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At least 1,567 records · Page 87

Effect of zeolite type, temperature, and pH on Stage III glass alteration behavior for two nuclear waste glasses

We report long-term laboratory scale static alteration tests (up to 1500 d) were conducted on two low-activity waste glasses (LAWA44 and IDF18-A161) at S/V = 2000 m –1 . Tests were seeded with either analcime, clinoptilolite, zeolite P1, or zeolite P2 to induce Stage III glass alteration behavior. The effect of several parameters on glass Stage III behavior was studied with consideration of several variables, including temperature (22 °C – 90 °C) and pH (floating or initially set using KOH at values from 9.5 to 11.5). Temporal solution data and solids characterization at the end of the experiments are reported. Solution data demonstrated the occurrence of a sustained rate acceleration at temperatures down to 40 °C and the activation energy for these Stage III rates was determined for both glasses. Three major secondary phases were identified at the end of the experiments for both glasses: zeolite P1, zeolite P2, and/or analcime (along with minor phases: zeolites, clays, carbonates). The identification of the crystalline phases at the end of the experiment often differed from the zeolite seed phase. In addition, the use of the Avrami equation showed unimpeded zeolite growth (3-dimensional) in certain conditions, suggesting that in certain conditions the glass dissolution rate is controlled by zeolite formation kinetics whereas in other conditions the glass corrosion process impeded zeolite formation kinetics. The morphological evolution of the samples revealed the growth of the zeolites which completely fill the intergranular space in the powder bed. These results are discussed with regards to previous seeded and unseeded Stage III dissolution rate experiments performed on low- and high-activity nuclear waste glasses.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Exploiting data representation for fault tolerance

Incorrect computer hardware behavior may corrupt intermediate computations in numerical algorithms, possibly resulting in incorrect answers. Prior work models misbehaving hardware by randomly flipping bits in memory. We start by accepting this premise, and present an analytic model for the error introduced by a bit flip in an IEEE 754 floating-point number. We then relate this finding to the linear algebra concepts of normalization and matrix equilibration. In particular, we present a case study illustrating that normalizing both vector inputs of a dot product minimizes the probability of a single bit flip causing a large error in the dot product's result. Moreover, the absolute error is either less than one or very large, which allows detection of large errors. Then, we apply this to the GMRES iterative solver. We count all possible errors that can be introduced through faults in arithmetic in the computationally intensive orthogonalization phase of GMRES, and show that when the matrix is equilibrated, the absolute error is bounded above by one.

97 MATHEMATICS AND COMPUTING↗

Conversion of Nuclear Waste into Nuclear Waste Glass: Experimental Investigation and Mathematical Modeling

The melter feed, slurry, or calcine charged on the top of a pool of molten glass forms a floating layer of reacting material called the cold cap. Between the cold-cap top, which is covered with boiling slurry, and its bottom, where bubbles separate it from molten glass, the temperature changes by up to 1000 K. The processes that occur over this temperature interval within the cold cap include liberation of gases, conduction and consumption of heat, dissolution of quartz particles, formation and dissolution of intermediate crystalline phases, and generation of foam and gas cavities. These processes have been investigated using thermal analyses, optical and electronic microscopies, x-ray diffraction, as well as other techniques. Properties of the reacting feed, such as heat conductivity and density, were measured as functions of temperature. Investigating the structure of quenched cold caps produced in a laboratory-scale melter complemented the crucible studies. The cold cap consists of two main layers. The top layer contains solid particles dissolving in the glass-forming melt and open pores through which gases are escaping. The bottom layer contains bubbly melt or foam where bubbles coalesce into larger cavities that move sideways and release the gas to the atmosphere. The feed-to-glass conversion became sufficiently understood for representing the cold-cap processes via mathematical models. These models, which comprise heat transfer, mass transfer, and reaction kinetics models, have been developed with the final goal to relate feed parameters to the rate of glass melting.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Multicycle flash sintering of cubic Y 2 O 3 -stabilized ZrO 2 : An in situ energy dispersive synchrotron x-ray diffraction study with high temporal resolution

The current induced unit cell volume changes, (111) Bragg peak full width at half maximum (FWHM) and its integrated intensity in 8 % Y 2 O 3 stabilized ZrO 2 (8 %YSZ) solid state electrolyte was monitored during a triple-flash sintering experiment by in situ energy dispersive x-ray diffraction using a polychromatic synchrotron probe (max, photon energy 200 keV) with 2 second temporal resolution. The first spontaneous singularity in the unit cell volume (+0.54 %) was observed at 899 °C under 15 V/mm applied field intensity, which was associated with 13 mA/mm 2 current draw and an increase in density to 97 %. Following anelastic relaxation of the unit cell volume under open circuit conditions, the same applied field was applied twice in a row which resulted in additional induced singularities at 925 °C (+0.48 %) and 944 °C (+0.42 %). A floating baseline, which was above the thermal expansion baseline, was observed from 833 to 969 °C and was attributed to Joule heating. In conclusion, the singularity at 899 °C is associated with a sharp change in (111) FWHM and a 34 % decrease in integrated peak area that was attributed to changes in the distribution of oxygen vacancies and the changes in their concentration as induced by the applied field in the spontaneous transient stage of flash sintering.

36 MATERIALS SCIENCE↗

Impact of low-dose electron irradiation on $n^{+}p$ silicon strip sensors

The response of n + p silicon strip sensors to electrons from a 90 Sr source was measured using a multi-channel read-out system with 25 ns sampling time. The measurements were performed over a period of several weeks, during which the operating conditions were varied. The sensors were fabricated by Hamamatsu Photonics on 200 μm thick float-zone and magnetic-Czochralski silicon. Their pitch was 80 μm, and both p-stop and p-spray isolation of the n + strips were studied. The electrons from the 90 Sr source were collimated to a spot with a full-width-at-half-maximum of 2 mm at the sensor surface, and the dose rate in the SiO 2 at the maximum was about 50 Gy(SiO 2 )/d. After only a few hours of making measurements, significant changes in charge collection and charge sharing were observed. Annealing studies, with temperatures up to 80 °C and annealing times of 18 h showed that the changes can only be partially annealed. The observations can be qualitatively explained by the increase of the positive oxide-charge density due to the ionization of the SiO 2 by the radiation from the β source. TCAD simulations of the electric field in the sensor for different oxide-charge densities and different boundary conditions at the sensor surface support this explanation. As a result, the relevance of the measurements for the design of n + p strip sensors is discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Design of the first full size ATLAS ITk strip sensor for the endcap region

The ATLAS collaboration is designing the all-silicon Inner Tracker (ITk) that will operate in the HL-LHC replacing the current design. The silicon microstrip sensors for the barrel and the endcap regions in the ITk are fabricated in 6 inch, p-type, float-zone wafers, where large-area strip sensor designs are laid out together with a number of miniature sensors. The radiation tolerance and specific system issues like the need for slim edge of 450 μm have been tested with square shaped sensors intended for the barrel part of the tracker. This work presents the design of the first full size silicon microstrip sensor for the endcap region with a slim edge of 450 μm. The strip endcaps will consist of several wheels with two layers of silicon strip sensors each. The strips have to lie along the azimuthal direction, apart from a small stereo angle rotation (20 mrad on each side, giving 40 mrad total) for measuring the second coordinate of tracks. This stereo angle is built into the strip layout of the sensor and, in order to avoid orphan strips, the sensor edges are inclined by the stereo angle. On top of this, the top and bottom edges are designed as arcs to have equal length strips. Together with the design of this new Stereo Annulus sensor, we will report on the initial measurements of the leakage current as a function of bias voltage, after dicing, and the depletion voltage.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Large Area Picosecond Photodetector (LAPPD TM ) - Pilot production and development status

Here, we discuss performance results achieved for fully functional sealed Large Area Picosecond Photodetectors (LAPPD (TM)) in tests performed at Incom Inc., as well as independent test results reported by our early adopters. The LAPPD is a microchannel plate (MCP) based large area picosecond photodetector, capable of imaging with single-photon sensitivity at high spatial and temporal resolutions in a hermetic package. The LAPPD has an active area of 350 square centimeters in an all-glass hermetic package with a fused silica window and bottom plate and sidewalls made of borosilicate float glass. Signals are generated by a bi-alkali Na 2 KSb photocathode and amplified with a stacked chevron pair of MCPs produced by applying resistive and emissive atomic layer deposition coatings to glass capillary array (GCA) substrates. Signals are collected on RF stripline anodes applied to the bottom plates which exit the detector via pin-free hermetic seals under the side walls. LAPPD test and performance results for product produced and delivered to early adopter customers during the first half of 2018 are reviewed. These results include electron gains ≥ 7.5 x 10 6 @ 850/950 V (entry/exit MCP), low dark noise rates (22 Cts/s/cm 2 ), single photoelectron (PE) timing resolution of 64 picoseconds RMS, and single photoelectron spatial resolution along and across strips of 2.8 mm and 1.3 mm RMS respectively. Many of these devices also had very high QE photocathodes that were uniform over the full 195 mm x 195 mm window active area (LAPPD #15 QE% @ 365 nm Max/Avg/Min = 25.8/22.3 ± 3/15.7). An update is additionally provided of developments that enable capacitive signal coupling from the detector to application specific pads or stripline readout patterns deployed on printed circuit boards positioned beneath the file, outside of the vacuum package. We conclude with examples of how sensors offering picosecond timing, in diverse applications can bring transformative change to detector technology and applications in future experiments.

47 OTHER INSTRUMENTATION↗

Production and characterization of thin, self-supporting Si foils for use as targets in radioactive beam experiments

Development of thin, self-supporting silicon foils (both natural and isotopically-enriched) for use as targets in reaction studies with radioactive beams is detailed. Foils with a thickness of ~220 μg/cm 2 were produced using vapor deposition and were floated onto aluminum frames with 10–15 mm diameter holes. During their production, the foil thickness was measured using a quartz crystal monitor. Subsequently, the foil thickness was characterized by particle energy loss measurements and Rutherford backscattering (RBS). These measurements demonstrated that the thickness could be determined to within a 0.5% uncertainty. The elemental purity of the foils was assessed using RBS and X-ray photoelectron spectroscopy. Lastly, this analysis demonstrated that the foils have 87%–90% silicon abundance.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Resistive AC-Coupled Silicon Detectors: principles of operation and first results from a combined analysis of beam test and laser data

This paper presents the principles of operation of Resistive AC-Coupled Silicon Detectors (RSDs) and measurements of the temporal and spatial resolutions using a combined analysis of laser and beam test data. RSDs are a new type of n-in-p silicon sensor based on the Low-Gain Avalanche Diode (LGAD) technology, where the n+ implant has been designed to be resistive, and the read-out is obtained via AC-coupling. The truly innovative feature of RSD is that the signal generated by an impinging particle is shared isotropically among multiple read-out pads without the need for floating electrodes or an external magnetic field. Careful tuning of the coupling oxide thickness and the n+ doping profile is at the basis of the successful functioning of this device. Several RSD matrices with different pad width-pitch geometries have been extensively tested with a laser setup in the Laboratory for Innovative Silicon Sensors in Torino, while a smaller set of devices have been tested at the Fermilab Test Beam Facility with a 120 GeV/c proton beam. The measured spatial resolution ranges between 2.5μm for 70–100 pad-pitch geometry and 17μm with 200–500 matrices, a factor of 10 better than what is achievable in binary read-out (bin size/12). Beam test data show a temporal resolution of ~40ps for 200 μm pitch devices, in line with the best performances of LGAD sensors at the same gain.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Numerical simulation of vortex-induced motion of a deep-draft paired-column semi-submersible offshore platform

Understanding and predicting vortex-induced motion (VIM) of offshore systems for deep seawater applications is crucial to improve the system safety and integrity. In this paper, we report on experimental tow-tank measurements and numerical simulations of VIM of a deep-draft offshore platform, specifically Paired-Column Semisubmersible (PC-Semi). The study is carried out in model scale (1:54), at subcritical flow regime with Re~10 4 . Motion of the floating structure has three degrees of freedom: in-line, cross-flow, and yaw. Large periodic cross-flow motion is measured for headings 0°, 11.25°, and 22.5°, for reduced velocities (U r ) between 5 and 10. Considerably smaller cross-flow amplitude is recorded at 45° heading across the U r range considered. An extensive sensitivity study is performed using computational fluid dynamics (CFD) to capture the transient displacement history of VIM (in-line, cross-flow, and yaw motion components). Amplitude and period of cross-flow (transverse) motion are obtained from statistical analysis of VIM time history and subsequently used as the validation criterion between the CFD simulation and the model tests. Satisfactory agreement between the CFD results and tow-tank measurements is achieved with a Delayed Detached Eddy Simulation – Shear Stress Transport (DDES-SST) formulation. Finally, this work provides experimental results and serves as a practical starting point to set up a CFD problem to estimate amplitude and period of cross-flow VIM motion for offshore engineering applications.

42 ENGINEERING↗

A symbiotic approach to the design of offshore wind turbines with other energy harvesting systems

The capital cost of a 5 MW floating wind turbine (FWT) runs as high as $\$ 20.7$ million, leading to an energy cost of $\$ 0.20\mathrm{/kWh}$, four times that of natural gas (Myhr et al., 2014). Although a single type of energy harvesting device may be too expensive to deploy, if it can operate symbiotically with others, the combined cost of energy might be acceptable. In this study, we show that attaching a wave energy converter (WEC) to the FWT may simultaneously produce an average of 240 kW wave power, reduce the WEC levelized cost of energy by 14% by eliminating redundant components, and reduce the FWT tower lifetime equivalent fatigue stress by 23% by reducing platform motion. Furthermore, the offshore wind turbine may also serve as a structure for the harvesting of valuable elements from seawater, such as uranium, lithium, and cobalt. The major cost drivers for the harvesting of uranium from seawater have been identified to be those associated with the mooring and deployment of the metal adsorbing polymers (Schneider and Sachde, 2013; Byers and Schneider, 2016). Finally, in the case of uranium, a symbiotic system coupled with an offshore wind turbine was found to reduce the seawater uranium production cost by at least 11% and up to 30% (Byers et al., 2016, 2018; Haji, 2017).

17 WIND ENERGY↗

OC6 Phase Ib: Validation of the CFD predictions of difference-frequency wave excitation on a FOWT semisubmersible

During the previous OC5 11 project, state-of-the-art mid-fidelity engineering tools for floating wind systems were found to consistently underpredict the nonlinear, low-frequency responses of semisubmersible offshore wind platforms, leading to substantial errors in the structural loads because of low-frequency surge and pitch resonance. To examine this underprediction, a coordinated investigation with computational fluid dynamics (CFD) simulations and model-basin experiments was carried out. Both investigations involved a fixed and simplified OC5-DeepCwind semisubmersible in bichromatic waves. The wave excitations - especially the nonlinear, difference-frequency excitation - on the structure from the CFD simulations were compared to the experimental measurements for validation, with uncertainty analyses for both the experimental and the CFD results. Furthermore, the wave excitations on each column of the semisubmersible were measured separately in the experiment, allowing the validation of the CFD results to be done on a per-column basis. Overall, the CFD predictions of the difference-frequency excitations agree with the experimental measurements, suggesting the CFD solutions can be used as a reference for tuning and improving the engineering-level tools and can provide a means to better understand the underprediction at low frequencies.

16 TIDAL AND WAVE POWER↗

OC7 phase I: Toward practical sea-state-dependent modeling of hydrodynamic viscous drag and damping

Here, this article presents a collaborative research campaign under the OC7 project on refining the engineering modeling approach for hydrodynamic viscous drag and damping on floating wind platforms, focusing on the adjustment of hydrodynamic drag and damping coefficients for different sea states. The participant simulation results show significant improvements over the previous OC6 project in predicting the low-frequency resonance motion under nonoperational conditions. The improvements are mainly due to enhanced modeling, including the adoption of wave stretching, and directly tuning the coefficients to measured platform motion in waves instead of free decay. For accurate predictions of mean- and slow-drift motion, the better performing models use a decreasing column splash zone drag coefficient and increasing surge damping/drag with increasing wave height. The model tuning for heave and pitch resonance shows less consistency. Generally, both quadratic drag and additional heave or pitch damping are needed for accurate predictions. Alternatively, a quadratic drag formulation with velocity filtering for the rectangular pontoons leads to improved predictions without additional damping. This model is also potentially more predictive, requiring minimal adjustment to its parameters for different conditions.

17 WIND ENERGY↗

OC7 phase I: CFD investigation of viscous forces on rectangular members of semisubmersibles

In Phase I of the Offshore Code Comparison Collaboration 7 (OC7) project, we aim to address key questions related to the modeling of viscous hydrodynamic loads on floating platforms. Here, this paper presents results from a collaborative effort within Phase I of the OC7 project. We investigate viscous forces acting on the rectangular members of semisubmersible platforms using high-fidelity computational fluid dynamics (CFD) simulations. The parametric CFD analyses include two-and-a-half-dimensional (2.5D) simulations of pontoon sections of two different semisubmersible platform designs (the VolturnUS-S and the INO WINDMOOR) and full three-dimensional (3D) structure simulations of the VolturnUS-S platform. We extract both the added mass and drag coefficients that are typically used in engineering-level hydrodynamic models from the 2.5D forced oscillation simulations with various Keulegan-Carpenter numbers and compare them to the coefficients from the 3D forced oscillation simulations. We observe consistent variation of the coefficients along the pontoon legs due to 3D platform and free-surface effects. With the breadth of the simulations and component-level detailed analyses, this work establishes a useful database and several empirical formulas for selecting hydrodynamic coefficients when modeling semisubmersible platforms in engineering tools.

13 HYDRO ENERGY↗

Special Issue on Data-Intensive Scalable Computing Systems

Traditional high performance computing (HPC) systems were designed from a compute-centric perspective, with an emphasis on high floating point performance. As scientific and analytics applications become more data intensive, there is a need to rethink HPC system architectures, programming models, runtime systems, and tools with a focus on scalable data intensive computing. Industry approaches supporting data intensive applications have been highly successful, leading many in the HPC community to search for ways to adapt them to HPC hardware and software contexts. Conversely, industry looks to the HPC community for their expertise in designing, deploying, and using extremely large and high performance computing systems. This special issue contains seven articles, each of which is an extended version of a paper presented in the 2015 International Workshop on Data Intensive Scalable Computing Systems (DISCS-2015) held in Austin, Texas on November 15, 2015. The workshop program included papers that ranged from programming models to systems software to storage, each with a strong focus on data intensive computing.

97 MATHEMATICS AND COMPUTING↗

Roof ponds combined with a water-to-air heat exchanger as a passive cooling system: Experimental comparison of two system variants

Two roof pond configurations combined with a water-to-air heat exchanger (WAHE) are evaluated. Test cells of 1.35 m × 1.35 m x 1.35 m with the same thermal properties, except for the roofs, are built in a hot-dry climate with mild winters. They are connected with a WAHE placed inside the roof pond's water by a pipe through which the indoor air is re-circulated. The first roof consists of a 0.35 m deep water pond covered with a floating polystyrene insulation 0.03 m thick, and a spray system located 0.5 m above it that operates at night. The second roof is covered with an aluminum plate separated by a 0.10 m air gap above a 0.25 m deep water pond. We ran multiple series and compared the results to a control cell that had a California energy code compliant insulated roof. Predictive equations are developed to dimension the WAHE system. Results demonstrate that the cells with roof ponds have better cooling performance than the code compliant control cell. The best performance is obtained in the cell with the WAHE operating continuously. In this case, the indoor temperature stayed below 24 °C even with ambient temperatures above 35 °C.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance estimation of resonance-enhanced dual-buoy wave energy converter using coupled time-domain simulation

This article presents the modeling methodology and performance evaluation of the resonance-enhanced dual-buoy WEC (Wave Energy Converter) by HEM (hydrodynamic & electro-magnetic) fully-coupled-dynamics time-domain-simulation program. The numerical results are systematically compared with the authors’ 1/6-scale experiment. With a direct-drive linear generator, the WEC consists of dual floating cylinders and a moon-pool between the cylinders, which can utilize three resonance phenomena from moon-pool dynamics as well as heave motions of inner and outer buoys. The contact and friction between the two buoys observed in the experiment are also properly modeled in the time-domain simulation by the Coulomb-friction model. Moon-pool resonance peaks significantly exaggerated in linear potential theory are empirically adjusted through comparisons with measured values. A systematic comparative study between the simulations and experiments with and without PTO (power-take-off) is conducted, and the relative heave displacements/velocities and power outputs are well matched. Then, parametric studies are carried out with the simulation program to determine optimum generator parameters. The performance with various wave conditions is also assessed.

16 TIDAL AND WAVE POWER↗