LARGE-AREA ATOMIC LAYER DEPOSITION (ALD) OF TITANIUM NITRIDE FOR RF WINDOWS
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21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
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Proximity ferroelectricity in wurtzite heterostructures
Proximity ferroelectricity is an interface-associated phenomenon in electric-field-driven polarization reversal in a non-ferroelectric polar material induced by one or more adjacent ferroelectric materials. Here, in this paper, we report proximity ferroelectricity in wurtzite ferroelectric heterostructures. In the present case, the non-ferroelectric layers are AlN and ZnO, whereas the ferroelectric layers are Al 1−x B x N, Al 1−x Sc x N and Zn 1−x Mg x O. The layered structures include nitride–nitride, oxide–oxide and nitride–oxide stacks that feature two-layer (asymmetric) and three-layer (symmetric) configurations. Ferroelectric switching in both layers is validated by multimodal characterization methods, including polarization hysteresis, anisotropic chemical etching, second harmonic generation, piezo response force microscopy, electromechanical testing and atomic resolution polarization orientation imaging in real space by scanning transmission electron microscopy. We present a physical switching model in which antipolar nuclei originate in the ferroelectric layer and propagate towards the internal non-ferroelectric interface. The domain wall leading edge produces elastic and electric fields that extend beyond the interface at close proximity, reducing the switching barrier in the non-ferroelectric layer, and allowing complete domain propagation without breakdown. Density functional theory calculations of polymorph energies, reversal barriers and domain wall energies support this model. Proximity ferroelectricity enables polarization reversal in wurtzites without the chemical or structural disorder that accompanies elemental substitution, opening new questions and opportunities regarding interface-based ferroelectricity.
36 MATERIALS SCIENCE↗
Modification of LiMn 2 O 4 surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition
In this combined theoretical and experimental study, we report the effects of Al precursor selection on the growth chemistry, interfacial structure, and electrochemistry of Al 2 O 3 coatings on spinel LiMn 2 O 4 (LMO) surfaces by atomic layer deposition (ALD). Five Al precursors, exhibiting a range of Lewis acid-base properties, were used to establish trends in the ALD Al 2 O 3 growth chemistry on LMO powders in comparison to redox-inactive planar silicon substrates. We show that the Lewis acid-base properties of the Al precursor ligands can be used to tune both the Mn oxidation states and the Al 2 O 3 coverage on the LMO surface. Density functional theory calculations are used to examine the reaction mechanism of each precursor on LMO surfaces, elucidating a correlation between the Lewis acidity of the ligands and the decomposition thermochemistry. In-depth X-ray photoelectron spectroscopy and in situ Fourier transform infrared spectroscopy measurements support these theoretical predictions and further reveal how different Al precursors modify the atomic and electronic structure near the LMO surface during ALD. While the Mn oxidation state is strongly influenced by the Lewis acidity of the precursor ligand, the surface coverage and thickness of the Al 2 O 3 coating are a more representative descriptor of the electrochemical performance measured in coin cell experiments. Finally, we show how the ligand acid-base properties of ALD precursors can be used to rationally tailor atomic layer growth mechanisms, which may enable atomic level control over the structure of functionalized interfaces for various applications related to catalysis, semiconductors, and energy storage.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A pillar-layered metal-organic framework as luminescent sensor for selective and reversible response of chloroform
A new 3D metal-organic framework, namely, (Zn{sub 4}(H{sub 2}BPTC){sub 2}(HCOO){sub 4}){sub n} (SNNU-1, H{sub 4}BPTC=biphenyl-3,3',5,5'-tetracarboxylic acid, SNNU=Shaanxi Normal University) has been solvothermal synthesized. Four independent tetrahedral Zn atoms are connected by organic ligands to form a 2D Zn-H{sub 2}BPTC layer, which is further bridged by in-situ generated HCOO{sup -} to give the 3D pillar-layered framework of SNNU-1. Unique Zn and H{sub 2}BPTC all act as 4-connected nodes leading to a new 4,4,4-connected topological net with point symbol of (4·5·6{sup 2}·8{sup 2})(4·5{sup 2}·6{sup 2}·8)(5{sup 2}·6{sup 3}·7). Notably, intense blue emission band is observed for SNNU-1, which exhibits solvent-dependent effect. Compared to other common organic solvents, chloroform can specially improve the photoluminescent intensity of SNNU-1. Further repeated response and release experiments clearly showed that SNNU-1 can act as luminescent sensor for selective and reversible detection of chloroform. - Graphical abstract: Zn{sup 2+} ions are bridged by aromatic tetracarboxylate ligands and inorganic formate anions to give a microporous pillar layered open-framework, which exhibits not only strong photoluminescence but also selective and reversible luminescent sensing for chloroform. - Highlights: • Novel Zn-tetracarboxylate-formate microporous pillar layered open-framework. • New 4,4,4-connected topology and rod-packing net. • Solvent-dependent photoluminescent intensity. • Selective and reversible response for chloroform.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Mechanism and Features of Field Emission in Semiconductors
The field electron emission from individual grains on the surface of Si and III–V semiconductors, namely, gallium arsenide, indium arsenide, and indium antimonide is investigated by scanning tunneling microscopy. From the correspondence of the functional dependence of the I–V characteristic to the theory, the emission mechanism is determined as direct tunneling through a depleted or enriched subsurface layer at the voltages V < 1 V and the tunneling emission from the surface electronic states at the voltages V > 1 V. A field-emission threshold of (1–5) × 10{sup 6} V/cm is obtained, which is significantly lower than the values for metals and carbon. The determining factors of this emission mechanism are the Schottky effect, the localization and size quantization of “light” electrons in the surface area of III–V semiconductors, and the presence of a subsurface depletion layer in silicon. According to the data obtained for the values of the field-emission threshold, indium antimonide in the form of submicron grain particles is the most efficient field emitter.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Correlated lateral phase separations in stacks of lipid membranes
Motivated by the experimental study of Tayebi et al. [Nat. Mater. 11, 1074 (2012)] on phase separation of stacked multi-component lipid bilayers, we propose a model composed of stacked two-dimensional Ising spins. We study both its static and dynamical features using Monte Carlo simulations with Kawasaki spin exchange dynamics that conserves the order parameter. We show that at thermodynamical equilibrium, due to strong inter-layer correlations, the system forms a continuous columnar structure for any finite interaction across adjacent layers. Furthermore, the phase separation shows a faster dynamics as the inter-layer interaction is increased. This temporal behavior is mainly due to an effective deeper temperature quench because of the larger value of the critical temperature, T{sub c}, for larger inter-layer interaction. When the temperature ratio, T/T{sub c}, is kept fixed, the temporal growth exponent does not increase and even slightly decreases as a function of the increased inter-layer interaction.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Hybrid equilibria of field-reversed configurations
This paper presents the first detailed model of hybrid equilibria relevant to field-reversed configuration experiments, leading to a system of equations that are solved for a range of fully two-dimensional equilibria. Several features of these highly kinetic objects are explored. The range of equilibria is primarily dependent on a single free parameter related to the flow shear. The level of flow shear has a profound effect on the structure, especially near the separatrix. This likely has a strong influence on both stability and transport properties. Higher flow shear is favorable in every respect. The key factor behind the influence of flow shear is the relatively rapid end loss of unconfined ions. Differences between hybrid and static-fluid equilibrium models are highlighted, including the integrity of surface functions, the effect of flow shear, and the scrape-off layer thickness.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
White-blue electroluminescence from a Si quantum dot hybrid light-emitting diode
A silicon (Si) quantum dot (QD)-based hybrid inorganic/organic light-emitting diode (LED) was fabricated via solution processing. This device exhibited white-blue electroluminescence at a low applied voltage of 6 V, with 78% of the effective emission obtained from the Si QDs. This hybrid LED produced current and optical power densities 280 and 350 times greater than those previously reported for such device. The superior performance of this hybrid device was obtained by both the prepared Si QDs and the optimized layer structure and thereby improving carrier migration through the hybrid LED and carrier recombination in the homogeneous Si QD layer.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Modification of surface oxide layers of titanium targets for increasing lifetime of neutron tubes
The peculiarities of interaction of hydrogen ions with a titanium target and its surface oxide layer were studied. Two ways of modification of the surface oxide layers of titanium targets for increasing the lifetime of neutron tubes were proposed: (1) deposition of an yttrium oxide barrier layer on the target surface; (2) implementation of neutron tube work regime in which the target is irradiated with ions with energies lower than 1000 eV between high-energy ion irradiation pulses.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Kelvin-Helmholtz instability in a current-vortex sheet at a 3D magnetic null
We report here, for the first time, an observed instability of a Kelvin-Helmholtz nature occurring in a fully three-dimensional (3D) current-vortex sheet at the fan plane of a 3D magnetic null point. The current-vortex layer forms self-consistently in response to foot point driving around the spine lines of the null. The layer first becomes unstable at an intermediate distance from the null point, with the instability being characterized by a rippling of the fan surface and a filamentation of the current density and vorticity in the shear layer. Owing to the 3D geometry of the shear layer, a branching of the current filaments and vortices is observed. The instability results in a mixing of plasma between the two topologically distinct regions of magnetic flux on either side of the fan separatrix surface, as flux is reconnected across this surface. We make a preliminary investigation of the scaling of the system with the dissipation parameters. Our results indicate that the fan plane separatrix surface is an ideal candidate for the formation of current-vortex sheets in complex magnetic fields and, therefore, the enhanced heating and connectivity change associated with the instabilities of such layers.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Role of dislocation scattering on electron mobility in coalescent epitaxial lateral overgrowth layers of InP
In order to clarify the effects of dislocation scattering on electron transport properties, temperature dependent (15-300 K) Hall-effect measurements were applied to the dislocated coalescent and dislocation-free non-coalescent ELO layers of InP prepared by the liquid phase epitaxy. The coalescent ELO layers contain a large number of dislocations, and the non-coalescent ELO layers are dislocation-free. Taking into account, the various electron scattering mechanisms in compound semiconductors, the temperature dependences of electron mobility were analyzed. It is shown that the dislocation scattering based on the charged dislocation line model is dominant transport mechanism in the dislocated coalescent ELO layers at low temperature.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
An Assessment of Our Ability to Model the Upper Troposphere and Lower Stratosphere in Interactive Climate Models
The physics of the upper troposphere is dominated by the different phases of water, while the lower stratosphere is governed by the presence of ozone. The tropopause may be regarded as the layer which separates the regions where stratospheric and tropospheric processes dominate the physics, but it is clearly not a smooth transition level. Modelling this region in comprehensive climate models is complicated, partly because of the constraints inherent in numerical methods (such as the finite resolution used in models) and partly because of our incomplete knowledge of the physical and chemical interactions which occur (such as the phase transitions of water and the composition of aerosols). However, studies of stratospheric impacts on climate change clearly require the tropopause region to be modelled with a high degree of accuracy. This paper will examine how well we can currently model the structure and dynamics of the tropopause region; this includes some comparisons of the simulated atmospheric composition with observational estimates of these species, some studies of discrepancies between forecasts and observations in the Data Assimilation System of the Data Assimilation office, and inferences for sparsely observed quantities. The analysis will focus on meteorological quantities, physical forcing mechanisms, and the transport and interactions of trace species.
Pawson, Steven↗
Polar Layered Terrains: Links Between the Martian Volatile and Dust Cycles
The nature, origin and evolution of the polar layered terrains are a major mystery of Martian climate. Almost every aspect of these enigmatic terrains surrounding, and probably underlying, the polar residual ice caps is in contention. Are the polar laminae forming today? Are they inactive or even eroding, being mere relics of the past? Are the north and south polar layered terrains fundamentally different in composition, age or process? Are they a physical record of past, possibly cyclic, climate change and, if so, can we learn to read that record? We know from past Mariner 9 and Viking orbital observations that there are layered terrains at high latitudes, defined by alternating bands of visually lighter and darker material appearing in stacks hundreds of meters thick with individual bands as thin as could then be resolved (tens of meters). In this talk, aspects of the polar layered terrains will be reviewed with emphasis on issues likely to be addressed with data from ongoing and near-term flight missions to Mars. Particular attention will be given to what might be learned from observing the present seasonal cycles of dust, water and carbon dioxide on Mars, in conjunction with in situ data from one site on the south polar layered terrain.
Zurek, R. W.↗
Performance of Spherical Quantum Well Down Converters in Solid State Lighting
We report the color conversion performance of amber and red emitting quantum dots (QDs) on InGaN solid-state lighting (SSL) light emitting diode (LED) packages. Spherical quantum well (SQW) architectures (CdS/CdSe 1- x S x /CdS) were prepared using a library of thio- and selenourea synthesis reagents and high throughput synthesis robotics. CdS/CdSe 1- x S x QDs with narrow luminescence bands were coated with thick CdS shells (thickness = 1.6-7.5 nm) to achieve photoluminescence quantum yields (PLQY) up to 88% at amber and red emission wavelengths (λ max = 600-642 nm, FWHM < 45 nm). The photoluminescence from SQWs encapsulated in silicone and deposited on LED packages was monitored under accelerated aging conditions (oven temperature = 85 °C, relative humidity = 5-85%, blue optical power density = 3-45 W/cm 2 ) by monitoring the red photon output over several hundred hours of continuous operation. The growth of a ZnS shell on the SQW surface increases the stability under long-term operation but also reduces the PLQY, especially of SQWs with thick CdS shells. The results illustrate that the outer ZnS shell layer is key to optimizing the PLQY and the long-term stability of QDs during operation on SSL packages.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Wavelet analysis methods for radiography of multidimensional growth of planar mixing layers
The counter-propagating shear campaign is examining instability growth and its transition to turbulence in the high-energy-density physics regime using a laser-driven counter-propagating flow platform. In these experiments, we observe consistent complex break-up of and structure growth in a tracer layer placed at the shear flow interface during the instability growth phase. We present a wavelet-transform based analysis technique capable of characterizing the scale- and directionality-resolved average intensity perturbations in static radiographs of the experiment. This technique uses the complete spatial information available in each radiograph to describe the structure evolution. We designed this analysis technique to generate a two-dimensional power spectrum for each radiograph from which we can recover information about structure widths, amplitudes, and orientations. The evolution of the distribution of power in the spectra for an experimental series is a potential metric for quantifying the structure size evolution as well as a system’s evolution towards isotropy.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Influence of piezoelectric strain on the Raman spectra of BiFeO 3 films deposited on PMN-PT substrates
In this study, BiFeO 3 epitaxial thin films were deposited on piezoelectric 0.72Pb(Mg 1/3 Nb 2/3 )O 3 -0.28PbTiO 3 (PMN-PT) substrates with a conductive buffer layer (La 0.7 Sr 0.3 MnO 3 or SrRuO 3 ) using pulsed laser deposition. The calibration of the strain values induced by the electric field applied on the piezoelectric PMN-PT substrates was realised using X-Ray diffraction measurements. The method of piezoelectrically induced strain allows to obtain a quantitative correlation between strain and the shift of the Raman-active phonons, ruling out the influence of extrinsic factors, such as growth conditions, crystalline quality of substrates, or film thickness. Using the Poisson number for BiFeO 3 one can determine the volume change induced by strain, and therefore the Gr neisen parameters for specific phonon modes.
36 MATERIALS SCIENCE↗
High mobility in a van der Waals layered antiferromagnetic metal
Van der Waals (vdW) materials with magnetic order have been heavily pursued for fundamental physics as well as for device design. Despite the rapid advances, so far, they are mainly insulating or semiconducting, and none of them has a high electronic mobility—a property that is rare in layered vdW materials in general. The realization of a high-mobility vdW material that also exhibits magnetic order would open the possibility for novel magnetic twistronic or spintronic devices. Here, we report very high carrier mobility in the layered vdW antiferromagnet GdTe 3 . The electron mobility is beyond 60,000 cm 2 V –1 s –1 , which is the highest among all known layered magnetic materials, to the best of our knowledge. Among all known vdW materials, the mobility of bulk GdTe 3 is comparable to that of black phosphorus. By mechanical exfoliation, we further demonstrate that GdTe 3 can be exfoliated to ultrathin flakes of three monolayers.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Free Energy Relationships in the Electrical Double Layer Over Single Layer Graphene
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catalysis (heterogeneous)↗