Assessing First-Order Dependence of Thermolytic HGR on Glycolate at Low Glycolate Concentrations
This report describes the results of testing performed to investigate the assumed first-order behavior of glycolate at low concentrations in the current Glycolate Thermolytic Hydrogen Generation Rate (HGR) expression. Four experiments were performed at 100 °C using a simulant based on a Tank 28 supernate sample, and the glycolate concentration in the experiments ranged from 5 - 175 mg/L. The thermolytic HGR results from all tests were well-described by the current Glycolate Thermolytic HGR Model. A linear fit of the Ln(HGR) and Ln(Gly) gave a suggested reaction order of 1.15. Additionally, by taking into account prior knowledge on how varying chemistry impacts the HGR, a reaction order of 0.99 was obtained. Both cases suggest that the data validates the assumed first-order dependence of HGR on glycolate.