Doped and functionalized non-Ti-MXenes for flexible and wearable electronic devices
The unique physicochemical properties of non-Ti-MXenes make them excellent class of materials for flexible and wearable electronics.
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The unique physicochemical properties of non-Ti-MXenes make them excellent class of materials for flexible and wearable electronics.
The carbon content in SiOCN coatings governs the steel oxidation behavior at 800 °C. Carbon-rich coatings form Fe-rich oxides and gaps at the coating/alloy interface, carbon-free ones offer protection, and intermediate ones show partial degradation.
We investigate medium-induced modifications to jet substructure observables that characterize hard components in central Pb-Pb collisions at $\sqrt{𝑠_{𝑁𝑁}}$ = 5.02 TeV. Using a multistage Monte Carlo simulation of in-medium jet shower evolution, we explore flavor-dependent medium effects through simulations of inclusive and 𝛾-tagged jets. The results show that quark jets undergo a nonmonotonic modification compared with gluon jets in observables such as the Pb-Pb to 𝑝−𝑝 ratio of the soft drop prong angle 𝑟 𝑔 , the relative prong transverse momentum 𝑘 𝑇,𝑔 , and the groomed mass 𝑚 𝑔 distributions. Due to this nonmonotonic modification, 𝛾-tagged jets, enriched in quark jets, provide surprisingly clear signals of medium-induced structural modifications, distinct from effects dominated by selection bias. Further systematic studies demonstrate that these effects are dominated by recoil medium response. This work highlights the potential of hard substructures in 𝛾-tagged jets as powerful tools for probing the jet-medium interactions in high-energy heavy-ion collisions, in particular by enabling detailed investigations of jet-medium parton scatterings via their associated medium response. All simulations for 𝛾-tagged jet analyses carried out in this paper used triggered events containing at least one hard photon, which highlights the utility of these observables for future Bayesian analysis.
Abstract Several mechanisms have been proposed to explain why the isotope ratios of precipitation vary in space and time and why they correlate with other climate variables like temperature and precipitation. Here, we argue that this behavior is best understood through the lens of radiative transfer, which treats the depletion of atmospheric vapor transport by precipitation as analogous to the attenuation of light by absorption or scattering. Building on earlier work by Siler et al., we introduce a simple model that uses the equations of radiative transfer to approximate the two-dimensional pattern of the oxygen isotope composition of precipitation ( δ p ) from monthly mean hydrologic variables. The model accurately simulates the spatial and seasonal variability in δ p within a state-of-the-art climate model and permits a simple decomposition of δ p variability into contributions from gradients in evaporation and the length scale of vapor transport. Outside the tropics, δ p is mostly controlled by gradients in evaporation, whose dependence on temperature explains the positive correlation between δ p and temperature (i.e., the temperature effect). At low latitudes, δ p is mostly controlled by gradients in the transport length scale, whose inverse relationship with precipitation explains the negative correlation between δ p and precipitation (i.e., the amount effect). This suggests that the temperature and amount effects are both mostly explained by the variability in upstream rainout, but they reflect distinct mechanisms governing rainout at different latitudes. Significance Statement The isotopic composition of precipitation has long been used to make inferences about past climates based on its observed relationship with precipitation in the tropics and with temperature at higher latitudes. These relationships—known as the “amount effect” and “temperature effect,” respectively—have been attributed to many different mechanisms, most of which are thought to operate at either high or low latitudes but not both. Here, we present a unified framework for interpreting the isotope variability that can explain the latitude dependence of the temperature and amount effects despite making no distinction between high and low latitudes. Although our results are generally consistent with certain interpretations of the amount effect, they suggest that the temperature effect is widely misunderstood.
This report is an FY21 Deliverable for NA-21.1, International Nuclear Security, WBS 21.1.1.1.4 Counter Unmanned Aircraft Systems (CUAS), under C.1.4, Develop Suite of Engagement Materials and Tools for Country/Regional Teams. The responsibility for protecting nuclear assets is an immense challenge for governments. Policy changes based on geopolitics, instability of government regimes, and technological advances that facilitate theft of nuclear material all contribute to the enduring task of staying current with these and other threats. One of the recent threats to come along is the use of drones or Unmanned Aircraft Systems (UAS) to circumvent traditional Physical Security Systems. There are significant resources invested on physical protection systems for securing nuclear assets, but many of these systems can now be bypassed by simply flying over these measures intended to guard against ground attacks. In recent years the threat increased to hostile groups to attack or surveil due to advances and availability of UAS platforms. It is now more urgent to implement systems and procedures to counter the UAS threat. The United States (U.S.) federal government granted authority to the Department of Energy (DOE) to implement a Counter UAS to protect nuclear assets. This document provides a very practical and transparent view of the trials, tribulations and challenges we encountered while implementing the first Counter-Unmanned Aircraft System (CUAS) Program in the DOE at Los Alamos National Laboratory (LANL).
The delivery of Home Energy Scores (HES) has been significantly impacted over the last year by the recent pandemic and ongoing limitations to person-to-person interactions. There are also historic challenges in providing HES to more remote geographies where assessor infrastructure is not in place. Alternative approaches to in-person, on-site home energy assessments could help address these current restrictions, while also potentially providing opportunities for the efficient delivery of HES in certain use cases after COVID-related restrictions are lifted. From the program administrator’s perspective, there needs to be confidence that the remote scores closely match what they would have been if the assessment had been performed on-site. The recommendations shown on a report generated from a remote score should closely match those of an onsite assessment. A remote assessment should be an option for all HES Partners and have direction on how to deliver those scores. From the HES partner’s and assessor’s perspective, there needs to be understanding of what level of experience is needed, what system infrastructure is required, the time expenditure of the remote assessment process, and the limitations of a remote assessment. From the homeowner’s perspective, there needs to be an awareness and comfort with the time commitment, the level of knowledge of the home, the equipment needed, and any physical requirements of the remote assessment process. During this study, Earth Advantage assessed methods for delivering Home Energy Score assessments remotely through web-based technology platforms and resident interaction in a diverse array of home types in different geographic locations. Earth Advantage developed remote assessment test protocols and integrated those testing protocols into existing Home Energy Score programs being overseen by USDOE Home Energy Score partners New York State Energy Research & Development Authority (NYSERDA), the Oregon Department of Energy (ODOE), and the City of Portland (PDX). Earth Advantage staff acted as the Remote assessor and gathered HES data remotely during the video sessions with participants. Authorized Home Energy Score assessors performed the onsite assessments that were then used to compare with the remote assessment data. This allowed the research to effectively test the efficacy of various remote assessment approaches in a diverse array of home-types. Earth advantage identified the key components of a remote assessment infrastructure which included Remote Home Energy Score Assessments Page vi processes, tools, services, methods and mechanisms that would better enable remote assessments. This report details methods, results, and findings of the HES remote assessment research. In addition, the report provides recommendations and best practices that could be used as guidance for the Home Energy Score administrator and the HES partners seeking to effectively conduct remote assessments.
Analysis and interpretation of time series data is easiest when the data values occur at uniform intervals in time, but actual data may have differing data sampling frequencies, such as monthly and daily readings. Applying data analysis techniques, such as smoothing, to such a data set may not give a representative result between time segments. The ability to automatically distinguish time segments of differing data frequency would provide a means for applying data analysis independently to each segment, though a suitable blending at segment boundaries would be required. A method for detecting frequency changes was developed and applied to Gaussian and median smoothing of hydraulic head data from groundwater wells at the U.S. Department of Energy Hanford Site in southeastern Washington state. The process identifies time segments of high-frequency (daily) or low-frequency (greater than daily) data using adjusted-bandwidth Gaussian kernel density estimation and a threshold value, which are further refined to address small blocks of low-frequency data within larger blocks of high-frequency data. User-selectable levels of smoothing are then applied independently to the time segments prior to combining the segment results for a single smoothed data set. This time segment identification approach provides effective low- and high-frequency data separation, which provides a method to apply data analysis independently to each time segment.
This report covers the inspection findings for the Routine and Nonredundant Steel Tension Member (NSTM) Inspection of the Los Alamos Canyon Bridge over Omega Rd conducted on June 7-9, 2024. The inspections were completed according to the standards referenced in DOE O 437.1 Bridge and Tunnel Management including the National Bridge Inspection Standards (23 CFR Part 650, dated 12/14/2004) and other Federal Highway Administration (FHWA), New Mexico Department of Transportation (NMDOT), and American Association of State Highway and Transportation Officials (AASHTO) codes and standards.
This is the final technical report for cooperative agreement DE-SC0000661, between the Department of Energy Office of Science and Michigan State University, for the design and establishment of the Facility for Rare Isotope Beams, its transition to operations and early operations, and the effort to plan and design the High Rigidity Spectrometer.
Abstract. Data on irrigation patterns and trends at field-level detail across broad extents are vital for assessing and managing limited water resources. Until recently, there has been a scarcity of comprehensive, consistent, and frequent irrigation maps for the US. Here we present the new Landsat-based Irrigation Dataset (LANID), which is comprised of 30 m resolution annual irrigation maps covering the conterminous US (CONUS) for the period of 1997–2017. The main dataset identifies the annual extent of irrigated croplands, pastureland, and hay for each year in the study period. Derivative maps include layers on maximum irrigated extent, irrigation frequency and trends, and identification of formerly irrigated areas and intermittently irrigated lands. Temporal analysis reveals that 38.5×106 ha of croplands and pasture–hay has been irrigated, among which the yearly active area ranged from ∼22.6 to 24.7×106 ha. The LANID products provide several improvements over other irrigation data including field-level details on irrigation change and frequency, an annual time step, and a collection of ∼10 000 visually interpreted ground reference locations for the eastern US where such data have been lacking. Our maps demonstrated overall accuracy above 90 % across all years and regions, including in the more humid and challenging-to-map eastern US, marking a significant advancement over other products, whose accuracies ranged from 50 % to 80 %. In terms of change detection, our maps yield per-pixel transition accuracy of 81 % and show good agreement with US Department of Agriculture reports at both county and state levels. The described annual maps, derivative layers, and ground reference data provide users with unique opportunities to study local to nationwide trends, driving forces, and consequences of irrigation and encourage the further development and assessment of new approaches for improved mapping of irrigation, especially in challenging areas like the eastern US. The annual LANID maps, derivative products, and ground reference data are available through https://doi.org/10.5281/zenodo.5548555 (Xie and Lark, 2021a).
Discover Earth is a NASA-sponsored project for teachers of grades 5-12, designed to: enhance understanding of the Earth as an integrated system enhance the interdisciplinary approach to science instruction, and provide classroom materials that focus on those goals. Discover Earth is conducted by the Institute for Global Environmental Strategies in collaboration with Dr. Eric Barron, Director, Earth System Science Center, The Pennsylvania State University; and Dr. Robert Hudson, Chair, the Department of Meteorology, University of Maryland at College Park.
Discover Earth is a NASA-sponsored project for teachers of grades 5-12, designed to: (1) enhance understanding of the Earth as an integrated system; (2) enhance the interdisciplinary approach to science instruction; and (3) provide classroom materials that focus on those goals. Discover Earth is conducted by the Institute for Global Environmental Strategies in collaboration with Dr. Eric Barron, Director, Earth System Science Center, The Pennsylvania State University; and Dr. Robert Hudson, Chair, the Department of Meteorology, University of Maryland at College Park. The enclosed materials: (1) represent only part of the Discover Earth materials; (2) were developed by classroom teachers who are participating in the Discover Earth project; (3) utilize an investigative approach and on-line data; and (4) can be effectively adjusted to classrooms with greater/without technology access. The Discover Earth classroom materials focus on the Earth system and key issues of global climate change including topics such as the greenhouse effect, clouds and Earth's radiation balance, surface hydrology and land cover, and volcanoes and climate change. All the materials developed to date are available on line at (http://www.strategies.org) You are encouraged to submit comments and recommendations about these materials to the Discover Earth project manager, contact information is listed below. You are welcome to duplicate all these materials.
The Future Air Traffic Growth and Schedule Model was developed as an implementation of the Fratar algorithm to project future traffic flow between airports in a system and of then scheduling the additional flights to reflect current passenger time-of-travel preferences. The methodology produces an unconstrained future schedule from a current (or baseline) schedule and the airport operations growth rates. As an example of the use of the model, future schedules are projected for 2010 and 2022 for all flights arriving at, departing from, or flying between all continental United States airports that had commercial scheduled service for May 17, 2002. Inter-continental US traffic and airports are included and the traffic is also grown with the Fratar methodology to account for their arrivals and departures to the continental US airports. Input data sets derived from the Official Airline Guide (OAG) data and FAA Terminal Area Forecast (TAF) are included in the examples of the computer code execution.
The Future Air Traffic Growth and Schedule Model was developed as an implementation of the Fratar algorithm to project future traffic flow between airports in a system and of then scheduling the additional flights to reflect current passenger time-of-travel preferences. The methodology produces an unconstrained future schedule from a current (or baseline) schedule and the airport operations growth rates. As an example of the use of the model, future schedules are projected for 2010 and 2022 for all flights arriving at, departing from, or flying between all continental United States airports that had commercial scheduled service for May 17, 2002. Inter-continental US traffic and airports are included and the traffic is also grown with the Fratar methodology to account for their arrivals and departures to the continental US airports. Input data sets derived from the Official Airline Guide (OAG) data and FAA Terminal Area Forecast (TAF) are included in the examples of the computer code execution.
Aerospace Meteorology came into being in the 1950s as the development of rockets for military and civilian usage grew in the United States. The term was coined to identify those involved in the development of natural environment models, design/operational requirements, and environment measurement systems to support the needs of aerospace vehicles, both launch vehicles and spacecraft. It encompassed the atmospheric environment of the Earth, including Earth orbit environments. Several groups within the United States were active in this area, including the Department of Defense, National Aeronautics and Space Administration, and a few of the aerospace industry groups. Some aerospace meteorology efforts were similar to those being undertaken relative to aviation interests. As part of the aerospace meteorology activities a number of lessons learned resulted that produced follow on efforts which benefited from these experiences, thus leading to the rather efficient and technologically current descriptions of terrestrial environment design requirements, prelaunch monitoring systems, and forecast capabilities available to support the development and operations of aerospace vehicles.
Major declines in Atlantic salmon (Salmo salar) populations have occurred alongside dam construction, shifting temperatures, and changing land use and land cover (LULC), restricting the last remaining wild population in the United States to Maine. In collaboration with the Maine Department of Marine Resources and the Downeast Salmon Federation, the NASA DEVELOP team utilized Earth observations to assess changes within critical salmon habitat. The team used the Landsat 5 Thematic Mapper (TM), Landsat 8 Operation Land Imager (OLI), Sentinel-2 MultiSpectral Instrument (MSI), and National Land Cover Database (NLCD) to refine historical LULC maps from 1985 to 2021. The team also used elevation data from the Shuttle Radar Topography Mission (SRTM) and IDRISI TerrSet Land Change Modeler to forecast LULC change to 2040. From Terra Moderate Resolution Imaging Spectroradiometer (MODIS) land surface temperature (LST) data, the team derived a time series, summer averages, and anomaly maps between 2000 and 2021. The team analyzed LST in relation to LULC classes, specifically forest cover type, and in-situ stream temperature from the Spatial Hydro-Ecological Decision System (EcoSHEDS). LULC trends from 1985 to 2021 revealed a net transition of coniferous forest to other classes, such as deciduous forest and developed land. The team found an association between warmer temperatures and a greater presence of developed and mixed forest classes per 10,000 acres across Maine. These visualizations and analyses will aid partners in identifying riparian locations with ideal or unfavorable habitat conditions to inform Atlantic salmon population recovery efforts.
Areas of high chlorinated volatile organic compound (cVOC) contamination at the Savannah River Site (SRS) have been undergoing remediation via soil vapor extraction, sometimes coupled with thermal treatments to enhance extraction rates. These active systems are effective in removing large amounts of contaminant mass from the subsurface and mitigating the impacts to groundwater. However, as extraction rates decline, costs must be evaluated with respect to the benefit of continued active operation. A decision framework for identifying conditions when a transition to a more passive remediation is appropriate has been developed with state and federal regulatory agencies. Two remediation areas have recently been transitioned from active soil vapor extraction (ASVE) to passive soil vapor extraction (PSVE) at the SRS. Performance evaluation goals including plume stabilization, overall mass removal trends, environmental sustainability and costs were considered in transitioning from active remediation to passive technologies at both sites. At the Dynamic Underground Stripping (DUS) project at the M-Area Settling Basin, ASVE was combined with steam injection to extract cVOCs during active operations. Steam injection occurred from September 2005 to September 2009. DUS utilized 63 steam injection wells, 34 active vapor extraction wells, and 3 active soil vapor extraction units (SVEUs). Two active SVEUs had 60 horsepower blowers; the third had a 25-horsepower blower. Mass removal was closely tracked during DUS operations; over 181,437 kilograms (400,000 pounds) of cVOCs were removed while active steam injection occurred. After steaming was stopped, ASVE continued. The 34 active wells were evaluated in 2012. The ASVE wells were grouped into categories of high, medium, and low extraction rates. High producing wells remained connected to a single active SVEU. Low producing wells were abandoned, and the medium producing wells were transitioned to PSVE (Microblowers{sup TM}). Microblowers{sup TM} utilize a dedicated blower per well and are solar powered. This passive technology provides energy, maintenance, and operation costs savings while still providing an efficient reduction in cVOC migration to groundwater. In 2018, the remaining ASVE wells were evaluated again. The purpose of this testing was to identify which wells removed the most mass. An optimal well configuration was determined. The criteria to discontinue ASVE was removal of less than 18 kilograms (40 pounds) per week of cVOCs. After 3 months of shutdown (rebound conditions), 2.7 kilograms (5.9 pounds) of cVOCs per week were being removed. Data from the rebound test justified ending ASVE and transitioning wells with higher extraction rates to PSVE. Wells that had depleted the cVOC mass within their zone of influence were abandoned. Performance data from existing PSVE wells justified ending PSVE at wells with depleted extraction rates. Currently the system has 16 PSVE wells operating. Another ASVE system was being used to treat cVOC contaminated soil at the A-Area Miscellaneous Rubble Pile (AMRP) at SRS. System operation began in 2004, with 7 ASVE wells connected to a 60- horsepower blower. Mass removal rates and contaminant concentrations remained consistently low over the ASVE lifespan at AMRP. This indicated that mass removal was diffusion limited. With this data, the 7 ASVE wells were transitioned to PSVE in 2017. Twelve pressure monitoring points were also transitioned to PSVE wells. AMRP currently has 19 PSVE wells operating. Both transitions from active to passive remediation had concurrence from the United States Environmental Protection Agency and the South Carolina Department of Health and Environmental Control. These transitions ensure that only the necessary amount of energy is being exerted to remediate the environment. (authors)
The paper presents a distributed approach for operating a network of inverter-based energy storage resources embedded in a bulk power system. Departing from their traditional role of steady-state reserves, the storage assets in the network are utilized as frequency-responsive resources shaping system dynamics. The power electronics converter systems interfacing the storage resources are equipped with local controllers designed to respond under transient disturbances. To this end, a safety-constrained distributed control strategy is explored. The paper compares the performance of converter-interfaced grid-forming and grid-following storage networks for fast frequency control and disturbance containment/localization. Sensitivity studies are performed to study the impact of storage size, steady-state dispatch, and controller design on dynamic performance. The findings are presented through case studies with results from the IEEE test systems.