and magnetosheath, into the magnetosphere, and down to the dayside ionosphere. Each pressure pulse had an intrinsic solar wind origin, i.e., was not generated by processes occurring at the earth's bow shock. Both upstream and downstream of the earth's bow shock, the pulses were identified by depressed magnetic field strengths and enhanced plasma densities. The pulses compressed the magnetosheath and magnetosphere, causing satellites in the magnetosphere to briefly observe enhanced magnetic field strengths, and/or enter the low-latitude boundary layer or magnetosheath. Satellites already in the magnetosheath observed a brief burst of enhanced magnetosheath flow caused by the relative inward motion of magnetosheath flow patterns. Alfven and fast mode compressional waves propagated rapidly down to the polar ionosphere, where they produced transient ionospheric flows at latitudes equatorward of the convection reversal boundary. The flow patterns moved westward around the auroral oval.

Sibeck, D. G.↗
DOE OSTI2023

Efficient SABRE-SHEATH Hyperpolarization of Potent Branched-Chain-Amino-Acid Metabolic Probe [1-13C]ketoisocaproate

Efficient 13C hyperpolarization of ketoisocaproate is demonstrated in natural isotopic abundance and [1-13C]enriched forms via SABRE-SHEATH (Signal Amplification By Reversible Exchange in SHield Enables Alignment Transfer to Heteronuclei). Parahydrogen, as the source of nuclear spin order, and ketoisocaproate undergo simultaneous chemical exchange with an Ir-IMes-based hexacoordinate complex in CD3OD. SABRE-SHEATH enables spontaneous polarization transfer from parahydrogen-derived hydrides to the 13C nucleus of transiently bound ketoisocaproate. 13C polarization values of up to 18% are achieved at the 1-13C site in 1 min in the liquid state at 30 mM substrate concentration. The efficient polarization build-up becomes possible due to favorable relaxation dynamics. Specifically, the exponential build-up time constant (14.3 ± 0.6 s) is substantially lower than the corresponding polarization decay time constant (22.8 ± 1.2 s) at the optimum polarization transfer field (0.4 microtesla) and temperature (10 °C). The experiments with natural abundance ketoisocaproate revealed polarization level on the 13C-2 site of less than 1%—i.e., one order of magnitude lower than that of the 1-13C site—which is only partially due to more-efficient relaxation dynamics in sub-microtesla fields. We rationalize the overall much lower 13C-2 polarization efficiency in part by less favorable catalyst-binding dynamics of the C-2 site. Pilot SABRE experiments at pH 4.0 (acidified sample) versus pH 6.1 (unaltered sodium [1-13C]ketoisocaproate) reveal substantial modulation of SABRE-SHEATH processes by pH, warranting future systematic pH titration studies of ketoisocaproate, as well as other structurally similar ketocarboxylate motifs including pyruvate and alpha-ketoglutarate, with the overarching goal of maximizing 13C polarization levels in these potent molecular probes. Finally, we also report on the pilot post-mortem use of HP [1-13C]ketoisocaproate in a euthanized mouse, demonstrating that SABRE-hyperpolarized 13C contrast agents hold promise for future metabolic studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Microkinetic Modeling: A Tool for Rational Catalyst Design

The design of heterogeneous catalysts relies on understanding the fundamental surface kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help the researcher in streamlining the process of catalyst design. Microkinetic modeling is used to identify critical reaction intermediates and rate-determining elementary reactions, thereby providing vital information for designing an improved catalyst. In this review, we summarize general procedures for developing microkinetic models using reaction kinetics parameters obtained from experimental data, theoretical correlations, and quantum chemical calculations. We examine the methods required to ensure the thermodynamic consistency of the microkinetic model. We describe procedures required for parameter adjustments to account for the heterogeneity of the catalyst and the inherent errors in parameter estimation. We discuss the analysis of microkinetic models to determine the rate determining reactions using the degree of rate control and reversibility of each elementary reaction. We introduce incorporation of Brønsted–Evans–Polanyi relations and scaling relations in microkinetic models and the effects of these relations on catalytic performance and formation of volcano curves. We review the analysis of reaction schemes in terms of the maximum rate of elementary reactions, and we outline a procedure to identify kinetically significant transition states and adsorbed intermediates. Here, we explore the application of generalized rate expressions for the prediction of optimal binding energies of important surface intermediates and to estimate the extent of potential rate improvement. We also explore the application of microkinetic modeling in homogeneous catalysis, electro-catalysis, and transient reaction kinetics. We conclude by highlighting the challenges and opportunities in the application of microkinetic modeling for catalyst design.

42 ENGINEERING↗
DOE OSTI2022

Resistivity of Surface Steps in Bulk-Insulating Topological Insulators

Electron transport in topological insulators usually involves both topologically protected surface states and trivial electronic states in the bulk material. The surface transport is particularly interesting; however, it is also susceptible to atomic defects on the surfaces, such as vacancies, impurities, and step edges. Experimental determination of scattering effects of these surface defects requires both nanoscale spatial resolution and the ability to decipher surface transport from bulk transport. Here we directly measure the resistivity of individual surface steps in the surface dominating transport process of topological insulator Bi 2 Te 2 Se. A variable probe-spacing transport spectroscopy with a multiprobe scanning tunneling microscope is used to differentiate the surface conductance from bulk conductance, allowing the identification of a surface dominant transport regime. The technique also reveals a deviation from ideal 2D transport at atomic steps. Then, a multi-probe scanning tunneling potentiometry is employed to visualize the electrochemical potentials across individual step edges. A quantitative analysis of the potential distributions enables us to acquire a resistivity of 0.530 mΩ · cm for the one quintuple-layer atomic step. The result indicates that atomic defects, despite preserving the time-reversal symmetry, can still significantly affect the transport in topological insulators.

36 MATERIALS SCIENCE↗
NASA NTRSDate not supplied

Silver Electrolysis for Disinfection of Spacecraft Potable Water: 2023 Update

Anodic dissolution of silver electrodes, or “silver electrolysis,” is being investigated as a means of introducing biocidal silver into potable water on exploration spacecraft. Last year’s paper reported a fault condition termed “electrode bridging,” in which silver deposits on interelectrode wetted materials, eventually bridging the electrode gap and providing an alternate conduction pathway that diminishes the silver output of the reactor. Since then, two strategies have been developed that prevent this fault from occurring: 1) increasing the frequency of polarity reversal and 2) separating the active surface of the electrode from the interelectrode wetted material. These strategies were tested independently, and in both cases, the reactor performed as expected with no occurrence of bridging for at least one crew-year equivalent of cumulative operation. Additional tests were conducted at varying levels of influent dissolved oxygen to better understand the nature of the cathode reaction and its impact on reactor performance. Results indicate that the primary cathode reaction is the reduction of dissolved oxygen, which could imply a dependence of reactor performance on dissolved oxygen concentration. However, it was found that at the typical oxygen concentrations anticipated for spacecraft processed water, the impact on silver electrolysis performance was negligible. Finally, multiphysics modelling of the reactor fluid mechanics and electrochemistry was undertaken to provide the capability to optimize the design of a future reactor prototype.

silver electrolysis↗
NASA NTRSDate not supplied

Silver Electrolysis for Disinfection of Spacecraft Potable Water: 2023 Update

Anodic dissolution of silver electrodes, or “silver electrolysis,” is being investigated as a means of introducing biocidal silver into potable water on exploration spacecraft. Last year’s paper reported a fault condition termed “electrode bridging,” in which silver deposits on interelectrode wetted materials, eventually bridging the electrode gap and providing an alternate conduction pathway that diminishes the silver output of the reactor. Since then, two strategies have been developed that prevent this fault from occurring: 1) increasing the frequency of polarity reversal and 2) separating the active surface of the electrode from the interelectrode wetted material. These strategies were tested independently, and in both cases, the reactor performed as expected with no occurrence of bridging for at least one crew-year equivalent of cumulative operation. Additional tests were conducted at varying levels of influent dissolved oxygen to better understand the nature of the cathode reaction and its impact on reactor performance. Results indicate that the primary cathode reaction is the reduction of dissolved oxygen, which could imply a dependence of reactor performance on dissolved oxygen concentration. However, it was found that at the typical oxygen concentrations anticipated for spacecraft processed water, the impact on silver electrolysis performance was negligible. Finally, multiphysics modelling of the reactor fluid mechanics and electrochemistry was undertaken to provide the capability to optimize the design of a future reactor prototype.

silver electrolysis↗
DOE OSTI2025

Undercooling minimization in ultrasound coupled DTA measurements of molten salts

Molten salts are ionic liquids that are used for the electrolytic pyroprocessing of metals and as heat transfer fluids in very high temperature processes. Recently, halide-based molten salt reactors (MSR) have gained momentum for high density and environmentally responsible electricity generation. The function of these reactors and their fuel cycle depend on a knowledge of the halide salt’s thermodynamic properties [1]. Therefore, high accuracy phase equilibria of MSR relevant base halide and actinide containing salts are needed. Modern thermal analysis of the phase transitions of halide salts is usually done during heating at relatively high scan rates with commercial devices. Normally such measurements are adequate for pure or pseudo-binary salts. However, as the number of components in the mixture increases, accurately resolving the liquidus becomes increasingly difficult. Reversing the scanning mode greatly increases the sensitivity of phase transition measurements but can decrease accuracy due to undercooling [2] — a common occurrence in molten halide systems [3]. This work presents the development of a differential thermal analysis (DTA) cell intended for use in radiological gloveboxes. Non-contact ultrasonic agitation of the halide salt is implemented to limit kinetic limitations on crystallization during cooling to minimize undercooling [4]. Measurements on halide salts are also presented to elucidate the effect of non-contact mixing on undercooling. Reference [1] S. Boyd and C. Taylor, “3 - Chemical fundamentals and applications of molten salts,” in Molten Salt Reactors and Thorium Energy, T. J. Dolan, Ed., Woodhead Publishing, 2017, pp. 29–91. doi: 10.1016/B978-0-08-101126-3.00003-8. [2] K. Nitsch, A. Cihlár, and M. Rodová, “Molten state and supercooling of lead halides,” J. Cryst. Growth, vol. 264, no. 1, pp. 492–498, Mar. 2004, doi: 10.1016/j.jcrysgro.2004.01.011. [3] L. Rycerz, “Practical remarks concerning phase diagrams determination on the basis of differential scanning calorimetry measurements,” J. Therm. Anal. Calorim., vol. 113, no. 1, pp. 231–238, Jul. 2013, doi: 10.1007/s10973-013-3097-0. [4] Md. H. Zahir, S. A. Mohamed, R. Saidur, and F. A. Al-Sulaiman, “Supercooling of phase-change materials and the techniques used to mitigate the phenomenon,” Appl. Energy, vol. 240, pp. 793–817, Apr. 2019, doi: 10.1016/j.apenergy.2019.02.045.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2003

Inhibition of HSP70 and a Collagen-Specific Molecular Chaperone (HSP47) Expression in Rat Osteoblasts by Microgravity

Rat osteoblasts were cultured aboard a space shuttle for 4 or 5 days. Cells were exposed to 1alpha, 25 dihydroxyvitamin D(3) during the last 20 h and then solubilized by guanidine solution. The mRNA levels for molecular chaperones were analyzed by semi-quantitative RT-PCR. ELISA was used to quantify TGF-beta1 in the conditioned medium. The HSP70 mRNA levels in the flight cultures were almost completely suppressed, as compared to the ground (1 x g) controls. The inducible HSP70 is known as the major heat shock protein that prevents stress-induced apoptosis. The mean mRNA levels for the constitutive HSC73 in the flight cultures were reduced to 69%, approximately 60% of the ground controls. HSC73 is reported to prevent the pathological state that is induced by disruption of microtubule network. The mean HSP47 mRNA levels in the flight cultures were decreased to 50% and 19% of the ground controls on the 4th and 5th days. Concomitantly, the concentration of TGF-beta1 in the conditioned medium of the flight cultures was reduced to 37% and 19% of the ground controls on the 4th and 5th days. HSP47 is the collagen-specific molecular chaperone that controls collagen processing and quality and is regulated by TGF-beta1. Microgravity differentially modulated the expression of molecular chaperones in osteoblasts, which might be involved in induction and/or prevention of osteopenia in space.

Animals↗
NASA NTRS1987

An experimental investigation of the plasma contacting process

Measurements including plasma potential profile measurements made on a simple hollow cathode plasma contactor operating in the electron collection and emission modes are described. The ignited electron collection mode of contactor operation is identified, shown to improve contactor performance and found to be facilitated by increasing the size of the contactor anode. Potential profile data are compared to the predictions of a simple theoretical model that describes space-charge-current limitations imposed by the formation of a double sheath and found to agree with each other to within about + or - 25 percent. Because electrons, which are the dominant charge carriers, tend to be emitted from the hollow cathode in the emission mode and collected by the anode in the collection mode it is suggested that operation at high electrodynamic tether currents will probably require switching the point of tether connection to the contactor between its cathode and anode when the direction of tether current is reversed.

Wilbur, Paul J.↗
DOE OSTI2022

An experimental and modeling study on auto-ignition kinetics of ammonia/methanol mixtures at intermediate temperature and high pressure

A rapid compression machine (RCM) has been applied to measure the ignition delay times of NH 3 /CH 3 OH mixtures covering pressures of 20 and 40 bar, equivalence ratios of 0.5, 1.0 and 2.0, and temperatures between 845 and 1100 K. Here the measurements show that the NH 3 /CH 3 OH mixtures become more reactive with increasing methanol addition. Addition of merely 1% (molar basis) of CH 3 OH to NH 3 lowers the ignition temperature around 100 K at 40 bar in comparison to pure NH 3 . The ignition delay is a complex function of fuel mixture and stoichiometry. For the 1% CH 3 OH mixture, the leaner mixtures are more reactive, while the reverse trend is found for mixtures with 5%, 20% and pure CH 3 OH. Analysis of the pressure profiles shows three distinct ignition modes for NH 3/ CH 3 OH mixtures, facilitated by the pre-ignition heat release from NH 3 consumption. A detailed mechanism for ignition of NH 3 /CH 3 OH fuel blends has been developed, capable of reproducing the ignition behavior of mixtures with reasonable accuracy. A subset for amine / methanol interactions was established, with rate constants for the key reaction between NH 2 and CH 3 OH calculated from ab initio theory. A sensitivity analysis indicates that the critical reactions during the auto-ignition process vary with the CH 3 OH mole fraction in the fuel. The ammonia chemistry, namely NH 2 + NO, NH2 + NO 2 and NH 2 + HO 2 , is dominant for the mixture with 1% CH 3 OH, while the reactions related to CH 3 OH and H 2 O 2 are more important for the 20% CH 3 OH mixture. The interaction between ammonia and methanol shows a more prominent effect on auto-ignition for mixtures with 5% CH 3 OH in fuel as compared to those with 1% and 20% CH 3 OH. According to the modeling results, methanol addition is found to enrich the O/H radical pool, consuming ammonia and promoting auto-ignition through different reaction pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Optical pulse-induced ultrafast antiferrodistortive transition in SrTiO 3

The ultrafast dynamics of the antiferrodistortive phase transition in perovskite SrTiO 3 is monitored via time-domain Brillouin scattering. Using femtosecond optical pulses, we initiate a thermally driven tetragonal-to-cubic structural transformation and detect the crystal phase through changes in the frequency of Brillouin oscillations (BO) induced by propagating acoustic phonons. Coupling the measured BO frequency with a spatiotemporal heat diffusion model, we demonstrate that, for a sample kept in the tetragonal phase, deposition of sufficient thermal energy induces a rapid transformation of the heat-affected region to the cubic phase. The initial phase change is followed by a slower reverse cubic-to-tetragonal phase transformation occurring on a timescale of hundreds of picoseconds. Here, we attribute this ultrafast phase transformation in the perovskite to a structural resemblance between atomic displacements of the R-point soft optic mode of the cubic phase and the tetragonal phase, both characterized by anti-phase rotation of oxygen octahedra. The structural relaxation time exhibits a strong temperature dependence consistent with the prediction of the equation of motion describing collective oxygen octahedra rotation based on the energy landscape of the phenomenological Landau theory of phase transitions. Evidence of such a fast structural transition in perovskites can open up new avenues in information processing and energy storage sectors.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Study of the Stark effect in the resonance lines of sodium by an atomic jet method

The reversal of the magnetic moment of a part of the atoms of a consecutive jet with optical excitation and on the return to the fundamental level is applied to the case of sodium, in order to complete previous results dealing with the alkalis. A conventional atomic jet apparatus consisting of two electromagnets with Rabi-type poles which produce magnetic field gradients of the same sense was used. The accuracy of measurement of the Stark effect by excitation of an atomic jet of high collimation is limited by the Doppler width of the lines emitted by the source or, if this width is diminished with the help of a connected process, by the luminous power available. The results make it possible to extend the experiments to the measurement of isotopic displacements of sodium.

Duong, H. T.↗
NASA NTRS1984

Magnetospheric topology of fields and currents

The interaction of the solar wind with the magnetosphere is examined from the standpoint of fundamental processes in physics and, whenever possible, observational data. A conceptual model is developed which incorporates several features of the magnetosphere that are still open to debate, such as open magnetic field lines in the polar cap and a boundary layer just inside the magnetopause. It is shown that the length of the magnetotail, the existence of the polar rain, the bursts of particles at the edge of the plasma sheet, and the poleward motion of auroral forms during the recovery phase of a magnetospheric substorm may all have a natural explanation with the proposed model. The one exception, however, is the topology of the electric field. The problems associated with reversal of the electric field within the magnetotail are examined.

Heikkila, W. J.↗
DOE OSTI2025

Gas-solid reaction-based selective lithium leaching strategy for efficient LiFePO 4 recycling

As the electric-vehicle market continues to expand, LiFePO 4 (LFP) batteries, valued for their intrinsic safety and cost-effectiveness, are being increasingly utilized. However, this widespread adoption highlights the urgent need for innovative and environmentally friendly recycling methods for spent LFP batteries due to their relatively low material value and the environmental challenges associated with traditional recycling processes. Here, in this study, we present a novel selective lithium leaching technique that involves a gas–solid reaction with chlorine gas. This method achieves a remarkable leaching efficiency of 99.8 % and a selectivity of 98.8 % at 200 °C within just 10 min, without generating acidic wastewater. The resulting LiCl solution was successfully converted into Li 2 CO 3 with an excellent purity of 99.5 %, while producing NaCl solution as the only byproduct. Notably, the olivine structure of the LFP was preserved as FePO 4 after lithium leaching. The regenerated LFP demonstrated excellent performance, retaining 94.1 % of its capacity after 150 cycles, while the lithium-leached FePO 4 delivered a reversible capacity exceeding 150 mAh/g. This approach not only enhances the efficiency of LFP recycling but also paves the way for more sustainable battery technologies.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Room Temperature Cyclic Deformation Behavior of Cast and Extruded NiAl

The fully reversed, strain controlled fatigue behavior of cast and extruded NiAl was evaluated at room temperature for plastic strain ranges of 0.0006 to 0.0002 to provide baseline data on the fatigue life of NiAl and to investigate whether the low ductility of NiAl would result in poor low-cycle fatigue behavior. Except at the smallest plastic strain range investigated, NiAl work hardened continuously until failure with a final fracture stress under cyclic conditions which was at least 60 percent greater than the monotonic fracture strength of NiAl. Fatigue fracture initiation occurred at large internal tear-shaped pores, and fatigue life was controlled or limited by the presence of these processing-related defects. Even with the processing defects present in this material and the limited ductility of NiAl in general, cast and extruded NiAl exhibited much greater fatigue life at room temperature than comparable B2 ordered compounds when compared on a strain range basis.

Noebe, R. D.↗
NASA NTRS1994

Structural and stratigraphic features and ERS 1 synthetic aperture radar backscatter characteristics of ice growing on shallow lakes in NW Alaska, winter 1991-1992

Changes in Earth Remote-Sensing Satellite (ERS) 1 C band synthetic aperture radar (SAR) backscatter intensity (sigma(exp 0)) from ice growing on shallow tundra lakes at three locations in NW Alaska are described. Ice core analysis shows that all lakes on the coast at Barrow the ice, whether floating or frozen to the bottom, includes an inclusion-free layer overlying a layer of ice with tubular bubbles oriented parallel to the direction of growth. The clear ice may also be overlain by a discontinuous layer of bubbly snow ice. Backscatter is low (-16 to -22 dB) at the time of initial ice formation, probably due to the specular nature of the upper and lower ice surfaces causing the radar pulse to be reflected away from the radar. As the ice thickens during the autumn, backscatter rises steadily. Once the ice freezes to the lake bottom, regardless of the presence of foward scattering tubular bubbles, low backscatter values of -17 to -18 dB are caused by absorption of the radar signal in the lake bed. For ice that remains afloat all winter the ice-water interface and the tubular bubbles combine, presumably via an incoherent double-bounce mechanism, to cause maximum backscatter values of the order of -6 to -7 dB. The sigma(exp 0) saturates at -6 to -7 dB before maximum ice thickness and tubular bubble content are attained. A simple ice growth model suggests that the layer of ice with tubular bubbles need be only a few centimeters thick midway through the growth season to cause maximum backscatter from floating ice. During the spring thaw a previously unreported backscatter reversal is observed on the floating and grounded portions of the coastal lakes but not on the lakes farther inland. This reversal may be related to the ice surface topography and wetness plus the effects of a longer, cooler melt period by the coast. Time series of backscatter variations from shallow tundra lakes are a record of (1) the development of tubular bubbles in the ice and, by association, changes in the gas content of the underlying water and (2) the freezing of ice to the bottoms of the lakes and therefore lake bathymetry and water availability. SAR is also able to detect the onset of lake ice growth in autumn and the initiation of the spring thaw and thus has potential for monitoring high-altitude lake ice growth and decay processes in relation to climate variability.

Jeffries, M. O.↗
NASA NTRS1994

Cosmic ray transverse gradient for a Hale cycle

We have used neutron monitor data obtained at Deep River and Huancayo as well as the vertical underground telescope data obtained at Embudo to compute the cosmic ray transverse gradient (G(sub theta)) for the 1965 to 1990 period. The computed mean value of G(sub theta) for a given qA epoch, changes sign with the change in the solar magnetic polairty in accordance with the predictions of some contemporary hypotheses. Also, we find that the magnitude of G(sub theta) undergoes a significant time variation during a given polarity epoch. It has the largest value near the solar polar field reversal epoch boundaries, when magnetic polarity in the solar northern hemisphere is positive (qA greater than O). For each of the three solar polar field reversals, the change in the magnitude of G(sub theta) is steeper across the epoch boundaries. There is a good correlation between G(sub theta) and the tilt angle of the helisopheric neutral current sheet (HNCS). Our results are in agreement with the reported piecemeal measurements of the latitudinal gradient made by spacecrafts, at different times, at lower primary energies, at far off distances from Earth's orbit. As such, their global significace is appreciable. Even so, it is not clear yet how these findings reflect upon the drift hypothesis in its present form. However, they do affirm the important role played by the tilt angle of HNCS in the modulation processes.

Ahluwalia, H. S.↗