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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,549 records · Page 86
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Bandgap Engineering of Lead‐Free Double Perovskite Cs 2 AgBiBr 6 through Trivalent Metal Alloying

Abstract The double perovskite family, A 2 M I M III X 6 , is a promising route to overcome the lead toxicity issue confronting the current photovoltaic (PV) standout, CH 3 NH 3 PbI 3 . Given the generally large indirect band gap within most known double perovskites, band‐gap engineering provides an important approach for targeting outstanding PV performance within this family. Using Cs 2 AgBiBr 6 as host, band‐gap engineering through alloying of In III /Sb III has been demonstrated in the current work. Cs 2 Ag(Bi 1− x M x )Br 6 (M=In, Sb) accommodates up to 75 % In III with increased band gap, and up to 37.5 % Sb III with reduced band gap; that is, enabling ca. 0.41 eV band gap modulation through introduction of the two metals, with smallest value of 1.86 eV for Cs 2 Ag(Bi 0.625 Sb 0.375 )Br 6 . Band structure calculations indicate that opposite band gap shift directions associated with Sb/In substitution arise from different atomic configurations for these atoms. Associated photoluminescence and environmental stability of the three‐metal systems are also assessed.

Du, Ke‐zhao↗
DOE OSTI2024

A New Ecosystem Model for Arctic Phytoplankton Phenology From Ice‐Covered to Open‐Water Periods: Implications for Future Sea Ice Retreat Scenarios

Abstract To predict ecosystem change in the Arctic Ocean, understanding Arctic phytoplankton phenology is essential. We develop a marine ecosystem model focusing on phytoplankton dynamics and the competition for multiple resources based on knowledge from in situ data obtained in the Chukchi Sea. The model is designed to include the unique ecological characteristics of the Arctic Ocean. To the best of our knowledge, this is the first model successfully simulating the current paradigm for Arctic phytoplankton phenology, including both under‐ice blooms and succession of phytoplankton groups. Sensitivity experiments show that the dominance of diatoms can be sustained by lateral transport of a high‐silicate water mass (Pacific Winter Water). Experiments for future scenarios show that sea ice retreat drives a decrease in large diatoms and an increase in the other relatively small non‐diatom groups. These results suggest that dominant phytoplankton groups can be shifted from diatoms to non‐diatoms under ongoing Arctic Ocean sea ice retreat.

Choi, Jang‐Geun↗
DOE OSTI2024

Multifaceted aerosol effects on precipitation

Aerosols have been proposed to influence precipitation rates and spatial patterns from scales of individual clouds to the globe. However, large uncertainty remains regarding the underlying mechanisms and importance of multiple effects across spatial and temporal scales. Here, in this study, we review the evidence and scientific consensus behind these effects, categorized into radiative effects via modification of radiative fluxes and the energy balance, and microphysical effects via modification of cloud droplets and ice crystals. Broad consensus and strong theoretical evidence exist that aerosol radiative effects (aerosol–radiation interactions and aerosol–cloud interactions) act as drivers of precipitation changes because global mean precipitation is constrained by energetics and surface evaporation. Likewise, aerosol radiative effects cause well-documented shifts of large-scale precipitation patterns, such as the intertropical convergence zone. The extent of aerosol effects on precipitation at smaller scales is less clear. Although there is broad consensus and strong evidence that aerosol perturbations microphysically increase cloud droplet numbers and decrease droplet sizes, thereby slowing precipitation droplet formation, the overall aerosol effect on precipitation across scales remains highly uncertain. Global cloud-resolving models provide opportunities to investigate mechanisms that are currently not well represented in global climate models and to robustly connect local effects with larger scales. This will increase our confidence in predicted impacts of climate change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Projecting Future Energy Production from Operating Wind Farms in North America. Part II: Statistical Downscaling

Abstract Capacity factors (CFs) derived from daily expected power at 22 operating wind farms in different regions of North America are used as predictands to train statistical downscaling algorithms using output from ERA5. The statistical downscaling models are then used to make CF projections for a suite of CMIP6 Earth System Models (ESMs). Downscaling is performed using a hybrid statistical approach that employs synoptic types derived using k -means clustering applied to sea level pressure fields with variance corrections applied as a function of the pressure gradient intensity. ESMs exhibit marked variability in terms of the skill with which the frequency of synoptic types and pressure gradients are reproduced relative to ERA5, and that differential skill is used to infer differential credibility in the associated CF projections. Projections of median annual mean CF [P50(CF)] in each 20-yr period from 1980 to 2099 show evidence of declines at most wind farms except in parts of the southern Great Plains, although the magnitude of the changes is strongly dependent on the ESM. For example, P50(CF) in 2080–99 deviate from those in 1980–99 by from −3.1 to +0.2 percentage points in the Northeast. The largest-magnitude declines in P50(CF) ranging from −3.9 to −2 percentage points are projected for the southern West Coast. CF trends exhibit marked seasonality and are strongly linked to changes in the relative intensity of future synoptic patterns, with much less impact from shifts in the occurrence of synoptic types over time. Internal climate modes continue to play a significant role in inducing interannual variability in wind power production, even under high radiative forcing scenarios. Significance Statement We describe how future climate changes may affect wind resources and wind power generation. Near-term changes in projected wind power electricity generation potential at operating wind farms over North America are small, but by the end of the current century electricity production is projected to decrease in many areas but may increase in parts of the southern Great Plains. The amount of change in projected wind power production is a strong function of the Earth system model that is downscaled and also depends on the continued presence of internally forced climate variability. An additional dependence on the amount of greenhouse gas–induced global warming indicates the transition of the energy sector to low-carbon sources may assist in maintaining the abundant U.S. wind resource.

Meteorology & Atmospheric Sciences↗
NASA NTRS1990

High-T(sub c) squid application in medicine and geophysics

In the Laboratory a high-T(sub c) one-hole squid was built from Y1Ba2Cu3O(7-x) ceramics obtained by a standard procedure of solid state reaction. The ceramics with critical current density J(sub c) is greater than 100 A/sq cm was selected. In the middle of 10 x 10 x 2 mm ceramics pellet a 0.8 mm hole was drilled in which superconducting loop of the squid was located. Between the hole and the edge of the pellet a cut was mechanically filed out with a bridge inside it connecting the superconducting ring. A scheme of the magnetometer is presented. The resonant frequency shift of the tank circuit, the connection of the squid with this circuit, and the squid inductance are evaluated. One of the most interesting fields of the squid-based magnetometer application is biomagnetism, particularly, the human heart magnetocardiogram measuring. The low-temperature squids were used in this area and many interesting and important scientific results have been obtained. The observations have shown that the main noise contribution was not due to the squid but to the Earth's magnetic field variations, industrial inductions, and mainly to the vibrations caused by liquid nitrogen boiling and by vibrations of the box. Further attempts are needed to reduce the magnetic noise inductions. Nevertheless, the estimations promise the maximum signal/noise relation of the high-T(sub c) squid-magnetocardiometer to be not less than 10:1 in a bandwidth of 60 Hz. Apparently, such resolution would be enough not only for steady cardiogram reading but even for thin structure investigation at average technique application.

Polushkin, V. N.↗
NASA NTRS1982

End region and current consolidation effects upon the performance of an MHD channel for the ETF conceptual design

It is noted that operating conditions which yielded a peak thermodynamic efficiency (41%) for an EFT-size MHD/steam power plant were previously (Wang et al., 1981; Staiger, 1981) identified by considering only the active region (the primary portion for power production) of an MHD channel. These previous efforts are extended here to include an investigation of the effects of the channel end regions on overall power generation. Considering these effects, the peak plant thermodynamic efficiency is found to be slightly lowered (40.7%); the channel operating point for peak efficiency is shifted to the supersonic mode (Mach number of approximately 1.1) rather than the previous subsonic operation (Mach number of approximately 0.9). Also discussed is the sensitivity of the channel performance to the B-field, diffuser recovery coefficient, channel load parameter, Mach number, and combustor pressure.

Wang, S. Y.↗
DOE OSTI2022

Riverine bacterioplankton and phytoplankton assembly along an environmental gradient induced by urbanization

In the Anthropocene, human activities are intensifying stresses on biological communities across ecosystems. Knowledge on how environmental changes influence microbial community dynamics is crucial but currently limited. Here we unraveled ecological processes generating distribution patterns of bacterioplankton and phytoplankton communities in a river draining an urbanizing watershed in southern China. In this ecosystem, longitudinal environmental heterogeneity and directional flow potentially have counteracting effects on planktonic community assembly. Using simultaneously multiple approaches, we showed that the observed compositional patterns result from an interplay of stochastic and deterministic processes, indicating that dispersal via fluvial connectivity could not override local selective pressures. Successional shifts in the relative importance of the above processes were associated with trends in climatic factors. High diversity was observed at the intermediate levels of ecological processes alongside intense inter-species interactions maintained by a few keystone taxa. Altogether, interactions between climatic conditions, landscape and hydrology control plankton community dynamics.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Chemical Reaction Rate Coefficients from Ring Polymer Molecular Dynamics: Theory and Practical Applications

This Feature Article presents an overview of the current status of ring polymer molecular dynamics (RPMD) rate theory. We first analyze the RPMD approach and its connection to quantum transition-state theory. We then focus on its practical applications to prototypical chemical reactions in the gas phase, which demonstrate how accurate and reliable RPMD is for calculating thermal chemical reaction rate coefficients in multifarious cases. This review serves as an important checkpoint in RPMD rate theory development, which shows that RPMD is shifting from being just one of recent novel ideas to a well-established and validated alternative to conventional techniques for calculating thermal chemical rate coefficients. We also hope it will motivate further applications of RPMD to various chemical reactions.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Fabrication of Large-Area Metal-on-Carbon Catalytic Condensers for Programmable Catalysis

Catalytic condensers stabilize charge on either side of a high-k dielectric film to modulate the electronic states of a catalytic layer for the electronic control of surface reactions. Here, carbon sputtering provided for fast, large-scale fabrication of metal–carbon catalytic condensers required for industrial application. Carbon films were sputtered on HfO 2 dielectric/p-type Si with different thicknesses (1, 3, 6, and 10 nm), and the enhancement of conductance and capacitance of carbon films was observed upon increasing the carbon thickness following thermal treatment at 400 °C. After Pt deposition on the carbon films, the Pt catalytic condenser exhibited a high capacitance of ∼210 nF/cm 2 that was maintained at a frequency ∼1000 Hz, satisfying the requirement for a dynamic catalyst to implement catalytic resonance. Temperature-programmed desorption of carbon monoxide yielded CO desorption peaks that shifted in temperature with the varying potential applied to the condenser (−6 or +6 V), indicating a shift in the binding energy of carbon monoxide on the Pt condenser surface. A substantial increase in capacitance (∼2000 nF/cm 2 ) of the Pt-on-carbon devices was observed at elevated temperatures of 400 °C that can modulate ∼10% of charge per metal atom when 10 V potential was applied. A large catalytic condenser of 42 cm 2 area Pt/C/HfO 2 /Si exhibited a high capacitance of 9393 nF with a low leakage current/capacitive current ratio (<0.1), demonstrating the practicality and versatility of the facile, large-scale fabrication method for metal–carbon catalytic condensers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Scintillation event imaging with a single photon avalanche diode camera

Position and time measurements of scintillation events encode information about the radiation source. Single photon avalanche diode (SPAD) arrays offer multiple-megapixel spatial resolution and tens of picoseconds temporal resolution for detecting single photons. Current lensless designs for measuring scintillation events use sensors that are lower in spatial resolution. Camera-based designs use sensors that are lower in temporal resolution or readout rate and cannot image individual interactions. Here we propose to image scintillation events in a thick, monolithic scintillator using a high-resolution SPAD camera. We demonstrate that a commercial SPAD camera is able to gather sufficient signal to image individual scintillation events and observe 3D shifts in their spatial distribution. Simulations show that a SPAD camera can localize individual scintillation events in 3D. We report direct imaging of gamma-ray interactions in a scintillator with a SPAD camera. The proposed design may allow to measure complex signatures of individual particles interacting in the scintillator.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Quantitative spatiotemporal density evolution of aluminum heated purely by monochromatic electrons

A spatially resolved air-wedge shearing interferometer and shadowgraph diagnostic provides measurements of electron density with a resolution of ∼40 μm. A ∼100-ns-long, monoenergetic electron bunch at 19.8 MeV and a current of 1.4 kA (8.5×1014 e−) heats 100-μm-thick aluminum (Al) foils in a 1-mm-spot to Te∼1 eV. A 5-ns-long, ∼60 mJ, frequency doubled Nd:YAG laser probes the dense Al plasma. Electron densities up to 1020cm−3 are resolved; the maximum resolvable density is limited by opacity, transmission, and spatial fringe density achievable with the detector. This diagnostic provides measurements of the total phase shift, transmission, and electron density. Several measurements at different time slices provide the ability to determine the velocity of the leading edge of the shadowgraph and compare it to the motion of different density shells. These measurements are also compared to radiation hydrodynamics simulations. A rough quantitative agreement is shown between the hydro simulations and the measurements; there are differences in the exact density distributions.

Coleman, J. E. (ORCID:0000000308873757)↗
DOE OSTI2021

Bayesian inference of the incompressibility, skewness and kurtosis of nuclear matter from empirical pressures in relativistic heavy-ion collisions

Within the Bayesian statistical framework we infer the incompressibility K 0 , skewness J 0 and kurtosis Z 0 parameters of symmetric nuclear matter (SNM) at its saturation density ρ 0 using the constraining bands on the pressure in cold SNM in the density range of 1.3ρ 0 to 4.5ρ 0 from transport model analyses of kaon production and nuclear collective flow in relativistic heavy-ion collisions. As the default option assuming the K 0 , J 0 and Z 0 have Gaussian prior probability distribution functions (PDFs) with the means and variances of 235±30, -200±200 and -146±1728 MeV, their posterior most probable values are narrowed down to 192$^{+12}_{-16}$ MeV, -180$^{+100}_{-110}$ MeV and ${\mathrm{200}}_{-250}^{+250}$ at 68% confidence level, respectively. The results are largely independent of the prior PDFs of J 0 and Z 0 used. However, if one adopts the strong belief that the incompressibility K 0 has a uniform prior PDF within its absolute boundary of 220–260 MeV as one can find easily in the literature, the posterior most probable values of K 0 , J 0 and Z 0 shift to ${K}_{0}=22{0}_{-0}^{+6}$ MeV, ${J}_{0}=-39{0}_{-70}^{+60}$ MeV and ${Z}_{0}=60{0}_{-200}^{+200}$ MeV, respectively. While the posterior PDFs of the SNM EOS parameters depend somewhat on the prior PDF of K 0 used, the results from using different prior PDFs are qualitatively consistent. The uncertainties of all three parameters are significantly reduced especially for the J 0 and Z 0 parameters compared to their current values.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2017

A tale of two modes: neutrino free-streaming in the early universe

We present updated constraints on the free-streaming nature of cosmological neutrinos from cosmic microwave background (CMB) temperature and polarization power spectra, baryonic acoustic oscillation data, and distance ladder measurements of the Hubble constant. Specifically, we consider a Fermi-like four-fermion interaction between massless neutrinos, characterized by an effective coupling constant G {sub eff}, and resulting in a neutrino opacity τ-dot {sub ν∝} G {sub eff}{sup 2} T {sub ν}{sup 5}. Using a conservative flat prior on the parameter log{sub 10}( G {sub eff} MeV{sup 2}), we find a bimodal posterior distribution with two clearly separated regions of high probability. The first of these modes is consistent with the standard ΛCDM cosmology and corresponds to neutrinos decoupling at redshift z {sub ν,dec} > 1.3×10{sup 5}, that is before the Fourier modes probed by the CMB damping tail enter the causal horizon. The other mode of the posterior, dubbed the 'interacting neutrino mode', corresponds to neutrino decoupling occurring within a narrow redshift window centered around z {sub ν,dec}∼8300. This mode is characterized by a high value of the effective neutrino coupling constant, log{sub 10}( G {sub eff} MeV{sup 2}) = −1.72 ± 0.10 (68% C.L.), together with a lower value of the scalar spectral index and amplitude of fluctuations, and a higher value of the Hubble parameter. Using both a maximum likelihood analysis and the ratio of the two mode's Bayesian evidence, we find the interacting neutrino mode to be statistically disfavored compared to the standard ΛCDM cosmology, and determine this result to be largely driven by the low- l CMB temperature data. Interestingly, the addition of CMB polarization and direct Hubble constant measurements significantly raises the statistical significance of this secondary mode, indicating that new physics in the neutrino sector could help explain the difference between local measurements of H {sub 0}, and those inferred from CMB data. A robust consequence of our results is that neutrinos must be free streaming long before the epoch of matter-radiation equality in order to fit current cosmological data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Towards a fiber barrel detector for next-generation high-pressure gaseous xenon TPCs

Abstract The NEXT (Neutrino Experiment with a Xenon TPC) project is an international collaboration aimed at finding evidence of neutrinoless double beta decay using gaseous xenon. The current phase of the project involves the construction and operation of NEXT-100, which is designed to hold 100 kg of xenon at 15 bar and is expected to start commissioning in the first quarter of 2024. NEXT-HD will be a tonne scale experiment following NEXT-100 and will incorporate a symmetric design, with one cathode and two anodes. For this detector, the collaboration is considering to implement a barrel of wavelength-shifting fibers read-out by silicon photomultipliers to measure the energy of the particles interacting in the gaseous xenon. In this document, we will discuss the characteristics of this approach and provide an update on the related R&D efforts.

Instruments & Instrumentation↗
DOE OSTI2021

Powering the Blue Economy: A Survey of Station-Keeping Methods for Mooringless Platforms

The term “ocean platform” is used to reference everything from stationary, typically moored, buoys to mobile water vehicles, whether they operate on the ocean’s surface or underwater. For certain applications for which relatively stationary station-keeping conditions are desired, the use of mooring systems is not always a viable alternative either for economic, environmental, regulatory, or otherwise practical reasons, or a combination thereof, (e.g., short deployments, sensitive ecosystems, very deep project sites). Maintaining a platform at a single waypoint or reference location without being moored would require additional control systems and a power source to counteract the drift forces that would naturally displace it. Mobile platforms, which are usually untethered except for remotely operated vehicles, typically require energy input to power their station-keeping capabilities so that they hold or control their location in the ocean. Currently, most of these platforms use combustion engines or batteries for this purpose, which, depending on the specific systems, may be costly, pollute the environment, or create limitations on the length of the deployment. However, powering this kind of platforms with surrounding renewable resources (waves, currents, winds, or sun) has been identified as a promising solution to expand their application. The intent of this report is to investigate station-keeping methods for various ocean platforms that are not moored or otherwise anchored to the ocean floor, or another platform or vessel, paying particular interest to technologies that use marine renewable resources to power their operation, because that is of particular interest to the U.S. Department of Energy’s Powering the Blue Economy (PBE) initiative. As a first step, 72 articles and technical reports related to mooringless station-keeping methods were collected for review. The preliminary literature review provided a broad overview of common themes across the literature from which a descriptive methodology for analyzing various platforms was developed. That is, station-keeping methods were categorized based on their predominant energy source and consumption (renewable, nonrenewable, or hybrid if the platform uses renewable and nonrenewable resources equally), and their localization strategy (drift reduction, “path-planning or “waypoint-holding”). In addition, platform types were segregated into the following groups: buoys, surface drifters, and unoccupied surface vehicles (USVs); offshore renewable energy systems; and unoccupied underwater vehicles (UUVs). The main types of station-keeping methods encountered in this report achieve their intended localization strategy by means of drift mitigation, steering, and/or propulsion. Drift mitigation is commonly accomplished via drogues and sea anchors. Stand-along steering subsystems use control surfaces (e.g., ship rudder, wing sail, etc.) that react to ocean currents, waves, or winds to provide varying-degrees of course adjustments. Combined steering and propulsion subsystems include differential thrusters, directional thrusters separate from a primary thruster that cause the platform to pitch up/down or yaw clockwise/counterclockwise, or vectored thrusters that direct the propulsion in a range of directions relative to the platform’s local coordinate system. Propulsion is often achieved by running a motor and applying active control strategies but can also involve buoyancy shifts and using sails to generate lifting forces that propel a platform in a desired direction. Future research is primarily expected to take place in the form of a technoeconomic analysis that would aim to determine the technological viability, cost, and added value of mooringless station-keeping use cases identified through this research, including docking for UUV recharging or for georeferencing drifter buoys, deep-sea floating wind farms, U.S. Navy sonar arrays, and a Pacific Ocean wave buoy network.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

The impact of unresolved turbulence on the escape fraction of Lyman Continuum photons

We investigate the relation between the turbulent Mach number (M) and the escape fraction of Lyman continuum photons (f{sub esc}) in high-redshift galaxies. Approximating the turbulence as isothermal and isotropic, we show that the increase in the variance in column densities from M=1 to M=10 causes f{sub esc} to increase by ≈25%, and the increase from M=1 to M=20 causes f{sub esc} to increases by ≈50% for a medium with opacity τ≈1. At a fixed Mach number, the correction factor for escape fraction relative to a constant column density case scales exponentially with the opacity in the cell, which has a large impact for simulated star-forming regions. Furthermore, in simulations of isotropic turbulence with full atomic/ionic cooling and chemistry, the fraction of HI drops by a factor of ≈2.5 at M≈10 even when the mean temperature is ≈5×10{sup 3} K. If turbulence is unresolved, these effects together enhance f{sub esc} by a factor >3 at Mach numbers above 10. Such Mach numbers are common at high redshifts where vigorous turbulence is driven by supernovae, gravitational instabilities, and merger activity, as shown both by numerical simulations and observations. These results, if implemented in the current hydrodynamical cosmological simulations to account for unresolved turbulence, can boost the theoretical predictions of the Lyman Continuum photon escape fraction and further constrain the sources of reionization.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2010

What the Heck is Going On at NASA?

On February 1, 2010, the federal budget for Fiscal Year 2011 was released. NASA received an increase, unlike almost any other federal agency. At the same time, the budget revealed that the Constellation Program would be cancelled and that NASA would look to private sector providers for transportation of cargo, and eventually crew members, to the International Space Station. The Constellation Program had included a human return to the Moon by the year 2020, and the program plans called for a permanent surface facility capable of supporting human explorers. In the FY2011 announcement, the prescription of a lunar objective was replaced by a concept called flexible path that was advertised to open possibilities of other types of human missions beyond low Earth orbit. The policy direction has polarized the U.S. space community, where the reactions have been swift and polemical. The new policy has been described both as the death knell of human space exploration and as the only hope to save human space exploration. Some members of Congress have threatened legal action based on the current law regarding appropriation of funds to NASA, which states that Constellation cannot be cancelled without prior consultation with Congress. As might be expected, some of the reaction is directly related to losses or gains of jobs in districts associated with NASA facilities. However, various statements show high emotional content, suggesting that personal belief systems have been challenged. Meanwhile, many details of the new policy are not yet clear; and some aspects seem to be shifting in response to political reaction. The final direction for NASA will not be known until the FY2011 budget has been passed by Congress and signed by the President. I will draw upon my 28 years of studying, writing, and speaking on the topic of future human exploration beyond low Earth orbit to discuss the various issues at stake and the historical context for the debate. My own work has had a central theme of lunar exploration and development, but I have also come to believe that human exploration will never be more than a political sideshow until a significant economic sector can be created in space off of the Earth. Disclaimer: The views presented will be my own and in no way reflect official policies of the NASA.

Mendell, Wendell↗
NASA NTRS2011

Evaluation of Mars CO2 Capture and Gas Separation Technologies

Recent national policy statements have established that the ultimate destination of NASA's human exploration program is Mars. In Situ Resource Utilization (ISRU) is a key technology required to ,enable such missions and it is appropriate to review progress in this area and continue to advance the systems required to produce rocket propellant, oxygen, and other consumables on Mars using the carbon dioxide atmosphere and other potential resources. The Mars Atmospheric Capture and Gas separation project is selecting, developing, and demonstrating techniques to capture and purify Martian atmospheric gases for their utilization for the production of hydrocarbons, oxygen, and water in ISRU systems. Trace gases will be required to be separated from Martian atmospheric gases to provide pure CO2 to processing elements. In addition, other Martian gases, such as nitrogen and argon, occur in concentrations high enough to be useful as buffer gas and should be captured as well. To achieve these goals, highly efficient gas separation processes will be required. These gas separation techniques are also required across various areas within the ISRU project to support various consumable production processes. The development of innovative gas separation techniques will evaluate the current state-of-the-art for the gas separation required, with the objective to demonstrate and develop light-weight, low-power methods for gas separation. Gas separation requirements include, but are not limited to the selective separation of: (1) methane and water from unreacted carbon oxides (C02-CO) and hydrogen typical of a Sabatier-type process, (2) carbon oxides and water from unreacted hydrogen from a Reverse Water-Gas Shift process, (3)/carbon oxides from oxygen from a trash/waste processing reaction, and (4) helium from hydrogen or oxygen from a propellant scavenging process. Potential technologies for the separations include' freezers, selective membranes, selective solvents, polymeric sorbents, zeolites, and new technologies. This paper summarizes the results of an extensive literature review of candidate technologies for the capture and separation of CO2 and other relevant gases. This information will be used to prioritize the technologies to be developed further during this and other ISRU projects.

Muscatello, Anthony C.↗