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At least 1,549 records · Page 86

Component-based SHGC determination of BIPV glazing for product comparison

Building-integrated photovoltaic (BIPV) systems are intrinsically designed to generate electricity and to provide at least one building-related function. When BIPV modules act as glazing products in windows, skylights or curtain walls, their ability to control the transmission of solar energy into the building must be characterised by a Solar Heat Gain Coefficient (SHGC) or g value (also known as Total Solar Energy Transmittance – TSET – or “solar factor”). For the comparison of BIPV glazing products consisting of one PV laminate and possibly further, conventional glazing layers separated by gas-filled cavities, the procedures documented in international standards for architectural glazing (e.g. ISO 9050 and EN 410) form a suitable starting point. Easily implemented modifications to these procedures are proposed to take both optical inhomogeneity (if relevant) and extraction of electricity from BIPV glazing units into account. Geometrically complex glazing and shading devices, and light-scattering glazing layers, are outside the scope of the proposed methodology; SHGC determination for obliquely incident solar radiation is also excluded. For these cases, the experimental calorimetric approach documented in [ISO 19467:2017; ISO 19467-2:2021] is recommended. The paper also presents results and conclusions from an implementation exercise and sensitivity study carried out by participants of the IEA-PVPS Task 15 on BIPV. The cell coverage ratio in the PV laminate, the thermal resistance offered by the glazing configuration, the choice of boundary conditions and the effect of extracting electricity were all identified as parameters which significantly affect the SHGC value determined for a given type of BIPV glazing. A practicable approach to accommodate the great variety of dimensions typical for BIPV glazing is also proposed. These findings should pave the way for modifying the existing component-based standards for architectural glazing to take the specific features of BIPV glazing into account.

14 SOLAR ENERGY↗

Terrestrial atmospheric ion implantation occurred in the nearside lunar regolith during the history of Earth’s dynamo

Light volatile elements in lunar regolith are thought to be a mixture of the solar wind and Earth’s atmosphere, the latter sourced in the absence of geomagnetic field. However, the extent to which both the current and primitive geodynamo influence the transport of terres trial ions still remains unclear, and this uncertainty is further complicated by the enigmatic composition and poorly constrained location of the Eoarchean exosphere. Here we use 3-D MHD numerical simulations with contemporary magnetized and Archean unmagnetized atmospheres to investigate how Earth’s intrinsic magnetic field affects this transfer, aiming to constrain how and when the lunar isotopic signature provides a record of Earth’s pale-oatmosphere. We find that atmospheric transfer is efficient only when the Moon is within Earth’s magnetotail. The non-solar contribution to the lunar soil is best explained by implantation during the long history of the geodynamo with present-day solar wind conditions, rather than any short, putatively unmagnetized epoch of early Archean Earth. This further suggests the history of the terrestrial atmosphere, spanning billions of years, could be preserved in buried lunar soils. Our results indicate that the elemental abundances of Apollo samples are very sensitive to Earth’s hydrodynamic exobase altitude, which, at the time of ion implantation, was never smaller than 190 km.

Atmospheric dynamics↗

Electron shuttle in the MOF derived TiO 2 /CuO heterojunction boosts light driven hydrogen evolution

Metal organic frameworks (MOFs) have emerged as a novel template to develop porous photocatalytic materials for solar fuel conversion. In this work, we report the synthesis, charge separation dynamics, and photocatalytic performance of the TiO 2 /CuO heterostructure derived from mixed-phase MOFs based on Ti and Cu metal nodes, which demonstrates significantly enhanced catalytic activity for the hydrogen evolution reaction (HER) compared to metal oxides derived from single node MOFs. More importantly, using transient absorption spectroscopy, we identified the specific role each component in the heterostructure plays and unravelled the key intermediate species that is responsible for the exceptional photocatalytic activity of the heterostructure. We found that the HER is initiated with ultrafast electron transfer (<150 fs) from the molecular photosensitizer to the conduction band of TiO 2 , where TiO 2 acts as an electron mediator and shuttles the electron to the CuO cocatalyst, facilitating charge separation and ultimately boosting the HER efficiency. Overall, these results not only demonstrate the great potential of using mixed-phase MOFs as templates to synthesize mesoporous heterostructure photocatalysts but also provide important insight into the HER mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mitigation of the internal p-n junction in CoS 2 -contacted FeS 2 single crystals: Accessing bulk semiconducting transport

Pyrite FeS 2 is an outstanding candidate for a low-cost, nontoxic, sustainable photovoltaic material, but efficient pyrite-based solar cells are yet to materialize. Recent studies of single crystals have shed much light on this by uncovering a p-type surface inversion layer on n-type (S-vacancy doped) crystals, and the resulting internal p-n junction. This leaky internal junction likely plays a key role in limiting efficiency in pyrite-based photovoltaic devices, also obscuring the true bulk semiconducting transport properties of pyrite crystals. Here, we demonstrate complete mitigation of the internal p-n junction in FeS 2 crystals by fabricating metallic CoS 2 contacts via a process that simultaneously diffuses Co (a shallow donor) into the crystal, the resulting heavy n doping yielding direct Ohmic contact to the interior. Low-temperature bulk transport studies of controllably Co- and S-vacancy doped semiconducting crystals then enable a host of previously inaccessible observations and measurements, including determination of donor activation energies (which are as low as 5 meV for Co), observation of an unexpected second activated transport regime, realization of electron mobility up to 2100 cm 2 V –1 s –1 , elucidation of very different mobilities in Co- and S-vacancy-doped cases, and observation of an abrupt temperaturedependent crossover to bulk Efros-Shklovskii variable-range hopping, accompanied by an unusual form of nonlinear Hall effect. Aspects of the results are interpreted with the aid of first-principles electronic structure calculations on both Co- and S-vacancy-doped FeS 2 . Furthermore, this work thus demonstrates unequivocal mitigation of the internal p-n junction in pyrite single crystals, with important implications for both future fundamental studies and photovoltaic devices

36 MATERIALS SCIENCE↗

From remotely sensed solar-induced chlorophyll fluorescence to ecosystem structure, function, and service: Part I—Harnessing theory

Solar-induced chlorophyll fluorescence (SIF) is a remotely sensed optical signal emitted during the light reactions of photosynthesis. The past two decades have witnessed an explosion in availability of SIF data at increasingly higher spatial and temporal resolutions, sparking applications in diverse research sectors (e.g., ecology, agriculture, hydrology, climate, and socioeconomics). These applications must deal with complexities caused by tremendous variations in scale and the impacts of interacting and superimposing plant physiology and three-dimensional vegetation structure on the emission and scattering of SIF. At present, these complexities have not been overcome. To advance future research, the two companion reviews aim to (1) develop an analytical framework for inferring terrestrial vegetation structures and function that are tied to SIF emission, (2) synthesize progress and identify challenges in SIF research via the lens of multi-sector applications, and (3) map out actionable solutions to tackle these challenges and offer our vision for research priorities over the next 5-10 years based on the proposed analytical framework. This paper is the first of the two companion reviews, and theory oriented. It introduces a theoretically rigorous yet practically applicable analytical framework. Guided by this framework, we offer theoretical perspectives on three overarching questions: (1) The forward (mechanism) question—How are the dynamics of SIF affected by terrestrial ecosystem structure and function? (2) The inference question: What aspects of terrestrial ecosystem structure, function, and service can be reliably inferred from remotely sensed SIF and how? (3) The innovation question: What innovations are needed to realize the full potential of SIF remote sensing for real-world applications under climate change? In conclusion, the analytical framework elucidates that process complexity must be appreciated in inferring ecosystem structure and function from the observed SIF; this framework can serve as a diagnosis and inference tool for versatile applications across diverse spatial and temporal scales.

59 BASIC BIOLOGICAL SCIENCES↗

Lab Homes

This dataset includes processed data from the Lab Homes (LH) Test Facility located on the PNNL campus in Richland, WA. This a set of 2 identical homes that allow for the side-by-side comparison/performance evaluation of different technologies under the same weather at any given time. The dataset spans December 6, 2021 to December 27, 2021 and represents a series of tests performed; calibration, set-point excitation, pre-heating, free-floating and warm up. The measurements correspond to whole building electrical power, HVAC energy use, water heating, appliances and lighting, as well as space temperatures, space humidity, window glass surface temperatures, through glass solar radiation, and meterological data from an onsite meteorological weather station. In addition to the measurements, a metadata .json file, a .ttl file to visualize the data as per BRICK schema, and a detailed .pdf description of the dataset are also provided.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Models of the zodiacal light.

Zodiacal light models /including spherical and nonspherical models/, discussing mechanisms for orientation of particles in solar orbits

Greenberg, J. M.↗

A plant canopy light absorption model with application to wheat

From the light absorption model the absorption of light in the photosynthetically active region of the spectrum was calculated for a Penjamo wheat crop for several situations including: (1) the percent absorption of the incident radiation by a canopy having a four layer structure; (2) the percent absorption of light by the individual layers within a four layer canopy and by the underlying soil; (3) the percent absorption of light by each vegetative canopy layer for variable sun angle; and (4) the cumulative solar energy absorbed by the developing wheat canopy as it progresses from a single layer through its growth stages to a three layer canopy. This calculation was also presented as a function of the leaf area index.

Chance, J. E.↗

Plant canopy light absorption model with application to wheat

A light absorption model (LAM) for vegetative plant canopies has been derived from the Suits reflectance model. From the LAM the absorption of light in the photosynthetically active region of the spectrum (400-700 nm) has been calculated for a Penjamo wheat crop for several situations including (a) the percent absorption of the incident radiation by a canopy of LAI 3.1 having a four-layer structure, (b) the percent absorption of light by the individual layers within a four-layer canopy and by the underlying soil, (c) the percent absorption of light by each vegetative canopy layer for variable sun angle, and (d) the cumulative solar energy absorbed by the developing wheat canopy as it progresses from a single layer through its growth stages to a three-layer canopy. This calculation is also presented as a function of the leaf area index and is shown to be in agreement with experimental data reported by Kanemasu on Plainsman V wheat.

Chance, J. E.↗

Advanced space system concepts and their orbital support needs (1980 - 2000)

Possible uses of satellite technology up to the year 2000 are suggested and discussed. Included are electronic mail transmission, a personal communications capability, quick location of vehicles or shipments, monitoring of disputed territorial borders, upgraded scientific exploration of the universe, providing better maps of the Earth by remote sensing, space solar power stations and the safe transmission of the electrical energy to Earth, night lighting, and a small personal navigation capability. Support requirements are outlined.

Butts, J.↗

Anomalous atmospheric spectral features between 300 and 310 nm interpreted in light or new ozone absorption coefficient measurements

Real structure is revealed, by an analysis of continuous scan data from the solar backscattered UV instrument on Nimbus 7, in the backscattered atmospheric albedo region between 300 and 310 nm where spectral anomalies have been reported in ground-based observation. The spectral anomalies are explainable as structure at the 1-5% level in the ozone absorption coefficient, as measured by Bass and Paur (1981). The new absorption coefficient measurements are judged to approach the 1%-level of accuracy in atmospheric radiation calculation, which should resolve discrepancies between different Dobson wavelength pairs and between different instruments and permit the more accurate analysis of such second-order effects as NO emission, SO2 absorption in polluted atmospheres, and Raman scattering effects.

Mcpeters, R. D.↗

Radio propagation experiments in the outer solar system with Voyager

The outer solar system's planetary atmospheres, ionospheres, rings, and magnetic fields are under study in light of microwave telecommunications from the two Voyager spacecraft. The use of the hydrogen maser frequency standards on the ground, in conjunction with thermally controlled quartz oscillators aboard the spacecraft, ensures long coherence intervals and allows the application of novel signal processing methods. On this basis, studies of atmospheric structure and scintillation parameters, planetary ring structure, and magnetic control of small ionospheric irregularities have been undertaken; information concerning planetary evolution, composition, and dynamics is thereby obtained.

Tyler, G. Leonard↗

Orbital and photometric properties of SZ Lyncis

New photometric results based on 3760 observations made on the Johnson BVRI system and 69 new radial-velocity measurements of the large-amplitude Delta Scuti binary SZ Lyncis are reported. Using these data and previous observations from the literature, improved values for the pulsation and orbital parameters are derived. The pulsation period is found to be 0.12052115 days, which is shorter than earlier determinations. The pulsation period is undergoing a secular period change of 3 X 10 to the -12th days/cycle. The orbital period of the binary is found to be 1181.1 days, with an orbital eccentricity of 0.188. A new ephemeris is given, which accurately predicts the times of light maximum and is consistent with the spectroscopic orbit. The mass function is 0.101 solar, which, together with other known properties of SZ Lyn, indicates that the unseen companion is most likely on the main sequence with a spectral type between F2 and K3.

Moffett, Thomas J.↗

Asteroid volatiles inventory

Asteroids appear in light of telescopic and meteority studies to be the most accessible repositories of early solar system history available. In the cooler regions of the outer asteroid belt, apparently unaffected by severe heating, the C, P, and D populations appear to harbor significant inventories of volatiles; the larger primordial belt population may have had an even greater percentage of volatile-rich, low-albedo asteroids, constituting a potent asteroid for veneering early terrestrial planet atmospheres. The volatile-rich asteroids contain carbon, structurally bound and adsorbed water, as well as remnants of interstellar material predating the solar system.

Lebofsky, L. A.↗

Remote sensing of Mars' ionosphere and solar wind interaction - Lessons from Venus

Although the Phobos spacecraft will make some limited in situ measurements of Mars' upper ionosphere during its transfer orbits, the major part of the mission will be limited to remote sensing by radio occultation and topside sounding methods. To 'calibrate' the former as a means of studying the ionosphere and solar wind interaction, the Pioneer Venus Orbiter radio occultation experiment results are examined in light of what is known from in situ plasma and magnetic field data. This calibration can be used to reassess the data from previous Mars missions and to provide a basis for interpreting data from the upcoming Phobos mission.

Luhmann, J. G.↗