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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Airborne Observations of Particle Density in High Ice Water Content (HWC) Cloud Systems

A series of airborne field campaigns has been conducted since 2014 to measure the microphysical properties of high ice-water content (HIWC) clouds in maritime mesoscale convective systems (MCS) and tropical storms. Two of these, the HIWC RADAR-2 campaign (2018) targeting cloud systems in the Gulf of Mexico and Pacific Ocean, and the HIWC-2022 campaign targeting cloud systems in the Gulf of Mexico, Caribbean Sea, and Atlantic Ocean, have been analyzed to investigate graupel encounters at typical jet aircraft cruise altitudes. In-situ cloud observations from these two campaigns confirmed results from the prior studies, indicating that high concentrations of small ice particles exist in areas of HIWC. However, in the 2022 campaign, 90% of the cloud regions with ice water content (IWC) above 2.0 g/m3 also contained significant amounts of graupel and/or frozen drops. Using a mass-size parameterization that accounts for both small ice and larger high-density particles, we show that the mass distributions in cloud regions above 2.0 g/m3 are often strongly bimodal, with the small particle mode containing roughly half of the collective cloud mass, and the graupel mode containing the other half. In contrast, HIWC cloud passes in a 2018 tropical cyclone contained less relative graupel mass than the MCS cloud systems of 2018 and 2022. We present two different methods of estimating particle mass for mixed populations of small-ice and graupel particles, one using a hybrid two-class approach, and another using a single-class approach that takes both particle size and shape metrics into account. Derived IWC using these methods are compared to bulk IWC measurements collected during the campaigns. We also show the relative occurrence of graupel at various IWC levels and discuss the potential application of these results in evaluating density-aware microphysical schemes in cloud and weather models.

Aircraft Icing↗
DOE OSTI2020

NCS design and evaluation of new high-density storage containers

Changes in mission at Y-12 National Security Complex evolving over the past five years have resulted in increased levels of storage utilization. This has prompted a need to reevaluate storage capacity and efficiency. As a result, Y-12 Nuclear Criticality Safety (NCS) and Packaging Engineering developed and designed a new modified neutron absorbing container. The high-density storage container is known as the 12-Place Rackable Can Storage Box (12-Place RCSB) and will allow safe and efficient storage of fissile material at the Highly Enriched Uranium Materials Facility (HEUMF).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1983

Flare loop radiative hydrodynamics. III - Nonlocal radiative transfer effects

The study has three goals. The first is to demonstrate that processes exist whose intrinsic nonlocal nature cannot be represented by local approximations. The second is to elucidate the physical nature and origins of these nonlocal processes. The third is to suggest that the methods and results described here may prove useful in constructing semiempirical models of the chromosphere by means more efficient than trial and error. Matrices are computed that describe the effect of a temperature perturbation at an arbitrary point in the loop on density, hydrogen ionized fraction, total radiative loss rate, and radiative loss rate of selected hydrogen lines and continua at all other points. It is found that the dominant nonlocal radiative transfer effects can be separated into flux divergence coefficient effects and upper level population effects. The former are most important when the perturbation takes place in a region of significant opacity. Upper level population effects arise in both optically thick and thin regions in response to nonlocal density, ionization, and interlocking effects.

Canfield, R. C.↗
NASA NTRS2014

Investigation of Structure and Transport in Li-Doped Ionic Liquid Electrolytes: [pyr14][TFSI], [pyr13][FSI] and [EMIM][BF4]

Ionic liquid electrolytes have been proposed as a means of improving the safety and cycling behavior of advanced lithium batteries; however, the properties of these electrolytes under high lithium doping are poorly understood. Here, we employ both polarizable molecular dynamics simulation and experiment to investigate the structure, thermodynamics and transport of three potential electrolytes, N-methyl-Nbutylpyrrolidinium bis(trifluoromethylsufonyl)imide ([pyr14][TFSI]), N- methyl-Npropylpyrrolidinium bis(fluorosufonyl)imide ([pyr13][FSI]), and 1-ethyl-3-- methylimidazolium boron tetrafluoride ([EMIM][BF4]), as a function of Li-salt concentration and temperature. Structurally, Li(+) is shown to be solvated by three anion neighbors in [pyr14][TFSI] and four anion neighbors in both [pyr13][FSI] and [EMIM][BF4], and at all levels of x(sub Li) we find the presence of lithium aggregates. Furthermore, the computed density, diffusion, viscosity, and ionic conductivity show excellent agreement with experimental data. While the diffusion and viscosity exhibit a systematic decrease and increase, respectively, with increasing x(sub Li), the contribution of Li(+) to ionic conductivity increases until reaching a saturation doping level of x(sub Li) is approximately 0.10. Comparatively, the Li(+) conductivity of [pyr14][TFSI] is an order of magnitude lower than that of the other liquids, which range between 0.1 - 0.3 mS/cm. The differences in Li(+) transport are reflected in the residence times of Li(+) with the anions, which are revealed to be much larger for [pyr14][TFSI] (up to 100 ns at the highest doping levels) than in either [EMIM][BF4] or [pyr13][FSI]. Finally, we comment on the relative kinetics of Li(+) transport in each liquid and we present strong evidence for transport through anion exchange (hopping) as opposed to the net motion of Li(+) with its solvation shell (vehicular).

lithium batteries↗
DOE OSTI2021

Progress in Constraining Nuclear Symmetry Energy Using Neutron Star Observables Since GW170817

The density dependence of nuclear symmetry energy is among the most uncertain parts of the Equation of State (EOS) of dense neutron-rich nuclear matter. It is currently poorly known especially at suprasaturation densities partially because of our poor knowledge about isovector nuclear interactions at short distances. Because of its broad impacts on many interesting issues, pinning down the density dependence of nuclear symmetry energy has been a longstanding and shared goal of both astrophysics and nuclear physics. New observational data of neutron stars including their masses, radii, and tidal deformations since GW170817 have helped improve our knowledge about nuclear symmetry energy, especially at high densities. Based on various model analyses of these new data by many people in the nuclear astrophysics community, while our brief review might be incomplete and biased unintentionally, we learned in particular the following: (1) The slope parameter L of nuclear symmetry energy at saturation density ρ0 of nuclear matter from 24 new analyses of neutron star observables was about L≈57.7±19 MeV at a 68% confidence level, consistent with its fiducial value from surveys of over 50 earlier analyses of both terrestrial and astrophysical data within error bars. (2) The curvature Ksym of nuclear symmetry energy at ρ0 from 16 new analyses of neutron star observables was about Ksym≈−107±88 MeV at a 68% confidence level, in very good agreement with the systematics of earlier analyses. (3) The magnitude of nuclear symmetry energy at 2ρ0, i.e., Esym(2ρ0)≈51±13 MeV at a 68% confidence level, was extracted from nine new analyses of neutron star observables, consistent with the results from earlier analyses of heavy-ion reactions and the latest predictions of the state-of-the-art nuclear many-body theories. (4) While the available data from canonical neutron stars did not provide tight constraints on nuclear symmetry energy at densities above about 2ρ0, the lower radius boundary R2.01=12.2 km from NICER’s very recent observation of PSR J0740+6620 of mass 2.08±0.07M⊙ and radius R=12.2–16.3 km at a 68% confidence level set a tight lower limit for nuclear symmetry energy at densities above 2ρ0. (5) Bayesian inferences of nuclear symmetry energy using models encapsulating a first-order hadron–quark phase transition from observables of canonical neutron stars indicated that the phase transition shifted appreciably both L and Ksym to higher values, but with larger uncertainties compared to analyses assuming no such phase transition. (6) The high-density behavior of nuclear symmetry energy significantly affected the minimum frequency necessary to rotationally support GW190814’s secondary component of mass (2.50–2.67) M⊙ as the fastest and most massive pulsar discovered so far. Overall, thanks to the hard work of many people in the astrophysics and nuclear physics community, new data of neutron star observations since the discovery of GW170817 have significantly enriched our knowledge about the symmetry energy of dense neutron-rich nuclear matter.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2011

A Topside Equatorial Ionospheric Density and Composition Climatology During and After Extreme Solar Minimum

During the recent solar minimum, solar activity reached the lowest levels observed during the space age. This extremely low solar activity has accompanied a number of unexpected observations in the Earth's ionosphere and thermosphere when compared to previous solar minima. Among these are the fact that the ionosphere is significantly contracted beyond expectations based on empirical models. Climatological altitude profiles of ion density and composition measurements near the magnetic dip equator are constructed from the C/NOFS satellite to characterize the shape of the top side ionosphere during the recent solar minimum and into the new solar cycle. The variation of the profiles with respect to local time, season, and solar activity are compared to the IRI-2007 model. Building on initial results reported by Heelis et al. [2009], here we describe the extent of the contracted ionosphere, which is found to persist throughout 2009. The shape of the ionosphere during 2010 is found to be consistent with observations from previous solar minima.

Klenzing, J. H.↗
NASA NTRS1987

The abundance of interstellar CO

Data from recent observations of interstellar CO column densities are compiled in tables and graphs and compared with the predictions of theoretical models. The energy-level structure of CO and the excitation of interstellar CO are discussed; UV-absorption and IR line observations are characterized; and techniques used to estimate the CO column density from mm-wavelength observations (based on calibration of the CO line intensity with the column density of H2) are described in detail. Consideration is then given to CO chemistry under interstellar-cloud conditions (isotope fractionation and photodissociation) and models for diffuse, translucent, and dense clouds. A number of unsolved problems requiring additional observations or laboratory investigations are identified.

Van Dishoeck, Ewine F.↗
NASA NTRS1989

Ionization by line photons and its effect on hydrogen line ratios

Inside a line-emitting cloud the density of trapped photons could be so high that they ionize hydrogen atoms from excited levels far more efficiently than electronic collisions. Such ionizations can reduce the population of high-level hydrogen and consequently reduce the Balmer line emissivity by a factor of 3 or more. As a result, the Balmer line emission is not enhanced as significantly in the partially ionized zone as predicted by current models unless an exceptionally large column density is assumed.

Zheng, Wei↗
DOE OSTI2020

CsV 3 Sb 5 : A $\mathbb{Z}_2$ Topological Kagome Metal with a Superconducting Ground State

Recently discovered alongside its sister compounds KV 3 Sb 5 and RbV 3 Sb 5 , CsV 3 Sb 5 crystallizes with an ideal kagome network of vanadium and antimonene layers separated by alkali metal ions. This work presents the electronic properties of CsV 3 Sb 5 , demonstrating bulk superconductivity in single crystals with a T c = 2.5 K. The normal state electronic structure is studied via angle-resolved photoemission spectroscopy and density-functional theory, which categorize CsV 3 Sb 5 as a Z 2 topological metal. Multiple protected Dirac crossings are predicted in close proximity to the Fermi level (E F ), and signatures of normal state correlation effects are also suggested by a high-temperature charge density wavelike instability. Finally, the implications for the formation of unconventional superconductivity in this material are discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Mechanical properties of zeolite-templated carbons from approximate density functional theory calculations

Zeolite-templated carbon (ZTC) is a unique porous carbonaceous material whose structure is ordered at the nanometre scale, enabling a representative periodic description at the atomistic level. Utilizing an existing, well-defined reference model for ZTCs, a structural library of varying compositions was developed by refinement using density-functional tight-binding (DFTB) potentials parameterized for materials science applications. We first determined the quantum chemical-refined structures of models with CH, CHO, CHON, CHOB, and CHOBN compositions with various degrees of heteroatom substitution. These structural models comprise the characteristic morphological features of highly porous carbon materials, such as open-blade surfaces, edges, saddles, and closed-strut formations, spanning a range of curvatures and characteristic sizes. Second, we carried out alternating compression and expansion of the CHO model unit cell to determine the lowest energy structure as well as to obtain its bulk modulus in order to demonstrate a close connection between macroscopic observations and atomic-scale structures. Further, the agreement between experimental measurements and the computational model is remarkable and demonstrates the power of approximate density functional theory as a cost-effective computational tool with chemical accuracy for the investigation of structure/property relationships in real-world carbon-based solids.

03 NATURAL GAS↗
NASA NTRS1989

Nonlinear evolution of the auroral electron beam

The nonlinear spatial evolution, from the source to the atmosphere, of the auroral electron beam and the beam-generated electrostatic whistler noise was studied, calculating changes in beam parameters from equations for the conservation of total particle and wave energy and momentum flux density. Wave power fluxes were calculated by numerically integrating the wave kinetic equations, and the levels of beam-generated noise were determined by using thermal levels of Cerenkov radiation as a source. It was found that beam parameters evolve on ionospheric scale lengths, and their positive slope feature in velocity space is maintained over altitudes measured in thousands of kilometers of altitude, even though they can generate wave energy density fluxes sufficient to modify the ionospheric density profile.

Maggs, James E.↗
DOE OSTI2024

High performance power handling in the absence of an H-mode edge in negative triangularity DIII-D plasmas

Abstract Experiments performed during strongly-shaped high-power diverted negative triangularity (NT) experiments in DIII-D achieved detached divertor conditions and a transient-free edge, showcasing the potential for application of NT to a core-edge integrated reactor-like scenario and providing the first characterization of the parametric dependencies for detachment onset. Detached divertor conditions will be required in future devices to mitigate divertor heat fluxes. Access to dissipative divertor conditions was investigated via an increase in upstream density. Detachment onset at the outer strike point was achieved with H-mode level confinement H 98 − y 2 ∼ 1 and reactor-relevant normalized pressures β N ∼ 2 . Confinement degradation was observed with deeper detachment, associated with the loss of an electron temperature pedestal. Differences in geometry, radial transport, impact of cross field drifts are discussed to explain differences in access to detachment in NT discharges. Higher normalized densities, with respect to equivalent discharges in positive triangularity, were necessary to achieve detachment, partially explained by the shorter parallel connection length to the targets. The effect of cross-field particle drifts ( E × B , B × ∇ B ) on access to detachment was demonstrated by the lower upstream density needed to access detachment with ion B × ∇ B drift directed outside of the active divertor (Greenwald fraction f Gw ∼ 0.9–1.0 vs f Gw ∼ 1.3). The upstream density at detachment onset was observed to increase linearly with plasma current with ion B × ∇ B drift into the divertor, consistent with the observed narrowing of the scrape-off layer heat flux width λ q . Edge fluid simulations capture separatrix densities needed to achieve detachment in NT plasma and their dependence on drift direction. The ability to reproduce detachment dynamics in NT plasma increases the confidence in future design studies for NT divertors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Absence of hydrogen insertion into highly crystalline superconducting infinite layer nickelates

Here, the discovery of superconductivity in the infinite layer nickelates introduced a materials system analogous to the cuprates for the study of unconventional superconductivity. The synthesis of infinite layer nickelates, (RNiO 2 , R = lanthanide) often uses calcium hydride (CaH 2 ) to facilitate the deintercalation of apical site oxygen atoms from a precursor perovskite (RNiO 3 ) phase via topotactic reduction. However, it remains uncertain whether the use of CaH 2 results in the insertion of hydrogen into the infinite layer structure, and if it does, what the implications are for superconductivity. To quantify the hydrogen composition of highly crystalline infinite layer nickelates, we synthesized Nd 1-x⁢ Sr x ⁢NiO 2 thin films on LSAT substrates and conducted time-of-flight secondary ion mass spectroscopy measurements to generate hydrogen depth profiles. We compare the hydrogen density of nickelates prepared with and without a SrTiO 3 capping layer. Additionally, we measure the hydrogen content in nickelate samples at various doping levels spanning the superconducting phase space, including the underdoped, optimally doped, and overdoped regime. We report no significant increase in hydrogen density between the perovskite and infinite layer phases in any of the measured samples. Furthermore, we put an upperbound on the hydrogen concentration of our nickelate samples to Nd 1-x Sr x ⁢NiO 2 ⁢H 0.05 . Our results imply that hydrogen is not responsible for the emergence of superconductivity in the infinite layer nickelates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1977

Estimation of old field ecosystem biomass using low altitude imagery

Color-infrared photography was used to evaluate the biomass of experimental plots in an old-field ecosystem that was treated with different levels of waste water from a sewage treatment facility. Cibachrome prints at a scale of approximately 1:1,600 produced from 35 mm color infrared slides were used to analyze density patterns using prepared tonal density scales and multicell grids registered to ground panels shown on the photograph. Correlation analyses between tonal density and vegetation biomass obtained from ground samples and harvests were carried out. Correlations between mean tonal density and harvest biomass data gave consistently high coefficients ranging from 0.530 to 0.896 at the 0.001 significance level. Corresponding multiple regression analysis resulted in higher correlation coefficients. The results of this study indicate that aerial infrared photography can be used to estimate standing crop biomass on waste water irrigated old field ecosystems. Combined with minimal ground truth data, this technique could enable managers of wastewater irrigation projects to precisely time harvest of such systems for maximal removal of nutrients in harvested biomass.

Nor, S. M.↗
NASA NTRS1977

Estimation of old field ecosystem biomass using low altitude imagery

Color-infrared photography was used to evaluate the biomass of experimental plots in an old-field ecosystem that was treated with different levels of waste water from a sewage treatment facility. Cibachrome prints at a scale of approximately 1:1,600 produced from 35 mm color infrared slides were used to analyze density patterns using prepared tonal density scales and multicell grids registered to ground panels shown on the photograph. Correlations between mean tonal density and harvest biomass data gave consistently high coefficients ranging from 0.530 to 0.896 at the 0.001 significance level. Corresponding multiple regression analysis resulted in higher correlation coefficients. The results indicate that aerial infrared photography can be used to estimate standing crop biomass on waste water irrigated old field ecosystems. Combined with minimal ground truth data, this technique could enable managers of waste water irrigation projects to precisely time harvest of such systems for maximal removal of nutrients in harvested biomass.

Nor, S. M.↗
NASA NTRS2018

The WFIRST Coronagraph Instrument: A Major Step in the Exploration of Sun-Like Planetary Systems Via Direct Imaging

The Wide Field Infrared Survey Telescope (WFIRST) Coronagraph Instrument (CGI) will be the first high-performance stellar coronagraph using active wavefront control for deep starlight suppression in space, providing unprecedented levels of contrast and spatial resolution for astronomical observations in the optical. One science case enabled by the CGI will be taking visible images and (R~50) spectra of faint interplanetary dust structures present in the habitable zone of nearby sunlike stars (~10 pc) and within the snow-line of more distant ones (~20 pc), down to dust brightness levels commensurate with that of the solar system zodiacal cloud. Reaching contrast levels below 10-7 at sub-arcsecond angular scales for the first time, CGI will cross an important threshold in debris disks physics, accessing disks with low enough optical depths that their structure is dominated by transport mechanisms rather than collisions. Hence, CGI will help us understand how exozodiacal dust grains are produced and transported in low-density disks around mature stars. Additionally, CGI will be able to measure the brightness level and constrain the degree of asymmetry of exozodiacal clouds around individual nearby sunlike stars in the optical, at the ~3x solar zodiacal emission level. This information will be extremely valuable for optimizing the observational strategy of possible future exo-Earth direct imaging missions, especially those planning to operate at optical wavelengths as well, such as the Habitable Exoplanet Observatory (HabEx) and the Large Ultraviolet/Optical/Infrared Surveyor (LUVOIR).

Demers, R.↗
DOE OSTI2026

Characterization of Electronic Stress-Induced Changes in Multilayer MoS 2

Transition metal dichalcogenides like molybdenum disulfide (MoS 2 ) are compelling for next-generation electronic devices. In this work, we investigate the impact of electronic stress on MoS 2 to illustrate that observational and phenomenological information on multiple devices can be useful to describe changes in the device, and caution against the rationalization of paltry results as representative or correlative to device behavior. Here, we stress MoS 2 by applying a sustained 20 V DC bias to study the material’s response. Post-stress electronic characterization revealed nonuniform shifts in current–voltage (I–V) behavior alongside microscale changes. Complementary mechanical, spectroscopic, and scanning microwave impedance measurements showed that stress-induced features locally modulate stiffness, surface potential, Raman intensity, and charge carrier density. We correlated I–V behavior with morphological features (wrinkles, tears, folds, height) and device-level geometry (MoS 2 overlap with electrodes, channel area, contact length) on 50 test structures across five chips to move beyond anecdotal conclusions. We found no universal correlations before DC stress. However, device-level geometry was correlated with I–V behavior after DC stress, suggesting that electrode contacts play a more dominant role than morphology in determining performance. Delamination and thinning induced by DC stress led to localized reductions in charge carrier density within the affected regions. Further, delamination and thinning appear to map to I–V device performance in a few samples, but the correlation is lost when a larger sample size is considered. This suggests significant sample-to-sample variability in surface electronic states of the test structures. We also discuss how environmental factors introduced during fabrication may contribute to the observed heterogeneous device response. Progress will require high-resolution, multimodal analysis across many samples constructed under controlled, clean conditions. By building data sets that capture variability, we can better identify the true drivers of performance.

36 MATERIALS SCIENCE↗