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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Return of the coral reef hypothesis - Basin to shelf partitioning of CaCO3 and its effect on atmospheric CO2

CaCO3 deposition rates in shallow water are assumed to vary in a sawtoothed manner about a long-term average deposition rate of 8 x 10 exp 12 mol/yr. It is proposed that rising sea level serves as the driving mechanism for changing the locus of CaCO3 deposition from deep sea to shallow shelf. Deposition on the shelves occurs when sea level is rising, while shelf carbonates dissolve when sea level is falling. It is shown that this mechanism alone can account for variations of atmospheric CO2 and can contribute to the pelagic carbonate dissolution cycles observed in the equatorial Pacific.

Opdyke, Bradley N.↗
NASA NTRS1993

Model simulations of the competing climatic effects of SO2 and CO2

Sulfur dioxide-derived cloud condensation nuclei are expected to enhance the planetary albedo, thereby cooling the planet. This effect might counteract the global warming expected from enhanced greenhouse gases. A detailed treatment of the relationship between fossil fuel burning and the SO2 effect on cloud albedo is implemented in a two-dimensional model for assessing the climate impact. Using a conservative approach, results show that the cooling induced by the SO2 emission can presently counteract 50 percent of the CO2 greenhouse warming. Since 1980, a strong warming trend has been predicted by the model: 0.15 C during the 1980-1990 period alone. The model predicts that by the year 2060 the SO2 cooling reduces climate warming by 0.5 C or 25 percent for the Intergovernmental Panel on Climate Change (IPCC) business as usual (BAU) scenario and 0.2 C or 20 percent for scenario D (for a slow pace of fossil fuel burning). The hypothesis is examined that the different responses between the Northern Hemisphere and the Southern Hemisphere can be used to validate the presence of the SO2-induced cooling.

Kaufman, Yoram J.↗
NASA NTRS1993

Intensities and broadening coefficients for the Q branch of the 4nu-2 - nu-1 + nu-2 (471.511/cm) band of CO2

Absolute intensities for the Q-branch of the 4nu-2 - nu-1 + nu-1/2 (20,003-11,101) band in CO2 were measured for the first time. Measurements were performed for lines Q10 to Q28, at temperatures ranging from 385 to 426 K, for pressures from 3 to 40 torr, using our long wavelength tunable diode laser spectrometer. The combination of tunable diode lasers, a White cell, and a blocked impurity band detector made it possible to obtain signal to noise ratios greater than 1000 in the 471/cm spectral region, with about 3 x 10 exp -4/cm spectral resolution. The band strength was found to be 8.6(2) x 10 exp -25 cm/molec at 296 K, and the Hermann-Wallis factor was determined. Comparison with the values listed in the HITRAN 92 data base are presented. Self-, N2- and O2-broadening coefficients were also measured.

Sirota, J. M.↗
NASA NTRS1992

Pulsed CO2 characterization for lidar use

An account is given of a scaled functional testbed laser for space-qualified coherent-detection lidar applications which employs a CO2 laser. This laser has undergone modification and characterization for inherent performance capabilities as a model of coherent detection. While characterization results show good overall performance that is in agreement with theoretical predictions, frequency-stability and pulse-length limitations severely limit the laser's use in coherent detection.

Jaenisch, Holger M.↗
NASA NTRS1993

CO2 production by impact in carbonates? An ATEM and stable isotope (C,O) study

Carbonates may have been a common target for large impacts on the Earth and possible related CO2 outgassing would have important consequences for the composition of the atmosphere. To estimate volatile release during such impacts, isotopic ratios (C-13/C-12 and O-18/O-16) were determined on highly shocked carbonate samples in combination with SEM and analytical transmission electron microscopy (ATEM) investigations. The study was performed on both naturally and experimentally shocked rocks, i.e. 50-60 GPa shocked limestone-dolomite fragments from the Haughton impact crater (Canada), and carbonates shocked in shock recovery experiments. For the experiments, unshocked carbonates consisting of mixture of dolomite and calcite from the Haughton area were used. Naturally shocked samples were collected in the polymict breccia near the center of the Haughton crater.

Martinez, I.↗
NASA NTRS1993

CO2 lidar observations of Mount Pinatubo debris: FIRE 2 and longer-term measurements

The volcanic debris in the stratosphere from the June 1991 eruption of Mt. Pinatubo first appeared over the NOAA Wave Propagation Laboratory (WPL) field site near Boulder, Colorado (40.15 N, 105.23 W), in July of 1991. The presence of the Pinatubo cloud has allowed us to characterize both the tropospheric and stratospheric aerosol backscatter using the NOAA/WPL CO2 Doppler lidar. The lidar has measured vertical backscatter profiles at lambda = 10.59 mu m for over a decade. Analysis of this dense set of profiles reveals the effects of atmospheric and microphysical processes during the buildup and decay of Mt. Pinatubo's clouds. Further information on the NOAA lidar, specifically calibrations using a hard target, can be found in Post and Cupp (1990). We present results of those measurements for June 15, 1991, through December 31, 1992. During that period of longer-term measurements, WPL took part in FIRE II (First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment II), from November 12 through December 8, 1991, measuring vertical backscatter profiles almost daily. One of the mechanisms for purging stratospheric aerosols is tropopause folding, which occurs in cold-core extratropical cyclones. Tropospheric mass loading occurs during folding events which can substantially increase the amount of ice nuclei in the upper troposphere, and may affect the formation of cirrus in that region. Spring and fall are prominent times for tropopause folding events because of the migration of the subtropical and polar jet streams during the transition seasons. Sassen has suggested that the volcanic aerosols from Pinatubo played a role in the formation of cirrus during FIRE II, particularly during a period of moist subtropical flow on December 5-6, 1991.

Levinson, David H.↗
NASA NTRS1995

The effects of CO2 on the negative reactant ions of IMS

In the presence of CO2, the negative reactant ions of ion mobility spectrometry (IMS) are ion clusters of CO4(-) and CO3(-). Methyl salicylate is ionized by the CO4(-)(H2O(n))(N2(m)) reactant ions, but not by the CO3(-)(H2O(n))(N2(m)) reactant ions. While the CO4(-) ions are formed by direct association, the CO3(-) ions require additional energy to be formed. The additional energy is provided by either excited neutral gas molecules in a metastable state or UV (ultraviolet) radiation.

Spangler, Glenn E.↗
NASA NTRS1994

Airborne CO2 coherent lidar measurements of cloud backscatter and opacity over the ocean surface

The use of an airborne CO2 lidar to obtain cloud backscatter and extinction data at a thermal infrared wavelength is described. The extinction in this spectral region is proportional to the cloud liquid water content. The use of coherent detection results in high sensitivity and narrow field of view, the latter property greatly reducing multiple-scattering effects. Backscatter measurements in absolute units are obtained through a hard target calibration methodology. For clouds of low to moderate optical thickness at the lidar wavelength, both geometric thickness and optical thickness can be measured. The sea surface reflectance signal is used to obtain estimates of the cloud optical thickness. The utility of this technique results from studies that indicate that the spatial scale of variability of the sea surface reflectance is generally large compared with that of cloud optical thickness. Selected results are presented from data taken during flights over the Pacific Ocean.

Menzies, Robert T.↗
NASA NTRS1994

The impact of a 2 X CO2 climate on lightning-caused fires

Future climate change could have significant repercussions for lightning-caused wildfires. Two empirical fire models are presented relating the frequency of lightning fires and the area burned by these fires to the effective precipitation and the frequency of thunderstorm activity. One model deals with the seasonal variations in lightning fires, while the second model deals with the interannual variations of lightning fires. These fire models are then used with the Goddard Institute for Space Studies General Circulation Model to investigate possible changes in fire frequency and area burned in a 2 X CO2 climate. In the United States, the annual mean number of lightning fires increases by 44%, while the area burned increases by 78%. On a global scale, the largest increase in lightning fires can be expected in untouched tropical ecosystems where few natural fires occur today.

Price, Colin↗
NASA NTRS1995

Stratospheric and mesospheric pressure-temperature profiles from rotational analysis of CO2 lines in atmospheric trace molecule spectroscopy/ATLAS 1 infrared solar occultation spectra

A simple, classical, and expedient method for the retrieval of atmospheric pressure-temperature profiles has been applied to the high-resolution infrared solar absorption spectra obtained with the atmospheric trace molecule spectroscopy (ATMOS) instrument. The basis for this method is a rotational analysis of retrieved apparent abundances from CO2 rovibrational absorption lines, employing existing constituent concentration retrieval software used in the analysis of data returned by ATMOS. Pressure-temperature profiles derived from spectra acquired during the ATLAS 1 space shuttle mission of March-April 1992 are quantitatively evaluated and compared with climatological and meteorological data as a means of assessing the validity of this approach.

Stiller, G. P.↗
NASA NTRS1994

A compilation of first-order line-mixing coefficients for CO2 Q-branches

A parameterization of first-order line-mixing in CO2 Q-branches is presented for use in atmospheric radiative transfer codes. Regression coefficients for the temperature dependence of the first-order line-mixing parameters for each J in 11 of the strongest Q-branches between 600 and 3000/cm are given. These coefficients may only be used with the line strengths and widths reported in the HITRAN92 line compilation; otherwise large errors will be introduced into the calculated line shape. Other potential problems in the implementation of first-order line-mixing in radiative transfer codes are also discussed.

Strow, L. Larrabee↗
NASA NTRS1995

Single crystal silicon filaments fabricated in SOI: A potential IR source for a microfabricated photometric CO2 sensor

The objective of this project was to design, fabricate, and test single crystal silicon filaments as potential black body IR sources for a spectrophotometric CO2 sensing microsystem. The design and fabrication of the silicon-on-insulator (SOI) filaments are summarized and figures showing the composite layout of the filament die (which contains four filaments of different lengths -- 500 microns, 1 mm, 1.5 mm and 2 mm -- and equal widths of 15 microns) are presented. The composite includes four mask layers: (1) silicon - defines the filament dimensions and contact pads; (2) release pit - defines the oxide removed from under the filament and hence, the length of the released filament; (3) Pyrex pit - defines the pit etched in the Pyrex cap (not used); and (4) metal - defines a metal pattern on the contact pads or used as a contact hole etch. I/V characteristics testing of the fabricated SOI filaments is described along with the nitride-coating procedures carried out to prevent oxidation and resistance instability.

Tu, Juliana↗
NASA NTRS1996

Stable isotope analysis of molecular oxygen from silicates and oxides using CO2 laser extraction

A laser-excited system for determination of the oxygen isotope composition of small quantities of silicate and oxide minerals was constructed and tested at JSC. This device is the first reported to use a commercially available helium cryostat to transfer and purify oxygen gas quantitatively within the system. The system uses oxygen gas instead of the conventional CO2 for mass spectrometer analyses. This modification of technique permits determination of all three stable oxygen isotopes, an essential requirement for oxygen isotope analysis of meteoritic material. Tests of the system included analysis of standard silicate materials NBS 28 and UWMG2 garnet, six SNC meteorites, and inclusions and chondrules from the Allende meteorite. Calibration with terrestrial standards was excellent. Meteorite values are close to published values and show no evidence of terrestrial oxygen contamination. The one limitation observed is that, in some runs on fine-grained SNC matrix material, sample results were affected by other samples in the sample holder within the reaction chamber. This reemphasizes the need for special precautions in dealing with fine-grained, reactive samples. Performance of the JSC instrument compares favorably with that of any other instrument currently producing published oxygen isotope data.

Perry, Eugene↗
NASA NTRS1996

Collisional Removal of OH (X (sup 2)Pi, nu=7) by O2, N2, CO2, and N2O

Collisional removal rate constants for the OH (X 2PI, nu = 7) radical are measured for the colliders O2, CO2, and N2O, and an upper limit is established for N2. OH(nu = 4) molecules, generated in a microwave discharge flow cell by the reaction of hydrogen atoms with ozone, are excited to v = 7 by the output of a pulsed infrared laser via direct vibrational overtone excitation. The temporal evolution of the P = 7 population is probed as a function of the collider gas partial pressure by a time-delayed pulsed ultraviolet laser. Fluorescence from the B 21 + state is detected in the visible spectral region.

Knutsen, Karen↗
NASA NTRS1996

Enhanced Molecular Sieve CO2 Removal Evaluation

The objective of this research is to quantitatively characterize the performance of two major types of molecular sieves for two-bed regenerative carbon dioxide removal at the conditions compatible with both a spacesuit and station application. One sorbent is a zeolite-based molecular sieve that has been substantially improved over the materials used in Skylab. The second sorbent is a recently developed carbon-based molecular sieve. Both molecular sieves offer the potential of high payoff for future manned missions by reducing system complexity, weight (including consumables), and power consumption in comparison with competing concepts. The research reported here provides the technical data required to improve CO2 removal systems for regenerative life support systems for future IVA and EVA missions.

Rose, Susan↗
NASA NTRS1997

Measurement of Momentum Transfer Coefficients for H2, N2, CO, and CO2 Incident Upon Spacecraft Surfaces

Measurements of momentum transfer coefficients were made for gas-surface interactions between the Space Shuttle reaction control jet plume gases and the solar panel array materials to be used on the International Space Station. Actual conditions were simulated using a supersonic nozzle source to produce beams of the gases with approximately the same average velocities as the gases have in the Shuttle plumes. Samples of the actual solar panel materials were mounted on a torsion balance that was used to measure the force exerted on the surfaces by the molecular beams. Measurements were made with H2, N2, CO, and CO2 incident upon the solar array material, Kapton, SiO2-coated Kapton, and Z93-coated Al. The measurements showed that molecules scatter from the surfaces more specularly as the angle of incidence increases and that the scattering behavior has a strong dependence upon both the incident gas and velocity. These results show that for some technical surfaces the simple assumption of diffuse scattering with complete thermal accommodation is entirely inadequate. It is clear that additional measurements are required to produce models that more accurately describe the gas-surface interactions encountered in rarefied flow regimes.

Cook, Steven R.↗
NASA NTRS1997

Measurements of momentum transfer coefficients for H2, N2, CO and CO2 incident upon spacecraft surfaces

Measurements of momentum transfer coefficients were made for gas-surface interactions between the Space Shuttle reaction control jet plume gases and the solar panel array materials to be used on the International Space Station. Actual conditions were simulated using a supersonic nozzle source to produce beams of the gases with approximately the same average velocities as the gases have in the Shuttle plumes. Samples of the actual solar panel materials were mounted on a torsion balance that was used to measure the force exerted on the surfaces by the molecular beams. Measurements were made with H2, N2, CO, and CO2 incident upon the solar array material, Kapton, SiO2-coated Kapton, and Z93-coated Al. The measurements showed that molecules scatter from the surfaces more specularly as the angle of incidence increases and that scattering behavior has a strong dependence upon both the incident gas and velocity. These results show that for some technical surfaces the simple assumption of diffuse scattering with complete thermal accommodation is entirely inadequate. It is clear that additional measurements are required to produce models that more accurately describe the gas-surface interactions encountered in rarefied flow regimes.

Cook, S. R.↗
NASA NTRS1999

Interference of Backscatter from Two Droplets in a Focused Continuous-Wave CO2 Doppler Lidar Beam

With a focused continuous-wave CO2 Doppler lidar at 9.1-microns wavelength, the superposition of backscatter from two approximately 14.12-micron-diameter silicone oil droplets in the lidar beam produced interference that resulted in a single backscatter pulse from the two droplets with a distinct periodic structure. This interference is caused by the phase difference in backscatter from the two droplets while they are traversing the lidar beam at different speeds, and thus the droplet separation is not constant. The complete cycle of interference, with periodicity 2(pi), gives excellent agreement between measurements and lidar theory.

Jarzembski, Maurice A.↗