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All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Hysteresis in the Active Oxidation of SiC

Si and SiC show both passive oxidation behavior where a protective film of SiO2 forms and active oxidation behavior where a volatile suboxide SiO(g) forms. The active-to-passive and passive-to-active oxidation transitions are explored for both Si and SiC. Si shows a dramatic difference between the P(O2) for the two transitions of ~10-4 bar. The active-to-passive transition is controlled by the condition for SiO2/Si equilibrium and the passive-to-active transition is controlled by the decomposition of SiO2. In the case of SiC, the P(O2) for these transitions are much closer. The active-to-passive transition appears to be controlled by the condition for SiO2/SiC equilibrium. The passive-to-active transition appears to be controlled by the interfacial reaction of SiC and SiO2 and subsequent generation of gases at the interface which leads to scale breakdown.

Jacobson, Nathan S.↗
NASA NTRS2011

Observational Evidence of Aerosol Enhancement of Lightning Activity and Convective Invigoration

Lightning activity over the West Pacific Ocean east of the Philippines is usually much less frequent than over the nearby maritime continents. However, in 2005 the Lightning Imaging Sensor (LIS) aboard the TRMM satellite observed anomalously high lightning activity in that area. In the same year the Moderate resolution Imaging Spectroradiometer (MODIS) measured anomalously high aerosol loading. The high aerosol loading was traced to volcanic activity, and not to any factor linked to meteorology, disentangling the usual convolution between aerosols and meteorology. We show that in general lightning activity is tightly correlated with aerosol loadings at both inter-annual and biweekly time scales. We estimate that a approximately 60% increase in aerosol loading leads to more than 150% increase in lightning flashes. Aerosols increase lightning activity through modification of cloud microphysics. Cloud ice particle sizes are reduced and cloud glaciation is delayed to colder temperature when aerosol loading is increased. TRMM precipitation radar measurements indicate that anomalously high aerosol loading is associated with enhanced cloud mixed phase activity and invigorated convection over the maritime ocean. These observed associations between aerosols, cloud microphysics, morphology and lightning activity are not related to meteorological variables or ENSO events. The results have important implications for understanding the variability of lightning and resulting aerosol-chemistry interactions.

Yuan, Tianle↗
NASA NTRS2012

Active Oxidation of a UHTC-Based CMC

The active oxidation of ceramic matrix composites (CMC) is a severe problem that must be avoided for multi-use hypersonic vehicles. Much work has been performed studying the active oxidation of silicon-based CMCs such as C/SiC and SiC-coated carbon/carbon (C/C). Ultra high temperature ceramics (UTHC) have been proposed as a possible material solution for high-temperature applications on hypersonic vehicles. However, little work has been performed studying the active oxidation of UHTCs. The intent of this paper is to present test data indicating an active oxidation process for a UHTC-based CMC similar to the active oxidation observed with Si-based CMCs. A UHTC-based CMC was tested in the HyMETS arc-jet facility (or plasma wind tunnel, PWT) at NASA Langley Research Center, Hampton, VA. The coupon was tested at a nominal surface temperature of 3000 F (1650 C), with a stagnation pressure of 0.026 atm. A sudden and large increase in surface temperature was noticed with negligible increase in the heat flux, indicative of the onset of active oxidation. It is shown that the surface conditions, both temperature and pressure, fall within the region for a passive to active transition (PAT) of the oxidation.

Glass, David E.↗
NASA NTRS2012

Forecasting the Solar Drivers of Severe Space Weather from Active-Region Magnetograms

Large flares and fast CMEs are the drivers of the most severe space weather including Solar Energetic Particle Events (SEP Events). Large flares and their co-produced CMEs are powered by the explosive release of free magnetic energy stored in non-potential magnetic fields of sunspot active regions. The free energy is stored in and released from the low-beta regime of the active region s magnetic field above the photosphere, in the chromosphere and low corona. From our work over the past decade and from similar work of several other groups, it is now well established that (1) a proxy of the free magnetic energy stored above the photosphere can be measured from photospheric magnetograms, and (2) an active region s rate of production of major CME/flare eruptions in the coming day or so is strongly correlated with its present measured value of the free-energy proxy. These results have led us to use the large database of SOHO/MDI full-disk magnetograms spanning Solar Cycle 23 to obtain empirical forecasting curves that from an active region s present measured value of the free-energy proxy give the active region s expected rates of production of major flares, CMEs, fast CMEs, and SEP Events in the coming day or so (Falconer et al 2011, Space Weather, 9, S04003). We will present these forecasting curves and demonstrate the accuracy of their forecasts. In addition, we will show that the forecasts for major flares and fast CMEs can be made significantly more accurate by taking into account not only the value of the free energy proxy but also the active region s recent productivity of major flares; specifically, whether the active region has produced a major flare (GOES class M or X) during the past 24 hours before the time of the measured magnetogram. By empirically determining the conversion of the value of free-energy proxy measured from a GONG or HMI magnetogram to that which would be measured from an MDI magnetogram, we have made GONG and HMI magnetograms useable with our MDI-based forecasting curves to forecast event rates.

Falconer, David A.↗
NASA NTRS2012

Forecasting the Solar Drivers of Severe Space Weather from Active-Region Magnetograms

Large flares and fast CMEs are the drivers of the most severe space weather including Solar Energetic Particle Events (SEP Events). Large flares and their co-produced CMEs are powered by the explosive release of free magnetic energy stored in non-potential magnetic fields of sunspot active regions. The free energy is stored in and released from the low-beta regime of the active region s magnetic field above the photosphere, in the chromosphere and low corona. From our work over the past decade and from similar work of several other groups, it is now well established that (1) a proxy of the free magnetic energy stored above the photosphere can be measured from photospheric magnetograms, and (2) an active region s rate of production of major CME/flare eruptions in the coming day or so is strongly correlated with its present measured value of the free-energy proxy. These results have led us to use the large database of SOHO/MDI full-disk magnetograms spanning Solar Cycle 23 to obtain empirical forecasting curves that from an active region s present measured value of the free-energy proxy give the active region s expected rates of production of major flares, CMEs, fast CMEs, and SEP Events in the coming day or so (Falconer et al 2011, Space Weather, 9, S04003). We will present these forecasting curves and demonstrate the accuracy of their forecasts. In addition, we will show that the forecasts for major flares and fast CMEs can be made significantly more accurate by taking into account not only the value of the free energy proxy but also the active region s recent productivity of major flares; specifically, whether the active region has produced a major flare (GOES class M or X) during the past 24 hours before the time of the measured magnetogram. By empirically determining the conversion of the value of free-energy proxy measured from a GONG or HMI magnetogram to that which would be measured from an MDI magnetogram, we have made GONG and HMI magnetograms useable with our MDI-based forecasting curves to forecast event rates.

Falconer, David A.↗
NASA NTRS2014

Management and Climate Contributions to Satellite-Derived Active Fire Trends in the Contiguous United States

Fires in croplands, plantations, and rangelands contribute significantly to fire emissions in the United States, yet are often overshadowed by wildland fires in efforts to develop inventories or estimate responses to climate change. Here we quantified decadal trends, interannual variability, and seasonality of Terra Moderate Resolution Imaging Spectroradiometer (MODIS) observations of active fires (thermal anomalies) as a function of management type in the contiguous U.S. during 2001-2010. We used the Monitoring Trends in Burn Severity database to identify active fires within the perimeter of large wildland fires and land cover maps to identify active fires in croplands. A third class of fires defined as prescribed/other included all residual satellite active fire detections. Large wildland fires were the most variable of all three fire types and had no significant annual trend in the contiguous U.S. during 2001-2010. Active fires in croplands, in contrast, increased at a rate of 3.4 percent per year. Cropland and prescribed/other fire types combined were responsible for 77 percent of the total active fire detections within the U.S and were most abundant in the south and southeast. In the west, cropland active fires decreased at a rate of 5.9 percent per year, likely in response to intensive air quality policies. Potential evaporation was a dominant regulator of the interannual variability of large wildland fires, but had a weaker influence on the other two fire types. Our analysis suggests it may be possible to modify landscape fire emissions within the U.S. by influencing the way fires are used in managed ecosystems.

Satellite-derived↗
NASA NTRS2017

Integrated Extravehicular Activity Human Research Plan: 2017

Multiple organizations within NASA as well as industry and academia fund and participate in research related to extravehicular activity (EVA). In October 2015, representatives of the EVA Office, the Crew and Thermal Systems Division (CTSD), and the Human Research Program (HRP) at NASA Johnson Space Center agreed on a formal framework to improve multi-year coordination and collaboration in EVA research. At the core of the framework is an Integrated EVA Human Research Plan and a process by which it will be annually reviewed and updated. The over-arching objective of the collaborative framework is to conduct multi-disciplinary cost-effective research that will enable humans to perform EVAs safely, effectively, comfortably, and efficiently, as needed to enable and enhance human space exploration missions. Research activities must be defined, prioritized, planned and executed to comprehensively address the right questions, avoid duplication, leverage other complementary activities where possible, and ultimately provide actionable evidence-based results in time to inform subsequent tests, developments and/or research activities. Representation of all appropriate stakeholders in the definition, prioritization, planning and execution of research activities is essential to accomplishing the over-arching objective. A formal review of the Integrated EVA Human Research Plan will be conducted annually. Coordination with stakeholders outside of the EVA Office, CTSD, and HRP is already in effect on a study-by-study basis; closer coordination on multi-year planning with other EVA stakeholders including academia is being actively pursued. Details of the preliminary Integrated EVA Human Research Plan are presented including description of ongoing and planned research activities in the areas of: physiological and performance capabilities; suit design parameters; EVA human health and performance modeling; EVA tasks and concepts of operations; EVA informatics; human-suit sensors; suit sizing and fit; and EVA injury risk and mitigation. This paper represents the 2017 update to the Integrated EVA Human Research Plan.

Abercromby, Andrew↗
NASA NTRS2020

Forecasting Rates of Volcanic Activity on Terrestrial Exoplanets

Similar to the planets and moons in our solar system, terrestrial exoplanets may be shaped by volcanism and tectonics. The magnitudes and rates of geological activity on terrestrial exoplanets will be intimately linked to their sizes and internal heating rates, and can either facilitate, or preclude, the existence of habitable environments. In order to place bounds on the potential for such activity, we estimate total internal heating rates for 52 exoplanets, with masses and radii up to ~ 8M(sub E) and 2R(sub E), respectively, assuming that internal heating is drawn from both radiogenic and tidal sources. We then compare these internal heating rates to those of the bodies in our solar system in an attempt to constrain the rates of volcanic activity on extrasolar worlds. We find that all of the exoplanets surveyed are likely to exhibit volcanic activity at their surfaces. We also find that at least 25% of the of the planets in our study may be extrasolar ocean worlds, the majority of which may contain internal oceans beneath layers of surface ice. These planets may be similar in structure to the icy moons of the giant planets and may have persistent cryovolcanic activity at their surfaces. Volcanic activity on exoplanets could be detected by next-generation space telescopes in transit spectra. In the case of planets with densities and/or effective temperatures that are consistent with H2O-rich compositions, spectral identification of excess water vapor and other molecules that are explosively vented into space during cryovolcanic eruptions could serve as a way to infer the presence of subsurface oceans, and therefore indirectly assess their habitability. Considering the implications for habitability, our results suggest that characterizing Earth-like exoplanets in terms of the potential for geological activity at their surfaces should be a priority in the coming years.

Lynnae C Quick↗
NASA NTRSDate not supplied

Conceptual Integration Studies of Localized Active Flow Control on the Wing of a Commercial Aircraft

A study of conceptual integration and performance of localized active flow control technology onto wings of short-to-medium-range project passenger airplanes is summarized. Using predicted aerodynamic performance improvement opportunities on a computational fluid dynamics reference aircraft, this paper presents the estimated performance opportunities for conceptual implementation of studied wing localized active flow control technology for low-speed (takeoff and landing) application on a Project Research Aircraft configuration. Using conceptual active flow control systems and structural integration weight penalties for studied concepts, potential relevant net performance benefits can be obtained with reliable active flow control in takeoff and landing. The conceptual integration study identifies potential localized wing active flow control application opportunities for high-lift conditions using energy sources available on modern aircraft. Material benefits are estimated for takeoff and landing configurations for selected localized wing active flow control applications. The study concluded that substantial low-speed Maximum Lift and Lift/Drag related performance improvements may be possible with localized wing high-lift active flow control systems powered by auxiliary power unit, engine bleed, or electrical compressors - with due consideration of integration and weight impacts as well as availability requirements of such systems.

drag reduction↗
NASA NTRSDate not supplied

The Project “Analogs for VENus’s GEologically Recent Surfaces” (AVENGERS): Unveiling Active Volcanism on Venus

The recently selected missions to Venus opened a new era for the exploration of the Earth’s hellish twin sister. One of the key questions that the selected missions to Venus will address is whether the planet is volcanically active. The identification of ongoing volcanic activity on Venus can indeed unveil important clues on the geologic evolution of the planet, also helping us to better understand how volcanic and atmospheric processes work on Earth, especially those related to the climate change produced by greenhouse gases. To fully contextualize the higher resolution datasets to be provided by the future missions to Venus, we need to be able to exploit the wealth of data to be produced in the best possible way. Different types of instruments will indeed perform unprecedent orbiting and in-situ investigations of the surface and subsurface of Venus. To this regard, the Project “Analogs for VENus’s GEologically Recent Surfaces” (AVENGERS) aims to build a comprehensive database of Terrestrial active volcanoes which may act as suitable analogs for identifying ongoing volcanic activity on Venus. To do this, the project AVENGERS will combine the implementation of terrestrial orbiter radar data analysis techniques (i.e., radar interferometry) with infrared and laboratory analyses of lava flow samples from Terrestrial active volcanoes. As a first suitable analog of the Project AVENGERS, we selected Mount Etna in Sicily for a direct comparison with potentially active volcanic structures of Venus, and with Idunn Mons, one of the most promising possibly active volcanoes of Venus. Given its composite nature, Mount Etna offers the opportunity to identify and study multiple types of eruptive products (both effusive and explosive) from the analysis of high-resolution radar images. The frequent eruptions characterizing this volcano will also allow to test techniques of radar interferometry. Moreover, its ease of access facilitates geologic field trips and in-situ investigations with related sample retrieving. Ongoing infrared laboratory analysis on several altered and unaltered samples retrieved by Mount Etna will help to distinguish spectral signatures of fresh vs weathered volcanic deposits.

P. D’Incecco↗
NASA NTRS2017

Analysis of in Vitro Evolution Reveals the Underlying Distribution of Catalytic Activity Among Random Sequences

The emergence of catalytic RNA is believed to have been a key event during the origin of life. Understanding how catalytic activity is distributed across random sequences is fundamental to estimating the probability that catalytic sequences would emerge. Here, we analyze the in vitro evolution of triphosphorylating ribozymes and translate their fitnesses into absolute estimates of catalytic activity for hundreds of ribozyme families. The analysis efficiently identified highly active ribozymes and estimated catalytic activity with good accuracy. The evolutionary dynamics follow Fisher’s Fundamental Theorem of Natural Selection and a corollary, permitting retrospective inference of the distribution of fitness and activity in the random sequence pool for the first time. The frequency distribution of rate constants appears to be log-normal, with a surprisingly steep dropoff at higher activity, consistent with a mechanism for the emergence of activity as the product of many independent contributions.

Abe Pressman↗
DOE OSTI2015

Hybrid energy storage systems utilizing redox active organic compounds

Redox flow batteries (RFB) have attracted considerable interest due to their ability to store large amounts of power and energy. Non-aqueous energy storage systems that utilize at least some aspects of RFB systems are attractive because they can offer an expansion of the operating potential window, which can improve on the system energy and power densities. One example of such systems has a separator separating first and second electrodes. The first electrode includes a first current collector and volume containing a first active material. The second electrode includes a second current collector and volume containing a second active material. During operation, the first source provides a flow of first active material to the first volume. The first active material includes a redox active organic compound dissolved in a non-aqueous, liquid electrolyte and the second active material includes a redox active metal.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Semiconductor topologies and devices for soft starting and active fault protection of power converters

Various examples are provided related to semiconductor topologies and devices that can be used for soft starting and active fault protection of power converters. In one example, an active switch device includes an active switch having a gating control input; and a thyristor having a gating control input. The thyristor is coupled in parallel with the active switch. The active switch can be an IGBT, MOSFET, or other appropriate device. In another example, a power converter can include the active switch devices and switching control circuitry coupled to gating control inputs of the active switch devices.

Beddingfield, Richard B.↗
DOE OSTI2015

Endangered species act impacts on office of legacy management activities at the Rocky Flats, Colorado, Site - 15268

The Endangered Species Act was passed by Congress in 1973 to protect and recover imperiled species and the ecosystems they rely on. The Preble's meadow jumping mouse (Preble's mouse, Zapus hudsonius preblei) was discovered living along the streams at the Rocky Flats Site on the Front Range of Colorado, in the early 1990's during baseline ecological monitoring. In 1998, the Preble's mouse was classified as a federally listed threatened species under the Endangered Species Act. As a result, the mouse and its habitat are protected and Section 7 consultation with the US Fish and Wildlife Service (US FWS) is required before activities may be conducted in Preble's mouse habitat. This requirement has the potential to impact Rocky Flats project schedules and costs since approval from US FWS is needed prior to conducting activities. To reduce the need to consult with US FWS for projects on a case-by-case basis, a programmatic approach was taken. A master list of ongoing activities and other potential future activities was developed and evaluated in a Programmatic Biological Assessment (PBA) that was written for site activities. The PBA that was approved in 2004 worked well during closure, but did not address many ongoing, postclosure US DOE Office of Legacy Management activities. As a result, the PBA was rewritten in 2013 to address postclosure routine and project-specific activities. The use of a programmatic approach has reduced the time and costs associated with getting individual US FWS approvals, which has in turn minimized impacts to schedules. The programmatic approach could prove useful for other US DOE sites with federally listed species. (authors)

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Characterization of plutonium activities in soil - 15429

Plutonium (Pu) contamination in soils at the Nevada National Security Site (NNSS) is characterized using Am-241 activity results from gamma spectroscopy (gamma Am-241) analysis. This is done by inferring the Pu activities using Pu to Am-241 ratios developed from Pu and Am-241 results from alpha spectroscopy isotopic analyses (isotopic Pu and isotopic Am-241). Although the isotopic Pu and Am-241 methods can accurately measure isotopic activities within the sampled material, the amount of soil analyzed is small (typically 1 gram [g] of soil). If there is heterogeneity of particle distribution within the contaminated release site soil, isotopic methods may provide results that are not representative of the contaminated site. The degree of potential heterogeneity needs to be considered before using isotopic analyses to characterize a Pu-contaminated site. Results from various Pu-contaminated sites at the NNSS are presented that demonstrate significant heterogeneity. A larger sample size (∼1,600 g) within a Marinelli container is used for the gamma spectroscopy analysis. This greatly reduces the impact of heterogeneously distributed discrete particles and provides results that are more representative of true contaminant activities at the release site. However, this method cannot provide Pu activities and has the potential to provide less accurate results due to the haphazard location of contaminant particles within the Marinelli container at the time of measurement. The distance of particles from the detector would result in some differential self-absorption of the emissions from radioactive particles. As the magnitude of this problem was not previously understood, a study was conducted to evaluate the variability in Am-241 results due to self-absorption from particle position. Results from this study are shown that demonstrate that this effect provides minimal variability in replicate Am-241 measurements. The method used at the NNSS to characterize Pu activities in soil takes advantage of the accuracy of the alpha spectroscopy isotopic analyses to establish Pu to Am-241 ratios and the more representative gamma spectroscopy results for Am-241 to provide a reliable characterization of Pu activities at contaminant release sites. (authors)

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Implementing a Direct-Feed Low-Activity Waste Capability in the Hanford Waste Treatment Plant - 18332

The original design of the Waste Treatment and Immobilization Plant (WTP) requires that all waste be processed through the Pretreatment (PT) Facility in order to separate the low-activity waste and high-level waste streams. The U.S. Department of Energy (DOE) has developed a sequenced approach to completing the WTP Project, beginning with feeding some liquid waste directly to the Low-Activity Waste (LAW) Facility, bypassing the PT Facility. Sending low-activity waste from the tank farms to the LAW Facility is referred to as direct-feed LAW (DFLAW). Under this plan, low-activity waste will be pretreated in the Hanford tank farms for cesium and solids separation to meet LAW Facility waste acceptance criteria and produce an acceptable low-activity waste product. The waste feed will then be transferred to the LAW Facility where it will be immobilized in glass, poured into stainless steel containers, and then transported by truck to the Integrated Disposal Facility, a mixed low-level waste disposal site located in the Hanford 200 East Area. The DFLAW operation will deliver about 1 million gallons of double-shell tank waste for treatment each year of operation, and nominally produce 21 metric tons of immobilized low-activity waste glass per day. The resultant freed space in the double-shell tanks will support safe tank farm operations and staging of additional waste for treatment. In December 2016 DOE executed a contract modification and approved a change to the project's performance baseline to complete the LAW Facility, Balance of Facilities (BOF), and Analytical Laboratory (LAB) and incorporate modifications needed to allow direct feed of low-activity waste to the LAW Facility. The contract modification and revised performance baseline support completion and hot commissioning of WTP facilities needed for DFLAW operations is as early as January 2022. DOE has made significant progress on design, equipment procurements, and civil construction of modifications required to implement the DFLAW capability in the WTP, including progress on civil construction of a new effluent management facility, which will process secondary liquid waste resulting from LAW Facility vitrification operations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Affinity and Treatment of LDR Organics in Low Activity Waste by Cementitious Materials – 26109

The physiochemical interactions between organic contaminants, minerals, and polymer additives in grout/cementitious materials are being identified. This research supports a proposed Resource Conservation and Recovery Act (RCRA) treatment variance relevant to the Land Disposal Restriction (LDR) organics present in Hanford tank waste. It provides the technical basis to address the aspects documented by the Environmental Protection Agency in a draft memo necessary to establish that organics can be immobilized/stabilized in a cementitious matrix. The organic species may interact with cementitious minerals, including slag, fly ash, cement, and other components/dopants like activated carbon. A list of 132 reasonably expected LDR organics associated with Hanford tank waste (RPP-RPT-63493, Rev 1a) was screened by functional groups, octanol-water partitioning coefficients, and detection frequency in Hanford tank waste samples. A subset of 15 compounds spanning the identified properties was tested using sorption and leachate tests. These compounds were subjected to traditional batch sorption tests and leaching tests on/from Cast Stone cementitious material with and without activated carbon (a potential organic adsorption additive). The interactions between organic compounds were observed in traditional batch sorption and modified TCLP leachate tests for surrogate Cast Stone material with and without activated carbon addition. Specifically, phthalic acid (negatively charged) and 4-chloroaniline (polar) sorbed strongly to unmodified Cast Stone, while a group of three phenolic compounds (2,4,6-Trichlorophenol, Pentachlorophenol, o-Cresol) sorbed to and were retained by Cast Stone with a 1% activated carbon amendment. Mixtures of these compounds demonstrated visible retention of the organics within the matrix with a quantifiable affinity of the organics to the cement. This novel testing supports the notion that organics within Hanford tank waste would be retained onto the cement phase with the addition of simple materials easily added to the formulation as part of the treatment process. To further provide additional support to this claim, models employing Flory-Huggins theory in conjunction with macromolecular and organic molecule solubility parameters and species activity coefficients are being utilized to better understand these interactions. Within this context, Van Krevelen (VK) and Hansen organic and polymer solubility parameters were used to inform the Flory-Huggins interaction parameter, allowing for a quantifiable method of evaluating polymer-solvent compatibility and, by extension, interactions with proposed binding additives (e.g., activated carbon). These models and measurement should test the hypothesis for our systems understanding and applicability of Flory-Huggins theory, and whether the prediction of organics in the polymer phase versus the aqueous phase can be confidently made using this strategy. The estimation of the organic molecular activity coefficient in these high salt-saturated aqueous systems is another factor that will be assessed. This project aims to predict and understand complicated organic interactions in these heterogenous systems, guiding optimal treatment and stabilization methodologies.

Jolin, Will [Savannah River National Laboratory (S↗
DOE OSTI2021

Manipulating Surface Termination of Perovskite Manganate for Oxygen Activation

For ABO 3 perovskite oxides, one of the key issues limiting their utilization in heterogeneous catalysis is the dominant presence of catalytically inactive A-site cations at the surface. The engineering of B-site terminated perovskites is considered as an effective method to address this issue, especially when dealing with Mn/Co-based perovskite catalysts. However, to date, such a strategy has not been fully successful and remains a major challenge in the field. Herein, a Mn-terminated La 0.45 Sr 0.45 MnO 3 (B-LSM) is successfully synthesized via a one-pot hydrothermal method, in which low-valence Mn ions partially occupy the A site to form the active Mn-excess phase. Additionally, experimental results and theoretical calculations reveal that the presence of the surface Mn termination in B-LSM optimizes the hybrid orbitals of Mn 3d-O 2p and promotes the activation of surface lattice oxygen, where the pristine inert lattice O 2- is evolved into active and stable lattice O 2-x . Such structural optimization significantly reduces the activation energy barriers on going from O 2 ⁻ species to important intermediate O - species during O 2 activation. Moreover, this results in good stability and Pt-like activity for the B-LSM during CO oxidation. This work offers a new chemical route for the design of advanced perovskite-type oxides possessing novel functions.

36 MATERIALS SCIENCE↗